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Buckminsterfullerene

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Concurrent but unconnected to the Kroto-Smalley work, astrophysicists were working with spectroscopists to study infrared emissions from giant red carbon stars. Smalley and team were able to use a laser vaporization technique to create carbon clusters which could potentially emit infrared at the same
1418:, 32 faces (20 hexagons and 12 pentagons where no pentagons share a vertex), and 90 edges (60 edges between 5-membered & 6-membered rings and 30 edges are shared between 6-membered & 6-membered rings), with a carbon atom at the vertices of each polygon and a bond along each polygon edge. The 3375:
cage. These endohedral fullerenes are usually synthesized by doping in the metal atoms in an arc reactor or by laser evaporation. These methods gives low yields of endohedral fullerenes, and a better method involves the opening of the cage, packing in the atoms or molecules, and closing the opening
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molecules. Thus individual molecules transmit some blue and red light resulting in a purple color. Upon drying, intermolecular interaction results in the overlap and broadening of the energy bands, thereby eliminating the blue light transmittance and causing the purple to brown color change.
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products for human ingestion requires cautionary measures such as: elaboration in very dark environments, encasing into bottles of great opacity, and storing in dark places, and others like consumption under low light conditions and using labels to warn about the problems with light.
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Theoretical predictions of buckminsterfullerene molecules appeared in the late 1960s and early 1970s. It was first generated in 1984 by Eric Rohlfing, Donald Cox, and Andrew Kaldor using a laser to vaporize carbon in a supersonic helium beam, although the group did not realize that
1269:, indicated that a carbon molecule with 60 carbon atoms was forming, but provided no structural information. The research group concluded after reactivity experiments, that the most likely structure was a spheroidal molecule. The idea was quickly rationalized as the basis of an 404:
InChI=1S/C60/c1-2-5-6-3(1)8-12-10-4(1)9-11-7(2)17-21-13(5)23-24-14(6)22-18(8)28-20(12)30-26-16(10)15(9)25-29-19(11)27(17)37-41-31(21)33(23)43-44-34(24)32(22)42-38(28)48-40(30)46-36(26)35(25)45-39(29)47(37)55-49(41)51(43)57-52(44)50(42)56(48)59-54(46)53(45)58(55)60(57)59
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InChI=1S/C60/c1-2-5-6-3(1)8-12-10-4(1)9-11-7(2)17-21-13(5)23-24-14(6)22-18(8)28-20(12)30-26-16(10)15(9)25-29-19(11)27(17)37-41-31(21)33(23)43-44-34(24)32(22)42-38(28)48-40(30)46-36(26)35(25)45-39(29)47(37)55-49(41)51(43)57-52(44)50(42)56(48)59-54(46)53(45)58(55)60(57)59
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InChI=1/C60/c1-2-5-6-3(1)8-12-10-4(1)9-11-7(2)17-21-13(5)23-24-14(6)22-18(8)28-20(12)30-26-16(10)15(9)25-29-19(11)27(17)37-41-31(21)33(23)43-44-34(24)32(22)42-38(28)48-40(30)46-36(26)35(25)45-39(29)47(37)55-49(41)51(43)57-52(44)50(42)56(48)59-54(46)53(45)58(55)60(57)59
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Endohedral fullerenes show distinct and intriguing chemical properties that can be completely different from the encapsulated atom or molecule, as well as the fullerene itself. The encapsulated atoms have been shown to perform circular motions inside the
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in a helium atmosphere where the electrode material evaporates and condenses forming soot in the quenching atmosphere. Among other features, the IR spectra of the soot showed four discrete bands in close agreement to those proposed for
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have a deep purple color which leaves a brown residue upon evaporation. The reason for this color change is the relatively narrow energy width of the band of molecular levels responsible for green light absorption by individual
211: 2089:) motif. They start rotating at about −20 °C. This change is associated with a first-order phase transition to an fcc structure and a small, yet abrupt increase in the lattice constant from 1.411 to 1.4154 nm. 2556:
results in polymerized fullerene chains and networks. These polymers remain stable at ambient pressure and temperature once formed, and have remarkably interesting electronic and magnetic properties, such as being
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Another paper on the characterization and verification of the molecular structure followed on in the same year (1990) from their thin film experiments, and detailed also the extraction of an evaporable as well as
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oils must be made in very dark environments, encased into bottles of great opacity, and kept in darkness, consumed under low light conditions and accompanied by labels to warn about the dangers of light for
1466:" and are shorter than the 6:5 bonds (between a hexagon and a pentagon). Its average bond length is 0.14 nm. Each carbon atom in the structure is bonded covalently with 3 others. A carbon atom in the 1347:. The method was simple and efficient to prepare the material in gram amounts per day (1990) which has boosted the fullerene research and is even today applied for the commercial production of fullerenes. 1246:. A solid rotating graphite disk was used as the surface from which carbon was vaporized using a laser beam creating hot plasma that was then passed through a stream of high-density helium gas. The carbon 598: 3500:
have been sold as antioxidant products, but it does not avoid the problem of their sensitivity to light, that can turn them toxic. A later research confirmed that exposure to light degrades solutions of
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can be produced, some with an extraordinary selectivity on one or two isomers over the other possible ones. Addition of fluorine and chlorine usually results in a flattening of the C
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Shang, Yuchen; Liu, Zhaodong; Dong, Jiajun; Yao, Mingguang; Yang, Zhenxing; Li, Quanjun; Zhai, Chunguang; Shen, Fangren; Hou, Xuyuan; Wang, Lin; Zhang, Nianqiang (November 2021).
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remains in the body for a longer time than usual, especially in the liver, where it tends to be accumulated, and therefore has the potential to induce detrimental health effects.
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contains voids at its octahedral and tetrahedral sites which are sufficiently large (0.6 and 0.2 nm respectively) to accommodate impurity atoms. When alkali metals are
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wavelength as had been emitted by the red carbon star. Hence, the inspiration came to Smalley and team to use the laser technique on graphite to generate fullerenes.
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were subsequently cooled and ionized resulting in the formation of clusters. Clusters ranged in molecular masses, but Kroto and Smalley found predominance in a C
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films and solution have strong non-linear optical properties; in particular, their optical absorption increases with light intensity (saturable absorption).
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to produce a violet solution. The substance was discovered in 1985 and has received intense study, although few real world applications have been found.
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Arndt, Markus; Nairz, Olaf; Vos-Andreae, Julian; Keller, Claudia; Van Der Zouw, Gerbrand; Zeilinger, Anton (1999). "Wave–particle duality of C
2411:, the Br atoms are in 1,3- or 1,4-positions with respect to each other. Under various conditions a vast number of halogenated derivatives of C 6886: 6283: 1302:
observed unusual optical absorptions in thin films of carbon dust (soot). The soot had been generated by an arc-process between two graphite
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Leger, A.; d'Hendecourt, L.; Verstraete, L.; Schmidt, W. (1988). "Remarkable candidates for the carrier of the diffuse interstellar bands: C
7508: 6434: 420: 6345: 5507: 5992: 3439: 2717: = 1–6). The midpoint potentials of 1-electron reduction of buckminsterfullerene and its anions is given in the table below: 799: 5568: 2552:
molecules when heated at 450 K (177 °C; 350 °F). Under high pressure and temperature, repeated cycloaddition between C
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Another web portal dedicated to buckminsterfullerene, authored and supported by the Chemistry Department at the University of Bristol
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Rodríguez-Fortea, Antonio; Balch, Alan L.; Poblet, Josep M. (2011). "Endohedral metallofullerenes: a unique host–guest association".
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Baati, Tarek; Moussa, Fathi (June 2012). "The prolongation of the lifespan of rats by repeated oral administration of fullerene".
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exhibits a small degree of aromatic character, but it still reflects localized double and single C–C bond characters. Therefore, C
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solution, showing diminished absorption for the blue (~450 nm) and red (~700 nm) light that results in the purple color.
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c12c3c4c5c2c2c6c7c1c1c8c3c3c9c4c4c%10c5c5c2c2c6c6c%11c7c1c1c7c8c3c3c8c9c4c4c9c%10c5c5c2c2c6c6c%11c1c1c7c3c3c8c4c4c9c5c2c2c6c1c3c42
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Extensive statistical data compiled by the University of Sussex on the numerical quantitative properties of buckminsterfullerene
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with a low activation energy of 0.1–0.3 eV; this conductivity is attributed to intrinsic or oxygen-related defects. Fcc C
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in oil, making it toxic and leading to a "massive" increase of the risk of developing cancer (tumors) after its consumption.
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Dietz, T. G.; Duncan, M. A.; Powers, D. E.; Smalley, R. E. (1981). "Laser production of supersonic metal cluster beams".
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One such iridium complex, has been prepared where the metal center projects two electron-rich 'arms' that embrace the C
7378: 5600: 4528: 4361:"The infrared and ultraviolet absorption spectra of laboratory-produced carbon dust: evidence for the presence of the C 3745:
Cami, J.; Bernard-Salas, J.; Peeters, E.; Malek, S. E. (2010). "Detection of C60 and C70 in a Young Planetary Nebula".
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Rohlfing, Eric A; Cox, D. M; Kaldor, A (1984). "Production and characterization of supersonic carbon cluster beams".
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Howard, Jack B.; McKinnon, J. Thomas; Makarovsky, Yakov; Lafleur, Arthur L.; Johnson, M. Elaine (1991). "Fullerenes C
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exhibited the duality that is more famously attributed to light, electrons and other small particles and molecules.
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and who had died in 1983, the year before discovery. Another common name for buckminsterfullerene is "buckyballs".
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Howard, J; Lafleur, A; Makarovsky, Y; Mitra, S; Pope, C; Yadav, T (1992). "Fullerenes synthesis in combustion".
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dissolved in olive oil or water, as long as they are preserved from light, have been found nontoxic to rodents.
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Buckminsterfullerene is the most common naturally occurring fullerene. Small quantities of it can be found in
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Ryuichi, Mitsumoto (1998). "Electronic Structures and Chemical Bonding of Fluorinated Fullerenes Studied".
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solutions that have been exposed to light could lead to developing cancer (tumors). So the management of C
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and a supporting electrolyte with extremely high oxidation resistance and low nucleophilicity, such as .
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cluster that could be enhanced further by allowing the plasma to react longer. They also discovered that C
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Ruoff, R. S.; Tse, Doris S.; Malhotra, Ripudaman; Lorents, Donald C. (1993). "Solubility of fullerene (C
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In the case of platinum complex, the labile ethylene ligand is the leaving group in a thermal reaction:
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at 296 K gives the epoxide, but photolysis gives a product in which the O atom bridges a 5,6-edge.
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with 9,9′,10,10′-dihydroanthracene under the same conditions, depending on the time of reaction, gives C
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in olive oil to rats, achieving a major prolongation of their lifespan. Since then, many oils with C
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used in donor/acceptor based solar cells. Conversion efficiencies up to 5.7% have been reported in C
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A web portal dedicated to buckminsterfullerene, authored and supported by the University of Bristol
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for their roles in the discovery of buckminsterfullerene and the related class of molecules, the
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Maier, J. P.; Gerlich, D.; Holz, M.; Campbell, E. K. (July 2015). "Laboratory confirmation of C
3131: 2154: 2021:. Like other solvates, this one readily releases benzene to give the usual face-centred cubic C 1684: 1419: 1006: 5449:
Hebgen, Peter; Goel, Anish; Howard, Jack B.; Rainey, Lenore C.; Vander Sande, John B. (2000).
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crystallises with some solvents in the lattice ("solvates"). For example, crystallization of C
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forms a brownish solid with an optical absorption threshold at ≈1.6 eV. It is an n-type
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with combustion research published in 2000 at the 28th International Symposium on Combustion
5323:"Disposition of fullerene C60 in rats following intratracheal or intravenous administration" 4237: 3882: 1462:
molecule has two bond lengths. The 6:6 ring bonds (between two hexagons) can be considered "
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Kroto, H. W.; Heath, J. R.; O'Brien, S. C.; Curl, R. F.; Smalley, R. E. (November 1985). "C
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Shipkowski, K. A.; Sanders, J. M.; McDonald, J. D.; Walker, N. J.; Waidyanatha, S. (2019).
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oxidizes with difficulty. Three reversible oxidation processes have been observed by using
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has the structure in which a four-membered ring is surrounded by four six-membered rings.
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A brief overview of buckminsterfullerene described by the University of Wisconsin-Madison
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being the dominating product. This mixture of polyhydrofullerenes can be re-oxidized by
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Bezmel'nitsyn, V. N.; Eletskii, A. V.; Okun', M. V. (1998). "Fullerenes in solutions".
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Krätschmer, W.; Lamb, Lowell D.; Fostiropoulos, K.; Huffman, Donald R. (1990). "Solid C
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Molecules of buckminsterfullerene (or of fullerenes in general) are commonly nicknamed
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Talyzin, A. V.; Engström, I. (1998). "C70 in Benzene, Hexane, and Toluene Solutions".
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The discoverers of the allotrope named the newfound molecule after American architect
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led to the exploration of a new field of chemistry involving the study of fullerenes.
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Catherine E. Housecroft; Alan G. Sharpe (2008). "Chapter 14: The group 14 elements".
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R. Buckminster Fuller Collection: Architect, Systems Theorist, Designer, and Inventor
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Kroto, H. W.; Health, J. R.; O'Brien, S. C.; Curl, R. F.; Smalley, R. E. (1985). "C
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For a time buckminsterfullerene was the largest known molecule observed to exhibit
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Donald R. Huffman and Wolfgang Krätschmer's paper pertaining to the synthesis of C
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Herbig, E. (1975). "The diffuse interstellar bands. IV – the region 4400-6850 A".
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Kroto, H. W.; Heath, J. R.; O'Brien, S. C.; Curl, R. F.; Smalley, R. E. (1985). "C
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Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013
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under light exposure causes it to degrade, becoming dangerous. The ingestion of C
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The first cyclopropanation was carried out by treating the β-bromomalonate with C
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tends to avoid having double bonds in the pentagonal rings, which makes electron
1938: 1818: 1200: 1196: 770: 3408:-based films could be useful for photovoltaic applications. Because of its high 7663: 7571: 7308: 7273: 7056: 6946: 6911: 6896: 6831: 6826: 6725: 6625: 6544: 6519: 6484: 6429: 6404: 6273: 6121: 5935: 5744: 5708: 5136: 3106:
forms complexes akin to the more common alkenes. Complexes have been reported
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A report by Ming Kai College detailing the properties of buckminsterfullerene
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The AZo Journal of Materials Online. AZoM.com. "Buckminsterfullerene." 2006.
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The AZo Journal of Materials Online. AZoM.com. "Buckminsterfullerene." 2006.
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in water to avoid possible problems with oils, but that would not protect C
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buckminsterfullerene had been produced. In 1985 their work was repeated by
1153: 852: 5503:'s discovery carried out by the Chemistry Department at Bristol University 3688: 3561: 2107:, but when compressed to less than 70% of its volume it transforms into a 2049: 7613: 7388: 7298: 7263: 7230: 7156: 7131: 6971: 6876: 6846: 6730: 6645: 6635: 6365: 6293: 5920: 5899: 5642: 5540:
An article about buckminsterfullerene on Connexions Science Encyclopaedia
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derivative prepared through cyclopropanation has been studied for use in
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undergoes six reversible, one-electron reductions, ultimately generating
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separation relatively small. This small gap suggests that reduction of C
656: 7607: 7595: 7303: 7245: 7208: 7183: 7081: 6891: 6754: 5585: 5054: 4664:"Wave-particle duality in action—big molecules surf on their own waves" 4335:
Conference proceedings of "Dusty Objects in the Universe", pp.b 89–93,
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Piacente; Gigli; Scardala; Giustini; Ferro (1995). "Vapor Pressure of C
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converts from a semiconductor into a conductor or even superconductor.
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under "ideal" spherical (left) and "real" icosahedral symmetry (right).
1435: 1390:. Fullerenes are extracted from the soot with organic solvents using a 1303: 459: 254: 37: 5564:
and its discovery, structure, production, properties, and applications
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can be grown from solution both for solvates and for pure fullerenes.
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American Chemical Society's complete article on buckminsterfullerene
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in the presence of a base. Cyclopropanation also occur readily with
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Except where otherwise noted, data are given for materials in their
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mostly occurs at the junction of 2 hexagons due to steric factors.
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with appropriate substituted diene gives the corresponding adduct.
2372: 2368: 2104: 1898: 1838: 1398:, as well as other fullerenes. These fractions are separated using 1273: 1222: 1053: 954: 4725: 4632: 4428: 3873: 3814: 989: 696: 210: 7368: 7198: 7151: 7110: 7066: 7008: 7003: 6966: 6956: 6951: 6906: 6901: 6841: 6774: 6665: 6660: 6610: 6489: 6479: 6232: 5915: 5636: 3123: 2432: 2376: 2280:
can undergo addition with hydrogen to give polyhydrofullerenes. C
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Xenobiotica; the Fate of Foreign Compounds in Biological Systems
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Smalley, Richard E. (1997-07-01). "Discovering the fullerenes".
1319:-soluble material from the arc-generated soot. This extract had 1170:
have the same arrangement of polygons as buckminsterfullerene, C
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should occur at mild potentials leading to fulleride anions, (
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0.4–0.5 Pa (T ≈ 800 K); 14 Pa (T ≈ 900 K)
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Roberts, Kyle R. G.; Smith, Keith T.; Sarre, Peter J. (2012).
2383:. Fluorine atoms are small enough for a 1,2-addition, while Cl 626: 121: 100: 6454: 6384: 3744: 3584: 1949: 1848: 1324: 1215: 684: 234: 200: 4156: 3709: 344: 5040: 4604: 2706: 2702: 2694: 2669: 2296:-butanol to give a mixture of polyhydrofullerenes such as C 2202: 1335:
as well as the expected molecular mass of 720 Da for C
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is irreversible. The first reduction occurs at ≈-1.0 
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can be substituted by a nitrogen or boron atom yielding a
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SR• forms spontaneously upon irradiation of the mixture.
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and 3,6-bis(4-methylphenyl)-3,6-dihydro-1,2,4,5-tetrazine
1147: 88: 79: 4560:(Fifth ed.). New York: W. H. Freeman. p. 356. 4402: 4400: 4250: 3911: 1071:
Buckminsterfullerene is a black solid that dissolves in
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Osawa, E. (1970). Kagaku (Kyoto) (in Japanese). 25: 854
3492:
An experiment in 2011–2012 administered a solution of C
3395: 2600:-butyl halide is photolyzed and allowed to react with C 1394:. This step yields a solution containing up to 75% of C 7737:
The Last Dymaxion: Buckminster Fuller’s Dream Restored
3404:
match the solar spectrum in a way that suggests that C
2339:
A selective hydrogenation method exists. Reaction of C
2169: 1327:
crystal analysis consistent with arrays of spherical C
6014: 4695:
Beck, Mihály T.; Mándi, Géza (1997). "Solubility of C
4397: 3423:
Further information on the basic polymer of the C
2614: 2443:
in 1,2-xylene at 257K gives an intermediate ozonide C
2009:
solution yields triclinic crystals with the formula C
124: 106: 94: 91: 82: 73: 5380:
Nanostructured materials for solar energy conversion
2164: 618: 118: 112: 97: 76: 5451:"Fullerenes and Nanostructures in Diffusion Flames" 4932:"Discrete Fulleride Anions and Fullerenium Cations" 3916:as the carrier of two diffuse interstellar bands". 3433: 2292:reacts with lithium in liquid ammonia, followed by 103: 85: 5253:"C60 in olive oil causes light-dependent toxicity" 1382:Soot is produced by laser ablation of graphite or 4930:Reed, Christopher A.; Bolskar, Robert D. (2000). 4065: 3802:Monthly Notices of the Royal Astronomical Society 3795: 3546:International Union of Pure and Applied Chemistry 2264:. For example, it reacts with some nucleophiles. 7779: 7701:R. Buckminster Fuller and Anne Hewlett Dome Home 5213: 5016:Jonathan W. Steed & Jerry L. Atwood (2009). 3854: 3367:Metal atoms or certain small molecules such as H 2623:) is another common method for functionalizing C 1265:The experimental evidence, a strong peak at 720 306: 19:"Buckyball" redirects here. For other uses, see 5376:"Fullerene Thin Films as Photovoltaic Material" 5110: 4848: 4701:Fullerenes, Nanotubes and Carbon Nanostructures 4003:Jones, David E. H. (1966). "Hollow molecules". 3388:cage, and their motion has been followed using 3295:Coordinatively unsaturated precursors, such as 1279:Kroto, Curl, and Smalley were awarded the 1996 186: 4152: 4150: 4148: 4146: 3508:To avoid the degradation by effect of light, C 3371:and noble gas can be encapsulated inside the C 2604:, a reversible inter-cage C–C bond is formed: 692: 7502: 6000: 5601: 5104: 4555: 4523:. Mill Valley, CA: University Science Books. 4521:Synthesis and Teknique in Inorganic Chemistry 3528:from light, so the same cautions are needed. 3130:. The pentacarbonyl species are produced by 2581:is mixed with a disulfide RSSR, the radical C 1977:, but insoluble in water. Solutions of pure C 1969:Fullerenes are sparingly soluble in aromatic 1014: 5011: 5009: 4983: 4981: 4979: 4977: 4975: 4973: 5285: 4929: 4143: 3578: 3520:Some producers have been able to dissolve C 2497:and 3,6-diaryl-1,2,4,5-tetrazines affords C 2451:, which can be decomposed into 2 forms of C 2422: 1438:(nm). The nucleus to nucleus diameter of a 1044:. It has a cage-like fused-ring structure ( 7509: 7495: 6007: 5993: 5608: 5594: 4804:Talyzin, A. V. (1997). "Phase Transition C 4358: 4162:Science of Fullerenes and Carbon Nanotubes 3487: 3440:Health and safety hazards of nanomaterials 1021: 1007: 359: 284: 262: 5469: 5346: 5006: 4970: 4694: 4388: 4160:; Dresselhaus, G.; Eklund, P. C. (1996). 4042: 3872: 3831: 3813: 2564: 2528:molecules can also be coupled through a 2330:2,3-dichloro-5,6-dicyano-1,4-benzoquinone 1238:and even) of which the most common were C 326: 5615: 5442:– describing the original discovery of C 4284: 4282: 3352: 2507: 2060: 2048: 1948: 1622: 1497: 1331:molecules, approximately 1.0 nm in 1161: 5458:Proceedings of the Combustion Institute 5075: 4925: 4923: 4874: 4872: 4803: 4020: 3977: 3975: 3973: 3971: 2532:, giving the dumbbell-shaped compound C 2482:is commonly employed to functionalize C 2419:framework into a drum-shaped molecule. 355: 7780: 7516: 5484:– report describing the synthesis of C 4337:"Search for the UV and IR spectra of C 4184: 4178: 3448: 3400:The optical absorption properties of C 1350:The discovery of practical routes to C 275: 7729:Buckminster Fuller: Thinking Out Loud 7490: 5988: 5589: 5560:A brief article entirely devoted to C 5281: 5279: 5246: 5244: 5242: 5240: 5209: 5207: 5185: 5183: 5181: 4483:. Stanford University. 6 April 2017. 4279: 4244: 4213: 4016: 4014: 4002: 3987: 407:Key: XMWRBQBLMFGWIX-UHFFFAOYSA-N 387:Key: XMWRBQBLMFGWIX-UHFFFAOYSA-N 242: 7541:Operating Manual for Spaceship Earth 5535:by the Oak Ridge National Laboratory 4920: 4908: 4896: 4869: 4586: 4574: 4487:from the original on 12 January 2020 3968: 3396:Potential applications in technology 2081:In solid buckminsterfullerene, the C 1450:molecule is about 0.71 nm. The 4661: 4515:Girolami, G. S.; Rauchfuss, T. B.; 4341:in laboratory-produced carbon dust" 4224:and other polyhedral carbon ions". 3457:is sensitive to light, so leaving C 3220:complexes have also been reported: 2260:behaves like an electron deficient 2224:is a reluctant electron acceptor. 2170:Redox (electron-transfer reactions) 1258:is a cage-like molecule, a regular 1203:, who recognized the structure of C 397:Key: XMWRBQBLMFGWIX-UHFFFAOYAU 297: 13: 7379:Nexus for Exoplanet System Science 5397: 5300:10.1016/j.biomaterials.2012.03.036 5276: 5251:Grohn, Kristopher J.; et al. 5237: 5204: 5178: 4011: 3444:Toxicology of carbon nanomaterials 3091: 2615:Cyclopropanation (Bingel reaction) 2606: 2588:Stability of the radical species C 2493:The Diels–Alder reaction between C 2465: 45: 36: 14: 7799: 7686:Proposed Brooklyn Dodgers stadium 7279:Atomic and molecular astrophysics 6016:Molecules detected in outer space 5492: 5250: 4164:. San Diego, CA: Academic Press. 2544:. The reaction is reversible as C 2473: 2165:Chemical reactions and properties 1370:structures that look similar to C 7469: 7457: 7445: 7434: 7433: 6240: 6231: 6222: 3833:10.1111/j.1365-2966.2012.20552.x 3434:Potential applications in health 2267: 2025:. Millimeter-sized crystals of C 1580: 1573: 1566: 1559: 1552: 1146: 988: 976: 761: 712: 588: 69: 7404:Polycyclic aromatic hydrocarbon 5643:Lonsdaleite (hexagonal diamond) 5367: 5314: 5265:from the original on 2021-04-15 5226:from the original on 2021-04-17 5167:from the original on 2021-11-26 5069: 5034: 4884: 4851:Journal of Physical Chemistry B 4842: 4823:Journal of Physical Chemistry B 4797: 4764: 4750:10.1070/PU1998v041n11ABEH000502 4719: 4688: 4676:from the original on 2021-09-26 4655: 4598: 4549: 4537: 4508: 4499: 4469: 4422: 4352: 4329: 4094: 4059: 3996: 3905: 3480:Otherwise, a study found that C 2927:tetrakis(dimethylamino)ethylene 2701:is triply degenerate, with the 2362: 1953:Optical absorption spectrum of 749:Part of a series of articles on 708:(at 25 °C , 100 kPa). 7626:Expo 67 United States Pavilion 5382:. Elsevier. pp. 361–443. 3848: 3789: 3738: 3703: 3644: 3635: 3609: 3554:The Royal Society of Chemistry 3538: 2991:oxidation at low temperatures 2960: 2516:derivative synthesized from C 2359:respectively and selectively. 449: 1: 7329:Extraterrestrial liquid water 5480:10.1016/S0082-0784(00)80355-0 5339:10.1080/00498254.2018.1528646 5200:. Vol. 351. 23 May 1991. 5191:"Degradation of C60 by light" 4778:Journal of Physical Chemistry 4775:) in a variety of solvents". 3859:(2013). "Interstellar C60+". 3531: 3412:it is one of the most common 3363:Endohedral hydrogen fullerene 2678: 2391:add to remote C atoms due to 1634: 1510: 1120:, has been identified in the 1088: 16:Cage-like allotrope of carbon 7723:Buckminster Fuller Challenge 7696:Old Man River's City project 7671:Cloud Nine tensegrity sphere 5579:The Periodic Table of Videos 4390:10.1016/0009-2614(90)87109-5 3861:Astronomy & Astrophysics 3732:10.1016/0008-6223(92)90061-Z 1587: 1434:molecule is about 1.01  1405: 1377: 1357: 7: 6560:Protonated hydrogen cyanide 5531:A thorough description of C 4068:Journal of Chemical Physics 3891:10.1051/0004-6361/201220730 2540:with a catalytic amount of 1618: 1611:. In 2020 the dye molecule 32: 10: 7804: 5974:Aggregated diamond nanorod 5582:(University of Nottingham) 5216:"Comp grad leads research" 5137:10.1038/s41586-021-03882-9 4477:"What is a geodesic dome?" 3437: 3422: 3356: 3095: 2686: 2660:-butyric acid methyl ester 2117:aggregated diamond nanorod 1502:Energy level diagram for C 1410:Buckminsterfullerene is a 1296:Konstantinos Fostiropoulos 1135: 1131: 1126:diffuse interstellar bands 475:Dark needle-like crystals 21:Buckyball (disambiguation) 18: 7757: 7659:Design science revolution 7635: 7564: 7524: 7428: 7319:Earliest known life forms 7314:Diffuse interstellar band 7254: 7174: 7099: 6990: 6925: 6865: 6793: 6785:Protonated cyanoacetylene 6699: 6593: 6555:Protonated carbon dioxide 6515:Hydromagnesium isocyanide 6463: 6249: 6220: 6031: 6022: 5944: 5874: 5813: 5780: 5772:(cyclo[18]carbon) 5730: 5651: 5623: 5408:: Buckminsterfullerene". 5378:. In Sōga, Tetsuo (ed.). 5373: 4992:(3rd ed.). Pearson. 4914: 4902: 4890: 4878: 4713:10.1080/15363839708011993 4662:Lee, Chris (2020-07-21). 4592: 4580: 4543: 4433:: A new form of carbon". 4293:: Buckminsterfullerene". 4105:: Buckminsterfullerene". 4053:10.1103/RevModPhys.69.723 4023:Reviews of Modern Physics 3981: 3623:. Oxford University Press 3621:Oxford English Dictionary 2987:Reduction potentials of C 2986: 2923:charge-transfer complexes 2722: 2548:dissociates back to two C 2431:can be oxygenated to the 2085:molecules adopt the fcc ( 1207:as buckminsterfullerene. 1068:to its three neighbors. 702: 569: 564: 511: 436: 416: 371: 170: 158: 135: 59: 31: 7584:Dymaxion deployment unit 7364:Iron–sulfur world theory 7359:Photodissociation region 7062:Methyl-cyano-diacetylene 5756:(cyclo[6]carbon) 5740:Linear acetylenic carbon 5018:Supramolecular Chemistry 4556:Shriver; Atkins (2010). 4369:Chemical Physics Letters 2723:Reduction potential of C 2561:above room temperature. 2423:Addition of oxygen atoms 2044: 1281:Nobel Prize in Chemistry 1225:the Smalley team found C 965:Nanocrystalline material 941:Nanostructured materials 635:Precautionary statements 7533:Nine Chains to the Moon 7439:Category:Astrochemistry 7029:, fullerene, buckyball) 6716:Cyanobutadiynyl radical 6691:Silicon-carbide cluster 6681:Protonated formaldehyde 5020:(2nd ed.). Wiley. 4407:Buckminsterfullerene, C 4359:Krätschmer, W. (1990). 4238:1988A&A...203..145L 3883:2013A&A...550L...4B 3767:10.1126/science.1192035 3589:Buckminsterfullerene". 3488:Oils with C60 and risks 3132:photochemical reactions 2627:. Cyclopropanation of C 1516:Orthogonal projections 1276:closed cage structure. 1128:in the near-infrared. 161:Buckyballs; Fullerene-C 7452:Outer space portal 7294:Circumstellar envelope 6259:Aluminium(I) hydroxide 6169:Phosphorus mononitride 6046:Aluminium monofluoride 6041:Aluminium monochloride 5800:Carbide-derived carbon 5682:(buckminsterfullerene) 3855:Berné, O.; Mulas, G.; 2646:to give the compound C 2619:Cyclopropanation (the 2611: 2565:Free radical reactions 2521: 2470: 2078: 2058: 1966: 1685:1,2,4-trimethylbenzene 1632: 1507: 1420:van der Waals diameter 1339:(and 840 Da for C 1333:van der Waals diameter 1175: 559: = 1.4154 nm 50: 41: 7643:Allegra Fuller Snyder 7349:Interplanetary medium 7324:Extraterrestrial life 6962:Octatetraynyl radical 6580:Tricarbon monosulfide 6127:Magnesium monohydride 5214:Grohn, Kristopher J. 3562:10.1039/9781849733069 3353:Endohedral fullerenes 2610: 2592:Y depends largely on 2577:readily occur. When C 2511: 2469: 2455:O. Decomposition of C 2240:poor, and results in 2064: 2052: 1952: 1715:1,2,3-tribromopropane 1695:tetrahydronaphthalene 1626: 1609:wave–particle duality 1501: 1412:truncated icosahedron 1388:aromatic hydrocarbons 1364:R. Buckminster Fuller 1260:truncated icosahedron 1165: 1136:Further information: 1116:. The ionised form, C 1112:and several types of 1108:has been observed in 1046:truncated icosahedron 995:Technology portal 790:Mechanical properties 524:Face-centered cubic, 49: 40: 27:Buckminsterfullerene 7716:Buckminsterfullerene 7649:Current solar income 7476:Chemistry portal 7464:Astronomy portal 7410:RNA world hypothesis 7394:PAH world hypothesis 7087:Heptatrienyl radical 7019:Buckminsterfullerene 6907:Methylcyanoacetylene 6415:Silicon carbonitride 6390:Methylidynephosphane 6356:Magnesium isocyanide 6264:Aluminium isocyanide 6066:Carbon monophosphide 5617:Allotropes of carbon 5574:Buckminsterfullerene 5374:Katz, E. A. (2006). 4820:in Liquid Benzene". 3359:Endohedral fullerene 2480:Diels–Alder reaction 2103:solid is as soft as 1775:carbon tetrachloride 1366:, who designed many 1034:Buckminsterfullerene 960:Nanoporous materials 823:Buckminsterfullerene 137:Preferred IUPAC name 7556:Dymaxion Chronofile 7354:Interstellar medium 7334:Forbidden mechanism 7147:Hydrogen isocyanide 6837:Hexatriynyl radical 6420:c-Silicon dicarbide 6325:Hydrogen isocyanide 6189:Silicon monosulfide 6164:Phosphorus monoxide 6132:Methylidyne radical 6091:Fluoromethylidynium 6051:Aluminium(II) oxide 5422:1985Natur.318..162K 5129:2021Natur.599..599S 5090:1998JPCA..102..552M 4990:Inorganic Chemistry 4791:10.1021/j100115a049 4742:1998PhyU...41.1091B 4625:1999Natur.401..680A 4558:Inorganic Chemistry 4447:1990Natur.347..354K 4381:1990CPL...170..167K 4307:1985Natur.318..162K 4265:1981JChPh..74.6511D 4199:1975ApJ...196..129H 4121:1985Natur.318..162K 4080:1984JChPh..81.3322R 4035:1997RvMP...69..723S 3938:10.1038/nature14566 3930:2015Natur.523..322C 3824:2012MNRAS.421.3277R 3759:2010Sci...329.1180C 3753:(5996): 1180–1182. 3724:1992Carbo..30.1183H 3673:1991Natur.352..139H 3603:10.1021/j100038a041 3597:(38): 14052–14057. 3449:Ingestion and risks 3410:electronic affinity 2953:This salt exhibits 2925:, for example with 2921:forms a variety of 2670:Redox reactions – C 2664:organic solar cells 2395:. For example, in C 2157:into these voids, C 2087:face-centered cubic 1853:1.3 × 10 1675:1,2-dichlorobenzene 1665:1-methylnaphthalene 1655:1-chloronaphthalene 1640: 1517: 1292:Wolfgang Krätschmer 1290:In 1989 physicists 1122:interstellar medium 862:Carbon quantum dots 497:insoluble in water 492:Solubility in water 467: g·mol 224:Beilstein Reference 28: 7740:(2012 documentary) 7732:(1996 documentary) 7518:Buckminster Fuller 7374:Molecules in stars 7344:Intergalactic dust 7289:Circumstellar dust 7231:Naphthalene cation 7166:Trihydrogen cation 7142:Hydrogen deuteride 7067:Methyltriacetylene 6902:Hexapentaenylidene 6721:E-Cyanomethanimine 6641:Cyclopropenylidene 6575:Tricarbon monoxide 6565:Silicon tricarbide 6535:Methylene amidogen 6525:Isothiocyanic acid 6440:Thioxoethenylidene 6400:Trihydrogen cation 6214:Titanium(II) oxide 6174:Potassium chloride 6153:Sulfur mononitride 6096:Helium hydride ion 6071:Carbon monosulfide 5895:(cyclopropatriene) 5876:hypothetical forms 5697:Fullerene whiskers 5055:10.1039/C0CS00225A 4415:2021-02-27 at the 4346:2017-09-05 at the 4158:Dresselhaus, M. S. 3414:electron acceptors 2979:methylene chloride 2975:cyclic voltammetry 2674:anions and cations 2612: 2522: 2471: 2079: 2059: 1967: 1635: 1633: 1515: 1508: 1176: 1056:, and resembles a 1040:with the formula C 983:Science portal 795:Optical properties 735:Infobox references 51: 42: 26: 7775: 7774: 7484: 7483: 7399:Pseudo-panspermia 7095: 7094: 7042:Cyanodecapentayne 6982:N-Methylformamide 6957:Methyldiacetylene 6882:Aminoacetonitrile 6852:Methyl isocyanate 6770:Methyl isocyanide 6651:Isocyanoacetylene 6631:Cyanoformaldehyde 6510:Hydrogen peroxide 6395:Potassium cyanide 6351:Magnesium cyanide 6304:Disilicon carbide 6299:Dicarbon monoxide 6106:Hydrogen fluoride 6101:Hydrogen chloride 5982: 5981: 5850:(diatomic carbon) 5782:mixed sp/sp forms 5526:published in 1990 5389:978-0-444-52844-5 5294:(19): 4936–4946. 5123:(7886): 599–604. 5098:10.1021/jp972863t 5027:978-0-470-51233-3 4999:978-0-13-175553-6 4948:10.1021/cr980017o 4863:10.1021/jp9815255 4857:(34): 6477–6481. 4836:10.1021/jp9720303 4830:(47): 9679–9681. 4785:(13): 3379–3383. 4736:(11): 1091–1114. 4619:(6754): 680–682. 4567:978-0-19-923617-6 4441:(6291): 354–358. 4301:(6042): 162–163. 4226:Astron. Astrophys 4115:(6042): 162–163. 3924:(7560): 322–323. 3667:(6331): 139–141. 3571:978-0-85404-182-4 3378:organic reactions 3089: 3088: 2915: 2914: 2439:O. Ozonation of C 2220:), showing that C 1947: 1946: 1605: 1604: 1392:Soxhlet extractor 1300:Donald R. Huffman 1267:atomic mass units 1110:planetary nebulae 1060:. Each of its 60 1048:) made of twenty 1031: 1030: 843:Carbon allotropes 743:Chemical compound 741: 740: 613:Hazard statements 519:Crystal structure 340:CompTox Dashboard 212:Interactive image 55: 54: 7795: 7744:Karlis Johansons 7706:Ephemeralization 7511: 7504: 7497: 7488: 7487: 7474: 7473: 7472: 7462: 7461: 7460: 7450: 7449: 7448: 7437: 7436: 7384:Organic compound 7284:Chemical formula 7189:Dihydroxyacetone 7137:Hydrogen cyanide 6822:Cyanodiacetylene 6676:Propadienylidene 6570:Thioformaldehyde 6445:Titanium dioxide 6410:Sodium hydroxide 6331:Hydrogen sulfide 6319:Hydrogen cyanide 6279:Carbonyl sulfide 6244: 6235: 6226: 6184:Silicon monoxide 6117:Hydroxyl radical 6029: 6028: 6009: 6002: 5995: 5986: 5985: 5954:Activated carbon 5910: 5909: 5908: 5894: 5893: 5892: 5865: 5864: 5863: 5849: 5848: 5847: 5833: 5832: 5831: 5790:Amorphous carbon 5771: 5770: 5769: 5755: 5754: 5753: 5610: 5603: 5596: 5587: 5586: 5483: 5473: 5455: 5441: 5430:10.1038/318162a0 5393: 5361: 5360: 5350: 5333:(9): 1078–1085. 5318: 5312: 5311: 5283: 5274: 5273: 5271: 5270: 5264: 5257: 5248: 5235: 5234: 5232: 5231: 5211: 5202: 5201: 5195: 5187: 5176: 5175: 5173: 5172: 5108: 5102: 5101: 5078:J. Phys. Chem. A 5073: 5067: 5066: 5049:(7): 3551–3563. 5038: 5032: 5031: 5013: 5004: 5003: 4985: 4968: 4967: 4942:(3): 1075–1120. 4936:Chemical Reviews 4927: 4918: 4912: 4906: 4900: 4894: 4888: 4882: 4876: 4867: 4866: 4846: 4840: 4839: 4801: 4795: 4794: 4768: 4762: 4761: 4723: 4717: 4716: 4692: 4686: 4685: 4683: 4681: 4659: 4653: 4652: 4602: 4596: 4590: 4584: 4578: 4572: 4571: 4553: 4547: 4541: 4535: 4534: 4512: 4506: 4503: 4497: 4496: 4494: 4492: 4473: 4467: 4466: 4455:10.1038/347354a0 4426: 4420: 4404: 4395: 4394: 4392: 4375:(2–3): 167–170. 4356: 4350: 4333: 4327: 4326: 4315:10.1038/318162a0 4286: 4277: 4276: 4273:10.1063/1.440991 4248: 4242: 4241: 4217: 4211: 4210: 4182: 4176: 4175: 4171:978-012-221820-0 4154: 4141: 4140: 4129:10.1038/318162a0 4098: 4092: 4091: 4088:10.1063/1.447994 4063: 4057: 4056: 4046: 4018: 4009: 4008: 4000: 3994: 3991: 3985: 3979: 3966: 3965: 3909: 3903: 3902: 3876: 3852: 3846: 3845: 3835: 3817: 3808:(4): 3277–3285. 3793: 3787: 3786: 3742: 3736: 3735: 3718:(8): 1183–1201. 3707: 3701: 3700: 3681:10.1038/352139a0 3648: 3642: 3639: 3633: 3632: 3630: 3628: 3613: 3607: 3606: 3582: 3576: 3575: 3542: 3420:–polymer cells. 3390:NMR spectroscopy 3158:+ CO (M = Mo, W) 3098:Fullerene ligand 3082: 3081: 3080: 3070: 3069: 3068: 3052: 3051: 3050: 3040: 3039: 3038: 3022: 3021: 3020: 2984: 2983: 2908: 2907: 2906: 2896: 2895: 2894: 2878: 2877: 2876: 2866: 2865: 2864: 2848: 2847: 2846: 2836: 2835: 2834: 2818: 2817: 2816: 2806: 2805: 2804: 2788: 2787: 2786: 2776: 2775: 2774: 2758: 2757: 2756: 2720: 2719: 2288:. For example, C 2251: 2250: 2249: 2235: 2234: 2233: 2219: 2218: 2217: 2196: 2195: 2194: 2184: 2183: 2182: 2144: 2143: 2142: 2130: 2129: 2128: 2102: 2101: 2100: 2076: 2075: 2074: 2040: 2039: 2038: 2000: 1999: 1998: 1975:carbon disulfide 1964: 1963: 1962: 1705:carbon disulfide 1641: 1584: 1577: 1570: 1563: 1556: 1518: 1514: 1495:B respectively. 1490: 1488: 1487: 1477: 1476: 1475: 1461: 1460: 1459: 1449: 1448: 1447: 1433: 1432: 1431: 1237: 1231:clusters (where 1150: 1023: 1016: 1009: 993: 992: 981: 980: 932:Titanium dioxide 771:Carbon nanotubes 765: 746: 745: 725: 719: 716: 715: 698: 694: 690: 686: 682: 678: 674: 670: 666: 662: 658: 654: 650: 646: 642: 628: 624: 620: 592: 550:Lattice constant 543:m, No. 225 542: 466: 451: 444:Chemical formula 364: 363: 348: 346: 330: 310: 299: 288: 277: 266: 246: 214: 190: 131: 130: 127: 126: 123: 120: 117: 114: 111: 108: 105: 102: 99: 96: 93: 90: 87: 84: 81: 78: 75: 33: 29: 25: 7803: 7802: 7798: 7797: 7796: 7794: 7793: 7792: 7778: 7777: 7776: 7771: 7753: 7749:Kenneth Snelson 7631: 7560: 7520: 7515: 7485: 7480: 7470: 7468: 7458: 7456: 7446: 7444: 7424: 7250: 7226: 7217: 7170: 7160: 7103: 7091: 7072:Propionaldehyde 7047:Ethylene glycol 7036: 7028: 7024: 6995: 6993: 6986: 6942:Cyanohexatriyne 6928: 6921: 6868: 6861: 6796: 6789: 6749: 6702: 6695: 6666:Methoxy radical 6596: 6589: 6585:Thiocyanic acid 6466: 6459: 6369: 6309:Ethynyl radical 6245: 6239: 6238: 6237: 6236: 6230: 6229: 6228: 6227: 6218: 6209:Sulfur monoxide 6194:Sodium chloride 6179:Silicon carbide 6086:Diatomic carbon 6076:Carbon monoxide 6018: 6013: 5983: 5978: 5940: 5931:Metallic carbon 5907: 5904: 5903: 5902: 5900: 5891: 5888: 5887: 5886: 5884: 5870: 5862: 5859: 5858: 5857: 5855: 5846: 5843: 5842: 5841: 5839: 5834:(atomic carbon) 5830: 5827: 5826: 5825: 5823: 5809: 5795:Carbon nanofoam 5776: 5768: 5765: 5764: 5763: 5761: 5752: 5749: 5748: 5747: 5745: 5726: 5691: 5681: 5647: 5637:Diamond (cubic) 5619: 5614: 5563: 5534: 5521: 5502: 5495: 5487: 5471:10.1.1.574.8368 5453: 5445: 5416:(14): 162–163. 5407: 5400: 5398:Further reading 5390: 5370: 5365: 5364: 5319: 5315: 5284: 5277: 5268: 5266: 5262: 5255: 5249: 5238: 5229: 5227: 5212: 5205: 5193: 5189: 5188: 5179: 5170: 5168: 5109: 5105: 5074: 5070: 5039: 5035: 5028: 5014: 5007: 5000: 4986: 4971: 4928: 4921: 4913: 4909: 4901: 4897: 4889: 4885: 4877: 4870: 4847: 4843: 4819: 4815: 4811: 4807: 4802: 4798: 4774: 4769: 4765: 4729:Physics-Uspekhi 4724: 4720: 4698: 4693: 4689: 4679: 4677: 4660: 4656: 4608: 4603: 4599: 4591: 4587: 4579: 4575: 4568: 4554: 4550: 4542: 4538: 4531: 4517:Angelici, R. J. 4513: 4509: 4504: 4500: 4490: 4488: 4475: 4474: 4470: 4432: 4427: 4423: 4417:Wayback Machine 4410: 4405: 4398: 4364: 4357: 4353: 4348:Wayback Machine 4340: 4334: 4330: 4292: 4287: 4280: 4249: 4245: 4223: 4218: 4214: 4183: 4179: 4172: 4155: 4144: 4104: 4099: 4095: 4064: 4060: 4019: 4012: 4001: 3997: 3992: 3988: 3980: 3969: 3915: 3910: 3906: 3853: 3849: 3794: 3790: 3743: 3739: 3708: 3704: 3658: 3654: 3649: 3645: 3640: 3636: 3626: 3624: 3615: 3614: 3610: 3588: 3583: 3579: 3572: 3556:. p. 325. 3543: 3539: 3534: 3527: 3523: 3516: 3511: 3504: 3499: 3495: 3490: 3483: 3476: 3468: 3464: 3460: 3456: 3451: 3446: 3438:Main articles: 3436: 3431: 3427:monomer group: 3426: 3419: 3407: 3403: 3398: 3387: 3374: 3370: 3365: 3357:Main articles: 3355: 3348: 3341: 3337: 3333: 3325: 3321: 3317: 3306: 3297:Vaska's complex 3291: 3287: 3283: 3279: 3275: 3267: 3259: 3255: 3251: 3247: 3243: 3235: 3213: 3209: 3205: 3201: 3197: 3189: 3185: 3181: 3177: 3173: 3157: 3153: 3145: 3141: 3105: 3100: 3094: 3092:Metal complexes 3079: 3076: 3075: 3074: 3072: 3067: 3064: 3063: 3062: 3060: 3049: 3046: 3045: 3044: 3042: 3037: 3034: 3033: 3032: 3030: 3019: 3016: 3015: 3014: 3012: 3010: 2990: 2977:with ultra-dry 2972: 2967: 2964: 2948: 2944: 2940: 2936: 2920: 2905: 2902: 2901: 2900: 2898: 2893: 2890: 2889: 2888: 2886: 2875: 2872: 2871: 2870: 2868: 2863: 2860: 2859: 2858: 2856: 2845: 2842: 2841: 2840: 2838: 2833: 2830: 2829: 2828: 2826: 2815: 2812: 2811: 2810: 2808: 2803: 2800: 2799: 2798: 2796: 2785: 2782: 2781: 2780: 2778: 2773: 2770: 2769: 2768: 2766: 2755: 2752: 2751: 2750: 2748: 2746: 2726: 2712: 2700: 2691: 2685: 2682: 2676: 2673: 2659: 2653: 2649: 2645: 2637: 2630: 2626: 2621:Bingel reaction 2617: 2603: 2591: 2584: 2580: 2572: 2567: 2555: 2551: 2547: 2539: 2535: 2527: 2519: 2515: 2504: 2500: 2496: 2489: 2486:. Reaction of C 2485: 2476: 2462: 2458: 2454: 2450: 2446: 2442: 2438: 2430: 2425: 2418: 2414: 2410: 2406: 2402: 2398: 2390: 2386: 2382: 2365: 2358: 2354: 2350: 2346: 2342: 2335: 2327: 2323: 2319: 2315: 2311: 2307: 2303: 2299: 2291: 2286:Birch reduction 2284:also undergoes 2283: 2279: 2275: 2270: 2259: 2248: 2245: 2244: 2243: 2241: 2232: 2229: 2228: 2227: 2225: 2223: 2216: 2214: 2213: 2212: 2210: 2193: 2190: 2189: 2188: 2186: 2181: 2178: 2177: 2176: 2174: 2172: 2167: 2160: 2152: 2141: 2138: 2137: 2136: 2134: 2127: 2124: 2123: 2122: 2120: 2099: 2096: 2095: 2094: 2092: 2084: 2073: 2070: 2069: 2068: 2066: 2056: 2053:Micrograph of C 2047: 2037: 2034: 2033: 2032: 2030: 2028: 2024: 2020: 2016: 2012: 2004: 1997: 1994: 1993: 1992: 1990: 1985: 1980: 1961: 1958: 1957: 1956: 1954: 1939:dichloromethane 1819:tetrahydrofuran 1648: 1639: 1636:Solubility of C 1630: 1621: 1590: 1543: 1538: 1533: 1528: 1513: 1505: 1494: 1486: 1483: 1482: 1481: 1479: 1474: 1471: 1470: 1469: 1467: 1458: 1455: 1454: 1453: 1451: 1446: 1443: 1442: 1441: 1439: 1430: 1427: 1426: 1425: 1423: 1408: 1397: 1380: 1373: 1360: 1353: 1342: 1338: 1330: 1310: 1257: 1253: 1245: 1241: 1232: 1230: 1206: 1201:Rice University 1197:Richard Smalley 1189:Sean C. O'Brien 1173: 1160: 1159: 1158: 1157: 1156: 1151: 1140: 1134: 1119: 1107: 1102:exists in space 1091: 1043: 1027: 987: 975: 872:Aluminium oxide 744: 737: 732: 731: 730:  ?) 721: 717: 713: 709: 637: 615: 601: 585: 560: 552: 540: 536: 521: 494: 485:1.65 g/cm 464: 454: 446: 432: 429: 424: 423: 412: 409: 408: 405: 399: 398: 395: 389: 388: 385: 379: 378: 367: 349: 342: 333: 313: 300: 269: 249: 226: 217: 204: 193: 180: 166: 164: 154: 153: 151: 144: 72: 68: 24: 17: 12: 11: 5: 7801: 7791: 7790: 7773: 7772: 7770: 7769: 7764: 7758: 7755: 7754: 7752: 7751: 7746: 7741: 7733: 7725: 7720: 7719: 7718: 7708: 7703: 7698: 7693: 7688: 7683: 7678: 7673: 7668: 7667: 7666: 7664:Design science 7661: 7651: 7646: 7639: 7637: 7633: 7632: 7630: 7629: 7623: 7620:Fly's Eye Dome 7617: 7611: 7605: 7599: 7593: 7587: 7581: 7575: 7572:Dymaxion house 7568: 7566: 7562: 7561: 7559: 7558: 7553: 7545: 7537: 7528: 7526: 7522: 7521: 7514: 7513: 7506: 7499: 7491: 7482: 7481: 7479: 7478: 7466: 7454: 7442: 7429: 7426: 7425: 7423: 7422: 7417: 7412: 7407: 7401: 7396: 7391: 7386: 7381: 7376: 7371: 7366: 7361: 7356: 7351: 7346: 7341: 7336: 7331: 7326: 7321: 7316: 7311: 7309:Cosmochemistry 7306: 7301: 7296: 7291: 7286: 7281: 7276: 7274:Astrochemistry 7271: 7266: 7260: 7258: 7252: 7251: 7249: 7248: 7243: 7238: 7233: 7228: 7224: 7220: 7215: 7211: 7206: 7201: 7196: 7191: 7186: 7180: 7178: 7172: 7171: 7169: 7168: 7163: 7158: 7154: 7149: 7144: 7139: 7134: 7129: 7127:Formyl radical 7124: 7119: 7113: 7107: 7105: 7097: 7096: 7093: 7092: 7090: 7089: 7084: 7079: 7074: 7069: 7064: 7059: 7057:Methyl acetate 7054: 7049: 7044: 7039: 7034: 7030: 7026: 7022: 7016: 7011: 7006: 7000: 6998: 6988: 6987: 6985: 6984: 6979: 6974: 6969: 6964: 6959: 6954: 6949: 6947:Dimethyl ether 6944: 6939: 6933: 6931: 6923: 6922: 6920: 6919: 6914: 6912:Methyl formate 6909: 6904: 6899: 6897:Glycolaldehyde 6894: 6889: 6884: 6879: 6873: 6871: 6863: 6862: 6860: 6859: 6854: 6849: 6844: 6839: 6834: 6832:Glycolonitrile 6829: 6827:Ethylene oxide 6824: 6819: 6818: 6817: 6807: 6801: 6799: 6791: 6790: 6788: 6787: 6782: 6777: 6772: 6767: 6762: 6757: 6752: 6747: 6743: 6738: 6733: 6728: 6726:Cyclopropenone 6723: 6718: 6713: 6707: 6705: 6697: 6696: 6694: 6693: 6688: 6683: 6678: 6673: 6668: 6663: 6658: 6653: 6648: 6643: 6638: 6633: 6628: 6626:Cyanoacetylene 6623: 6618: 6613: 6608: 6601: 6599: 6591: 6590: 6588: 6587: 6582: 6577: 6572: 6567: 6562: 6557: 6552: 6547: 6545:Methyl radical 6542: 6537: 6532: 6527: 6522: 6520:Isocyanic acid 6517: 6512: 6507: 6502: 6497: 6492: 6487: 6485:Isocyanic acid 6482: 6477: 6471: 6469: 6461: 6460: 6458: 6457: 6452: 6447: 6442: 6437: 6432: 6430:Sulfur dioxide 6427: 6422: 6417: 6412: 6407: 6405:Sodium cyanide 6402: 6397: 6392: 6387: 6382: 6377: 6372: 6367: 6363: 6358: 6353: 6348: 6343: 6338: 6333: 6328: 6322: 6316: 6314:Formyl radical 6311: 6306: 6301: 6296: 6291: 6286: 6281: 6276: 6274:Carbon dioxide 6271: 6266: 6261: 6255: 6253: 6247: 6246: 6221: 6219: 6217: 6216: 6211: 6206: 6201: 6196: 6191: 6186: 6181: 6176: 6171: 6166: 6161: 6155: 6150: 6145: 6139: 6134: 6129: 6124: 6122:Iron(II) oxide 6119: 6114: 6108: 6103: 6098: 6093: 6088: 6083: 6078: 6073: 6068: 6063: 6058: 6053: 6048: 6043: 6037: 6035: 6026: 6020: 6019: 6012: 6011: 6004: 5997: 5989: 5980: 5979: 5977: 5976: 5971: 5966: 5961: 5956: 5950: 5948: 5942: 5941: 5939: 5938: 5936:Penta-graphene 5933: 5928: 5923: 5918: 5913: 5905: 5897: 5889: 5880: 5878: 5872: 5871: 5869: 5868: 5860: 5852: 5844: 5836: 5828: 5819: 5817: 5811: 5810: 5808: 5807: 5802: 5797: 5792: 5786: 5784: 5778: 5777: 5775: 5774: 5766: 5758: 5750: 5742: 5736: 5734: 5728: 5727: 5725: 5724: 5719: 5689: 5679: 5670: 5665: 5657: 5655: 5649: 5648: 5646: 5645: 5640: 5632: 5630: 5621: 5620: 5613: 5612: 5605: 5598: 5590: 5584: 5583: 5571: 5566: 5561: 5557: 5552: 5547: 5542: 5537: 5532: 5528: 5519: 5515: 5510: 5505: 5500: 5494: 5493:External links 5491: 5490: 5489: 5485: 5446: 5443: 5405: 5399: 5396: 5395: 5394: 5388: 5369: 5366: 5363: 5362: 5313: 5275: 5236: 5203: 5177: 5103: 5084:(3): 552–560. 5068: 5043:Chem. Soc. Rev 5033: 5026: 5005: 4998: 4969: 4919: 4907: 4895: 4883: 4868: 4841: 4817: 4813: 4809: 4805: 4796: 4772: 4763: 4718: 4707:(2): 291–310. 4696: 4687: 4654: 4606: 4597: 4585: 4573: 4566: 4548: 4536: 4530:978-0935702484 4529: 4507: 4498: 4468: 4430: 4421: 4408: 4396: 4362: 4351: 4338: 4328: 4290: 4278: 4243: 4221: 4212: 4207:10.1086/153400 4177: 4170: 4142: 4102: 4093: 4058: 4044:10.1.1.31.7103 4029:(3): 723–730. 4010: 3995: 3986: 3967: 3913: 3904: 3847: 3788: 3737: 3702: 3656: 3652: 3643: 3634: 3608: 3586: 3577: 3570: 3536: 3535: 3533: 3530: 3525: 3521: 3514: 3509: 3502: 3497: 3493: 3489: 3486: 3481: 3474: 3473:Solutions of C 3466: 3462: 3458: 3454: 3450: 3447: 3435: 3432: 3424: 3417: 3405: 3401: 3397: 3394: 3385: 3376:using certain 3372: 3368: 3354: 3351: 3346: 3343: 3342: 3339: 3335: 3331: 3323: 3319: 3315: 3304: 3293: 3292: 3289: 3285: 3281: 3277: 3273: 3265: 3257: 3253: 3249: 3245: 3241: 3233: 3215: 3214: 3211: 3207: 3203: 3199: 3195: 3187: 3183: 3179: 3175: 3171: 3160: 3159: 3155: 3151: 3143: 3139: 3103: 3096:Main article: 3093: 3090: 3087: 3086: 3083: 3077: 3065: 3057: 3056: 3053: 3047: 3035: 3027: 3026: 3023: 3017: 3008: 3004: 3003: 2997: 2993: 2992: 2988: 2970: 2966: 2962: 2959: 2957:at 16 K. 2955:ferromagnetism 2951: 2950: 2946: 2942: 2938: 2934: 2918: 2913: 2912: 2909: 2903: 2891: 2883: 2882: 2879: 2873: 2861: 2853: 2852: 2849: 2843: 2831: 2823: 2822: 2819: 2813: 2801: 2793: 2792: 2789: 2783: 2771: 2763: 2762: 2759: 2753: 2744: 2740: 2739: 2733: 2729: 2728: 2727:at 213 K 2724: 2710: 2698: 2684: 2680: 2677: 2675: 2671: 2668: 2657: 2651: 2647: 2643: 2635: 2628: 2624: 2616: 2613: 2601: 2594:steric factors 2589: 2582: 2578: 2570: 2569:Reactions of C 2566: 2563: 2553: 2549: 2545: 2537: 2533: 2525: 2517: 2513: 2502: 2498: 2494: 2487: 2483: 2475: 2474:Cycloadditions 2472: 2460: 2456: 2452: 2448: 2444: 2440: 2436: 2428: 2427:Solutions of C 2424: 2421: 2416: 2412: 2408: 2404: 2400: 2396: 2393:steric factors 2388: 2384: 2380: 2364: 2361: 2356: 2352: 2348: 2344: 2340: 2333: 2325: 2321: 2317: 2313: 2309: 2305: 2301: 2297: 2289: 2281: 2277: 2273: 2269: 2266: 2257: 2246: 2238:delocalization 2230: 2221: 2215: 2191: 2179: 2171: 2168: 2166: 2163: 2158: 2150: 2139: 2125: 2097: 2082: 2071: 2054: 2046: 2043: 2035: 2026: 2022: 2018: 2014: 2010: 2002: 1995: 1983: 1978: 1959: 1945: 1944: 1941: 1935: 1934: 1931: 1925: 1924: 1921: 1915: 1914: 1911: 1905: 1904: 1901: 1895: 1894: 1891: 1885: 1884: 1881: 1875: 1874: 1871: 1865: 1864: 1861: 1855: 1854: 1851: 1845: 1844: 1841: 1835: 1834: 1831: 1825: 1824: 1821: 1815: 1814: 1811: 1805: 1804: 1801: 1791: 1790: 1787: 1781: 1780: 1777: 1771: 1770: 1767: 1761: 1760: 1757: 1751: 1750: 1747: 1741: 1740: 1737: 1731: 1730: 1727: 1721: 1720: 1717: 1711: 1710: 1707: 1701: 1700: 1697: 1691: 1690: 1687: 1681: 1680: 1677: 1671: 1670: 1667: 1661: 1660: 1657: 1651: 1650: 1645: 1637: 1628: 1620: 1617: 1613:phthalocyanine 1603: 1602: 1600: 1598: 1596: 1594: 1592: 1586: 1585: 1578: 1571: 1564: 1557: 1550: 1546: 1545: 1540: 1535: 1530: 1525: 1522: 1512: 1509: 1503: 1492: 1484: 1472: 1456: 1444: 1428: 1407: 1404: 1400:chromatography 1395: 1379: 1376: 1371: 1359: 1356: 1351: 1340: 1336: 1328: 1308: 1255: 1251: 1243: 1239: 1226: 1204: 1185:James R. Heath 1171: 1152: 1145: 1144: 1143: 1142: 1141: 1133: 1130: 1117: 1105: 1090: 1087: 1041: 1029: 1028: 1026: 1025: 1018: 1011: 1003: 1000: 999: 998: 997: 985: 970: 969: 968: 967: 962: 957: 952: 944: 943: 937: 936: 935: 934: 929: 924: 919: 914: 909: 904: 899: 894: 889: 884: 879: 874: 869: 864: 856: 855: 848: 847: 846: 845: 840: 835: 830: 825: 817: 816: 810: 809: 808: 807: 802: 797: 792: 787: 782: 774: 773: 767: 766: 758: 757: 751: 750: 742: 739: 738: 733: 711: 710: 706:standard state 703: 700: 699: 665:P305+P351+P338 638: 633: 630: 629: 616: 611: 608: 607: 602: 597: 594: 593: 586: 581: 578: 577: 567: 566: 562: 561: 555: 553: 548: 545: 544: 537: 532: 529: 528: 522: 517: 514: 513: 509: 508: 505: 503:Vapor pressure 499: 498: 495: 490: 487: 486: 483: 477: 476: 473: 469: 468: 462: 456: 455: 452: 447: 442: 439: 438: 434: 433: 431: 430: 427: 419: 418: 417: 414: 413: 411: 410: 406: 403: 402: 400: 396: 393: 392: 390: 386: 383: 382: 374: 373: 372: 369: 368: 366: 365: 352: 350: 338: 335: 334: 332: 331: 323: 321: 315: 314: 312: 311: 303: 301: 293: 290: 289: 279: 271: 270: 268: 267: 259: 257: 251: 250: 248: 247: 239: 237: 231: 230: 227: 222: 219: 218: 216: 215: 207: 205: 198: 195: 194: 192: 191: 183: 181: 176: 173: 172: 168: 167: 162: 160: 156: 155: 149: 142: 140: 139: 133: 132: 66: 65:Pronunciation 62: 61: 57: 56: 53: 52: 43: 15: 9: 6: 4: 3: 2: 7800: 7789: 7786: 7785: 7783: 7768: 7765: 7763: 7760: 7759: 7756: 7750: 7747: 7745: 7742: 7739: 7738: 7734: 7731: 7730: 7726: 7724: 7721: 7717: 7714: 7713: 7712: 7709: 7707: 7704: 7702: 7699: 7697: 7694: 7692: 7689: 7687: 7684: 7682: 7679: 7677: 7674: 7672: 7669: 7665: 7662: 7660: 7657: 7656: 7655: 7652: 7650: 7647: 7644: 7641: 7640: 7638: 7634: 7627: 7624: 7621: 7618: 7615: 7612: 7609: 7606: 7603: 7602:Geodesic dome 7600: 7597: 7594: 7591: 7588: 7585: 7582: 7579: 7576: 7573: 7570: 7569: 7567: 7563: 7557: 7554: 7551: 7550: 7549:Critical Path 7546: 7543: 7542: 7538: 7535: 7534: 7530: 7529: 7527: 7523: 7519: 7512: 7507: 7505: 7500: 7498: 7493: 7492: 7489: 7477: 7467: 7465: 7455: 7453: 7443: 7441: 7440: 7431: 7430: 7427: 7421: 7418: 7416: 7413: 7411: 7408: 7405: 7402: 7400: 7397: 7395: 7392: 7390: 7387: 7385: 7382: 7380: 7377: 7375: 7372: 7370: 7367: 7365: 7362: 7360: 7357: 7355: 7352: 7350: 7347: 7345: 7342: 7340: 7339:Homochirality 7337: 7335: 7332: 7330: 7327: 7325: 7322: 7320: 7317: 7315: 7312: 7310: 7307: 7305: 7302: 7300: 7297: 7295: 7292: 7290: 7287: 7285: 7282: 7280: 7277: 7275: 7272: 7270: 7267: 7265: 7262: 7261: 7259: 7257: 7253: 7247: 7244: 7242: 7239: 7237: 7234: 7232: 7229: 7227: 7221: 7219: 7212: 7210: 7207: 7205: 7202: 7200: 7197: 7195: 7194:Methoxyethane 7192: 7190: 7187: 7185: 7182: 7181: 7179: 7177: 7173: 7167: 7164: 7162: 7155: 7153: 7150: 7148: 7145: 7143: 7140: 7138: 7135: 7133: 7130: 7128: 7125: 7123: 7120: 7117: 7114: 7112: 7109: 7108: 7106: 7102: 7098: 7088: 7085: 7083: 7080: 7078: 7077:Butyronitrile 7075: 7073: 7070: 7068: 7065: 7063: 7060: 7058: 7055: 7053: 7052:Ethyl formate 7050: 7048: 7045: 7043: 7040: 7038: 7031: 7020: 7017: 7015: 7012: 7010: 7007: 7005: 7002: 7001: 6999: 6997: 6989: 6983: 6980: 6978: 6977:Propionitrile 6975: 6973: 6970: 6968: 6965: 6963: 6960: 6958: 6955: 6953: 6950: 6948: 6945: 6943: 6940: 6938: 6935: 6934: 6932: 6930: 6924: 6918: 6915: 6913: 6910: 6908: 6905: 6903: 6900: 6898: 6895: 6893: 6890: 6888: 6885: 6883: 6880: 6878: 6875: 6874: 6872: 6870: 6864: 6858: 6857:Vinyl alcohol 6855: 6853: 6850: 6848: 6845: 6843: 6840: 6838: 6835: 6833: 6830: 6828: 6825: 6823: 6820: 6816: 6815:Vinyl cyanide 6813: 6812: 6811: 6810:Acrylonitrile 6808: 6806: 6803: 6802: 6800: 6798: 6792: 6786: 6783: 6781: 6778: 6776: 6775:Pentynylidyne 6773: 6771: 6768: 6766: 6763: 6761: 6758: 6756: 6753: 6751: 6744: 6742: 6739: 6737: 6734: 6732: 6729: 6727: 6724: 6722: 6719: 6717: 6714: 6712: 6709: 6708: 6706: 6704: 6698: 6692: 6689: 6687: 6684: 6682: 6679: 6677: 6674: 6672: 6671:Methylenimine 6669: 6667: 6664: 6662: 6659: 6657: 6654: 6652: 6649: 6647: 6644: 6642: 6639: 6637: 6634: 6632: 6629: 6627: 6624: 6622: 6619: 6617: 6614: 6612: 6609: 6606: 6603: 6602: 6600: 6598: 6592: 6586: 6583: 6581: 6578: 6576: 6573: 6571: 6568: 6566: 6563: 6561: 6558: 6556: 6553: 6551: 6550:Propynylidyne 6548: 6546: 6543: 6541: 6540:Methyl cation 6538: 6536: 6533: 6531: 6528: 6526: 6523: 6521: 6518: 6516: 6513: 6511: 6508: 6506: 6503: 6501: 6500:Fulminic acid 6498: 6496: 6493: 6491: 6488: 6486: 6483: 6481: 6478: 6476: 6473: 6472: 6470: 6468: 6462: 6456: 6453: 6451: 6448: 6446: 6443: 6441: 6438: 6436: 6433: 6431: 6428: 6426: 6423: 6421: 6418: 6416: 6413: 6411: 6408: 6406: 6403: 6401: 6398: 6396: 6393: 6391: 6388: 6386: 6383: 6381: 6378: 6376: 6375:Nitrous oxide 6373: 6371: 6364: 6362: 6359: 6357: 6354: 6352: 6349: 6347: 6344: 6342: 6339: 6337: 6334: 6332: 6329: 6326: 6323: 6320: 6317: 6315: 6312: 6310: 6307: 6305: 6302: 6300: 6297: 6295: 6292: 6290: 6287: 6285: 6282: 6280: 6277: 6275: 6272: 6270: 6269:Amino radical 6267: 6265: 6262: 6260: 6257: 6256: 6254: 6252: 6248: 6243: 6234: 6225: 6215: 6212: 6210: 6207: 6205: 6202: 6200: 6199:Sodium iodide 6197: 6195: 6192: 6190: 6187: 6185: 6182: 6180: 6177: 6175: 6172: 6170: 6167: 6165: 6162: 6159: 6156: 6154: 6151: 6149: 6146: 6143: 6140: 6138: 6135: 6133: 6130: 6128: 6125: 6123: 6120: 6118: 6115: 6112: 6109: 6107: 6104: 6102: 6099: 6097: 6094: 6092: 6089: 6087: 6084: 6082: 6081:Cyano radical 6079: 6077: 6074: 6072: 6069: 6067: 6064: 6062: 6061:Carbon cation 6059: 6057: 6054: 6052: 6049: 6047: 6044: 6042: 6039: 6038: 6036: 6034: 6030: 6027: 6025: 6021: 6017: 6010: 6005: 6003: 5998: 5996: 5991: 5990: 5987: 5975: 5972: 5970: 5967: 5965: 5962: 5960: 5957: 5955: 5952: 5951: 5949: 5947: 5943: 5937: 5934: 5932: 5929: 5927: 5924: 5922: 5919: 5917: 5914: 5912: 5911:(prismane C8) 5898: 5896: 5882: 5881: 5879: 5877: 5873: 5867: 5853: 5851: 5837: 5835: 5821: 5820: 5818: 5816: 5812: 5806: 5803: 5801: 5798: 5796: 5793: 5791: 5788: 5787: 5785: 5783: 5779: 5773: 5759: 5757: 5743: 5741: 5738: 5737: 5735: 5733: 5729: 5723: 5722:Glassy carbon 5720: 5717: 5716: 5711: 5710: 5705: 5704: 5699: 5698: 5693: 5692: 5684: 5683: 5674: 5671: 5669: 5666: 5664: 5663: 5659: 5658: 5656: 5654: 5650: 5644: 5641: 5639: 5638: 5634: 5633: 5631: 5629: 5628: 5622: 5618: 5611: 5606: 5604: 5599: 5597: 5592: 5591: 5588: 5581: 5580: 5575: 5572: 5570: 5567: 5565: 5558: 5556: 5553: 5551: 5548: 5546: 5543: 5541: 5538: 5536: 5529: 5527: 5525: 5516: 5514: 5511: 5509: 5506: 5504: 5497: 5496: 5481: 5477: 5472: 5467: 5464:: 1397–1404. 5463: 5459: 5452: 5447: 5439: 5435: 5431: 5427: 5423: 5419: 5415: 5411: 5402: 5401: 5391: 5385: 5381: 5377: 5372: 5371: 5358: 5354: 5349: 5344: 5340: 5336: 5332: 5328: 5324: 5317: 5309: 5305: 5301: 5297: 5293: 5289: 5282: 5280: 5261: 5254: 5247: 5245: 5243: 5241: 5225: 5221: 5220:WeyburnReview 5217: 5210: 5208: 5199: 5192: 5186: 5184: 5182: 5166: 5162: 5158: 5154: 5150: 5146: 5142: 5138: 5134: 5130: 5126: 5122: 5118: 5114: 5107: 5099: 5095: 5091: 5087: 5083: 5079: 5072: 5064: 5060: 5056: 5052: 5048: 5044: 5037: 5029: 5023: 5019: 5012: 5010: 5001: 4995: 4991: 4984: 4982: 4980: 4978: 4976: 4974: 4965: 4961: 4957: 4953: 4949: 4945: 4941: 4937: 4933: 4926: 4924: 4916: 4911: 4904: 4899: 4892: 4887: 4880: 4875: 4873: 4864: 4860: 4856: 4852: 4845: 4837: 4833: 4829: 4825: 4824: 4800: 4792: 4788: 4784: 4780: 4779: 4767: 4759: 4755: 4751: 4747: 4743: 4739: 4735: 4731: 4730: 4722: 4714: 4710: 4706: 4702: 4691: 4675: 4671: 4670: 4665: 4658: 4650: 4646: 4642: 4638: 4634: 4633:10.1038/44348 4630: 4626: 4622: 4618: 4614: 4613: 4601: 4594: 4589: 4582: 4577: 4569: 4563: 4559: 4552: 4545: 4540: 4532: 4526: 4522: 4518: 4511: 4502: 4486: 4482: 4478: 4472: 4464: 4460: 4456: 4452: 4448: 4444: 4440: 4436: 4425: 4418: 4414: 4411: 4403: 4401: 4391: 4386: 4382: 4378: 4374: 4370: 4366: 4355: 4349: 4345: 4342: 4332: 4324: 4320: 4316: 4312: 4308: 4304: 4300: 4296: 4285: 4283: 4274: 4270: 4266: 4262: 4258: 4254: 4253:J. Chem. Phys 4247: 4239: 4235: 4231: 4227: 4216: 4208: 4204: 4200: 4196: 4192: 4188: 4181: 4173: 4167: 4163: 4159: 4153: 4151: 4149: 4147: 4138: 4134: 4130: 4126: 4122: 4118: 4114: 4110: 4109: 4097: 4089: 4085: 4081: 4077: 4073: 4069: 4062: 4054: 4050: 4045: 4040: 4036: 4032: 4028: 4024: 4017: 4015: 4006: 4005:New Scientist 3999: 3990: 3983: 3978: 3976: 3974: 3972: 3963: 3959: 3955: 3951: 3947: 3943: 3939: 3935: 3931: 3927: 3923: 3919: 3908: 3900: 3896: 3892: 3888: 3884: 3880: 3875: 3870: 3866: 3862: 3858: 3851: 3843: 3839: 3834: 3829: 3825: 3821: 3816: 3811: 3807: 3803: 3799: 3792: 3784: 3780: 3776: 3772: 3768: 3764: 3760: 3756: 3752: 3748: 3741: 3733: 3729: 3725: 3721: 3717: 3713: 3706: 3698: 3694: 3690: 3686: 3682: 3678: 3674: 3670: 3666: 3662: 3647: 3638: 3622: 3618: 3612: 3604: 3600: 3596: 3592: 3591:J. Phys. Chem 3581: 3573: 3567: 3563: 3559: 3555: 3551: 3547: 3541: 3537: 3529: 3518: 3506: 3485: 3478: 3471: 3445: 3441: 3430: 3429:Polyfullerene 3421: 3415: 3411: 3393: 3391: 3381: 3379: 3364: 3360: 3350: 3329: 3314:-Ir(CO)Cl(PPh 3313: 3310: 3309: 3308: 3302: 3298: 3271: 3263: 3239: 3231: 3227: 3223: 3222: 3221: 3219: 3193: 3169: 3165: 3164: 3163: 3149: 3137: 3136: 3135: 3133: 3129: 3125: 3121: 3117: 3113: 3109: 3099: 3084: 3059: 3058: 3054: 3029: 3028: 3024: 3006: 3005: 3001: 2998: 2996:Half-reaction 2995: 2994: 2985: 2982: 2980: 2976: 2958: 2956: 2932: 2931: 2930: 2928: 2924: 2910: 2885: 2884: 2880: 2855: 2854: 2850: 2825: 2824: 2820: 2795: 2794: 2790: 2765: 2764: 2760: 2742: 2741: 2737: 2734: 2732:Half-reaction 2731: 2730: 2721: 2718: 2716: 2708: 2704: 2696: 2690: 2667: 2665: 2661: 2641: 2640:diazomethanes 2632: 2622: 2609: 2605: 2599: 2595: 2586: 2576: 2575:free radicals 2562: 2560: 2559:ferromagnetic 2543: 2531: 2530:cycloaddition 2510: 2506: 2491: 2481: 2468: 2464: 2434: 2420: 2394: 2378: 2374: 2370: 2360: 2337: 2331: 2295: 2287: 2268:Hydrogenation 2265: 2263: 2255: 2254:superaromatic 2239: 2208: 2204: 2200: 2162: 2156: 2148: 2147:semiconductor 2132: 2118: 2114: 2110: 2106: 2090: 2088: 2063: 2051: 2042: 2008: 1988: 1976: 1972: 1951: 1942: 1940: 1937: 1936: 1932: 1930: 1927: 1926: 1922: 1920: 1917: 1916: 1912: 1910: 1907: 1906: 1902: 1900: 1897: 1896: 1892: 1890: 1887: 1886: 1882: 1880: 1877: 1876: 1872: 1870: 1867: 1866: 1862: 1860: 1857: 1856: 1852: 1850: 1847: 1846: 1842: 1840: 1837: 1836: 1832: 1830: 1827: 1826: 1822: 1820: 1817: 1816: 1812: 1810: 1807: 1806: 1802: 1800: 1796: 1793: 1792: 1788: 1786: 1783: 1782: 1778: 1776: 1773: 1772: 1768: 1766: 1763: 1762: 1758: 1756: 1753: 1752: 1748: 1746: 1743: 1742: 1738: 1736: 1733: 1732: 1728: 1726: 1723: 1722: 1718: 1716: 1713: 1712: 1708: 1706: 1703: 1702: 1698: 1696: 1693: 1692: 1688: 1686: 1683: 1682: 1678: 1676: 1673: 1672: 1668: 1666: 1663: 1662: 1658: 1656: 1653: 1652: 1646: 1643: 1642: 1625: 1616: 1614: 1610: 1601: 1599: 1597: 1595: 1593: 1588: 1583: 1579: 1576: 1572: 1569: 1565: 1562: 1558: 1555: 1551: 1548: 1547: 1541: 1536: 1531: 1526: 1523: 1520: 1519: 1500: 1496: 1465: 1437: 1421: 1417: 1413: 1403: 1401: 1393: 1389: 1385: 1375: 1369: 1368:geodesic dome 1365: 1355: 1348: 1346: 1334: 1326: 1322: 1318: 1312: 1305: 1301: 1297: 1293: 1288: 1286: 1282: 1277: 1275: 1272: 1268: 1263: 1261: 1249: 1235: 1229: 1224: 1220: 1217: 1212: 1208: 1202: 1198: 1194: 1190: 1186: 1182: 1169: 1164: 1155: 1149: 1139: 1129: 1127: 1123: 1115: 1111: 1103: 1098: 1096: 1086: 1084: 1079: 1077: 1074: 1069: 1067: 1063: 1059: 1055: 1051: 1047: 1039: 1036:is a type of 1035: 1024: 1019: 1017: 1012: 1010: 1005: 1004: 1002: 1001: 996: 991: 986: 984: 979: 974: 973: 972: 971: 966: 963: 961: 958: 956: 953: 951: 950:Nanocomposite 948: 947: 946: 945: 942: 939: 938: 933: 930: 928: 925: 923: 920: 918: 915: 913: 912:Iron–platinum 910: 908: 905: 903: 900: 898: 895: 893: 890: 888: 885: 883: 880: 878: 875: 873: 870: 868: 865: 863: 860: 859: 858: 857: 854: 853:nanoparticles 850: 849: 844: 841: 839: 838:Health impact 836: 834: 831: 829: 828:C70 fullerene 826: 824: 821: 820: 819: 818: 815: 812: 811: 806: 803: 801: 798: 796: 793: 791: 788: 786: 783: 781: 778: 777: 776: 775: 772: 769: 768: 764: 760: 759: 756: 755:Nanomaterials 753: 752: 748: 747: 736: 729: 724: 707: 701: 639: 636: 632: 631: 617: 614: 610: 609: 606: 603: 600: 596: 595: 591: 587: 584: 580: 579: 575: 573: 568: 563: 558: 554: 551: 547: 546: 538: 535: 531: 530: 527: 523: 520: 516: 515: 510: 506: 504: 501: 500: 496: 493: 489: 488: 484: 482: 479: 478: 474: 471: 470: 463: 461: 458: 457: 448: 445: 441: 440: 435: 426: 425: 422: 415: 401: 391: 381: 380: 377: 370: 362: 358: 357:DTXSID4031772 354: 353: 351: 341: 337: 336: 329: 325: 324: 322: 320: 317: 316: 309: 305: 304: 302: 296: 292: 291: 287: 283: 280: 278: 276:ECHA InfoCard 273: 272: 265: 261: 260: 258: 256: 253: 252: 245: 241: 240: 238: 236: 233: 232: 228: 225: 221: 220: 213: 209: 208: 206: 202: 197: 196: 189: 185: 184: 182: 179: 175: 174: 169: 157: 148: 138: 134: 129: 67: 64: 63: 58: 48: 44: 39: 35: 34: 30: 22: 7735: 7727: 7715: 7590:Dymaxion map 7578:Dymaxion car 7547: 7539: 7531: 7432: 7415:Spectroscopy 7269:Astrobiology 7122:Formaldehyde 7018: 7014:Benzonitrile 6805:Acetaldehyde 6760:Methanethiol 6711:Acetonitrile 6616:Carbodiimide 6495:Formaldehyde 6490:Cyanoethynyl 6341:Iron cyanide 6336:Hydroperoxyl 6137:Nitric oxide 5969:Carbon fiber 5959:Carbon black 5945: 5926:Cubic carbon 5875: 5814: 5781: 5731: 5713: 5707: 5701: 5695: 5686: 5677: 5676: 5675:, including 5660: 5652: 5635: 5624: 5577: 5523: 5499:History of C 5461: 5457: 5413: 5409: 5379: 5368:Bibliography 5330: 5326: 5316: 5291: 5288:Biomaterials 5287: 5267:. Retrieved 5228:. Retrieved 5219: 5197: 5169:. Retrieved 5120: 5116: 5106: 5081: 5077: 5071: 5046: 5042: 5036: 5017: 4989: 4939: 4935: 4910: 4898: 4886: 4854: 4850: 4844: 4827: 4821: 4799: 4782: 4776: 4766: 4733: 4727: 4721: 4704: 4700: 4690: 4680:26 September 4678:. Retrieved 4669:Ars Technica 4667: 4657: 4616: 4610: 4600: 4588: 4576: 4557: 4551: 4539: 4520: 4510: 4501: 4489:. Retrieved 4480: 4471: 4438: 4434: 4424: 4372: 4368: 4354: 4331: 4298: 4294: 4259:(11): 6511. 4256: 4252: 4246: 4229: 4225: 4215: 4190: 4187:Astrophys. J 4186: 4180: 4161: 4112: 4106: 4096: 4071: 4067: 4061: 4026: 4022: 4004: 3998: 3989: 3921: 3917: 3907: 3864: 3860: 3850: 3805: 3801: 3791: 3750: 3746: 3740: 3715: 3711: 3705: 3664: 3660: 3659:in flames". 3646: 3637: 3625:. Retrieved 3620: 3611: 3594: 3590: 3580: 3549: 3540: 3519: 3507: 3491: 3479: 3472: 3452: 3399: 3382: 3366: 3344: 3327: 3311: 3294: 3269: 3261: 3237: 3225: 3216: 3191: 3167: 3161: 3147: 3101: 2999: 2968: 2952: 2916: 2735: 2714: 2692: 2633: 2618: 2597: 2587: 2568: 2523: 2492: 2477: 2426: 2379:occurs for C 2367:Addition of 2366: 2363:Halogenation 2338: 2293: 2271: 2173: 2133: 2091: 2080: 1989: 1968: 1829:acetonitrile 1794: 1606: 1521:Centered by 1464:double bonds 1409: 1381: 1361: 1349: 1345:mass spectra 1313: 1289: 1278: 1264: 1233: 1227: 1213: 1209: 1181:Harold Kroto 1177: 1154:Harold Kroto 1099: 1092: 1082: 1080: 1070: 1033: 1032: 887:Cobalt oxide 867:Quantum dots 822: 800:Applications 604: 571: 556: 171:Identifiers 159:Other names 146: 7654:Synergetics 7614:Octet truss 7389:Outer space 7299:Cosmic dust 7264:Abiogenesis 7176:Unconfirmed 7132:Heavy water 6972:Ethanethiol 6887:Cyanoallene 6877:Acetic acid 6847:Methylamine 6731:Diacetylene 6646:Formic acid 6636:Cyanomethyl 6294:Diazenylium 6284:CCP radical 6160:(molecular) 6144:(molecular) 6113:(molecular) 5921:Haeckelites 5866:(tricarbon) 5815:other forms 5715:Nanoscrolls 4074:(7): 3322. 3617:"Buckyball" 3326:→ Ir(CO)Cl( 2596:of Y. When 2252:not being " 2077:in crystal. 2065:Packing of 1909:tetradecane 1809:cyclohexane 1343:) in their 1271:icosahedral 1219:evaporation 1193:Robert Curl 1104:. Neutral C 1073:hydrocarbon 1052:and twelve 599:Signal word 534:Space group 472:Appearance 437:Properties 282:100.156.884 244:CHEBI:33128 165:; fullerene 7788:Fullerenes 7645:(daughter) 7608:World Game 7596:Tensegrity 7304:Cosmic ray 7246:Silylidyne 7209:Hemolithin 7184:Anthracene 7101:Deuterated 7082:Pyrimidine 6892:Ethanimine 6755:Ketenimine 6611:Butadiynyl 6435:Thioformyl 6289:Chloronium 5673:Fullerenes 5269:2021-04-15 5230:2021-04-17 5171:2021-11-26 4232:(1): 145. 4007:(32): 245. 3857:Joblin, C. 3532:References 3284:SiC≡CSi(CH 3248:SiC≡CSi(CH 3218:Titanocene 3108:molybdenum 2689:Fullerides 2687:See also: 1929:mesitylene 1785:chloroform 1647:Solubility 1589:Projective 1511:Properties 1436:nanometers 1304:electrodes 1285:fullerenes 1089:Occurrence 1083:buckyballs 907:Iron oxide 814:Fullerenes 583:Pictograms 512:Structure 460:Molar mass 328:NP9U26B839 255:ChemSpider 199:3D model ( 188:99685-96-8 178:CAS Number 152:)fullerene 7711:Fullerene 7691:Gold Dome 7236:Phosphine 7104:molecules 7037:fullerene 6937:Acetamide 6741:Formamide 6621:Cyanamide 6475:Acetylene 6450:Tricarbon 6361:Methylene 6346:Isoformyl 6251:Triatomic 6024:Molecules 5703:Nanotubes 5466:CiteSeerX 5161:244643471 5145:1476-4687 4758:250785669 4546:, 369–370 4365:molecule" 4039:CiteSeerX 3962:205244293 3946:1476-4687 3899:118684608 3874:1211.7252 3842:118739732 3815:1201.3542 3120:palladium 2332:to give C 2199:oxidation 2109:superhard 1879:isooctane 1735:bromoform 1591:symmetry 1544:Pentagon 1406:Structure 1384:pyrolysis 1378:Synthesis 1358:Etymology 1168:footballs 1138:Fullerene 1064:atoms is 1054:pentagons 1038:fullerene 877:Cellulose 833:Chemistry 785:Chemistry 780:Synthesis 689:P403+P233 681:P337+P313 677:P332+P313 661:P304+P340 657:P302+P352 574:labelling 7782:Category 7762:Category 7681:Dymaxion 7676:Geoscope 7223:Linear C 7204:Graphene 7116:Ammonium 6917:Acrolein 6780:Propynal 6765:Methanol 6736:Ethylene 6605:Ammonium 6380:Nitroxyl 6204:Sulfanyl 6148:Imidogen 6142:Nitrogen 6111:Hydrogen 6056:Argonium 6033:Diatomic 5964:Charcoal 5805:Q-carbon 5732:sp forms 5709:Nanobuds 5668:Graphene 5662:Graphite 5653:sp forms 5357:30257131 5308:22498298 5260:Archived 5224:Archived 5165:Archived 5153:34819685 5063:21505658 4964:40552372 4956:11749258 4674:Archived 4641:18494170 4519:(1999). 4485:Archived 4413:Archived 4344:Archived 3954:26178962 3783:33588270 3775:20651118 3697:37159968 3627:13 April 3548:(2014). 3128:titanium 3116:platinum 3112:tungsten 2656:Phenyl-C 2373:chlorine 2369:fluorine 2320:, with C 2111:form of 2105:graphite 1971:solvents 1899:dodecane 1843:0.00004 1839:methanol 1631:solution 1619:Solution 1539:Hexagon 1416:vertices 1414:with 60 1274:symmetry 1223:graphite 1100:It also 1076:solvents 1058:football 1050:hexagons 955:Nanofoam 922:Platinum 805:Timeline 565:Hazards 229:5901022 7767:Commons 7636:Related 7369:Kerogen 7256:Related 7199:Glycine 7152:Propyne 7111:Ammonia 7009:Benzene 7004:Acetone 6996:or more 6967:Propene 6952:Ethanol 6842:Propyne 6661:Methane 6530:Ketenyl 6480:Ammonia 5946:related 5916:Chaoite 5438:4314237 5418:Bibcode 5348:7005847 5125:Bibcode 5086:Bibcode 4738:Bibcode 4649:4424892 4621:Bibcode 4491:10 June 4463:4359360 4443:Bibcode 4377:Bibcode 4323:4314237 4303:Bibcode 4261:Bibcode 4234:Bibcode 4195:Bibcode 4193:: 129. 4137:4314237 4117:Bibcode 4076:Bibcode 4031:Bibcode 3926:Bibcode 3879:Bibcode 3820:Bibcode 3755:Bibcode 3747:Science 3720:Bibcode 3689:2067575 3669:Bibcode 3349:guest. 3301:adducts 3276:) + (CH 3124:iridium 2965:cations 2911:−2.479 2881:−2.069 2851:−1.579 2821:−1.129 2791:−0.599 2761:−0.169 2501:. The C 2433:epoxide 2377:bromine 2336:again. 2113:diamond 2007:benzene 1923:0.0041 1919:dioxane 1859:pentane 1765:benzene 1755:toluene 1644:Solvent 1524:Vertex 1317:benzene 1248:species 1236:> 20 1132:History 882:Ceramic 728:what is 726: ( 605:Warning 481:Density 465:720.660 295:PubChem 7628:(1967) 7622:(1965) 7616:(1961) 7610:(1961) 7604:(1953) 7598:(1949) 7592:(1946) 7586:(1940) 7580:(1933) 7574:(1928) 7552:(1981) 7544:(1968) 7536:(1938) 7420:Tholin 7241:Pyrene 6686:Silane 6656:Ketene 6158:Oxygen 5524:Nature 5468:  5436:  5410:Nature 5386:  5355:  5345:  5306:  5198:Nature 5159:  5151:  5143:  5117:Nature 5061:  5024:  4996:  4962:  4954:  4756:  4647:  4639:  4612:Nature 4564:  4527:  4461:  4435:Nature 4321:  4295:Nature 4168:  4135:  4108:Nature 4041:  3960:  3952:  3944:  3918:Nature 3897:  3867:: L4. 3840:  3781:  3773:  3712:Carbon 3695:  3687:  3661:Nature 3568:  3303:with C 3299:, for 3126:, and 3085:+2.14 3055:+1.71 3025:+1.27 3002:° (V) 2897:+ e ⇌ 2867:+ e ⇌ 2837:+ e ⇌ 2807:+ e ⇌ 2777:+ e ⇌ 2747:+ e ⇌ 2738:° (V) 2683:anions 2387:and Br 2375:, and 2262:alkene 2197:. 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2488:60 2484:60 2457:60 2453:60 2445:60 2441:60 2437:60 2429:60 2417:60 2413:60 2409:24 2407:Br 2405:60 2399:Br 2397:60 2381:60 2371:, 2357:18 2353:60 2349:32 2345:60 2341:60 2334:60 2326:32 2322:60 2318:36 2314:60 2310:32 2306:60 2302:18 2298:60 2290:60 2282:60 2278:60 2274:60 2258:60 2247:60 2231:60 2222:60 2211:Fc 2207:Fc 2192:60 2180:60 2159:60 2151:60 2140:60 2126:60 2098:60 2083:60 2072:60 2055:60 2036:70 2027:60 2023:60 2011:60 2003:60 1996:60 1984:60 1979:60 1960:60 1759:3 1749:4 1739:5 1729:5 1719:8 1709:8 1638:60 1629:60 1504:60 1493:59 1485:59 1473:60 1457:60 1445:60 1429:60 1396:60 1372:60 1352:60 1341:70 1337:60 1329:60 1311:. 1309:60 1294:, 1287:. 1262:. 1256:60 1252:60 1244:70 1240:60 1205:60 1191:, 1187:, 1183:, 1172:60 1118:60 1106:60 1085:. 1042:60 695:, 691:, 687:, 683:, 679:, 675:, 671:, 667:, 663:, 659:, 655:, 651:, 647:, 643:, 625:, 621:, 576:: 539:Fm 453:60 163:60 143:60 141:(C 122:iː 101:ər 7510:e 7503:t 7496:v 7225:5 7216:2 7214:H 7161:D 7159:2 7157:N 7033:C 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Index

Buckyball (disambiguation)


/ˌbʌkmɪnstərˈfʊlərn/
Preferred IUPAC name
CAS Number
99685-96-8
JSmol
Interactive image
Beilstein Reference
ChEBI
CHEBI:33128
ChemSpider
110185
ECHA InfoCard
100.156.884
Edit this at Wikidata
PubChem
123591
UNII
NP9U26B839
CompTox Dashboard
DTXSID4031772
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Density
Solubility in water

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