35:
496:, with the O−C−O angle varying between 120° and 130° depending on the context. The metal atoms interact with both oxygen atoms. However two geometrical arrangements for the lithium and caesium salts were detected, only one of them being symmetrical on the two oxygen atoms.
475:
to an oxygen atom from the substrate through its free bonds. In these contexts, it appears that the carbonite ion reacts with excess carbon monoxide to form an anion with the
377:. Interestingly, the disodium salt has not been directly observed under experimental conditions, suggesting that this is less stable than other alkali carbonites. Due to the
518:
Kafafi, Zakya H.; Hauge, Robert H.; Billups, W. Edward; Margrave, John L. (1983). "Carbon dioxide activation by lithium metal. 1. Infrared spectra of LiCO
574:
Kafafi, Zakya H.; Hauge, Robert H.; Billups, W. Edward; Margrave, John L. (1984). "Carbon dioxide activation by alkali metals. 2. Infrared spectra of MCO
224:
184:
121:
662:
Binet, Claude; Ahmed Badri; Magali
Boutonnet-Kizling; Jean-Claude Lavalley (1994). "FTIR study of carbon monoxide adsorption on ceria: CO
436:
was used as the metal. The alkali metal carbonites obtained in the cryogenic experiments decomposed to the corresponding
96:
247:
17:
82:
620:
Babaeva, M. A.; Tsyganenko, A. A. (1987). "Infrared spectroscopic evidence for the formation of carbonite
472:
493:
489:
661:
449:
58:
8:
405:
48:
699:
455:
The presence of carbonite ions has been proposed to be relevant to the absorption of
675:
641:
595:
547:
271:
144:
464:
456:
441:
209:
299:
241:
229:
214:
179:
693:
460:
295:
471:. In the former, it has been suggested that the carbon atom attaches via a
310:
448:. The carbonite ion is promptly converted to carbonate in the presence of
679:
394:
599:
551:
492:
data confirm earlier theoretical studies that the carbonite anion has a
645:
386:
166:
437:
378:
340:
204:
240:
Except where otherwise noted, data are given for materials in their
355:
291:
81:
445:
398:
390:
370:
325:
219:
34:
476:
433:
382:
374:
278:
275:
468:
267:
71:
573:
517:
263:
668:
Journal of the
Chemical Society, Faraday Transactions
632:ions in CO interaction with basic oxide surfaces".
619:
691:
57:
404:At lower metal concentrations, salts of the
385:atom, salts of the carbonite ion would be
373:carbonite), have been observed at 15
540:Journal of the American Chemical Society
634:Reaction Kinetics and Catalysis Letters
569:
567:
565:
563:
561:
513:
511:
509:
14:
692:
657:
655:
615:
613:
611:
609:
666:carbonite dianion adsorbed species".
108:Key: DEXSTXPKYXOQOB-UHFFFAOYSA-N
558:
506:
652:
606:
24:
432:. Carbonite was not detected when
25:
711:
586:in argon and nitrogen matrices".
33:
244:(at 25 °C , 100 kPa).
13:
1:
499:
7:
10:
716:
313:salts of carbonous acid,
238:
190:
137:
117:
92:
41:
32:
538:in inert-gas matrices".
473:coordinate covalent bond
105:InChI=1S/CO2/c2-1-3/q-2
490:Infrared spectroscopy
680:10.1039/FT9949001023
600:10.1021/ic00170a013
588:Inorganic Chemistry
552:10.1021/ja00350a025
174: g·mol
29:
646:10.1007/BF02069193
420:were favored over
397:, rather than the
248:Infobox references
191:Related compounds
27:
440:(with release of
256:Chemical compound
254:
253:
197:Related compounds
83:Interactive image
16:(Redirected from
707:
684:
683:
674:(7): 1023–1028.
659:
650:
649:
631:
630:
629:
617:
604:
603:
571:
556:
555:
515:
485:
431:
430:
429:
426:
419:
418:
417:
414:
368:
353:
338:
323:
308:
289:
288:
287:
284:
272:chemical formula
173:
160:
159:
158:
155:
145:Chemical formula
85:
61:
37:
30:
26:
21:
715:
714:
710:
709:
708:
706:
705:
704:
690:
689:
688:
687:
665:
660:
653:
628:
625:
624:
623:
621:
618:
607:
585:
581:
577:
572:
559:
537:
533:
529:
525:
521:
516:
507:
502:
484:
480:
465:magnesium oxide
457:carbon monoxide
442:carbon monoxide
427:
424:
423:
421:
415:
412:
411:
409:
367:
363:
359:
358:carbonite) and
352:
348:
344:
337:
333:
329:
322:
318:
314:
307:
303:
294:anion forms by
285:
282:
281:
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257:
250:
245:
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210:Carbon monoxide
198:
171:
156:
153:
152:
150:
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133:
130:
125:
124:
113:
110:
109:
106:
100:
99:
88:
75:
64:
51:
23:
22:
18:Carbonite (ion)
15:
12:
11:
5:
713:
703:
702:
686:
685:
663:
651:
626:
605:
594:(2): 177–183.
583:
579:
575:
557:
535:
531:
527:
523:
519:
504:
503:
501:
498:
494:bent structure
482:
365:
361:
350:
346:
335:
331:
320:
316:
305:
300:carbonous acid
255:
252:
251:
246:
242:standard state
239:
236:
235:
233:
232:
230:Carbonous acid
227:
222:
217:
215:Carbon dioxide
212:
207:
201:
199:
196:
193:
192:
188:
187:
182:
180:Conjugate acid
176:
175:
169:
163:
162:
148:
143:
140:
139:
135:
134:
132:
131:
128:
120:
119:
118:
115:
114:
112:
111:
107:
104:
103:
95:
94:
93:
90:
89:
87:
86:
78:
76:
69:
66:
65:
63:
62:
54:
52:
47:
44:
43:
39:
38:
28:Carbonite ion
9:
6:
4:
3:
2:
712:
701:
698:
697:
695:
681:
677:
673:
669:
658:
656:
647:
643:
639:
635:
616:
614:
612:
610:
601:
597:
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589:
570:
568:
566:
564:
562:
553:
549:
546:: 3886–3893.
545:
541:
514:
512:
510:
505:
497:
495:
491:
487:
478:
474:
470:
466:
462:
461:calcium oxide
458:
453:
451:
447:
443:
439:
435:
407:
402:
400:
396:
392:
388:
384:
380:
376:
372:
357:
342:
327:
312:
301:
297:
296:deprotonation
293:
280:
277:
273:
269:
265:
262:
249:
243:
237:
231:
228:
226:
223:
221:
218:
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202:
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183:
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149:
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136:
127:
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123:
116:
102:
101:
98:
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84:
80:
79:
77:
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68:
67:
60:
56:
55:
53:
50:
46:
45:
40:
36:
31:
19:
671:
667:
637:
633:
591:
587:
543:
539:
488:
454:
403:
343:carbonite),
328:carbonite),
311:Alkali metal
260:
258:
42:Identifiers
640:(1): 9–14.
479:structure,
395:formic acid
225:Bicarbonite
185:Bicarbonite
138:Properties
500:References
406:monovalent
387:protonated
167:Molar mass
70:3D model (
59:12709-62-5
49:CAS Number
700:Oxyanions
481:O=C=C(−O)
438:carbonate
379:lone pair
341:potassium
270:with the
261:carbonite
205:Carbonate
694:Category
530:, and Li
389:to form
356:rubidium
292:divalent
467:and on
446:oxalate
408:anions
399:carbene
391:formate
381:on the
371:caesium
326:lithium
290:. This
220:Oxalate
161:
477:ketene
450:oxygen
434:sodium
383:carbon
266:is an
172:44.009
122:SMILES
578:and M
522:, LiC
469:ceria
444:) or
304:C(OH)
268:anion
97:InChI
72:JSmol
463:and
393:and
259:The
676:doi
642:doi
596:doi
548:doi
544:183
459:on
309:).
298:of
264:ion
696::
672:90
670:.
654:^
638:34
636:.
622:CO
608:^
592:23
590:.
582:CO
560:^
542:.
534:CO
508:^
486:.
452:.
425:2−
422:CO
410:CO
401:.
364:CO
360:Cs
349:CO
345:Rb
334:CO
319:CO
315:Li
283:2−
154:2−
151:CO
129:()
682:.
678::
664:2
648:.
644::
627:2
602:.
598::
584:2
580:2
576:2
554:.
550::
536:2
532:2
528:4
526:O
524:2
520:2
483:2
428:2
416:2
413:−
375:K
369:(
366:2
362:2
354:(
351:2
347:2
339:(
336:2
332:2
330:K
324:(
321:2
317:2
306:2
302:(
286:2
279:O
276:C
157:2
74:)
20:)
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