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Hydrogen anion

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of stars like the Sun and cooler; its importance was first noted in the 1930s. The ion absorbs photons with energies in the range 0.75–4.0 eV, which ranges from the infrared into the visible spectrum. Most of the electrons in these negative ions come from the ionization of metals with low first
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Bryant, H. C.; Dieterle, B. D.; Donahue, J.; Sharifian, H.; Tootoonchi, H.; Wolfe, D. M.; Gram, P. A. M.; Yates-Williams, M. A. (1977). "Observation of Resonances near 11 eV in the Photodetachment Cross Section of the H Ion".
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The term hydride is probably most often used to describe compounds of hydrogen with other elements in which the hydrogen is in the formal −1
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that has captured an extra electron. The hydrogen anion is an important constituent of the atmosphere of
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This article is about the anion of hydrogen. For binary compounds of hydrogen with another element, see
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The binding energy of H equals the binding energy of an extra electron to a hydrogen atom, called
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Wildt, Rupert (1939). "Negative Ions of Hydrogen and the Opacity of Stellar Atmospheres".
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because the result is a neutral atom (rather than an ion) and a free electron.
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Bethe, H. (1929). "Berechnung der Elektronenaffinität des Wasserstoffs".
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Hill, R. N. (1977). "Proof that the H Ion Has Only One Bound State".
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Except where otherwise noted, data are given for materials in their
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H also occurs in the Earth's ionosphere and can be produced in
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in 1929. H is unusual because, in its free form, it has no
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source at visible and near-infrared wavelengths in the
843: 707:From White Dwarfs to Black Holes: The Legacy of 490:Its existence was first proven theoretically by 185: 84: 434:). The total ground state energy thus becomes 585:National Center for Biotechnology Information 577:"Hydride - PubChem Public Chemical Database" 704: 218: 148: 597: 214: 14: 844: 508:anion is hydrogen that has the formal 764: 663:Journal of Astrophysics and Astronomy 648: 646: 612: 462:ionization potentials, including the 246:Key: KLGZELKXQMTEMM-UHFFFAOYSA-N 128: 809: 705:Srinivasan, G. (1999). "Chapter 5". 401:to a nucleus containing one proton. 389:. In chemistry, this ion is called 652: 450:The hydrogen anion is the dominant 176: 24: 643: 408:of hydrogen. It is measured to be 25: 873: 501:, as was finally proven in 1977. 285: 43: 351:(at 25 °C , 100 kPa). 803: 758: 720: 698: 655:"The Negative Ion of Hydrogen" 606: 591: 569: 13: 1: 602:. W. H. Freeman. p. 102. 562: 445: 432:Electron affinity (data page) 7: 714:University of Chicago Press 553:, another very simple anion 538: 10: 878: 832:10.1103/PhysRevLett.38.643 752:10.1103/PhysRevLett.38.228 26: 345: 316: 272: 255: 230: 68: 56: 51: 42: 598:Mihalas, Dmitri (1978). 377:of hydrogen, that is, a 34:Negative ion of hydrogen 812:Physical Review Letters 731:Physical Review Letters 768:Zeitschrift für Physik 653:Rau, A. R. P. (1996). 616:Astrophysical Journal 485:particle accelerators 399:electromagnetic force 58:Systematic IUPAC name 824:1977PhRvL..38..643H 781:1929ZPhy...57..815B 744:1977PhRvL..38..228B 676:1996JApA...17..113R 629:1939ApJ....90..611W 600:Stellar Atmospheres 581:The PubChem Project 300: g·mol 39: 789:10.1007/BF01340659 775:(11–12): 815–821. 684:10.1007/BF02702300 504:In chemistry, the 355:Infobox references 37: 547:(hydrogen cation) 406:electron affinity 363:Chemical compound 361: 360: 199:CompTox Dashboard 110:Interactive image 16:(Redirected from 869: 852:Hydrogen physics 836: 835: 807: 801: 800: 762: 756: 755: 724: 718: 717: 709:S. Chandrasekhar 702: 696: 695: 659: 650: 641: 640: 610: 604: 603: 595: 589: 588: 573: 534: 533: 532: 441: 439: 429: 424: 418: 413: 337: 317:Thermochemistry 299: 287: 280:Chemical formula 223: 222: 207: 205: 189: 178: 162:Gmelin Reference 152: 132: 112: 88: 47: 40: 36: 21: 877: 876: 872: 871: 870: 868: 867: 866: 842: 841: 840: 839: 808: 804: 763: 759: 725: 721: 703: 699: 657: 651: 644: 611: 607: 596: 592: 575: 574: 570: 565: 541: 531: 528: 527: 526: 524: 517:oxidation state 510:oxidation state 477:photoionization 472:photodetachment 468:alkaline earths 448: 437: 435: 422: 420: 411: 409: 364: 357: 352: 341:108.96 J K mol 338: 335: 328: 325: 297: 282: 268: 263: 262: 251: 248: 247: 244: 238: 237: 226: 208: 201: 192: 179: 164: 155: 135: 115: 102: 91: 78: 64: 63: 38:Hydrogen anion 35: 32: 23: 22: 15: 12: 11: 5: 875: 865: 864: 859: 854: 838: 837: 802: 757: 719: 697: 670:(3): 113–145. 642: 637:10.1086/144125 605: 590: 567: 566: 564: 561: 560: 559: 554: 548: 540: 537: 529: 499:excited states 447: 444: 393:. The ion has 385:, such as the 368:hydrogen anion 362: 359: 358: 353: 349:standard state 346: 343: 342: 339: 333: 322: 319: 318: 314: 313: 308: 306:Conjugate acid 302: 301: 295: 289: 288: 283: 278: 275: 274: 270: 269: 267: 266: 258: 257: 256: 253: 252: 250: 249: 245: 243:InChI=1S/H/q-1 242: 241: 233: 232: 231: 228: 227: 225: 224: 211: 209: 197: 194: 193: 191: 190: 182: 180: 172: 169: 168: 165: 160: 157: 156: 154: 153: 145: 143: 137: 136: 134: 133: 125: 123: 117: 116: 114: 113: 105: 103: 96: 93: 92: 90: 89: 81: 79: 74: 71: 70: 66: 65: 61: 60: 54: 53: 49: 48: 33: 9: 6: 4: 3: 2: 874: 863: 860: 858: 855: 853: 850: 849: 847: 833: 829: 825: 821: 817: 813: 806: 798: 794: 790: 786: 782: 778: 774: 771:(in German). 770: 769: 761: 753: 749: 745: 741: 737: 733: 732: 723: 715: 711: 710: 701: 693: 689: 685: 681: 677: 673: 669: 665: 664: 656: 649: 647: 638: 634: 630: 626: 622: 618: 617: 609: 601: 594: 586: 582: 578: 572: 568: 558: 555: 552: 549: 546: 543: 542: 536: 522: 518: 513: 511: 507: 502: 500: 497: 493: 488: 486: 481: 479: 478: 473: 469: 465: 464:alkali metals 460: 456: 453: 443: 433: 428: 417: 407: 402: 400: 397:bound by the 396: 395:two electrons 392: 388: 384: 380: 379:hydrogen atom 376: 373: 369: 356: 350: 344: 340: 332: 327: 321: 320: 315: 312: 309: 307: 304: 303: 296: 294: 291: 290: 284: 281: 277: 276: 271: 265: 264: 261: 254: 240: 239: 236: 229: 221: 217: 216:DTXSID6075306 213: 212: 210: 200: 196: 195: 188: 184: 183: 181: 175: 171: 170: 166: 163: 159: 158: 151: 147: 146: 144: 142: 139: 138: 131: 127: 126: 124: 122: 119: 118: 111: 107: 106: 104: 100: 95: 94: 87: 83: 82: 80: 77: 73: 72: 67: 59: 55: 50: 46: 41: 30: 19: 857:Astrophysics 815: 811: 805: 772: 766: 760: 735: 729: 722: 706: 700: 667: 661: 620: 614: 608: 599: 593: 580: 571: 557:Hydrogen ion 514: 503: 489: 482: 475: 474:rather than 471: 449: 403: 390: 367: 365: 330: 69:Identifiers 818:(12): 643. 712:. Chicago: 521:borohydride 459:atmospheres 273:Properties 130:CHEBI:29239 18:Hydride ion 846:Categories 738:(5): 228. 563:References 492:Hans Bethe 452:bound-free 446:Occurrence 425:(62)  414:(19)  370:, H, is a 311:Dihydrogen 293:Molar mass 141:ChemSpider 97:3D model ( 86:12184-88-2 76:CAS Number 797:125100200 551:Electride 324:Std molar 692:56355519 539:See also 440: eV 372:negative 820:Bibcode 777:Bibcode 740:Bibcode 672:Bibcode 625:Bibcode 623:: 611. 583:. USA: 523:anion ( 506:hydride 455:opacity 436:−14.359 427:hartree 391:hydride 326:entropy 174:PubChem 62:Hydride 29:Hydride 862:Anions 795:  690:  545:Hydron 260:SMILES 187:166653 167:14911 150:145831 52:Names 793:S2CID 688:S2CID 658:(PDF) 496:bound 430:(see 421:0.027 410:0.754 383:stars 298:1.009 235:InChI 121:ChEBI 99:JSmol 512:−1. 466:and 423:7161 366:The 828:doi 785:doi 748:doi 680:doi 633:doi 535:). 487:. 438:888 419:or 412:195 387:Sun 375:ion 334:298 204:EPA 177:CID 848:: 826:. 816:38 814:. 791:. 783:. 773:57 746:. 736:38 734:. 686:. 678:. 668:17 666:. 660:. 645:^ 631:. 621:90 619:. 579:. 525:BH 442:. 416:eV 834:. 830:: 822:: 799:. 787:: 779:: 754:. 750:: 742:: 716:. 694:. 682:: 674:: 639:. 635:: 627:: 587:. 530:4 336:) 331:S 329:( 286:H 206:) 202:( 101:) 31:. 20:)

Index

Hydride ion
Hydride

Systematic IUPAC name
CAS Number
12184-88-2
JSmol
Interactive image
ChEBI
CHEBI:29239
ChemSpider
145831
Gmelin Reference
PubChem
166653
CompTox Dashboard
DTXSID6075306
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Conjugate acid
Dihydrogen
Std molar
entropy

standard state
Infobox references
negative
ion
hydrogen atom

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