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Ionic conductivity (solid state)

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In most solids, ions rigidly occupy fixed positions, strongly embraced by neighboring atoms or ions. In some solids, selected ions are highly mobile allowing ionic conduction. The mobility increases with temperature. Materials exhibiting this property are used in batteries. A well-known ion
155:) was found to have had extraordinary high ionic conductivity at temperatures above 147 Â°C, AgI changes into a phase that has an ionic conductivity of ~ 1 –1 cm. This high temperature phase of AgI is an example of a 241:
Lu, Xiaochuan; Xia, Guanguang; Lemmon, John P.; Yang, Zhenguo (2010). "Advanced materials for sodium-beta alumina batteries: Status, challenges and perspectives".
159:. The disordered structure of this solid allows the Ag ions to move easily. The present record holder for ionic conductivity is the related material 366: 292: 225: 17: 395: 359: 74: 385: 340: 310: 390: 352: 180: 116:
Ionic conduction in solids has been a subject of interest since the beginning of the 19th century.
98: 284: 61: 60:. The phenomenon is observed in solids and solutions. Ionic conduction is one mechanism of 250: 156: 105: 8: 254: 197: 172: 94: 288: 221: 125: 332: 276: 262: 258: 176: 32: 220:
Richard Turton. (2000).The Physics of Solids. New York:: Oxford University Press.
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that has channels through which sodium cations can hop. When this
202: 82: 90: 86: 57: 275: 52:) is a measure of a substance's tendency towards 377: 236: 234: 240: 360: 231: 367: 353: 67: 26: 175:in the search for a storage device for 14: 378: 56:. Ionic conduction is the movement of 124:are also obeyed in ionic solids like 120:established in 1839 that the laws of 319: 171:. β''-alumina was developed at the 24: 25: 407: 304: 323: 269: 263:10.1016/j.jpowsour.2009.11.120 214: 13: 1: 208: 339:. You can help Knowledge by 7: 186: 85:is complexed with a mobile 10: 412: 318: 111: 93:, it behaves as so-called 281:Chemistry of the Elements 279:; Earnshaw, Alan (1997). 243:Journal of Power Sources 396:Electrochemistry stubs 335:-related article is a 40: 285:Butterworth-Heinemann 277:Greenwood, Norman N. 181:sodium–sulfur battery 179:while developing the 97:. BASE is used as a 68:In crystalline solids 30: 157:superionic conductor 106:electrochemical cell 101:in several types of 77:("BASE"), a form of 73:conductive solid is 386:Physical quantities 255:2010JPS...195.2431L 198:Fast ion conductor 173:Ford Motor Company 147:). In 1921, solid 95:fast ion conductor 44:Ionic conductivity 41: 348: 347: 294:978-0-08-037941-8 177:electric vehicles 126:lead(II) fluoride 16:(Redirected from 403: 391:Electrochemistry 369: 362: 355: 333:electrochemistry 327: 320: 299: 298: 283:(2nd ed.). 273: 267: 266: 249:(9): 2431–2442. 238: 229: 218: 170: 154: 146: 134: 54:ionic conduction 51: 33:proton conductor 21: 18:Ion conductivity 411: 410: 406: 405: 404: 402: 401: 400: 376: 375: 374: 373: 316: 307: 302: 295: 287:. p. 800. 274: 270: 239: 232: 219: 215: 211: 189: 168: 164: 160: 152: 144: 140: 133: 129: 118:Michael Faraday 114: 79:aluminium oxide 70: 47: 23: 22: 15: 12: 11: 5: 409: 399: 398: 393: 388: 372: 371: 364: 357: 349: 346: 345: 328: 314: 313: 306: 305:External links 303: 301: 300: 293: 268: 230: 212: 210: 207: 206: 205: 200: 195: 193:Lattice energy 188: 185: 166: 162: 142: 137:silver sulfide 131: 113: 110: 69: 66: 37:electric field 9: 6: 4: 3: 2: 408: 397: 394: 392: 389: 387: 384: 383: 381: 370: 365: 363: 358: 356: 351: 350: 344: 342: 338: 334: 329: 326: 322: 321: 317: 312: 309: 308: 296: 290: 286: 282: 278: 272: 264: 260: 256: 252: 248: 244: 237: 235: 227: 226:0-19-850352-0 223: 217: 213: 204: 201: 199: 196: 194: 191: 190: 184: 182: 178: 174: 158: 150: 149:silver iodide 138: 127: 123: 119: 109: 107: 104: 100: 96: 92: 88: 84: 80: 76: 65: 63: 59: 55: 50: 45: 38: 34: 29: 19: 341:expanding it 330: 315: 280: 271: 246: 242: 216: 122:electrolysis 115: 71: 53: 48: 46:(denoted by 43: 42: 35:in a static 311:J Chem Phys 103:molten salt 75:β''-alumina 380:Categories 209:References 89:, such as 187:See also 165:[HgI 99:membrane 251:Bibcode 203:NASICON 112:History 83:ceramic 62:current 291:  224:  135:) and 331:This 337:stub 289:ISBN 222:ISBN 58:ions 259:doi 247:195 153:AgI 130:PbF 108:. 87:ion 64:. 382:: 257:. 245:. 233:^ 183:. 161:Ag 141:Ag 91:Na 31:A 368:e 361:t 354:v 343:. 297:. 265:. 261:: 253:: 228:. 169:] 167:4 163:2 151:( 145:S 143:2 139:( 132:2 128:( 49:λ 39:. 20:)

Index

Ion conductivity

proton conductor
electric field
ions
current
β''-alumina
aluminium oxide
ceramic
ion
Na
fast ion conductor
membrane
molten salt
electrochemical cell
Michael Faraday
electrolysis
lead(II) fluoride
silver sulfide
silver iodide
superionic conductor
Ford Motor Company
electric vehicles
sodium–sulfur battery
Lattice energy
Fast ion conductor
NASICON
ISBN
0-19-850352-0

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