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Iron boride

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FeB has zig-zag chains of boron atoms that are coordinated by seven iron atoms. Boron atoms have a slightly distorted mono-capped trigonal prismatic iron atom coordination and two boron atom neighbors. B-B single bond distance is 178 pm, Fe-B distance is 215–220 pm, and Fe-Fe distance is 240–272 pm.
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FeB is a soft ferromagnetic compound that becomes paramagnetic above ~325 °C (617 °F). In air, FeB powders begins to react with the ambient oxygen above 300 °C, though bulk FeB materials are expected to be stable in air to much higher temperatures. FeB is an extremely hard compound
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Iron based coatings recently gained attention for their mechanical, frictional, and corrosion resistant properties. As compared to the ceramic or cermet type of materials people have used before, iron based materials are relatively inexpensive, less strategic, and can be produced economically by
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FeB single crystal is taken by bond domains. Bond domains are parallel to the axis of easy magnetization and perpendicular to the axis of hard magnetization. The structure of closing domains is described as "rows and zigzags of asterisks". Its bond domains possess a distinguished direction in
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B. Some iron borides possess useful properties such as magnetism, electrical conductivity, corrosion resistance and extreme hardness. Some iron borides have found use as hardening coatings for iron. Iron borides have properties of
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B contains single boron atoms in square anti-prismatic iron atom coordination. Boron atoms are separated from each other and the shortest B-B distance is 213 pm. Fe-B distance is 218 pm and Fe-Fe distance is 240–272 pm.
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C) or crystalline boron, is sintered on the iron surface in a tetrafluoroborate flux to form the coatings. The boron atoms diffuse into the iron substrate between 1023 and 1373 K. They first form layers of
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resistance, and oxidation resistance. It is used in oil and gas refinery, chemical extraction, automotive, agricultural, stamping, textile extrusion and injection molding industries.
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B powders begin to react with the ambient oxygen above 400 °C. The high hardness of Fe2B (18.7 GPa or 1907 HV as measured by Vickers indentation) is why homogeneous Fe
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B and then form layers of FeB.The range of compounds and compositions formed depends on the reaction conditions including temperature and surrounding environment.
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Iron borides can be formed by thermochemically reacting boron rich compounds on an iron surface to form a mixture of iron borides, in a process known as
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Alyoshin, V.G. (1981). "Investigation of Composition and Chemical State of Elements in Iron Boride by the Method of X-Ray Photoelectron Spectroscopy".
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Bocarsly, Joshua D.; Levin, Emily E.; Humphrey, Samuel A.; Faske, Tom; Donner, Wolfgang; Wilson, Stephen D.; Seshadri, Ram (2019-07-09).
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Keddam, M; Chentouf, SM (2005). "A diffusion model for describing the bilayer growth (FeB/Fe2B) during the iron powder-pack boriding".
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Ma, Shengqiang; Huang, Zhifu; Xing, Jiandong; Liu, Guangzhu; He, Yaling; Fu, Hanguang; Wang, Yong; Li, Yefei; Yi, Dawei (2015-01-28).
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Zhdanova, O.V.; Lyakhova, M.B.; Pastushenkov, Y.G. (May 2013). "Magnetic Properties and Domain Structure of FeB Single Crystals".
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Carbucicchio, M.; Reverberi, R.; Palobarini, G.; Sambogna, G. (March 1989). "On the early stages of oxidation of iron borides".
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Joshi, A.A.; Hosmani, S.S. (2014). "Pack-Boronizing of AISI 4140 Steel: Boronizing Mechanism and the Role of Container Design".
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Lyakhova, M.B.; Pastushenkov, Y. G.; Zhdanova, O.V. (2013). "Magnetic Properties and Domain Structure of FeB Single Crystals".
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Bulk FeB can be formed by simple reaction between iron and boron in a high-temperature inert gas furnace or in a microwave.
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Gianoglio, C.; Badini, C. (1986). "Distribution equilibria of iron and nickel in two phase fields of the Fe-Ni-B system".
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B is a ferromagnetic compound that becomes paramagnetic at temperatures above 742 °C (1368 °F). In air, Fe
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Haynes, William M. Handbook of Chemistry and Physics (91 edition.). 2010, Boca Raton, Florida: CRC Press.
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Kapfenberger, C.; Albert, B.; Pottgen, R.; Huppertz, H. (2006). "Structure refinements of iron borides Fe
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Each trigonal prism shares two rectangular faces with the nearby prisms, forming infinite prism columns.
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Iron boride nanoparticles have been formed by reducing iron boride salts in highly coordinating
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Shigematsu, Toshihiko (1975-11-15). "Mössbauer and Structural Studies on (Fe 1- x Mn x ) 2 B".
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B layers are formed on top of iron or steel by boriding to make them more wear resistant.
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orientation of the boundaries of major domains with rhombic shape of closing domains.
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Dossett, Jon L.; Totten, George E., eds. (2013). "Boriding (Boronizing) of Metals".
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This article is about the well defined borides of iron. For the ferroalloy, see
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B were known to be interstitial in early studies. FeB is orthorhombic and Fe
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Except where otherwise noted, data are given for materials in their
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Except where otherwise noted, data are given for materials in their
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Natu, Varun; Kota, Sankalp S.; Barsoum, Michel W. (February 2020).
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various thermal methods with ease of fabrication and machining.
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B, but is more brittle and more easily fractured upon impact.
910: 537: 107: 1816: 970:. They have also been prepared by reducing iron salts using 196: 1101: 1399: 2789: 1481: 2390: 2015: 1395: 1393: 1151: 1390: 3734: 644: 178: 1355: 1182: 523: 511: 93: 85: 1718: 1446: 1320: 2963: 1871: 1567: 1026:B adopts body-centered tetragonal structure. 774:1,658 °C (3,016 °F; 1,931 K) 346:1,389 °C (2,532 °F; 1,662 K) 1013: 933: 2970: 2956: 1878: 1864: 1780:Friction, Lubrication, and Wear Technology 1675: 1571:Boriding (Boronizing) of Metals[1] 1226: 1224: 1222: 593: 581: 1373: 909:such as high hardness, and properties of 1678:Journal of the Physical Society of Japan 1316: 1314: 1782:. ASM International. pp. 653–660. 1574:. ASM International. pp. 709–724. 1440: 1362:Journal of the European Ceramic Society 1219: 212: 3735: 3011: 1773: 900:. Two main iron borides are FeB and Fe 3464: 2951: 1859: 1484:Materials and Manufacturing Processes 1311: 1288: 1286: 1155:CRC Handbook of Chemistry and Physics 1147: 1145: 1143: 1141: 1139: 1137: 685:Key: FSDZRQFSRALZQJ-UHFFFAOYSA-N 671:Key: ZDVYABSQRRRIOJ-UHFFFAOYSA-N 253:Key: FSDZRQFSRALZQJ-UHFFFAOYSA-N 243:Key: ZDVYABSQRRRIOJ-UHFFFAOYSA-N 634: 168: 13: 1885: 1375:10.1016/j.jeurceramsoc.2019.09.040 1283: 1134: 14: 3759: 2977: 1449:Journal of Solid State Chemistry 1233:Metal Science and Heat Treatment 1152:Haynes, William M., ed. (2011). 463: 29: 1810: 1774:Totten, George E., ed. (2017). 1767: 1712: 1669: 1622: 1561: 1510: 1475: 1092: 870:(at 25 °C , 100 kPa). 442:(at 25 °C , 100 kPa). 1349: 1267: 1176: 1: 1725:Journal of Materials Research 1655:10.1524/zkri.2006.221.5-7.477 1580:10.31399/asm.hb.v04a.a0005772 1418:10.1021/acs.chemmater.9b01476 1294:"Boriding / Boronizing (DHB)" 1128: 838: = 0.5506 nm, 834: = 0.4061 nm, 1788:10.31399/asm.hb.v18.a0006420 1496:10.1080/10426914.2014.921705 1469:10.1016/0022-4596(81)90478-3 1343:10.1016/j.apsusc.2005.01.016 1185:Journal of Materials Science 1018:The structures of FeB and Fe 957: 928: 7: 1111: 842: = 0.2952 nm 318:122.501 g/mol 10: 3764: 3466: 1085: 15: 3013: 2991: 2929: 2898: 2877: 2790:Organoiron(III) compounds 2554: 2519: 2498: 2071: 2051: 1999: 1928: 1893: 1839:10.1007/s11041-013-9581-0 1253:10.1007/s11041-013-9581-0 864: 790: 723: 694: 655: 494: 486: 476: 471: 462: 436: 362: 291: 262: 223: 64: 52: 42: 37: 28: 2391:Organoiron(II) compounds 1298:IBC Coating Technologies 1014:Structure and Properties 934:Thermochemical Formation 250:FeB: InChI=1S/B.2Fe 1078: 1046: 919:electrical conductivity 668:FeB: InChI=1S/B.Fe 410: = 0.511 nm, 406: = 0.511 nm, 1519:Hyperfine Interactions 1406:Chemistry of Materials 1029: 682:B: InChI=1S/B.2Fe 414: = 0.4249 nm 240:B: InChI=1S/B.Fe 2937:Hemolithin (protein) 1819:Met. Sci. Heat Treat 1745:10.1557/jmr.2014.383 1698:10.1143/JPSJ.39.1233 915:thermal conductivity 913:properties, such as 746:66.656 489:Iron monoboride, FeB 1831:2013MSHT...55...68Z 1737:2015JMatR..30..257M 1690:1975JPSJ...39.1233S 1647:2006ZK....221..477K 1531:1989HyInt..46..473C 1461:1981JSSCh..38..105A 1335:2005ApSS..252..393K 1245:2013MSHT...55...68Z 1197:1986JMatS..21.4331G 892:with the formula Fe 890:inorganic compounds 781:Solubility in water 615:FeB: 234-489-9 459: 353:Solubility in water 25: 1539:10.1007/BF02398233 1205:10.1007/BF01106551 972:sodium borohydride 968:sodium borohydride 888:refers to various 874:Infobox references 457: 446:Infobox references 23: 3730: 3729: 3724: 3723: 2945: 2944: 2873: 2872: 2494: 2493: 2047: 2046: 1797:978-1-62708-192-4 1589:978-1-62708-165-8 1412:(13): 4873–4881. 1191:(12): 4331–4334. 1158:(92nd ed.). 882:Chemical compound 880: 879: 798:Crystal structure 622:B: 234-490-4 562:Interactive image 550:Interactive image 454:Chemical compound 452: 451: 370:Crystal structure 326:refractory solid 192:CompTox Dashboard 156:B: 234-490-4 132:Interactive image 124:Interactive image 55:Diiron boride, Fe 3755: 2995: 2994: 2972: 2965: 2958: 2949: 2948: 2890: 2865: 2864: 2863: 2855: 2854: 2846: 2845: 2787: 2786: 2388: 2387: 2013: 2012: 1880: 1873: 1866: 1857: 1856: 1851: 1850: 1814: 1808: 1807: 1805: 1804: 1771: 1765: 1764: 1716: 1710: 1709: 1684:(5): 1233–1238. 1673: 1667: 1666: 1626: 1620: 1619: 1613: 1609: 1607: 1599: 1597: 1596: 1565: 1559: 1558: 1525:(1–4): 473–479. 1514: 1508: 1507: 1490:(9): 1062–1072. 1479: 1473: 1472: 1444: 1438: 1437: 1397: 1388: 1387: 1377: 1353: 1347: 1346: 1318: 1309: 1308: 1306: 1304: 1290: 1281: 1271: 1265: 1264: 1228: 1217: 1216: 1180: 1174: 1173: 1162:. p. 4.68. 1149: 1123:Iron tetraboride 1088:Iron tetraboride 825:Lattice constant 731:Chemical formula 648: 636: 608: 597: 585: 564: 552: 527: 515: 467: 460: 456: 397:Lattice constant 299:Chemical formula 216: 200: 198: 182: 170: 145: 134: 126: 97: 89: 33: 26: 22: 3763: 3762: 3758: 3757: 3756: 3754: 3753: 3752: 3733: 3732: 3731: 3726: 3725: 3695: 3684: 3662: 3657: 3655: 3647: 3642: 3640: 3632: 3627: 3625: 3617: 3612: 3610: 3602: 3597: 3595: 3587: 3582: 3580: 3572: 3567: 3565: 3557: 3549: 3544: 3542: 3531: 3526: 3524: 3516: 3511: 3509: 3501: 3496: 3494: 3486: 3481: 3479: 3370: 3362: 3354: 3350: 3342: 3334: 3326: 3321: 3319: 3308: 3265: 3251: 3243: 3235: 3225: 3187: 3182: 3179: 3171: 3167: 3159: 3155: 3150: 3148: 3129: 3121: 3111: 3106: 3104: 3079: 3071: 3066: 3064: 3056: 3006: 3002: 2987: 2986: 2976: 2946: 2941: 2925: 2921: 2913: 2909: 2894: 2889: 2885: 2869: 2862: 2859: 2858: 2857: 2853: 2850: 2849: 2848: 2844: 2841: 2840: 2839: 2837: 2832: 2828: 2824: 2820: 2812: 2808: 2804: 2800: 2785: 2780: 2776: 2772: 2768: 2760: 2756: 2748: 2744: 2740: 2732: 2728: 2720: 2716: 2712: 2704: 2700: 2692: 2688: 2684: 2680: 2672: 2668: 2664: 2656: 2652: 2648: 2644: 2636: 2614: 2606: 2602: 2589: 2581: 2573: 2565: 2550: 2546: 2542: 2534: 2530: 2515: 2490: 2486: 2482: 2478: 2470: 2466: 2462: 2454: 2450: 2446: 2442: 2438: 2434: 2425: 2421: 2417: 2409: 2405: 2401: 2386: 2382: 2378: 2370: 2366: 2362: 2354: 2350: 2346: 2338: 2334: 2330: 2326: 2318: 2314: 2310: 2306: 2298: 2294: 2286: 2278: 2270: 2262: 2258: 2250: 2246: 2238: 2230: 2226: 2222: 2214: 2210: 2202: 2188: 2184: 2180: 2176: 2172: 2164: 2151: 2138: 2130: 2122: 2118: 2110: 2102: 2094: 2090: 2082: 2067: 2062: 2043: 2040: 2036: 2032: 2028: 2011: 1995: 1991: 1987: 1983: 1979: 1975: 1971: 1963: 1959: 1951: 1947: 1939: 1924: 1920: 1916: 1908: 1904: 1889: 1884: 1854: 1815: 1811: 1802: 1800: 1798: 1772: 1768: 1717: 1713: 1674: 1670: 1632: 1627: 1623: 1611: 1610: 1601: 1600: 1594: 1592: 1590: 1566: 1562: 1515: 1511: 1480: 1476: 1445: 1441: 1398: 1391: 1354: 1350: 1323:Appl. Surf. Sci 1319: 1312: 1302: 1300: 1292: 1291: 1284: 1272: 1268: 1229: 1220: 1181: 1177: 1170: 1150: 1135: 1131: 1114: 1095: 1090: 1084: 1082: 1074: 1070: 1066: 1058: 1053: 1050: 1032: 1025: 1021: 1016: 1009: 1005: 1001: 997: 993: 989: 985: 981: 960: 950: 945: 936: 931: 924: 903: 899: 895: 883: 876: 871: 857: 843: 827: 815: 800: 783: 733: 719: 716: 714: 707: 702: 701: 690: 687: 686: 683: 681: 673: 672: 669: 663: 662: 651: 637: 625: 621: 600: 591: 567: 558: 541: 530: 521: 504: 490: 482: 455: 448: 443: 429: 415: 399: 390:I4/mc, No. 140 387: 372: 355: 307: 301: 287: 284: 279: 277: 270: 269: 258: 255: 254: 251: 245: 244: 241: 239: 231: 230: 219: 214:DTXSID401015517 210: 201: 194: 185: 171: 159: 155: 137: 120: 111: 100: 83: 74: 60: 58: 48: 21: 12: 11: 5: 3761: 3751: 3750: 3745: 3743:Iron compounds 3728: 3727: 3722: 3721: 3718: 3715: 3712: 3709: 3706: 3703: 3700: 3697: 3693: 3689: 3686: 3682: 3678: 3675: 3672: 3669: 3665: 3664: 3660: 3653: 3649: 3645: 3638: 3634: 3630: 3623: 3619: 3615: 3608: 3604: 3600: 3593: 3589: 3585: 3578: 3574: 3570: 3563: 3559: 3555: 3551: 3547: 3540: 3536: 3533: 3529: 3522: 3518: 3514: 3507: 3503: 3499: 3492: 3488: 3484: 3477: 3473: 3469: 3468: 3465: 3462: 3461: 3458: 3455: 3452: 3449: 3446: 3443: 3440: 3437: 3434: 3431: 3428: 3425: 3422: 3419: 3416: 3413: 3410: 3407: 3403: 3402: 3399: 3396: 3393: 3390: 3387: 3384: 3381: 3378: 3375: 3372: 3368: 3364: 3360: 3356: 3352: 3348: 3344: 3340: 3336: 3332: 3328: 3324: 3317: 3313: 3310: 3306: 3302: 3298: 3297: 3294: 3291: 3288: 3285: 3282: 3279: 3276: 3273: 3270: 3267: 3263: 3259: 3256: 3253: 3249: 3245: 3241: 3237: 3233: 3229: 3227: 3223: 3219: 3215: 3214: 3211: 3208: 3205: 3202: 3199: 3196: 3193: 3190: 3185: 3177: 3173: 3169: 3165: 3161: 3157: 3153: 3146: 3142: 3139: 3134: 3131: 3127: 3123: 3119: 3115: 3113: 3109: 3102: 3098: 3094: 3093: 3090: 3087: 3084: 3081: 3077: 3073: 3069: 3062: 3058: 3054: 3050: 3046: 3045: 3042: 3039: 3036: 3033: 3030: 3025: 3022: 3018: 3017: 3014: 3012: 3010: 3008: 3004: 3000: 2993: 2992: 2989: 2988: 2982: 2975: 2974: 2967: 2960: 2952: 2943: 2942: 2940: 2939: 2933: 2931: 2927: 2926: 2924: 2923: 2919: 2915: 2911: 2907: 2902: 2900: 2896: 2895: 2893: 2892: 2887: 2881: 2879: 2875: 2874: 2871: 2870: 2868: 2867: 2860: 2851: 2842: 2834: 2830: 2826: 2822: 2818: 2814: 2810: 2806: 2802: 2798: 2793: 2791: 2784: 2783: 2778: 2774: 2770: 2766: 2762: 2758: 2754: 2750: 2746: 2742: 2738: 2734: 2730: 2726: 2722: 2718: 2714: 2710: 2706: 2702: 2698: 2694: 2690: 2686: 2682: 2678: 2674: 2670: 2666: 2662: 2658: 2654: 2650: 2646: 2642: 2638: 2634: 2630: 2625: 2621: 2616: 2612: 2608: 2604: 2600: 2596: 2591: 2587: 2583: 2579: 2575: 2571: 2567: 2563: 2558: 2556: 2552: 2551: 2549: 2548: 2544: 2540: 2536: 2532: 2528: 2523: 2521: 2517: 2516: 2514: 2513: 2508: 2502: 2500: 2496: 2495: 2492: 2491: 2489: 2488: 2484: 2480: 2476: 2472: 2468: 2464: 2460: 2456: 2452: 2448: 2444: 2440: 2436: 2432: 2428: 2423: 2419: 2415: 2411: 2407: 2403: 2399: 2394: 2392: 2385: 2384: 2380: 2376: 2372: 2368: 2364: 2360: 2356: 2352: 2348: 2344: 2340: 2336: 2332: 2328: 2324: 2320: 2316: 2312: 2308: 2304: 2300: 2296: 2292: 2288: 2284: 2280: 2276: 2272: 2268: 2264: 2260: 2256: 2252: 2248: 2244: 2240: 2236: 2232: 2228: 2224: 2220: 2216: 2212: 2208: 2204: 2200: 2196: 2191: 2186: 2182: 2178: 2174: 2170: 2166: 2162: 2158: 2153: 2149: 2145: 2140: 2136: 2132: 2128: 2124: 2120: 2116: 2112: 2108: 2104: 2100: 2096: 2092: 2088: 2084: 2080: 2075: 2073: 2069: 2068: 2066: 2065: 2060: 2055: 2053: 2049: 2048: 2045: 2044: 2042: 2038: 2034: 2030: 2026: 2022: 2020: 2010: 2009: 2003: 2001: 1997: 1996: 1994: 1993: 1989: 1985: 1981: 1977: 1973: 1969: 1965: 1961: 1957: 1953: 1949: 1945: 1941: 1937: 1932: 1930: 1926: 1925: 1923: 1922: 1918: 1914: 1910: 1906: 1902: 1897: 1895: 1891: 1890: 1887:Iron compounds 1883: 1882: 1875: 1868: 1860: 1853: 1852: 1825:(1–2): 68–72. 1809: 1796: 1766: 1731:(2): 257–265. 1711: 1668: 1635:Z. Kristallogr 1630: 1621: 1588: 1560: 1509: 1474: 1455:(1): 105–111. 1439: 1389: 1368:(2): 305–314. 1348: 1329:(2): 393–399. 1310: 1282: 1279:978-1439820773 1266: 1239:(1–2): 68–72. 1218: 1175: 1169:978-1439855119 1168: 1132: 1130: 1127: 1126: 1125: 1120: 1113: 1110: 1094: 1091: 1086:Main article: 1083: 1080: 1077: 1072: 1068: 1064: 1056: 1052: 1048: 1045: 1031: 1028: 1023: 1019: 1015: 1012: 1011: 1010: 1007: 1003: 999: 995: 991: 987: 983: 979: 959: 956: 948: 943: 935: 932: 930: 927: 922: 901: 897: 893: 881: 878: 877: 872: 868:standard state 865: 862: 861: 858: 848: 845: 844: 830: 828: 823: 820: 819: 816: 811: 808: 807: 803:Orthorhombic, 801: 796: 793: 792: 788: 787: 784: 779: 776: 775: 772: 766: 765: 762: 756: 755: 752: 748: 747: 744: 738: 737: 734: 729: 726: 725: 721: 720: 718: 717: 712: 710: 708: 705: 697: 696: 695: 692: 691: 689: 688: 684: 679: 677: 676: 674: 670: 667: 666: 658: 657: 656: 653: 652: 650: 649: 640: 638: 630: 627: 626: 624: 623: 619: 616: 612: 610: 602: 601: 599: 598: 589: 586: 577: 575: 569: 568: 566: 565: 556: 553: 544: 542: 535: 532: 531: 529: 528: 519: 516: 507: 505: 500: 497: 496: 492: 491: 488: 484: 483: 480: 474: 473: 469: 468: 453: 450: 449: 444: 440:standard state 437: 434: 433: 430: 420: 417: 416: 402: 400: 395: 392: 391: 388: 383: 380: 379: 373: 368: 365: 364: 360: 359: 356: 351: 348: 347: 344: 338: 337: 334: 328: 327: 324: 320: 319: 316: 310: 309: 305: 302: 297: 294: 293: 289: 288: 286: 285: 282: 280: 275: 273: 265: 264: 263: 260: 259: 257: 256: 252: 249: 248: 246: 242: 237: 235: 234: 226: 225: 224: 221: 220: 218: 217: 208: 204: 202: 190: 187: 186: 184: 183: 174: 172: 164: 161: 160: 158: 157: 153: 149: 147: 139: 138: 136: 135: 127: 118: 114: 112: 105: 102: 101: 99: 98: 90: 81: 77: 75: 70: 67: 66: 62: 61: 56: 54: 50: 49: 46: 40: 39: 35: 34: 24:Diiron boride 9: 6: 4: 3: 2: 3760: 3749: 3746: 3744: 3741: 3740: 3738: 3719: 3716: 3713: 3710: 3707: 3704: 3701: 3698: 3696: 3690: 3687: 3685: 3679: 3676: 3673: 3670: 3667: 3666: 3663: 3656: 3650: 3648: 3641: 3635: 3633: 3626: 3620: 3618: 3611: 3605: 3603: 3596: 3590: 3588: 3581: 3575: 3573: 3566: 3560: 3558: 3552: 3550: 3543: 3537: 3534: 3532: 3525: 3519: 3517: 3510: 3504: 3502: 3495: 3489: 3487: 3480: 3474: 3471: 3470: 3463: 3459: 3456: 3453: 3450: 3447: 3444: 3441: 3438: 3435: 3432: 3429: 3426: 3423: 3420: 3417: 3414: 3411: 3408: 3405: 3404: 3400: 3397: 3394: 3391: 3388: 3385: 3382: 3379: 3376: 3373: 3371: 3365: 3363: 3357: 3355: 3345: 3343: 3337: 3335: 3329: 3327: 3320: 3314: 3311: 3309: 3303: 3300: 3299: 3295: 3292: 3289: 3286: 3283: 3280: 3277: 3274: 3271: 3268: 3266: 3260: 3257: 3254: 3252: 3246: 3244: 3238: 3236: 3230: 3228: 3226: 3220: 3217: 3216: 3212: 3209: 3206: 3203: 3200: 3197: 3194: 3191: 3189: 3181: 3174: 3172: 3162: 3160: 3149: 3143: 3140: 3138: 3135: 3132: 3130: 3124: 3122: 3116: 3114: 3112: 3105: 3099: 3096: 3095: 3091: 3088: 3085: 3082: 3080: 3074: 3072: 3065: 3059: 3057: 3051: 3048: 3047: 3043: 3040: 3037: 3034: 3031: 3029: 3026: 3023: 3020: 3019: 3015: 3009: 3007: 2997: 2996: 2990: 2985: 2980: 2973: 2968: 2966: 2961: 2959: 2954: 2953: 2950: 2938: 2935: 2934: 2932: 2928: 2922: 2916: 2914: 2904: 2903: 2901: 2897: 2891: 2883: 2882: 2880: 2876: 2866: 2835: 2833: 2815: 2813: 2795: 2794: 2792: 2788: 2782: 2763: 2761: 2751: 2749: 2735: 2733: 2723: 2721: 2707: 2705: 2695: 2693: 2675: 2673: 2659: 2657: 2639: 2637: 2631: 2629: 2626: 2624: 2622: 2620: 2617: 2615: 2609: 2607: 2597: 2595: 2592: 2590: 2584: 2582: 2576: 2574: 2568: 2566: 2560: 2559: 2557: 2553: 2547: 2537: 2535: 2525: 2524: 2522: 2518: 2512: 2509: 2507: 2504: 2503: 2501: 2497: 2487: 2473: 2471: 2457: 2455: 2429: 2427: 2412: 2410: 2396: 2395: 2393: 2389: 2383: 2373: 2371: 2357: 2355: 2341: 2339: 2321: 2319: 2301: 2299: 2289: 2287: 2281: 2279: 2273: 2271: 2265: 2263: 2253: 2251: 2241: 2239: 2233: 2231: 2217: 2215: 2205: 2203: 2197: 2195: 2192: 2190: 2167: 2165: 2159: 2157: 2154: 2152: 2146: 2144: 2141: 2139: 2133: 2131: 2125: 2123: 2113: 2111: 2105: 2103: 2097: 2095: 2085: 2083: 2077: 2076: 2074: 2070: 2064: 2057: 2056: 2054: 2050: 2041: 2023: 2021: 2019:(I) compounds 2018: 2014: 2008: 2005: 2004: 2002: 1998: 1992: 1966: 1964: 1954: 1952: 1942: 1940: 1934: 1933: 1931: 1927: 1921: 1911: 1909: 1899: 1898: 1896: 1892: 1888: 1881: 1876: 1874: 1869: 1867: 1862: 1861: 1858: 1848: 1844: 1840: 1836: 1832: 1828: 1824: 1820: 1813: 1799: 1793: 1789: 1785: 1781: 1777: 1770: 1762: 1758: 1754: 1750: 1746: 1742: 1738: 1734: 1730: 1726: 1722: 1715: 1707: 1703: 1699: 1695: 1691: 1687: 1683: 1679: 1672: 1664: 1660: 1656: 1652: 1648: 1644: 1640: 1636: 1625: 1617: 1605: 1591: 1585: 1581: 1577: 1573: 1572: 1564: 1556: 1552: 1548: 1544: 1540: 1536: 1532: 1528: 1524: 1520: 1513: 1505: 1501: 1497: 1493: 1489: 1485: 1478: 1470: 1466: 1462: 1458: 1454: 1450: 1443: 1435: 1431: 1427: 1423: 1419: 1415: 1411: 1407: 1403: 1396: 1394: 1385: 1381: 1376: 1371: 1367: 1363: 1359: 1352: 1344: 1340: 1336: 1332: 1328: 1324: 1317: 1315: 1299: 1295: 1289: 1287: 1280: 1276: 1270: 1262: 1258: 1254: 1250: 1246: 1242: 1238: 1234: 1227: 1225: 1223: 1214: 1210: 1206: 1202: 1198: 1194: 1190: 1186: 1179: 1171: 1165: 1161: 1157: 1156: 1148: 1146: 1144: 1142: 1140: 1138: 1133: 1124: 1121: 1119: 1116: 1115: 1109: 1105: 1103: 1099: 1089: 1076: 1061: 1044: 1040: 1036: 1027: 977: 976: 975: 973: 969: 965: 955: 952: 941: 926: 920: 916: 912: 908: 891: 887: 875: 869: 863: 859: 855: 851: 850:Formula units 847: 846: 841: 837: 833: 829: 826: 822: 821: 818:Pnma, No. 62 817: 814: 810: 809: 806: 802: 799: 795: 794: 789: 785: 782: 778: 777: 773: 771: 770:Melting point 768: 767: 763: 761: 758: 757: 753: 750: 749: 745: 743: 740: 739: 735: 732: 728: 727: 722: 709: 704: 703: 700: 693: 675: 665: 664: 661: 654: 647: 642: 641: 639: 633: 629: 628: 617: 614: 613: 611: 609: 604: 603: 596: 587: 584: 579: 578: 576: 574: 571: 570: 563: 554: 551: 546: 545: 543: 539: 534: 533: 526: 517: 514: 509: 508: 506: 503: 499: 498: 493: 485: 479: 475: 470: 466: 461: 447: 441: 435: 431: 427: 423: 422:Formula units 419: 418: 413: 409: 405: 401: 398: 394: 393: 389: 386: 382: 381: 378: 374: 371: 367: 366: 361: 357: 354: 350: 349: 345: 343: 342:Melting point 340: 339: 335: 333: 330: 329: 325: 322: 321: 317: 315: 312: 311: 303: 300: 296: 295: 290: 281: 272: 271: 268: 261: 247: 233: 232: 229: 222: 215: 206: 205: 203: 193: 189: 188: 181: 176: 175: 173: 167: 163: 162: 151: 150: 148: 146: 141: 140: 133: 128: 125: 116: 115: 113: 109: 104: 103: 96: 91: 88: 79: 78: 76: 73: 69: 68: 63: 51: 45: 41: 36: 32: 27: 19: 2983: 1822: 1818: 1812: 1801:. Retrieved 1779: 1769: 1728: 1724: 1714: 1681: 1677: 1671: 1641:(5–7): 477. 1638: 1634: 1633:B and FeB". 1624: 1593:. Retrieved 1570: 1563: 1522: 1518: 1512: 1487: 1483: 1477: 1452: 1448: 1442: 1409: 1405: 1365: 1361: 1351: 1326: 1322: 1301:. Retrieved 1297: 1269: 1236: 1232: 1188: 1184: 1178: 1154: 1106: 1096: 1093:Applications 1062: 1054: 1041: 1037: 1033: 1017: 961: 953: 937: 885: 884: 853: 839: 835: 831: 754:grey powder 495:Identifiers 487:Other names 458:Iron boride 425: 411: 407: 403: 375:Tetragonal, 65:Identifiers 53:Other names 1612:|work= 1303:17 November 1118:Boron steel 994:B + 6 B(OH) 886:Iron boride 813:Space group 751:Appearance 724:Properties 706:FeB: . 481:Iron boride 385:Space group 323:Appearance 292:Properties 283:FeB: # 47:Iron boride 3737:Categories 2520:Fe(II,III) 2017:Organoiron 1803:2020-03-08 1595:2020-03-08 1129:References 791:Structure 786:insoluble 742:Molar mass 736:FeB 715:B: .. 643:FeB: 580:FeB: 573:ChemSpider 547:FeB: 536:3D model ( 525:12006-85-8 513:12006-84-7 510:FeB: 502:CAS Number 478:IUPAC name 363:Structure 358:insoluble 314:Molar mass 278:B: .. 177:FeB: 129:FeB: 106:3D model ( 95:12006-84-7 92:FeB: 87:12006-85-8 72:CAS Number 44:IUPAC name 18:Ferroboron 2930:Purported 2499:Fe(0,III) 1847:136585232 1761:138979673 1753:0884-2914 1706:0031-9015 1614:ignored ( 1604:cite book 1547:0304-3843 1504:137130309 1434:197109775 1426:0897-4756 1384:204301968 1261:136585232 1160:CRC Press 958:Synthesis 929:Formation 607:EC Number 336:7.3 g/cm 144:EC Number 2829:⋅xFe⋅yNH 2611:Fe(acac) 2052:Fe(0,II) 1663:94924114 1555:93768377 1213:97916863 1112:See also 1098:Boriding 990:O → 2 Fe 982:+ 8 NaBH 964:solvents 940:boriding 907:ceramics 764:~7 g/cm 592:B: 559:B: 522:B: 308:B 211:B: 121:B: 84:B: 3748:Borides 3467:  2979:Borides 2628:FeO(OH) 2555:Fe(III) 1894:Fe(-II) 1827:Bibcode 1733:Bibcode 1686:Bibcode 1643:Bibcode 1527:Bibcode 1457:Bibcode 1331:Bibcode 1241:Bibcode 1193:Bibcode 760:Density 632:PubChem 595:4891846 332:Density 180:6336853 166:PubChem 2899:Fe(VI) 2878:Fe(IV) 2483:Fe(CO) 2467:Fe(CO) 2148:Fe(OH) 2115:Fe(ClO 2072:Fe(II) 1968:Fe(CO) 1936:Fe(CO) 1917:Fe(CO) 1905:Fe(CO) 1845:  1794:  1759:  1751:  1704:  1661:  1586:  1553:  1545:  1502:  1432:  1424:  1382:  1277:  1259:  1211:  1166:  1002:+ 4 Na 998:+ 25 H 978:4 FeSO 966:using 699:SMILES 472:Names 267:SMILES 38:Names 2918:BaFeO 2769:Fe(SO 2619:FeOCl 2599:Fe(NO 2422:)(CO) 2275:FeTiO 2267:FeMoO 2243:Fe(BF 2207:Fe(NO 2199:FeSeO 2177:Fe(SO 2033:FeCO) 2000:Fe(I) 1929:Fe(0) 1843:S2CID 1757:S2CID 1659:S2CID 1551:S2CID 1500:S2CID 1430:S2CID 1380:S2CID 1257:S2CID 1209:S2CID 986:+18 H 911:metal 660:InChI 646:82789 583:74711 538:JSmol 228:InChI 108:JSmol 2797:Fe(C 2777:·12H 2753:Fe(N 2713:(SeO 2665:(CrO 2633:FePO 2578:FeCl 2570:FeBr 2511:FeGe 2506:FeSi 2431:Fe(C 2414:Fe(C 2398:Fe(C 2379:(CO) 2323:Fe(C 2303:Fe(C 2283:FeCO 2255:FeCr 2235:FeSi 2194:FeSe 2161:FeSO 2127:FeBr 2107:FeCl 2037:(CO) 1960:(CO) 1948:(CO) 1792:ISBN 1749:ISSN 1702:ISSN 1616:help 1584:ISBN 1543:ISSN 1422:ISSN 1305:2014 1275:ISBN 1164:ISBN 1102:wear 917:and 377:tI12 3720:No 3717:Md 3714:Fm 3711:Es 3708:Cf 3705:Bk 3702:Cm 3699:Am 3692:PuB 3688:Np 3677:Pa 3674:Th 3671:Ac 3668:** 3659:YbB 3652:YbB 3644:TmB 3637:TmB 3629:ErB 3622:ErB 3614:HoB 3607:HoB 3599:DyB 3592:DyB 3584:TbB 3577:TbB 3569:GdB 3562:GdB 3554:EuB 3546:SmB 3539:SmB 3535:Pm 3528:NdB 3521:NdB 3513:PrB 3506:PrB 3498:CeB 3491:CeB 3483:LaB 3476:LaB 3460:Og 3457:Ts 3454:Lv 3451:Mc 3448:Fl 3445:Nh 3442:Cn 3439:Rg 3436:Ds 3433:Mt 3430:Hs 3427:Bh 3424:Sg 3421:Db 3418:Rf 3415:Lr 3412:** 3409:Ra 3406:Fr 3401:Rn 3398:At 3395:Po 3392:Bi 3389:Pb 3386:Tl 3383:Hg 3380:Au 3377:Pt 3374:Ir 3367:OsB 3359:ReB 3339:TaB 3331:HfB 3323:LuB 3316:LuB 3305:BaB 3301:Cs 3296:Xe 3290:Te 3287:Sb 3284:Sn 3281:In 3278:Cd 3275:Ag 3272:Pd 3269:Rh 3262:RuB 3258:Tc 3255:Mo 3248:NbB 3240:ZrB 3222:SrB 3218:Rb 3213:Kr 3210:Br 3207:Se 3204:As 3201:Ge 3198:Ga 3195:Zn 3192:Cu 3145:FeB 3141:Mn 3137:CrB 3126:TiB 3118:ScB 3108:CaB 3101:CaB 3092:Ar 3089:Cl 3076:SiB 3068:AlB 3061:AlB 3053:MgB 3049:Na 3044:Ne 3024:Be 3021:Li 3016:He 2910:FeO 2886:FeF 2856:FeO 2852:105 2741:(SO 2594:FeP 2586:FeF 2562:FeI 2439:P(C 2375:FeI 2359:FeC 2343:FeC 2291:FeC 2223:(PO 2185:·6H 2169:(NH 2156:FeS 2143:FeO 2135:FeI 2099:FeF 2091:FeH 2079:FeH 2007:FeH 1976:COC 1835:doi 1784:doi 1741:doi 1694:doi 1651:doi 1639:221 1576:doi 1535:doi 1492:doi 1465:doi 1414:doi 1370:doi 1339:doi 1327:252 1249:doi 1201:doi 1079:FeB 1030:FeB 805:oP8 635:CID 197:EPA 169:CID 3739:: 3681:UB 3472:* 3312:* 3293:I 3232:YB 3184:Ni 3176:Ni 3164:Co 3152:Fe 3133:V 3120:12 3097:K 3086:S 3083:P 3070:12 3041:F 3038:O 3035:N 3032:C 2843:54 2809:BF 2765:NH 2737:Fe 2725:Fe 2709:Fe 2697:Fe 2681:(C 2677:Fe 2661:Fe 2645:(P 2641:Fe 2539:Fe 2527:Fe 2369:14 2365:22 2361:12 2219:Fe 2087:Mg 2059:Fe 2025:(C 1972:CH 1962:12 1956:Fe 1944:Fe 1913:Na 1841:. 1833:. 1823:55 1821:. 1790:. 1778:. 1755:. 1747:. 1739:. 1729:30 1727:. 1723:. 1700:. 1692:. 1682:39 1680:. 1657:. 1649:. 1637:. 1608:: 1606:}} 1602:{{ 1582:. 1549:. 1541:. 1533:. 1523:46 1521:. 1498:. 1488:29 1486:. 1463:. 1453:38 1451:. 1428:. 1420:. 1410:31 1408:. 1404:. 1392:^ 1378:. 1366:40 1364:. 1360:. 1337:. 1325:. 1313:^ 1296:. 1285:^ 1255:. 1247:. 1237:55 1235:. 1221:^ 1207:. 1199:. 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Index

Ferroboron

IUPAC name
CAS Number
12006-85-8
12006-84-7
JSmol
Interactive image
Interactive image
EC Number
PubChem
6336853
CompTox Dashboard
DTXSID401015517
InChI
SMILES
Chemical formula
Molar mass
Density
Melting point
Solubility in water
Crystal structure
tI12
Space group
Lattice constant
Formula units
standard state
Infobox references

IUPAC name

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