33:
278:
177:
42:
599:
589:
594:
620:
624:
24:
881:
625:
1138:
in that the metal is treated with carbon monoxide to give a volatile gas. In the case of iron pentacarbonyl, the reaction is more sluggish. It is necessary to use iron sponge as the starting material, and harsher reaction conditions of 5â30 MPa of carbon monoxide and 150â200 °C. Similar to
623:
1752:
Brian E. Hanson; Kenton H. Whitmire (1990). "Exchange of axial and equatorial carbonyl groups in pentacoordinate metal carbonyls in the solid state. The variable temperature magic angle spinning carbon-13 NMR spectroscopy of iron pentacarbonyl, , and ".
956:
is a free-flowing, straw-colored liquid with a pungent odour. Older samples appear darker. This compound is a common precursor to diverse iron compounds, including many that are useful in small scale
1068:
and Langer in 1891 as "a somewhat viscous liquid of a pale-yellow colour." Samples were prepared by treatment of finely divided, oxide-free iron powder with carbon monoxide at room temperature.
569:
641:
1009:
fits this pattern with 8 valence electrons on Fe and five pairs of electrons provided by the CO ligands. Reflecting its symmetrical structure and charge neutrality, Fe(CO)
1150:
626:
3858:
1779:
Adams, R. D.; Barnard, T. S.; Cortopassi, J. E.; Wu, W.; Li, Z. "Platinum-ruthenium carbonyl cluster complexes" Inorganic
Syntheses 1998, volume 32, pp. 280-284.
1244:
and isocyanides can proceed to tetra- and pentasubstitution. These reactions are often induced with a catalyst or light. Illustrative is the synthesis of the
1691:
1652:
720:
1863:
Wildermuth, Egon; Stark, Hans; Friedrich, Gabriele; Ebenhöch, Franz Ludwig; KĂŒhborth, Brigitte; Silver, Jack; Rituper, Rafael (2000). "Iron
Compounds".
894:
1865:
1141:
114:
2131:
3297:
1555:
327:
3923:
1624:
is toxic, which is of concern because of its volatility (vapour pressure: 21 millimetres of mercury (2.8 kPa) at 20 °C). If
2951:
3684:
1471:. Receiving the greatest attention are complexes of the cyclohexadienes, the parent organic 1,4-dienes being available through the
648:
2205:
2758:
1982:
Keiter, R. L.; Keiter, E. A.; Boecker, C. A.; Miller, D. R.; Hecker, K. H. (1996). "Tricarbonylbis(Phosphine)Iron(0) Complexes".
1245:
3759:
3529:
2741:
889:
2352:
2136:. Fuels & Lubricants Division Conference, Society of Automotive Engineers. Baltimore, Maryland: environmentalhistory.org.
1491:
1550:
and commercially marketed under the trade names, âMotolinâ and âMonopolinâ. Two more modern alternative fuel additives are
2295:
1275:. The catalyst attacks a CO ligand, which labilizes another CO ligand toward substitution. The electrophilicity of Fe(CO)
3896:
3728:
3478:
3422:
3344:
1379:
3866:
1522:
with high quantum yield. Prolonged irradiation in gas phase may proceed to further CO detach until atomic Fe formation.
3775:
1882:
3496:
1999:
1946:
1844:
1736:
292:
4231:
3664:
3625:
3290:
1583:
901:
1925:
Therien, M. J.; Trogler, W. C. (1990). "Bis(Phosphine) Derivatives of Iron
Pentacarbonyl and Tetracarbonyl (Tri-
3991:
2938:
2786:
2091:
1444:
550:
4118:
3984:
3812:
3786:
3738:
3544:
3503:
3488:
32:
3617:
3586:
3559:
3124:
2240:
2037:"Nucleophilic Acylation with Disodium Tetracarbonylferrate: Methyl 7-Oxoheptanoate and Methyl 7-oxooctonoate"
1336:
634:
41:
3657:
2228:
2198:
1402:
225:
172:
4003:
3958:
3831:
3820:
3801:
3283:
2802:
2702:
1304:
1097:
855:
850:
835:
256:
1659:
for iron pentacarbonyl at 0.1 ppm (0.23 mg/m) over an eight-hour time-weighted average, and a
1435:, wherein two CO ligands have been replaced by two olefins. Many dienes undergo this reaction, notably
598:
4236:
3646:
3092:
2570:
2414:
1656:
1139:
the Mond process, sulfur acts as a catalyst. The crude iron pentacarbonyl is purified by distillation.
1075:
at 150 °C) as well as specialized, chemically resistant equipment (e.g. composed of copper-silver
744:
731:
4241:
3842:
2955:
2496:
1660:
1240:. Usually these ligands displace only one or two CO ligands, but certain acceptor ligands such as PF
2021:
1968:
3973:
3575:
1579:
1071:
Industrial synthesis of the compound requires relatively high temperatures and pressures (e.g. 175
840:
820:
671:
273:
1597:
inhibitor in oxygen based flames. A few hundred ppm of iron pentacarbonyl are known to reduce the
4062:
3794:
3752:
3144:
2968:
2191:
1422:
1346:, "tetracarbonylferrate" also called Collman's reagent. The dianion is isoelectronic with Ni(CO)
1036:
exhibits a relatively low rate of interchange between the axial and equatorial CO groups via the
810:
800:
588:
3947:
3605:
2283:
1382:
1189:, which captures a variety of ligands to give adducts. In the absence of trapping substrates,
825:
1079:). Preparation of the compound at the laboratory scale avoids these complications by using an
3916:
3635:
3552:
3522:
3510:
2147:
Lask, G.; Wagner, H. Gg. (1962). "Influence of additives on the velocity of laminar flames".
1083:
985:
845:
815:
805:
795:
581:
506:
54:
3966:
3676:
2866:
2442:
2344:
1645:
1608:âair flame by almost 50%. However due to its toxic nature it has not been used widely as a
1390:
860:
593:
234:
154:
90:
8:
3372:
2960:
2271:
1190:
981:
945:
830:
775:
80:
277:
176:
134:
3212:
3036:
2988:
2913:
2905:
2854:
2686:
2610:
2594:
2546:
2475:
2009:
1956:
1269:
518:
491:
3706:
3444:
3394:
3233:
3064:
3052:
2926:
2897:
2833:
2602:
2582:
2526:
2521:
2434:
2426:
2108:
2104:)-2-Methoxy-2,4-Cyclohexadien-1-yl]Iron(1+) Hexafluorophosphate(1â) from Anisole"
2069:
2041:
1995:
1942:
1878:
1840:
1732:
1629:
1515:
1483:
1268:). In addition to the photochemical route, substitution can also induced by NaOH or
1002:
958:
921:
769:
3711:
3449:
2946:
2889:
2670:
2650:
2630:
2618:
2534:
2488:
2483:
2454:
2406:
1987:
1934:
1907:
1870:
1812:
1780:
1762:
1722:
1714:
1535:
1118:
925:
466:
424:
350:
198:
3462:
3406:
3402:
3365:
3356:
3164:
3080:
3024:
2562:
2462:
2334:
1834:
1633:
1609:
1518:
and generating singlet and triplet coordinatively unsaturated intermediate Fe(CO)
1472:
1283:, so the nucleophilic catalyst, disengages and attacks another molecule of Fe(CO)
1161:
1090:
1061:
1037:
1026:
1014:
995:
977:
949:
684:
530:
2095:
2064:
2036:
1706:
1586:). It is famous as a chemical precursor for the synthesis of various iron-based
23:
3389:
3379:
3306:
3245:
3004:
2921:
2838:
2470:
2214:
1991:
1938:
1784:
1602:
1543:
1468:
1021:
adopts a trigonal bipyramidal structure with the Fe atom surrounded by five CO
973:
872:
455:
2162:
1687:
1017:; it is one of the most frequently encountered liquid metal complexes. Fe(CO)
708:
4225:
1874:
1839:. Vol. 2 (2nd ed.). New York: Academic Press. pp. 1743, 1751.
1567:
1563:
1440:
1436:
1157:
413:
403:
165:
3321:
3275:
2386:
1587:
1153:
in
Alabama have capacities of 9000 and 1500â2000 tonnes/year respectively.
1135:
1514:
absorbs light population and metal-to-CO charge transfer band inducing CO
1145:
reports that there are only three plants manufacturing pentacarbonyliron;
647:
1816:
1796:
1598:
1594:
1367:
1351:
1072:
1065:
992:
660:
1911:
1766:
1727:
1176:
633:
3264:
1718:
1575:
1225:
1208:
1165:
1029:
positions and two axially bound. The FeâCâO linkages are each linear.
970:
640:
435:
365:
145:
1134:
The industrial production of this compound is somewhat similar to the
2725:
1641:
1551:
1547:
1495:
1371:
1229:
245:
1800:
1156:
Most iron pentacarbonyl produced is decomposed on site to give pure
871:
Except where otherwise noted, data are given for materials in their
3454:
1295:
Most metal carbonyls can be halogenated. Thus, treatment of Fe(CO)
606:
2100:)-2,4-Cyclohexadien-1-one]iron and Tricarbonyl[(1,2,3,4,5-
1685:
1494:. This compound, called "Fp dimer" can be considered a hybrid of
113:
3384:
2183:
1751:
1605:
448:
443:
393:
185:
1862:
1625:
1539:
1531:
1300:
1237:
1233:
1080:
1044:
bands in the IR spectrum at 2034 and 2014 cm (gas phase).
1022:
936:
933:
2133:
Charles F. Kettering and the 1921 discovery of tetraethyl lead
1571:
1502:, although in terms of its reactivity, it resembles neither.
1475:. 1,4-Dienes isomerize to the 1,3-dienes upon complexation.
1386:
1076:
537:
209:
125:
103:
1898:
Wrighton, Mark (1974). "Photochemistry of Metal
Carbonyls".
261:
2169:. Centers for Disease Control and Prevention. April 4, 2011
1443:. One of the more historically significant derivatives is
1168:. Other uses of pentacarbonyliron are small in comparison.
1146:
1057:
929:
757:
383:
1981:
3117:
2718:
2343:
1578:
and for manufacture of the active ingredients of some
1692:
National
Institute for Occupational Safety and Health
1653:
National
Institute for Occupational Safety and Health
1177:
Decarbonylation and related CO substitution reactions
1047:
1566:", a finely divided form of Fe, a material used in
1593:Iron pentacarbonyl has been found to be a strong
1164:. Some iron pentacarbonyl is burned to give pure
984:with a metal. Other examples include octahedral
4223:
1704:
1628:, iron pentacarbonyl may cause lung irritation,
1129:
197:
1644:. It is, however, considerably less toxic than
751:TWA 0.1 ppm (0.23 mg/m) ST 0.2 ppm (0.45 mg/m)
622:
89:
1924:
1866:Ullmann's Encyclopedia of Industrial Chemistry
1711:Encyclopedia of Reagents for Organic Synthesis
1142:Ullmann's Encyclopedia of Industrial Chemistry
1064:. The compound was described in a journal by
3291:
2199:
3305:
2149:Eighth International Symposium on Combustion
2090:
1556:methylcyclopentadienyl manganese tricarbonyl
1505:
1836:Handbook of Preparative Inorganic Chemistry
408:â21.0 °C (â5.8 °F; 252.2 K)
3298:
3284:
2206:
2192:
2146:
1795:
1290:
276:
175:
153:
1858:
1856:
1726:
1534:, iron pentacarbonyl was once used as an
1401:. Acidification of solutions of gives
233:
2062:
2034:
1897:
1755:Journal of the American Chemical Society
1686:NIOSH Pocket Guide to Chemical Hazards.
378:straw-yellow to brilliant orange liquid
2129:
2123:
1828:
1826:
1615:
1246:bis(triphenylphosphine)iron tricarbonyl
272:
4224:
3331:
2167:NIOSH Pocket Guide to Chemical Hazards
1853:
1832:
1705:Samson, S.; Stephenson, G. R. (2004).
1681:
1679:
1677:
1675:
1357:
1203:Many compounds are derived from Fe(CO)
1040:. It is characterized by two intense Μ
418:103 °C (217 °F; 376 K)
166:
4107:
3279:
2187:
1713:. New York, NY: J. Wiley & Sons.
1636:. Like other metal carbonyls, Fe(CO)
1492:cyclopentadienyliron dicarbonyl dimer
679:49 °C (120 °F; 322 K)
304:Key: FYOFOKCECDGJBF-UHFFFAOYSA-N
133:
1823:
1773:
1056:is produced by the reaction of fine
665:â15 °C (5 °F; 258 K)
1672:
314:Key: FYOFOKCECDGJBF-UHFFFAOYAX
188:
13:
2213:
1986:. Vol. 31. pp. 210â214.
1663:at 0.2 ppm (0.45 mg/m).
1048:Synthesis and other iron carbonyls
618:
14:
4253:
2065:"Cyclobutadieneiron Tricarbonyl"
1933:. Vol. 28. pp. 173â9.
1416:
879:
597:
592:
587:
40:
31:
22:
2155:
2140:
2084:
2056:
2028:
1975:
1211:, L, to give derivatives Fe(CO)
875:(at 25 °C , 100 kPa).
1918:
1891:
1789:
1745:
1698:
1562:is used in the production of "
1445:cyclobutadieneiron tricarbonyl
1224:. Common Lewis bases include
551:Occupational safety and health
1:
2035:Finke, R. G.; Sorrell, T. N.
1666:
1525:
1279:L is less than that of Fe(CO)
1130:Industrial production and use
964:
725:(US health exposure limits):
564:Very toxic, highly flammable
2163:"Iron pentacarbonyl (as Fe)"
1570:of high-frequency coils for
1403:iron tetracarbonyl dihydride
1171:
1001:. Most metal carbonyls have
440:Soluble in organic solvents
7:
1378:with aqueous base produces
1305:iron tetracarbonyl diiodide
856:Tetrairidium dodecacarbonyl
851:Tetrarhodium dodecacarbonyl
836:Triruthenium dodecacarbonyl
697:or concentration (LD, LC):
10:
4258:
4109:
2118:, vol. 6, p. 996
2096:"Tricarbonyl[(2,3,4,5-
2079:, vol. 6, p. 310
2051:, vol. 6, p. 807
1992:10.1002/9780470132623.ch31
1939:10.1002/9780470132593.ch45
1929:-Butylphosphine)Iron(O)".
1785:10.1002/9780470132630.ch44
1657:recommended exposure limit
1510:Upon UV irradiation Fe(CO)
1467:is the otherwise unstable
1420:
370:195.90 g/mol
335:O=C=(=C=O)(=C=O)(=C=O)=C=O
3333:
3314:
3257:
3226:
3205:
3118:Organoiron(III) compounds
2882:
2847:
2826:
2399:
2379:
2327:
2256:
2221:
1709:. In Paquette, L. (ed.).
1661:short-term exposure limit
1580:radar absorbent materials
1506:CO substitution reactions
1207:by substitution of CO by
869:
781:
719:
693:
568:
548:
543:
484:
343:
323:
288:
73:
63:
53:
48:
39:
30:
21:
2719:Organoiron(II) compounds
1875:10.1002/14356007.a14_591
1427:Dienes react with Fe(CO)
1389:of this monoanion gives
1370:, but it is attacked by
969:Iron pentacarbonyl is a
841:Triosmium dodecacarbonyl
821:Dimanganese decacarbonyl
4232:Iron carbonyl complexes
2063:Pettit, R.; Henery, J.
1869:. Weinheim: Wiley-VCH.
1423:(Diene)iron_tricarbonyl
1291:Oxidation and reduction
1185:with UV produces Fe(CO)
1117:+ 10 Cu â 10
811:Seaborgium hexacarbonyl
801:Molybdenum hexacarbonyl
301:InChI=1S/5CO.Fe/c5*1-2;
2130:Kovarik, Bill (1994).
1833:Brauer, Georg (1963).
1374:. Treatment of Fe(CO)
826:Dirhenium decacarbonyl
629:
311:InChI=1/5CO.Fe/c5*1-2;
2094:; Chamberlain, K. B.
1799:; Langer, C. (1891).
1546:; it was produced by
1431:to give (diene)Fe(CO)
1181:Irradiation of Fe(CO)
846:Dicobalt octacarbonyl
816:Vanadium hexacarbonyl
806:Tungsten hexacarbonyl
796:Chromium hexacarbonyl
715:25 mg/kg (rat, oral)
628:
524:trigonal bipyramidal
512:trigonal bipyramidal
507:Coordination geometry
3265:Hemolithin (protein)
1817:10.1039/CT8915901090
1646:nickel tetracarbonyl
1616:Toxicity and hazards
1391:triiron dodecarbonyl
1003:18 valence electrons
861:Nickel tetracarbonyl
611:(fire diamond)
442:slightly soluble in
58:Pentacarbonyliron(0)
1984:Inorganic Syntheses
1931:Inorganic Syntheses
1912:10.1021/cr60290a001
1805:J. Chem. Soc. Trans
1801:"On iron carbonyls"
1767:10.1021/ja00159a011
1707:"Pentacarbonyliron"
1358:Acid-base reactions
1331:Reduction of Fe(CO)
980:is the only ligand
946:standard conditions
831:Diiron nonacarbonyl
425:Solubility in water
18:
17:Iron pentacarbonyl
1719:10.1002/047084289X
1385:intermediate. The
1383:metallacarboxylate
914:Iron pentacarbonyl
902:Infobox references
782:Related compounds
760:(Immediate danger)
630:
460:40 mmHg (30.6 °C)
66:Pentacarbonyl iron
16:
4237:Iron(0) compounds
4219:
4218:
4213:
4212:
3273:
3272:
3201:
3200:
2822:
2821:
2375:
2374:
2116:Collected Volumes
2109:Organic Syntheses
2077:Collected Volumes
2070:Organic Syntheses
2049:Collected Volumes
2042:Organic Syntheses
1630:toxic pneumonitis
1484:dicyclopentadiene
959:organic synthesis
910:Chemical compound
908:
907:
788:Related compounds
770:Safety data sheet
257:CompTox Dashboard
115:Interactive image
4249:
4242:Antiknock agents
3689:
3318:
3317:
3300:
3293:
3286:
3277:
3276:
3218:
3193:
3192:
3191:
3183:
3182:
3174:
3173:
3115:
3114:
2716:
2715:
2341:
2340:
2208:
2201:
2194:
2185:
2184:
2179:
2178:
2176:
2174:
2159:
2153:
2152:
2144:
2138:
2137:
2127:
2121:
2119:
2112:
2088:
2082:
2080:
2073:
2060:
2054:
2052:
2045:
2032:
2026:
2025:
2019:
2015:
2013:
2005:
1979:
1973:
1972:
1966:
1962:
1960:
1952:
1922:
1916:
1915:
1900:Chemical Reviews
1895:
1889:
1888:
1860:
1851:
1850:
1830:
1821:
1820:
1793:
1787:
1777:
1771:
1770:
1749:
1743:
1742:
1730:
1702:
1696:
1695:
1683:
1536:anti-knock agent
1473:Birch reductions
943:
916:, also known as
892:
886:
883:
882:
685:Explosive limits
650:
643:
636:
621:
601:
596:
591:
467:Refractive index
351:Chemical formula
281:
280:
265:
263:
237:
201:
190:
179:
168:
157:
137:
117:
93:
44:
35:
26:
19:
15:
4257:
4256:
4252:
4251:
4250:
4248:
4247:
4246:
4222:
4221:
4220:
4215:
4214:
4122:
4066:
4011:
4007:
3999:
3995:
3990:
3988:
3983:
3981:
3977:
3972:
3970:
3962:
3957:
3955:
3951:
3943:
3939:
3935:
3931:
3927:
3922:
3920:
3900:
3862:
3854:
3850:
3846:
3841:
3839:
3835:
3830:
3828:
3824:
3816:
3811:
3809:
3805:
3800:
3798:
3790:
3785:
3783:
3779:
3771:
3767:
3763:
3758:
3756:
3742:
3732:
3715:
3690:
3687:
3680:
3672:
3668:
3663:
3661:
3656:
3654:
3650:
3645:
3643:
3639:
3632:
3621:
3613:
3609:
3601:
3590:
3585:
3583:
3579:
3571:
3567:
3563:
3558:
3556:
3548:
3543:
3541:
3537:
3533:
3528:
3526:
3518:
3514:
3509:
3507:
3502:
3500:
3492:
3482:
3466:
3461:
3458:
3434:
3430:
3426:
3410:
3405:
3401:
3398:
3378:
3376:
3371:
3369:
3360:
3352:
3348:
3325:
3310:
3304:
3274:
3269:
3253:
3249:
3241:
3237:
3222:
3217:
3213:
3197:
3190:
3187:
3186:
3185:
3181:
3178:
3177:
3176:
3172:
3169:
3168:
3167:
3165:
3160:
3156:
3152:
3148:
3140:
3136:
3132:
3128:
3113:
3108:
3104:
3100:
3096:
3088:
3084:
3076:
3072:
3068:
3060:
3056:
3048:
3044:
3040:
3032:
3028:
3020:
3016:
3012:
3008:
3000:
2996:
2992:
2984:
2980:
2976:
2972:
2964:
2942:
2934:
2930:
2917:
2909:
2901:
2893:
2878:
2874:
2870:
2862:
2858:
2843:
2818:
2814:
2810:
2806:
2798:
2794:
2790:
2782:
2778:
2774:
2770:
2766:
2762:
2753:
2749:
2745:
2737:
2733:
2729:
2714:
2710:
2706:
2698:
2694:
2690:
2682:
2678:
2674:
2666:
2662:
2658:
2654:
2646:
2642:
2638:
2634:
2626:
2622:
2614:
2606:
2598:
2590:
2586:
2578:
2574:
2566:
2558:
2554:
2550:
2542:
2538:
2530:
2516:
2512:
2508:
2504:
2500:
2492:
2479:
2466:
2458:
2450:
2446:
2438:
2430:
2422:
2418:
2410:
2395:
2390:
2371:
2368:
2364:
2360:
2356:
2339:
2323:
2319:
2315:
2311:
2307:
2303:
2299:
2291:
2287:
2279:
2275:
2267:
2252:
2248:
2244:
2236:
2232:
2217:
2212:
2182:
2172:
2170:
2161:
2160:
2156:
2145:
2141:
2128:
2124:
2114:
2089:
2085:
2075:
2061:
2057:
2047:
2033:
2029:
2017:
2016:
2007:
2006:
2002:
1980:
1976:
1964:
1963:
1954:
1953:
1949:
1923:
1919:
1896:
1892:
1885:
1861:
1854:
1847:
1831:
1824:
1794:
1790:
1778:
1774:
1750:
1746:
1739:
1703:
1699:
1684:
1673:
1669:
1639:
1634:pulmonary edema
1623:
1618:
1610:flame retardant
1584:iron ball paint
1561:
1528:
1521:
1513:
1508:
1501:
1489:
1481:
1466:
1462:
1458:
1454:
1450:
1434:
1430:
1425:
1419:
1412:
1408:
1400:
1396:
1377:
1366:is not readily
1365:
1360:
1349:
1344:
1340:
1334:
1326:
1322:
1318:
1314:
1298:
1293:
1286:
1282:
1278:
1273:
1267:
1263:
1259:
1255:
1251:
1248:complex (Fe(CO)
1243:
1223:
1217:
1206:
1198:
1194:
1188:
1184:
1179:
1174:
1162:carbonyl nickel
1149:in Germany and
1132:
1124:
1121:+ 4 Fe(CO)
1116:
1112:
1105:
1101:
1094:
1062:carbon monoxide
1060:particles with
1055:
1050:
1043:
1038:Berry mechanism
1035:
1020:
1012:
1008:
999:
989:
978:carbon monoxide
967:
955:
942:
928:
911:
904:
899:
898:
897: ?)
888:
884:
880:
876:
865:
789:
761:
748:
735:
712:
706:
676:
673:
655:
654:
653:
652:
645:
638:
631:
627:
619:
584:
561:
533:
521:
519:Molecular shape
509:
500:
494:
480:1.5196 (20 °C)
477:
475:
446:
441:
427:
359:
353:
339:
336:
331:
330:
319:
316:
315:
312:
306:
305:
302:
296:
295:
284:
266:
259:
240:
220:
204:
191:
160:
140:
120:
107:
96:
83:
69:
67:
59:
12:
11:
5:
4255:
4245:
4244:
4239:
4234:
4217:
4216:
4211:
4210:
4207:
4204:
4201:
4198:
4195:
4192:
4189:
4186:
4183:
4180:
4177:
4174:
4171:
4168:
4164:
4163:
4160:
4157:
4154:
4151:
4148:
4145:
4142:
4139:
4136:
4133:
4130:
4127:
4124:
4120:
4116:
4112:
4111:
4108:
4105:
4104:
4101:
4098:
4095:
4092:
4089:
4086:
4083:
4080:
4077:
4074:
4071:
4068:
4064:
4060:
4057:
4054:
4051:
4048:
4045:
4041:
4040:
4037:
4034:
4031:
4028:
4025:
4022:
4019:
4016:
4013:
4009:
4005:
4001:
3997:
3993:
3986:
3979:
3975:
3968:
3964:
3960:
3953:
3949:
3945:
3941:
3937:
3933:
3929:
3925:
3918:
3914:
3911:
3908:
3905:
3902:
3898:
3894:
3890:
3889:
3886:
3883:
3880:
3877:
3874:
3871:
3868:
3864:
3860:
3856:
3852:
3848:
3844:
3837:
3833:
3826:
3822:
3818:
3814:
3807:
3803:
3796:
3792:
3788:
3781:
3777:
3773:
3769:
3765:
3761:
3754:
3750:
3747:
3744:
3740:
3736:
3734:
3730:
3726:
3722:
3721:
3718:
3713:
3709:
3704:
3701:
3698:
3695:
3692:
3686:
3682:
3678:
3674:
3670:
3666:
3659:
3652:
3648:
3641:
3637:
3633:
3631:
3630:
3623:
3619:
3615:
3611:
3607:
3603:
3599:
3594:
3592:
3588:
3581:
3577:
3573:
3569:
3565:
3561:
3554:
3550:
3546:
3539:
3535:
3531:
3524:
3520:
3516:
3512:
3505:
3498:
3494:
3490:
3486:
3484:
3480:
3476:
3472:
3471:
3468:
3464:
3456:
3452:
3447:
3442:
3439:
3436:
3432:
3428:
3424:
3420:
3416:
3415:
3412:
3408:
3396:
3392:
3387:
3382:
3374:
3367:
3363:
3358:
3354:
3350:
3346:
3342:
3338:
3337:
3334:
3332:
3330:
3328:
3323:
3316:
3315:
3312:
3311:
3307:Metal carbonyl
3303:
3302:
3295:
3288:
3280:
3271:
3270:
3268:
3267:
3261:
3259:
3255:
3254:
3252:
3251:
3247:
3243:
3239:
3235:
3230:
3228:
3224:
3223:
3221:
3220:
3215:
3209:
3207:
3203:
3202:
3199:
3198:
3196:
3195:
3188:
3179:
3170:
3162:
3158:
3154:
3150:
3146:
3142:
3138:
3134:
3130:
3126:
3121:
3119:
3112:
3111:
3106:
3102:
3098:
3094:
3090:
3086:
3082:
3078:
3074:
3070:
3066:
3062:
3058:
3054:
3050:
3046:
3042:
3038:
3034:
3030:
3026:
3022:
3018:
3014:
3010:
3006:
3002:
2998:
2994:
2990:
2986:
2982:
2978:
2974:
2970:
2966:
2962:
2958:
2953:
2949:
2944:
2940:
2936:
2932:
2928:
2924:
2919:
2915:
2911:
2907:
2903:
2899:
2895:
2891:
2886:
2884:
2880:
2879:
2877:
2876:
2872:
2868:
2864:
2860:
2856:
2851:
2849:
2845:
2844:
2842:
2841:
2836:
2830:
2828:
2824:
2823:
2820:
2819:
2817:
2816:
2812:
2808:
2804:
2800:
2796:
2792:
2788:
2784:
2780:
2776:
2772:
2768:
2764:
2760:
2756:
2751:
2747:
2743:
2739:
2735:
2731:
2727:
2722:
2720:
2713:
2712:
2708:
2704:
2700:
2696:
2692:
2688:
2684:
2680:
2676:
2672:
2668:
2664:
2660:
2656:
2652:
2648:
2644:
2640:
2636:
2632:
2628:
2624:
2620:
2616:
2612:
2608:
2604:
2600:
2596:
2592:
2588:
2584:
2580:
2576:
2572:
2568:
2564:
2560:
2556:
2552:
2548:
2544:
2540:
2536:
2532:
2528:
2524:
2519:
2514:
2510:
2506:
2502:
2498:
2494:
2490:
2486:
2481:
2477:
2473:
2468:
2464:
2460:
2456:
2452:
2448:
2444:
2440:
2436:
2432:
2428:
2424:
2420:
2416:
2412:
2408:
2403:
2401:
2397:
2396:
2394:
2393:
2388:
2383:
2381:
2377:
2376:
2373:
2372:
2370:
2366:
2362:
2358:
2354:
2350:
2348:
2338:
2337:
2331:
2329:
2325:
2324:
2322:
2321:
2317:
2313:
2309:
2305:
2301:
2297:
2293:
2289:
2285:
2281:
2277:
2273:
2269:
2265:
2260:
2258:
2254:
2253:
2251:
2250:
2246:
2242:
2238:
2234:
2230:
2225:
2223:
2219:
2218:
2215:Iron compounds
2211:
2210:
2203:
2196:
2188:
2181:
2180:
2154:
2139:
2122:
2083:
2055:
2027:
2018:|journal=
2000:
1974:
1965:|journal=
1947:
1917:
1906:(4): 401â430.
1890:
1884:978-3527306732
1883:
1852:
1845:
1822:
1788:
1772:
1761:(3): 974â977.
1744:
1737:
1697:
1670:
1668:
1665:
1637:
1621:
1617:
1614:
1603:stoichiometric
1568:magnetic cores
1559:
1544:tetraethyllead
1527:
1524:
1519:
1511:
1507:
1504:
1499:
1487:
1479:
1469:cyclobutadiene
1464:
1460:
1456:
1452:
1448:
1432:
1428:
1421:Main article:
1418:
1415:
1410:
1406:
1398:
1394:
1375:
1363:
1359:
1356:
1347:
1342:
1338:
1335:with Na gives
1332:
1329:
1328:
1324:
1320:
1316:
1312:
1296:
1292:
1289:
1284:
1280:
1276:
1271:
1265:
1261:
1257:
1253:
1249:
1241:
1219:
1212:
1204:
1196:
1192:
1186:
1182:
1178:
1175:
1173:
1170:
1160:in analogy to
1131:
1128:
1127:
1126:
1122:
1114:
1110:
1107:
1103:
1099:
1096:+ 4 CO â
1092:
1053:
1049:
1046:
1041:
1033:
1018:
1010:
1006:
997:
987:
974:metal carbonyl
966:
963:
953:
940:
909:
906:
905:
900:
878:
877:
873:standard state
870:
867:
866:
864:
863:
858:
853:
848:
843:
838:
833:
828:
823:
818:
813:
808:
803:
798:
792:
790:
787:
784:
783:
779:
778:
773:
766:
765:
762:
756:
753:
752:
749:
743:
740:
739:
736:
730:
727:
726:
717:
716:
713:
704:
702:
699:
698:
691:
690:
687:
681:
680:
677:
670:
667:
666:
663:
657:
656:
646:
639:
632:
617:
616:
615:
614:
612:
603:
602:
585:
580:
577:
576:
566:
565:
562:
559:
556:
555:
546:
545:
541:
540:
534:
529:
526:
525:
522:
517:
514:
513:
510:
505:
502:
501:
498:
495:
490:
487:
486:
482:
481:
478:
473:
465:
462:
461:
458:
456:Vapor pressure
452:
451:
438:
432:
431:
428:
423:
420:
419:
416:
410:
409:
406:
400:
399:
396:
390:
389:
386:
380:
379:
376:
372:
371:
368:
362:
361:
357:
354:
349:
346:
345:
341:
340:
338:
337:
334:
326:
325:
324:
321:
320:
318:
317:
313:
310:
309:
307:
303:
300:
299:
291:
290:
289:
286:
285:
283:
282:
269:
267:
255:
252:
251:
248:
242:
241:
239:
238:
230:
228:
222:
221:
219:
218:
214:
212:
206:
205:
203:
202:
194:
192:
184:
181:
180:
170:
162:
161:
159:
158:
150:
148:
142:
141:
139:
138:
130:
128:
122:
121:
119:
118:
110:
108:
101:
98:
97:
95:
94:
86:
84:
79:
76:
75:
71:
70:
65:
61:
60:
57:
51:
50:
46:
45:
37:
36:
28:
27:
9:
6:
4:
3:
2:
4254:
4243:
4240:
4238:
4235:
4233:
4230:
4229:
4227:
4208:
4205:
4202:
4199:
4196:
4193:
4190:
4187:
4184:
4181:
4178:
4175:
4172:
4169:
4166:
4165:
4161:
4158:
4155:
4152:
4149:
4146:
4143:
4140:
4137:
4134:
4131:
4128:
4125:
4123:
4117:
4114:
4113:
4106:
4102:
4099:
4096:
4093:
4090:
4087:
4084:
4081:
4078:
4075:
4072:
4069:
4067:
4061:
4058:
4055:
4052:
4049:
4046:
4043:
4042:
4038:
4035:
4032:
4029:
4026:
4023:
4020:
4017:
4014:
4012:
4002:
4000:
3989:
3982:
3971:
3965:
3963:
3956:
3946:
3944:
3921:
3915:
3912:
3909:
3906:
3903:
3901:
3895:
3892:
3891:
3887:
3884:
3881:
3878:
3875:
3872:
3869:
3867:
3865:
3863:
3857:
3855:
3840:
3829:
3819:
3817:
3810:
3799:
3793:
3791:
3784:
3774:
3772:
3757:
3751:
3748:
3745:
3743:
3737:
3735:
3733:
3727:
3724:
3723:
3719:
3717:
3710:
3708:
3705:
3702:
3699:
3696:
3693:
3691:
3683:
3681:
3675:
3673:
3662:
3655:
3644:
3634:
3629:
3628:
3624:
3622:
3616:
3614:
3604:
3602:
3596:
3595:
3593:
3591:
3584:
3574:
3572:
3557:
3551:
3549:
3542:
3527:
3521:
3519:
3508:
3501:
3495:
3493:
3487:
3485:
3483:
3477:
3474:
3473:
3469:
3467:
3460:
3453:
3451:
3448:
3446:
3443:
3440:
3437:
3435:
3421:
3418:
3417:
3413:
3411:
3404:
3400:
3393:
3391:
3388:
3386:
3383:
3381:
3377:
3370:
3364:
3362:
3355:
3353:
3343:
3340:
3339:
3335:
3329:
3327:
3320:
3319:
3313:
3308:
3301:
3296:
3294:
3289:
3287:
3282:
3281:
3278:
3266:
3263:
3262:
3260:
3256:
3250:
3244:
3242:
3232:
3231:
3229:
3225:
3219:
3211:
3210:
3208:
3204:
3194:
3163:
3161:
3143:
3141:
3123:
3122:
3120:
3116:
3110:
3091:
3089:
3079:
3077:
3063:
3061:
3051:
3049:
3035:
3033:
3023:
3021:
3003:
3001:
2987:
2985:
2967:
2965:
2959:
2957:
2954:
2952:
2950:
2948:
2945:
2943:
2937:
2935:
2925:
2923:
2920:
2918:
2912:
2910:
2904:
2902:
2896:
2894:
2888:
2887:
2885:
2881:
2875:
2865:
2863:
2853:
2852:
2850:
2846:
2840:
2837:
2835:
2832:
2831:
2829:
2825:
2815:
2801:
2799:
2785:
2783:
2757:
2755:
2740:
2738:
2724:
2723:
2721:
2717:
2711:
2701:
2699:
2685:
2683:
2669:
2667:
2649:
2647:
2629:
2627:
2617:
2615:
2609:
2607:
2601:
2599:
2593:
2591:
2581:
2579:
2569:
2567:
2561:
2559:
2545:
2543:
2533:
2531:
2525:
2523:
2520:
2518:
2495:
2493:
2487:
2485:
2482:
2480:
2474:
2472:
2469:
2467:
2461:
2459:
2453:
2451:
2441:
2439:
2433:
2431:
2425:
2423:
2413:
2411:
2405:
2404:
2402:
2398:
2392:
2385:
2384:
2382:
2378:
2369:
2351:
2349:
2347:(I) compounds
2346:
2342:
2336:
2333:
2332:
2330:
2326:
2320:
2294:
2292:
2282:
2280:
2270:
2268:
2262:
2261:
2259:
2255:
2249:
2239:
2237:
2227:
2226:
2224:
2220:
2216:
2209:
2204:
2202:
2197:
2195:
2190:
2189:
2186:
2168:
2164:
2158:
2150:
2143:
2135:
2134:
2126:
2117:
2111:
2110:
2105:
2103:
2099:
2093:
2087:
2078:
2072:
2071:
2066:
2059:
2050:
2044:
2043:
2038:
2031:
2023:
2011:
2003:
2001:9780470132623
1997:
1993:
1989:
1985:
1978:
1970:
1958:
1950:
1948:9780470132593
1944:
1940:
1936:
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1846:9780323161299
1842:
1838:
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1814:
1811:: 1090â1093.
1810:
1806:
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1782:
1776:
1768:
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1756:
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1738:9780471936237
1734:
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1600:
1596:
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1589:
1588:nanoparticles
1585:
1581:
1577:
1573:
1569:
1565:
1564:carbonyl iron
1557:
1553:
1549:
1545:
1541:
1537:
1533:
1523:
1517:
1503:
1497:
1493:
1485:
1476:
1474:
1470:
1446:
1442:
1441:1,3-butadiene
1438:
1437:norbornadiene
1424:
1417:Diene adducts
1414:
1404:
1392:
1388:
1384:
1380:
1373:
1369:
1355:
1353:
1345:
1310:
1309:
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1306:
1302:
1288:
1274:
1247:
1239:
1235:
1231:
1227:
1222:
1216:
1210:
1201:
1200:is produced.
1199:
1169:
1167:
1163:
1159:
1158:carbonyl iron
1154:
1152:
1148:
1144:
1143:
1137:
1120:
1109:5 Fe(CO)
1108:
1106:
1095:
1089:
1088:
1087:
1085:
1082:
1078:
1074:
1069:
1067:
1063:
1059:
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962:
960:
951:
947:
938:
935:
931:
927:
923:
919:
918:iron carbonyl
915:
903:
896:
891:
874:
868:
862:
859:
857:
854:
852:
849:
847:
844:
842:
839:
837:
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832:
829:
827:
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791:
786:
785:
780:
777:
774:
771:
768:
767:
763:
759:
755:
754:
750:
747:(Recommended)
746:
742:
741:
737:
734:(Permissible)
733:
729:
728:
724:
723:
718:
714:
710:
701:
700:
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692:
688:
686:
683:
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578:
574:
572:
567:
563:
558:
557:
553:
552:
547:
542:
539:
535:
532:
531:Dipole moment
528:
527:
523:
520:
516:
515:
511:
508:
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503:
496:
493:
489:
488:
483:
479:
472:
468:
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459:
457:
454:
453:
450:
447:insoluble in
445:
439:
437:
434:
433:
429:
426:
422:
421:
417:
415:
414:Boiling point
412:
411:
407:
405:
404:Melting point
402:
401:
397:
395:
392:
391:
387:
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382:
381:
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274:DTXSID3027746
271:
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258:
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211:
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187:
183:
182:
178:
174:
171:
169:
167:ECHA InfoCard
164:
163:
156:
152:
151:
149:
147:
144:
143:
136:
132:
131:
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127:
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109:
105:
100:
99:
92:
88:
87:
85:
82:
78:
77:
72:
68:Iron carbonyl
62:
56:
52:
47:
43:
38:
34:
29:
25:
20:
3626:
3597:
2263:
2173:November 19,
2171:. Retrieved
2166:
2157:
2148:
2142:
2132:
2125:
2115:
2107:
2101:
2097:
2092:Birch, A. J.
2086:
2076:
2068:
2058:
2048:
2040:
2030:
1983:
1977:
1930:
1926:
1920:
1903:
1899:
1893:
1864:
1835:
1808:
1804:
1791:
1775:
1758:
1754:
1747:
1728:10261/236866
1710:
1700:
1650:
1619:
1592:
1542:in place of
1529:
1509:
1477:
1426:
1361:
1352:nucleophilic
1330:
1294:
1228:, tertiary
1220:
1214:
1202:
1180:
1155:
1140:
1136:Mond process
1133:
1084:intermediate
1070:
1051:
1031:
1005:, and Fe(CO)
968:
917:
913:
912:
721:
694:
672:Autoignition
607:
570:
560:Main hazards
549:
470:
210:RTECS number
74:Identifiers
64:Other names
1599:flame speed
1595:flame speed
1576:televisions
1350:but highly
1226:isocyanides
1209:Lewis bases
1025:: three in
993:tetrahedral
709:median dose
695:Lethal dose
674:temperature
661:Flash point
554:(OHS/OSH):
492:Point group
398:1.453 g/cm
375:Appearance
344:Properties
173:100.033.323
135:CHEBI:30251
4226:Categories
3685:(Cu(CO)Cl)
2848:Fe(II,III)
2345:Organoiron
2151:: 432â438.
1667:References
1655:has set a
1526:Other uses
1516:photolysis
1498:and Fe(CO)
1482:reacts in
1381:, via the
1368:protonated
1230:phosphines
1166:iron oxide
1027:equatorial
971:homoleptic
965:Properties
689:3.7â12.5%
582:Pictograms
485:Structure
436:Solubility
430:Insoluble
366:Molar mass
235:6WQ62TAQ6Z
146:ChemSpider
102:3D model (
91:13463-40-6
81:CAS Number
55:IUPAC name
3665:HC(Co(CO)
3380:(HC=CH)CO
3373:(C=C)(CO)
3309:complexes
3258:Purported
2827:Fe(0,III)
2020:ignored (
2010:cite book
1967:ignored (
1957:cite book
1642:flammable
1558:. Fe(CO)
1552:ferrocene
1548:IG Farben
1496:ferrocene
1459:, where C
1387:oxidation
1372:hydroxide
1319:â Fe(CO)
1172:Reactions
982:complexed
920:, is the
776:ICSC 0168
573:labelling
246:UN number
217:NO4900000
3157:â
xFeâ
yNH
2939:Fe(acac)
2380:Fe(0,II)
1797:Mond, L.
1694:(NIOSH).
1486:to form
1015:volatile
976:, where
944:. Under
922:compound
764:0.4 ppm
608:NFPA 704
544:Hazards
4110:
3627:more...
2956:FeO(OH)
2883:Fe(III)
2222:Fe(-II)
1688:"#0345"
1626:inhaled
1606:methane
1455:)Fe(CO)
1238:alkenes
1234:arsines
1023:ligands
926:formula
895:what is
893: (
449:ammonia
444:alcohol
394:Density
360:
186:PubChem
4119:La(CO)
4063:Sg(CO)
3985:Os(CO)
3967:Os(CO)
3959:Re(CO)
3897:Ba(CO)
3859:Pd(CO)
3813:Ru(CO)
3795:Ru(CO)
3787:Tc(CO)
3768:Mo(CO)
3753:Mo(CO)
3729:Sr(CO)
3677:Ni(CO)
3658:Co(CO)
3618:Fe(CO)
3598:Fe(CO)
3587:Mn(CO)
3568:Cr(CO)
3553:Cr(CO)
3515:Ti(CO)
3504:Ti(CO)
3497:Ti(CO)
3489:Sc(CO)
3479:Ca(CO)
3463:(ClCO)
3403:H(CO)F
3227:Fe(VI)
3206:Fe(IV)
2811:Fe(CO)
2795:Fe(CO)
2476:Fe(OH)
2443:Fe(ClO
2400:Fe(II)
2296:Fe(CO)
2264:Fe(CO)
2245:Fe(CO)
2233:Fe(CO)
1998:
1945:
1881:
1843:
1735:
1620:Fe(CO)
1582:(e.g.
1572:radios
1540:petrol
1532:Europe
1478:Fe(CO)
1409:Fe(CO)
1362:Fe(CO)
1341:Fe(CO)
1311:Fe(CO)
1303:gives
1301:iodine
1236:, and
1098:Fe(CO)
1081:iodide
1077:alloys
1052:Fe(CO)
1032:Fe(CO)
996:Ni(CO)
986:Cr(CO)
890:verify
887:
772:(SDS)
388:musty
356:Fe(CO)
328:SMILES
49:Names
3917:W(CO)
3739:Y(CO)
3545:V(CO)
3538:V(CO)
3523:V(CO)
3407:(FCO)
3366:C(CO)
3246:BaFeO
3097:Fe(SO
2947:FeOCl
2927:Fe(NO
2750:)(CO)
2603:FeTiO
2595:FeMoO
2571:Fe(BF
2535:Fe(NO
2527:FeSeO
2505:Fe(SO
2361:FeCO)
2328:Fe(I)
2257:Fe(0)
1632:, or
1327:+ CO
1299:with
924:with
738:none
722:NIOSH
293:InChI
250:1994
199:26040
155:24254
126:ChEBI
104:JSmol
4008:(CO)
3996:(CO)
3978:(CO)
3952:(CO)
3940:(CO)
3851:(CO)
3836:(CO)
3825:(CO)
3806:(CO)
3780:(CO)
3707:SeCO
3651:(CO)
3640:(CO)
3610:(CO)
3580:(CO)
3431:(CO)
3423:Mg(O
3349:(CO)
3125:Fe(C
3105:·12H
3081:Fe(N
3041:(SeO
2993:(CrO
2961:FePO
2906:FeCl
2898:FeBr
2839:FeGe
2834:FeSi
2759:Fe(C
2742:Fe(C
2726:Fe(C
2707:(CO)
2651:Fe(C
2631:Fe(C
2611:FeCO
2583:FeCr
2563:FeSi
2522:FeSe
2489:FeSO
2455:FeBr
2435:FeCl
2365:(CO)
2288:(CO)
2276:(CO)
2175:2013
2022:help
1996:ISBN
1969:help
1943:ISBN
1927:tert
1879:ISBN
1841:ISBN
1733:ISBN
1651:The
1574:and
1554:and
1439:and
1397:(CO)
1393:, Fe
1315:+ I
1270:NaBH
1252:(P(C
1232:and
1195:(CO)
1147:BASF
1125:+ Fe
1066:Mond
1058:iron
991:and
758:IDLH
384:Odor
226:UNII
4209:No
4206:Md
4203:Fm
4200:Es
4197:Cf
4194:Bk
4191:Cm
4188:Am
4185:Pu
4182:Np
4176:Pa
4173:Th
4170:Ac
4167:**
4162:Yb
4159:Tm
4156:Er
4153:Ho
4150:Dy
4147:Tb
4144:Gd
4141:Eu
4138:Sm
4135:Pm
4132:Nd
4129:Pr
4126:Ce
4103:Og
4100:Ts
4097:Lv
4094:Mc
4091:Fl
4088:Nh
4085:Cn
4082:Rg
4079:Ds
4076:Mt
4073:Hs
4070:Bh
4059:Db
4056:Rf
4053:Lr
4050:**
4047:Ra
4044:Fr
4039:Rn
4036:At
4033:Po
4030:Bi
4027:Pb
4024:Tl
4021:Hg
4018:Au
4015:Pt
3913:Ta
3910:Hf
3907:Lu
3893:Cs
3888:Xe
3882:Te
3879:Sb
3876:Sn
3873:In
3870:Cd
3749:Nb
3746:Zr
3725:Rb
3720:Kr
3703:As
3700:Ge
3697:Ga
3694:Zn
3470:Ar
3450:SCO
3445:PCO
3441:Si
3438:Al
3419:Na
3414:Ne
3390:OCO
3385:NCO
3361:BCO
3341:Li
3336:He
3238:FeO
3214:FeF
3184:FeO
3180:105
3069:(SO
2922:FeP
2914:FeF
2890:FeI
2767:P(C
2703:FeI
2687:FeC
2671:FeC
2619:FeC
2551:(PO
2513:·6H
2497:(NH
2484:FeS
2471:FeO
2463:FeI
2427:FeF
2419:FeH
2407:FeH
2335:FeH
2304:COC
1988:doi
1935:doi
1908:doi
1871:doi
1813:doi
1781:doi
1763:doi
1759:112
1723:hdl
1715:doi
1640:is
1601:of
1538:in
1530:In
1405:, H
1307::
1151:GAF
1119:CuI
1091:FeI
1073:atm
1013:is
948:Fe(
745:REL
732:PEL
571:GHS
262:EPA
189:CID
4228::
4179:U
4115:*
4010:12
4004:Ir
3998:10
3992:Os
3980:12
3974:Os
3954:10
3948:Re
3924:(C
3904:*
3885:I
3847:Cl
3843:Rh
3838:16
3832:Rh
3827:12
3821:Rh
3808:12
3802:Ru
3782:10
3776:Tc
3716:CO
3712:Br
3653:12
3647:Co
3636:Co
3612:12
3606:Fe
3582:10
3576:Mn
3511:Cp
3475:K
3459:CO
3455:Cl
3399:CO
3345:Be
3326:CO
3171:54
3137:BF
3093:NH
3065:Fe
3053:Fe
3037:Fe
3025:Fe
3009:(C
3005:Fe
2989:Fe
2973:(P
2969:Fe
2867:Fe
2855:Fe
2697:14
2693:22
2689:12
2547:Fe
2415:Mg
2387:Fe
2353:(C
2300:CH
2290:12
2284:Fe
2272:Fe
2241:Na
2165:.
2113:;
2106:.
2074:;
2067:.
2046:;
2039:.
2014::
2012:}}
2008:{{
1994:.
1961::
1959:}}
1955:{{
1941:.
1904:74
1902:.
1877:.
1855:^
1825:^
1809:59
1807:.
1803:.
1757:.
1731:.
1721:.
1690:.
1674:^
1648:.
1612:.
1590:.
1490:,
1447:(C
1413:.
1399:12
1354:.
1337:Na
1287:.
1213:5â
1191:Fe
1086::
1042:CO
961:.
950:CO
930:Fe
705:50
703:LD
575::
536:0
499:3h
4121:8
4065:6
4006:4
3994:3
3987:4
3976:3
3969:5
3961:5
3950:2
3942:6
3938:2
3936:W
3934:2
3932:)
3930:5
3928:H
3926:5
3919:6
3899:8
3861:4
3853:2
3849:2
3845:2
3834:6
3823:4
3815:4
3804:3
3797:5
3789:5
3778:2
3770:3
3766:8
3764:H
3762:7
3760:C
3755:6
3741:8
3731:8
3714:2
3688:n
3679:4
3671:3
3669:)
3667:3
3660:4
3649:4
3642:8
3638:2
3620:4
3608:3
3600:5
3589:5
3578:2
3570:3
3566:6
3564:H
3562:6
3560:C
3555:6
3547:6
3540:4
3536:5
3534:H
3532:5
3530:C
3525:6
3517:2
3513:2
3506:6
3499:7
3491:8
3481:8
3465:2
3457:2
3433:2
3429:2
3427:)
3425:3
3409:2
3397:2
3395:F
3375:2
3368:2
3359:3
3357:H
3351:4
3347:2
3324:2
3322:H
3299:e
3292:t
3285:v
3248:4
3240:4
3236:2
3234:K
3216:4
3189:6
3175:H
3166:C
3159:3
3155:7
3153:O
3151:8
3149:H
3147:6
3145:C
3139:4
3135:2
3133:)
3131:5
3129:H
3127:5
3109:O
3107:2
3103:2
3101:)
3099:4
3095:4
3087:3
3085:)
3083:3
3075:3
3073:)
3071:4
3067:2
3059:3
3057:S
3055:2
3047:3
3045:)
3043:3
3039:2
3031:3
3029:O
3027:2
3019:3
3017:)
3015:4
3013:O
3011:2
3007:2
2999:3
2997:)
2995:4
2991:2
2983:3
2981:)
2979:7
2977:O
2975:2
2971:4
2963:4
2941:3
2933:3
2931:)
2929:3
2916:3
2908:3
2900:3
2892:3
2873:4
2871:S
2869:3
2861:4
2859:O
2857:3
2813:3
2809:6
2807:H
2805:4
2803:C
2797:3
2793:4
2791:H
2789:4
2787:C
2781:2
2779:)
2777:2
2775:)
2773:5
2771:H
2769:6
2765:4
2763:H
2761:5
2754:I
2752:2
2748:5
2746:H
2744:5
2736:2
2734:)
2732:5
2730:H
2728:5
2709:4
2705:2
2695:O
2691:H
2681:7
2679:O
2677:6
2675:H
2673:6
2665:2
2663:)
2661:3
2659:O
2657:5
2655:H
2653:3
2645:2
2643:)
2641:2
2639:O
2637:3
2635:H
2633:2
2625:4
2623:O
2621:2
2613:3
2605:3
2597:4
2589:4
2587:O
2585:2
2577:2
2575:)
2573:4
2565:2
2557:2
2555:)
2553:4
2549:3
2541:2
2539:)
2537:3
2529:4
2517:O
2515:2
2511:2
2509:)
2507:4
2503:2
2501:)
2499:4
2491:4
2478:2
2465:2
2457:2
2449:2
2447:)
2445:4
2437:2
2429:2
2421:6
2417:2
2409:2
2391:C
2389:3
2367:2
2363:2
2359:5
2357:H
2355:5
2318:6
2316:H
2314:6
2312:C
2310:2
2308:H
2306:2
2302:3
2298:3
2286:3
2278:9
2274:2
2266:5
2247:4
2243:2
2235:4
2231:2
2229:H
2207:e
2200:t
2193:v
2177:.
2120:.
2102:η
2098:η
2081:.
2053:.
2024:)
2004:.
1990::
1971:)
1951:.
1937::
1914:.
1910::
1887:.
1873::
1849:.
1819:.
1815::
1783::
1769:.
1765::
1741:.
1725::
1717::
1638:5
1622:5
1560:5
1520:4
1512:5
1500:5
1488:2
1480:5
1465:4
1463:H
1461:4
1457:3
1453:4
1451:H
1449:4
1433:3
1429:5
1411:4
1407:2
1395:3
1376:5
1364:5
1348:4
1343:4
1339:2
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1197:9
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1187:4
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1111:4
1104:2
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1100:4
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937:O
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649:1
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635:4
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471:n
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358:5
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