38:
300:
191:
28:
596:
699:
54:
791:
704:
703:
1204:
Even, J.; Yakushev, A.; Dullmann, C. E.; Haba, H.; Asai, M.; Sato, T. K.; Brand, H.; Di Nitto, A.; Eichler, R.; Fan, F. L.; Hartmann, W.; Huang, M.; Jager, E.; Kaji, D.; Kanaya, J.; Kaneya, Y.; Khuyagbaatar, J.; Kindler, B.; Kratz, J. V.; Krier, J.; Kudou, Y.; Kurz, N.; Lommel, B.; Miyashita, S.;
702:
604:
576:
1017:. The two piperidine ligands in this yellow-colored compound are labile, which allows other ligands to be introduced under mild conditions. For instance, the reaction of with
670:
1570:
Feldmann, J.; Cullen, W. R. (1997). "Occurrence of
Volatile Transition Metal Compounds in Landfill Gas: Synthesis of Molybdenum and Tungsten Carbonyls in the Environment".
1398:
889:. As described in a 2023 survey of methods "most cost-effective routes for the synthesis of group 6 hexacarbonyls are based on the reduction of the metal chlorides (CrCl
705:
128:
1599:
Feldmann, J.; Grümping, R.; Hirner, A. V. (1994). "Determination of
Volatile Metal and Metalloid Compounds in Gases from Domestic Waste Deposits with GC/ICP-MS".
874:" compound. Usually, organometallic indicates the presence of a metal directly bonded via a M–C bond to an organic fragment, which must in turn have a C–H bond.
1769:
1914:
804:
37:
1205:
Morimoto, K.; Morita, K.; Murakami, M.; Nagame, Y.; Nitsche, H.; et al. (2014). "Synthesis and detection of a seaborgium carbonyl complex".
727:
1649:
1365:
339:
27:
720:
799:
1091:
545:
1409:
518:
885:
is generally prepared by "reductive carbonylation", which involves reduction of a metal halide with under an atmosphere of
1106:
technique - it is easily vaporized and decomposed by the electron beam providing a convenient source of molybdenum atoms.
2045:
1328:
1491:
Randolph, S. J.; Fowlkes, J. D.; Rack, P. D. (2006). "Focused, Nanoscale
Electron-Beam-Induced Deposition and Etching".
1781:
1642:
870:
radiating from the central Mo atom. A recurring minor debate in some chemical circles concerns the definition of an "
1475:
1261:"Group 6 Carbonyl Complexes of N,O,P-Ligands as Precursors of High-Valent Metal-Oxo Catalysts for Olefin Epoxidation"
1188:
314:
234:
1539:
2035:
1438:
Derivatives (L = Group 5a Ligand) and a
Qualitative Study of Their Thermal Reactivity toward Ligand Dissociation".
1103:
811:
1086:
gives and anions, respectively. These anions react with a variety of electrophiles. A related source of Mo(CO)
1382:
2050:
1991:
1979:
1635:
1440:
713:
76:
652:
186:
2040:
1971:
1963:
278:
666:
1074:
also can be converted to its tris(acetonitrile) derivative. The compound serves as a source of "Mo(CO)
53:
1326:
in Sewage Gas by Using
Cryotrapping Gas Chromatography Inductively Coupled Plasma Mass Spectrometry".
850:
analogues, is noteworthy as a volatile, air-stable derivative of a metal in its zero oxidation state.
745:
1363:
Faller, J. W.; Brummond, K. M.; Mitasev, B. (2006). "Hexacarbonylmolybdenum". In
Paquette, L. (ed.).
953:
198:
1158:
295:
1821:
1797:
1753:
1083:
228:
1157:
Faller, John W.; Brummond, Kay M.; Mitasev, Branko (15 September 2006). "Hexacarbonylmolybdenum".
2003:
1955:
1829:
1745:
1710:
1680:
847:
772:
1906:
1898:
1869:
1861:
1813:
1761:
1702:
168:
2011:
1879:
1853:
1726:
1718:
843:
839:
768:
762:
618:
588:
489:
66:
1845:
1658:
1579:
1500:
1214:
595:
104:
8:
1947:
1029:
1018:
964:
863:
94:
1583:
1504:
1218:
1139:
299:
190:
148:
1837:
1616:
1516:
1292:
1238:
1079:
1259:
Bruno, Sofia M.; Valente, Anabela A.; Gonçalves, Isabel S.; Pillinger, Martyn (2023).
1471:
1378:
1345:
1296:
1242:
1230:
1184:
1164:
949:
945:
831:
739:
477:
1620:
1520:
644:
1608:
1587:
1556:
1508:
1448:
1370:
1337:
1282:
1272:
1222:
1176:
1168:
439:
362:
1374:
921:
plants, the reducing, anaerobic environment being conducive to formation of Mo(CO)
256:
1119:
1025:
886:
501:
456:
217:
1399:"THE SYNTHESIS & SPECTROSCOPIC CHARACTERISATION OF METAL CARBONYL COMPLEXES"
878:
871:
782:
658:
1512:
1277:
1260:
1078:". For instance treatment with allyl chloride gives , whereas treatment with
2029:
1942:
662:
428:
418:
179:
1226:
1349:
1234:
1047:
464:
1561:
726:
1452:
1180:
712:
1627:
1612:
1287:
1172:
1006:
719:
450:
387:
199:
159:
1591:
1937:
1341:
267:
901:) with magnesium, zinc or aluminium powders... under CO pressures".
781:
Except where otherwise noted, data are given for materials in their
1426:
Darensbourg, D. J.; Kump, R. L. (1978). "A Convenient
Synthesis of
941:
933:
Molybdenum hexacarbonyl is a popular reagent in academic research.
914:
685:
678:
127:
1547:
1043:
1022:
460:
408:
243:
936:
One or more CO ligands can be displaced by other ligands. Mo(CO)
1039:
918:
867:
1258:
139:
117:
283:
636:
972:
1203:
928:
628:
1598:
1493:
Critical
Reviews of Solid State and Materials Sciences
1362:
1156:
632:
1490:
1465:
1118:is a dangerous source of volatile metal as well as
31:
Stereo, skeletal formula of molybdenum hexacarbonyl
1540:"Synlett Spotlight 119: Molybdenum Hexacarbonyl "
2027:
1144:Chemical Entities of Biological Interest (ChEBI)
624:
255:
1425:
701:
103:
41:Ball and stick model of molybdenum hexacarbonyl
1569:
1366:Encyclopedia of Reagents for Organic Synthesis
1160:Encyclopedia of Reagents for Organic Synthesis
674:
640:
1643:
1310:Feldmann, J. (1999). "Determination of Ni(CO)
940:, , and related derivatives are employed as
853:
1650:
1636:
1102:Molybdenum hexacarbonyl is widely used in
298:
189:
167:
1560:
1286:
1276:
1657:
1309:
1146:. UK: European Bioinformatics Institute.
1537:
1468:Organometallics: A Concise Introduction
1197:
294:
233:
2028:
1466:Elschenbroich, C.; Salzer, A. (1992).
1140:"Hexacarbonylmolybdenum (CHEBI:30508)"
1109:
1092:cycloheptatrienemolybdenum tricarbonyl
433:156 °C (313 °F; 429 K)
423:150 °C (302 °F; 423 K)
180:
1631:
1470:(2nd ed.). Weinheim: Wiley-VCH.
1097:
929:Inorganic and organometallic research
326:Key: KMKBZNSIJQWHJA-UHFFFAOYSA-N
147:
1329:Journal of Environmental Monitoring
403:Vivid, white, translucent crystals
246:
13:
1531:
1484:
697:
374:
36:
26:
14:
2062:
1369:. New York: J. Wiley & Sons.
838:. This colorless solid, like its
1114:Like all metal carbonyls, Mo(CO)
1104:electron beam-induced deposition
789:
594:
347:O=C=(=C=O)(=C=O)(=C=O)(=C=O)=C=O
52:
785:(at 25 °C , 100 kPa).
1459:
1419:
1391:
1356:
1303:
1265:Coordination Chemistry Reviews
1252:
1150:
1132:
1001:The thermal reaction of Mo(CO)
866:consisting of six rod-like CO
377:
368:
1:
1375:10.1002/047084289X.rh004.pub2
1125:
904:
1028:(b.p. ca. 40 °C) gives
971:(bipy). UV-photolysis of a
7:
22:
10:
2067:
2046:Organomolybdenum compounds
1930:
1891:
1806:
1738:
1695:
1665:
1513:10.1080/10408430600930438
1278:10.1016/j.ccr.2022.214983
779:
751:
575:
570:
511:
470:
355:
335:
310:
87:
75:
70:Hexacarbonylmolybdenum(0)
65:
60:
51:
21:
1601:Fresenius' J. Anal. Chem
1084:sodium cyclopentadienide
854:Structure and properties
653:Precautionary statements
17:Molybdenum hexacarbonyl
2036:Molybdenum(0) compounds
1248:(subscription required)
1227:10.1126/science.1255720
834:with the formula Mo(CO)
824:Molybdenum hexacarbonyl
773:Seaborgium hexacarbonyl
323:InChI=1S/6CO.Mo/c6*1-2;
708:
235:Hexacarbonylmolybdenum
81:Hexacarbonylmolybdenum
42:
32:
1572:Environ. Sci. Technol
1562:10.1055/s-2005-865206
954:Pauson–Khand reaction
913:has been detected in
769:Tungsten hexacarbonyl
763:Chromium hexacarbonyl
707:
490:Coordination geometry
77:Systematic IUPAC name
40:
30:
2051:Octahedral compounds
1659:Molybdenum compounds
1538:Marradi, M. (2005).
690:(fire diamond)
455:slightly soluble in
1584:1997EnST...31.2125F
1505:2006CRSSM..31...55R
1453:10.1021/ic50187a062
1219:2014Sci...345.1491E
1110:Safety and handling
1055:
1019:triphenyl phosphine
986:
864:octahedral geometry
828:molybdenum carbonyl
440:Solubility in water
395: g·mol
18:
2041:Carbonyl complexes
1613:10.1007/BF00322474
1406:www.chm.bris.ac.uk
1173:10.1002/047084289X
1098:Source of Mo atoms
975:solution of Mo(CO)
812:Infobox references
752:Related compounds
709:
43:
33:
16:
2023:
2022:
1592:10.1021/es960952y
1415:on March 9, 2008.
950:alkyne metathesis
946:organic synthesis
832:chemical compound
820:Chemical compound
818:
817:
758:Related compounds
740:Safety data sheet
619:Hazard statements
478:Crystal structure
279:CompTox Dashboard
129:Interactive image
47:
46:
2058:
1875:
1687:
1652:
1645:
1638:
1629:
1628:
1624:
1607:(4–5): 228–234.
1595:
1578:(7): 2125–2129.
1566:
1564:
1555:(7): 1195–1196.
1544:
1525:
1524:
1488:
1482:
1481:
1463:
1457:
1456:
1447:(9): 2680–2682.
1423:
1417:
1416:
1414:
1408:. Archived from
1403:
1395:
1389:
1388:
1360:
1354:
1353:
1342:10.1039/a807277i
1307:
1301:
1300:
1290:
1280:
1256:
1250:
1249:
1246:
1213:(6203): 1491–3.
1201:
1195:
1194:
1154:
1148:
1147:
1136:
1067:
1066:
1062:
998:
997:
993:
967:to afford Mo(CO)
802:
796:
793:
792:
729:
722:
715:
700:
680:
676:
672:
668:
664:
660:
646:
642:
638:
634:
630:
626:
598:
562:
535:
512:Thermochemistry
394:
379:
376:
370:
363:Chemical formula
303:
302:
287:
285:
259:
248:
237:
218:Gmelin Reference
201:
193:
182:
171:
151:
131:
107:
56:
23:
19:
15:
2066:
2065:
2061:
2060:
2059:
2057:
2056:
2055:
2026:
2025:
2024:
2019:
2015:
2007:
1999:
1995:
1987:
1983:
1975:
1967:
1959:
1951:
1926:
1922:
1918:
1910:
1902:
1887:
1883:
1874:
1870:
1865:
1857:
1849:
1841:
1833:
1825:
1817:
1802:
1793:
1785:
1777:
1773:
1765:
1757:
1749:
1734:
1730:
1722:
1714:
1706:
1691:
1685:
1681:
1676:
1661:
1656:
1542:
1534:
1532:Further reading
1529:
1528:
1489:
1485:
1478:
1464:
1460:
1437:
1433:
1424:
1420:
1412:
1401:
1397:
1396:
1392:
1385:
1361:
1357:
1325:
1321:
1317:
1313:
1308:
1304:
1257:
1253:
1247:
1202:
1198:
1191:
1155:
1151:
1138:
1137:
1133:
1128:
1117:
1112:
1100:
1089:
1077:
1073:
1068:
1064:
1060:
1058:
1057:
1026:dichloromethane
1016:
1012:
1004:
999:
995:
991:
989:
988:
982:
978:
970:
965:2,2′-bipyridine
962:
939:
931:
924:
912:
907:
900:
896:
892:
887:carbon monoxide
884:
879:metal carbonyls
861:
856:
837:
821:
814:
809:
808:
807: ?)
798:
794:
790:
786:
771:
767:
765:
759:
734:
733:
732:
731:
724:
717:
710:
706:
698:
655:
621:
607:
591:
566:−2123.4 kJ mol
563:
560:
554:
550:
547:
546:Std enthalpy of
536:
533:
527:
523:
520:
519:Std enthalpy of
504:
492:
480:
442:
392:
382:
373:
365:
351:
348:
343:
342:
331:
328:
327:
324:
318:
317:
306:
288:
281:
262:
249:
220:
211:
174:
154:
134:
121:
110:
97:
83:
82:
71:
12:
11:
5:
2064:
2054:
2053:
2048:
2043:
2038:
2021:
2020:
2018:
2017:
2013:
2009:
2005:
2001:
1997:
1993:
1989:
1985:
1981:
1977:
1973:
1969:
1965:
1961:
1957:
1953:
1949:
1945:
1940:
1934:
1932:
1928:
1927:
1925:
1924:
1920:
1916:
1912:
1908:
1904:
1900:
1895:
1893:
1889:
1888:
1886:
1885:
1881:
1877:
1872:
1867:
1863:
1859:
1855:
1851:
1847:
1843:
1839:
1835:
1831:
1827:
1823:
1819:
1815:
1810:
1808:
1804:
1803:
1801:
1800:
1795:
1791:
1783:
1779:
1775:
1771:
1767:
1763:
1759:
1755:
1751:
1747:
1742:
1740:
1736:
1735:
1733:
1732:
1728:
1724:
1720:
1716:
1712:
1708:
1704:
1699:
1697:
1693:
1692:
1690:
1689:
1683:
1678:
1674:
1669:
1667:
1663:
1662:
1655:
1654:
1647:
1640:
1632:
1626:
1625:
1596:
1567:
1533:
1530:
1527:
1526:
1483:
1476:
1458:
1435:
1431:
1418:
1390:
1383:
1355:
1323:
1319:
1315:
1311:
1302:
1251:
1196:
1189:
1149:
1130:
1129:
1127:
1124:
1115:
1111:
1108:
1099:
1096:
1087:
1075:
1071:
1056:
1054:
1014:
1010:
1009:affords Mo(CO)
1002:
987:
985:
980:
976:
968:
960:
937:
930:
927:
922:
910:
906:
903:
898:
894:
890:
882:
872:organometallic
859:
855:
852:
835:
819:
816:
815:
810:
788:
787:
783:standard state
780:
777:
776:
760:
757:
754:
753:
749:
748:
743:
736:
735:
725:
718:
711:
696:
695:
694:
693:
691:
682:
681:
671:P304+P340+P311
656:
651:
648:
647:
622:
617:
614:
613:
608:
603:
600:
599:
592:
587:
584:
583:
573:
572:
568:
567:
564:
558:
552:
544:
541:
540:
539:−989.1 kJ mol
537:
531:
525:
517:
514:
513:
509:
508:
505:
500:
497:
496:
493:
488:
485:
484:
481:
476:
473:
472:
468:
467:
453:
447:
446:
443:
438:
435:
434:
431:
425:
424:
421:
415:
414:
411:
405:
404:
401:
397:
396:
390:
384:
383:
380:
371:
366:
361:
358:
357:
353:
352:
350:
349:
346:
338:
337:
336:
333:
332:
330:
329:
325:
322:
321:
313:
312:
311:
308:
307:
305:
304:
296:DTXSID70894074
291:
289:
277:
274:
273:
270:
264:
263:
261:
260:
252:
250:
242:
239:
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231:
225:
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209:
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203:
195:
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176:
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156:
155:
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152:
144:
142:
136:
135:
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124:
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115:
112:
111:
109:
108:
100:
98:
93:
90:
89:
85:
84:
80:
79:
73:
72:
69:
63:
62:
58:
57:
49:
48:
45:
44:
34:
9:
6:
4:
3:
2:
2063:
2052:
2049:
2047:
2044:
2042:
2039:
2037:
2034:
2033:
2031:
2016:
2010:
2008:
2002:
2000:
1990:
1988:
1978:
1976:
1970:
1968:
1962:
1960:
1954:
1952:
1946:
1944:
1943:Molybdic acid
1941:
1939:
1936:
1935:
1933:
1929:
1923:
1913:
1911:
1905:
1903:
1897:
1896:
1894:
1890:
1884:
1878:
1876:
1868:
1866:
1860:
1858:
1852:
1850:
1844:
1842:
1836:
1834:
1828:
1826:
1820:
1818:
1812:
1811:
1809:
1805:
1799:
1796:
1794:
1789:
1780:
1778:
1768:
1766:
1760:
1758:
1752:
1750:
1744:
1743:
1741:
1737:
1731:
1725:
1723:
1717:
1715:
1709:
1707:
1701:
1700:
1698:
1694:
1688:
1679:
1677:
1671:
1670:
1668:
1664:
1660:
1653:
1648:
1646:
1641:
1639:
1634:
1633:
1630:
1622:
1618:
1614:
1610:
1606:
1602:
1597:
1593:
1589:
1585:
1581:
1577:
1573:
1568:
1563:
1558:
1554:
1550:
1549:
1541:
1536:
1535:
1522:
1518:
1514:
1510:
1506:
1502:
1498:
1494:
1487:
1479:
1477:3-527-28165-7
1473:
1469:
1462:
1454:
1450:
1446:
1443:
1442:
1429:
1422:
1411:
1407:
1400:
1394:
1386:
1380:
1376:
1372:
1368:
1367:
1359:
1351:
1347:
1343:
1339:
1335:
1331:
1330:
1306:
1298:
1294:
1289:
1284:
1279:
1274:
1270:
1266:
1262:
1255:
1244:
1240:
1236:
1232:
1228:
1224:
1220:
1216:
1212:
1208:
1200:
1192:
1190:9780470842898
1186:
1182:
1178:
1174:
1170:
1166:
1162:
1161:
1153:
1145:
1141:
1135:
1131:
1123:
1121:
1107:
1105:
1095:
1093:
1085:
1081:
1063:
1053:
1051:
1050:
1045:
1041:
1037:
1033:
1032:
1027:
1024:
1020:
1008:
994:
984:
974:
966:
957:
955:
951:
948:for example,
947:
943:
934:
926:
920:
916:
902:
888:
880:
875:
873:
869:
865:
851:
849:
845:
841:
833:
829:
826:(also called
825:
813:
806:
801:
784:
778:
775:
774:
770:
764:
761:
756:
755:
750:
747:
746:External MSDS
744:
741:
738:
737:
730:
723:
716:
692:
689:
688:
684:
683:
657:
654:
650:
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623:
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569:
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557:
549:
543:
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538:
530:
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510:
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502:Dipole moment
499:
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487:
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469:
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458:
454:
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429:Boiling point
427:
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419:Melting point
417:
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223:3798, 562210
222:
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188:
185:
183:
181:ECHA InfoCard
178:
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146:
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106:
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68:
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55:
50:
39:
35:
29:
25:
24:
20:
1787:
1672:
1604:
1600:
1575:
1571:
1552:
1546:
1499:(3): 55–89.
1496:
1492:
1486:
1467:
1461:
1444:
1441:Inorg. Chem.
1439:
1427:
1421:
1410:the original
1405:
1393:
1364:
1358:
1336:(1): 33–37.
1333:
1327:
1305:
1268:
1264:
1254:
1210:
1206:
1199:
1181:10261/236866
1159:
1152:
1143:
1134:
1113:
1101:
1069:
1048:
1035:
1030:
1013:(piperidine)
1000:
979:gives Mo(CO)
963:reacts with
958:
935:
932:
908:
876:
857:
827:
823:
822:
766:
686:
610:
577:
555:
528:
465:acetonitrile
88:Identifiers
1322:, and W(CO)
1288:10773/40120
605:Signal word
495:Octahedral
483:Orthogonal
400:Appearance
356:Properties
187:100.034.271
149:CHEBI:30508
2030:Categories
1938:Molybdates
1384:0471936235
1271:: 214983.
1126:References
1040:isomerizes
1007:piperidine
905:Occurrence
877:Like many
862:adopts an
848:seaborgium
589:Pictograms
548:combustion
471:Structure
451:Solubility
445:insoluble
413:1.96 g cm
388:Molar mass
160:ChemSpider
116:3D model (
105:13939-06-5
95:CAS Number
67:IUPAC name
1297:255329673
1243:206558746
942:catalysts
915:landfills
830:) is the
580:labelling
521:formation
268:UN number
208:237-713-3
200:EC Number
1621:95405500
1521:93769658
1350:11529076
1318:, Mo(CO)
1314:, Fe(CO)
1235:25237098
1038:complex
1034:-. This
952:and the
881:, Mo(CO)
844:tungsten
840:chromium
687:NFPA 704
571:Hazards
169:21428397
1739:Mo(III)
1580:Bibcode
1548:Synlett
1501:Bibcode
1430:-Mo(CO)
1215:Bibcode
1207:Science
1044:toluene
1023:boiling
983:(THF).
868:ligands
805:what is
803: (
461:diglyme
409:Density
244:PubChem
1931:Mo(VI)
1807:Mo(IV)
1696:Mo(II)
1673:Mo(CO)
1619:
1519:
1474:
1381:
1348:
1295:
1241:
1233:
1187:
1070:Mo(CO)
1059:": -->
990:": -->
959:Mo(CO)
919:sewage
909:Mo(CO)
897:or WCl
893:, MoCl
858:Mo(CO)
846:, and
800:verify
797:
742:(SDS)
611:Danger
393:264.01
340:SMILES
61:Names
1972:MoOCl
1892:Mo(V)
1666:Mo(0)
1617:S2CID
1543:(PDF)
1517:S2CID
1413:(PDF)
1402:(PDF)
1293:S2CID
1239:S2CID
1165:Wiley
1049:trans
1005:with
315:InChI
272:3466
257:98885
140:ChEBI
118:JSmol
1964:MoOF
1956:MoCl
1899:MoCl
1880:MoAs
1862:MoTe
1854:MoSe
1822:MoCl
1814:MoBr
1754:MoCl
1746:MoBr
1727:MoSi
1711:MoCl
1703:MoBr
1553:2005
1472:ISBN
1379:ISBN
1346:PMID
1231:PMID
1185:ISBN
1082:and
1061:edit
1036:cis-
992:edit
917:and
679:P501
675:P405
667:P280
663:P271
659:P261
645:H413
641:H330
637:H319
633:H315
629:H310
625:H300
507:0 D
229:MeSH
2012:MoS
2004:MoF
1992:MoO
1980:MoF
1948:MoO
1907:MoF
1871:MoP
1846:MoS
1838:MoO
1830:MoF
1798:MoP
1790:Bu)
1762:MoI
1719:MoI
1609:doi
1605:350
1588:doi
1557:doi
1509:doi
1449:doi
1428:cis
1371:doi
1338:doi
1283:hdl
1273:doi
1269:478
1223:doi
1211:345
1177:hdl
1169:doi
1090:is
1080:KTp
1052:-.
1046:to
1042:in
1031:cis
1021:in
973:THF
944:in
578:GHS
559:298
532:298
457:THF
284:EPA
247:CID
2032::
1996:Cl
1915:Mo
1786:(O
1782:Mo
1770:Mo
1682:Mo
1615:.
1603:.
1586:.
1576:31
1574:.
1551:.
1545:.
1515:.
1507:.
1497:31
1495:.
1445:17
1404:.
1377:.
1344:.
1332:.
1291:.
1281:.
1267:.
1263:.
1237:.
1229:.
1221:.
1209:.
1183:.
1175:.
1167:.
1163:.
1142:.
1122:.
1120:CO
1094:.
956:.
925:.
842:,
677:,
673:,
669:,
665:,
661:,
643:,
639:,
635:,
631:,
627:,
582::
551:(Δ
524:(Δ
463:,
459:,
375:Mo
2014:3
2006:6
1998:2
1994:2
1986:2
1984:O
1982:2
1974:4
1966:4
1958:6
1950:3
1921:5
1919:O
1917:2
1909:5
1901:5
1882:2
1873:2
1864:2
1856:2
1848:2
1840:2
1832:4
1824:4
1816:4
1792:6
1788:t
1784:2
1776:3
1774:O
1772:2
1764:3
1756:3
1748:3
1729:2
1721:2
1713:2
1705:2
1686:P
1684:3
1675:6
1651:e
1644:t
1637:v
1623:.
1611::
1594:.
1590::
1582::
1565:.
1559::
1523:.
1511::
1503::
1480:.
1455:.
1451::
1436:2
1434:L
1432:4
1387:.
1373::
1352:.
1340::
1334:1
1324:6
1320:6
1316:5
1312:4
1299:.
1285::
1275::
1245:.
1225::
1217::
1193:.
1179::
1171::
1116:6
1088:3
1076:3
1072:6
1065:]
1015:2
1011:4
1003:6
996:]
981:5
977:6
969:4
961:6
938:6
923:6
911:6
899:6
895:5
891:3
883:6
860:6
836:6
795:N
728:0
721:1
714:4
561:)
556:H
553:c
534:)
529:H
526:f
381:6
378:O
372:6
369:C
286:)
282:(
120:)
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