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Molybdenum hexacarbonyl

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Even, J.; Yakushev, A.; Dullmann, C. E.; Haba, H.; Asai, M.; Sato, T. K.; Brand, H.; Di Nitto, A.; Eichler, R.; Fan, F. L.; Hartmann, W.; Huang, M.; Jager, E.; Kaji, D.; Kanaya, J.; Kaneya, Y.; Khuyagbaatar, J.; Kindler, B.; Kratz, J. V.; Krier, J.; Kudou, Y.; Kurz, N.; Lommel, B.; Miyashita, S.;
702: 604: 576: 1017:. The two piperidine ligands in this yellow-colored compound are labile, which allows other ligands to be introduced under mild conditions. For instance, the reaction of with 670: 1570:
Feldmann, J.; Cullen, W. R. (1997). "Occurrence of Volatile Transition Metal Compounds in Landfill Gas: Synthesis of Molybdenum and Tungsten Carbonyls in the Environment".
1398: 889:. As described in a 2023 survey of methods "most cost-effective routes for the synthesis of group 6 hexacarbonyls are based on the reduction of the metal chlorides (CrCl 705: 128: 1599:
Feldmann, J.; Grümping, R.; Hirner, A. V. (1994). "Determination of Volatile Metal and Metalloid Compounds in Gases from Domestic Waste Deposits with GC/ICP-MS".
874:" compound. Usually, organometallic indicates the presence of a metal directly bonded via a M–C bond to an organic fragment, which must in turn have a C–H bond. 1769: 1914: 804: 37: 1205:
Morimoto, K.; Morita, K.; Murakami, M.; Nagame, Y.; Nitsche, H.; et al. (2014). "Synthesis and detection of a seaborgium carbonyl complex".
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is generally prepared by "reductive carbonylation", which involves reduction of a metal halide with under an atmosphere of
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technique - it is easily vaporized and decomposed by the electron beam providing a convenient source of molybdenum atoms.
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Randolph, S. J.; Fowlkes, J. D.; Rack, P. D. (2006). "Focused, Nanoscale Electron-Beam-Induced Deposition and Etching".
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radiating from the central Mo atom. A recurring minor debate in some chemical circles concerns the definition of an "
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Derivatives (L = Group 5a Ligand) and a Qualitative Study of Their Thermal Reactivity toward Ligand Dissociation".
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gives and anions, respectively. These anions react with a variety of electrophiles. A related source of Mo(CO)
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also can be converted to its tris(acetonitrile) derivative. The compound serves as a source of "Mo(CO)
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in Sewage Gas by Using Cryotrapping Gas Chromatography Inductively Coupled Plasma Mass Spectrometry".
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analogues, is noteworthy as a volatile, air-stable derivative of a metal in its zero oxidation state.
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Faller, J. W.; Brummond, K. M.; Mitasev, B. (2006). "Hexacarbonylmolybdenum". In Paquette, L. (ed.).
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Faller, John W.; Brummond, Kay M.; Mitasev, Branko (15 September 2006). "Hexacarbonylmolybdenum".
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Bruno, Sofia M.; Valente, Anabela A.; Gonçalves, Isabel S.; Pillinger, Martyn (2023).
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plants, the reducing, anaerobic environment being conducive to formation of Mo(CO)
256: 1119: 1025: 886: 501: 456: 217: 1399:"THE SYNTHESIS & SPECTROSCOPIC CHARACTERISATION OF METAL CARBONYL COMPLEXES" 878: 871: 782: 658: 1512: 1277: 1260: 1078:". For instance treatment with allyl chloride gives , whereas treatment with 2029: 1942: 662: 428: 418: 179: 1226: 1349: 1234: 1047: 464: 1561: 726: 1452: 1180: 712: 1627: 1612: 1287: 1172: 1006: 719: 450: 387: 199: 159: 1591: 1937: 1341: 267: 901:) with magnesium, zinc or aluminium powders... under CO pressures". 781:
Except where otherwise noted, data are given for materials in their
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Darensbourg, D. J.; Kump, R. L. (1978). "A Convenient Synthesis of
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Molybdenum hexacarbonyl is a popular reagent in academic research.
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One or more CO ligands can be displaced by other ligands. Mo(CO)
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Critical Reviews of Solid State and Materials Sciences
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Stereo, skeletal formula of molybdenum hexacarbonyl
1540:"Synlett Spotlight 119: Molybdenum Hexacarbonyl " 2027: 1144:Chemical Entities of Biological Interest (ChEBI) 624: 255: 1425: 701: 103: 41:Ball and stick model of molybdenum hexacarbonyl 1569: 1366:Encyclopedia of Reagents for Organic Synthesis 1160:Encyclopedia of Reagents for Organic Synthesis 674: 640: 1643: 1310:Feldmann, J. (1999). "Determination of Ni(CO) 940:, , and related derivatives are employed as 853: 1650: 1636: 1102:Molybdenum hexacarbonyl is widely used in 298: 189: 167: 1560: 1286: 1276: 1657: 1309: 1146:. UK: European Bioinformatics Institute. 1537: 1468:Organometallics: A Concise Introduction 1197: 294: 233: 2028: 1466:Elschenbroich, C.; Salzer, A. (1992). 1140:"Hexacarbonylmolybdenum (CHEBI:30508)" 1109: 1092:cycloheptatrienemolybdenum tricarbonyl 433:156 °C (313 °F; 429 K) 423:150 °C (302 °F; 423 K) 180: 1631: 1470:(2nd ed.). Weinheim: Wiley-VCH. 1097: 929:Inorganic and organometallic research 326:Key: KMKBZNSIJQWHJA-UHFFFAOYSA-N 147: 1329:Journal of Environmental Monitoring 403:Vivid, white, translucent crystals 246: 13: 1531: 1484: 697: 374: 36: 26: 14: 2062: 1369:. New York: J. Wiley & Sons. 838:. This colorless solid, like its 1114:Like all metal carbonyls, Mo(CO) 1104:electron beam-induced deposition 789: 594: 347:O=C=(=C=O)(=C=O)(=C=O)(=C=O)=C=O 52: 785:(at 25 °C , 100 kPa). 1459: 1419: 1391: 1356: 1303: 1265:Coordination Chemistry Reviews 1252: 1150: 1132: 1001:The thermal reaction of Mo(CO) 866:consisting of six rod-like CO 377: 368: 1: 1375:10.1002/047084289X.rh004.pub2 1125: 904: 1028:(b.p. ca. 40 °C) gives 971:(bipy). UV-photolysis of a 7: 22: 10: 2067: 2046:Organomolybdenum compounds 1930: 1891: 1806: 1738: 1695: 1665: 1513:10.1080/10408430600930438 1278:10.1016/j.ccr.2022.214983 779: 751: 575: 570: 511: 470: 355: 335: 310: 87: 75: 70:Hexacarbonylmolybdenum(0) 65: 60: 51: 21: 1601:Fresenius' J. Anal. Chem 1084:sodium cyclopentadienide 854:Structure and properties 653:Precautionary statements 17:Molybdenum hexacarbonyl 2036:Molybdenum(0) compounds 1248:(subscription required) 1227:10.1126/science.1255720 834:with the formula Mo(CO) 824:Molybdenum hexacarbonyl 773:Seaborgium hexacarbonyl 323:InChI=1S/6CO.Mo/c6*1-2; 708: 235:Hexacarbonylmolybdenum 81:Hexacarbonylmolybdenum 42: 32: 1572:Environ. Sci. Technol 1562:10.1055/s-2005-865206 954:Pauson–Khand reaction 913:has been detected in 769:Tungsten hexacarbonyl 763:Chromium hexacarbonyl 707: 490:Coordination geometry 77:Systematic IUPAC name 40: 30: 2051:Octahedral compounds 1659:Molybdenum compounds 1538:Marradi, M. (2005). 690:(fire diamond) 455:slightly soluble in 1584:1997EnST...31.2125F 1505:2006CRSSM..31...55R 1453:10.1021/ic50187a062 1219:2014Sci...345.1491E 1110:Safety and handling 1055: 1019:triphenyl phosphine 986: 864:octahedral geometry 828:molybdenum carbonyl 440:Solubility in water 395: g·mol 18: 2041:Carbonyl complexes 1613:10.1007/BF00322474 1406:www.chm.bris.ac.uk 1173:10.1002/047084289X 1098:Source of Mo atoms 975:solution of Mo(CO) 812:Infobox references 752:Related compounds 709: 43: 33: 16: 2023: 2022: 1592:10.1021/es960952y 1415:on March 9, 2008. 950:alkyne metathesis 946:organic synthesis 832:chemical compound 820:Chemical compound 818: 817: 758:Related compounds 740:Safety data sheet 619:Hazard statements 478:Crystal structure 279:CompTox Dashboard 129:Interactive image 47: 46: 2058: 1875: 1687: 1652: 1645: 1638: 1629: 1628: 1624: 1607:(4–5): 228–234. 1595: 1578:(7): 2125–2129. 1566: 1564: 1555:(7): 1195–1196. 1544: 1525: 1524: 1488: 1482: 1481: 1463: 1457: 1456: 1447:(9): 2680–2682. 1423: 1417: 1416: 1414: 1408:. Archived from 1403: 1395: 1389: 1388: 1360: 1354: 1353: 1342:10.1039/a807277i 1307: 1301: 1300: 1290: 1280: 1256: 1250: 1249: 1246: 1213:(6203): 1491–3. 1201: 1195: 1194: 1154: 1148: 1147: 1136: 1067: 1066: 1062: 998: 997: 993: 967:to afford Mo(CO) 802: 796: 793: 792: 729: 722: 715: 700: 680: 676: 672: 668: 664: 660: 646: 642: 638: 634: 630: 626: 598: 562: 535: 512:Thermochemistry 394: 379: 376: 370: 363:Chemical formula 303: 302: 287: 285: 259: 248: 237: 218:Gmelin Reference 201: 193: 182: 171: 151: 131: 107: 56: 23: 19: 15: 2066: 2065: 2061: 2060: 2059: 2057: 2056: 2055: 2026: 2025: 2024: 2019: 2015: 2007: 1999: 1995: 1987: 1983: 1975: 1967: 1959: 1951: 1926: 1922: 1918: 1910: 1902: 1887: 1883: 1874: 1870: 1865: 1857: 1849: 1841: 1833: 1825: 1817: 1802: 1793: 1785: 1777: 1773: 1765: 1757: 1749: 1734: 1730: 1722: 1714: 1706: 1691: 1685: 1681: 1676: 1661: 1656: 1542: 1534: 1532:Further reading 1529: 1528: 1489: 1485: 1478: 1464: 1460: 1437: 1433: 1424: 1420: 1412: 1401: 1397: 1396: 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743: 736: 735: 725: 718: 711: 696: 695: 694: 693: 691: 682: 681: 671:P304+P340+P311 656: 651: 648: 647: 622: 617: 614: 613: 608: 603: 600: 599: 592: 587: 584: 583: 573: 572: 568: 567: 564: 558: 552: 544: 541: 540: 539:−989.1 kJ mol 537: 531: 525: 517: 514: 513: 509: 508: 505: 500: 497: 496: 493: 488: 485: 484: 481: 476: 473: 472: 468: 467: 453: 447: 446: 443: 438: 435: 434: 431: 425: 424: 421: 415: 414: 411: 405: 404: 401: 397: 396: 390: 384: 383: 380: 371: 366: 361: 358: 357: 353: 352: 350: 349: 346: 338: 337: 336: 333: 332: 330: 329: 325: 322: 321: 313: 312: 311: 308: 307: 305: 304: 296:DTXSID70894074 291: 289: 277: 274: 273: 270: 264: 263: 261: 260: 252: 250: 242: 239: 238: 231: 225: 224: 221: 216: 213: 212: 210: 209: 205: 203: 195: 194: 184: 176: 175: 173: 172: 164: 162: 156: 155: 153: 152: 144: 142: 136: 135: 133: 132: 124: 122: 115: 112: 111: 109: 108: 100: 98: 93: 90: 89: 85: 84: 80: 79: 73: 72: 69: 63: 62: 58: 57: 49: 48: 45: 44: 34: 9: 6: 4: 3: 2: 2063: 2052: 2049: 2047: 2044: 2042: 2039: 2037: 2034: 2033: 2031: 2016: 2010: 2008: 2002: 2000: 1990: 1988: 1978: 1976: 1970: 1968: 1962: 1960: 1954: 1952: 1946: 1944: 1943:Molybdic acid 1941: 1939: 1936: 1935: 1933: 1929: 1923: 1913: 1911: 1905: 1903: 1897: 1896: 1894: 1890: 1884: 1878: 1876: 1868: 1866: 1860: 1858: 1852: 1850: 1844: 1842: 1836: 1834: 1828: 1826: 1820: 1818: 1812: 1811: 1809: 1805: 1799: 1796: 1794: 1789: 1780: 1778: 1768: 1766: 1760: 1758: 1752: 1750: 1744: 1743: 1741: 1737: 1731: 1725: 1723: 1717: 1715: 1709: 1707: 1701: 1700: 1698: 1694: 1688: 1679: 1677: 1671: 1670: 1668: 1664: 1660: 1653: 1648: 1646: 1641: 1639: 1634: 1633: 1630: 1622: 1618: 1614: 1610: 1606: 1602: 1597: 1593: 1589: 1585: 1581: 1577: 1573: 1568: 1563: 1558: 1554: 1550: 1549: 1541: 1536: 1535: 1522: 1518: 1514: 1510: 1506: 1502: 1498: 1494: 1487: 1479: 1477:3-527-28165-7 1473: 1469: 1462: 1454: 1450: 1446: 1443: 1442: 1429: 1422: 1411: 1407: 1400: 1394: 1386: 1380: 1376: 1372: 1368: 1367: 1359: 1351: 1347: 1343: 1339: 1335: 1331: 1330: 1306: 1298: 1294: 1289: 1284: 1279: 1274: 1270: 1266: 1262: 1255: 1244: 1240: 1236: 1232: 1228: 1224: 1220: 1216: 1212: 1208: 1200: 1192: 1190:9780470842898 1186: 1182: 1178: 1174: 1170: 1166: 1162: 1161: 1153: 1145: 1141: 1135: 1131: 1123: 1121: 1107: 1105: 1095: 1093: 1085: 1081: 1063: 1053: 1051: 1050: 1045: 1041: 1037: 1033: 1032: 1027: 1024: 1020: 1008: 994: 984: 974: 966: 957: 955: 951: 948:for example, 947: 943: 934: 926: 920: 916: 902: 888: 880: 875: 873: 869: 865: 851: 849: 845: 841: 833: 829: 826:(also called 825: 813: 806: 801: 784: 778: 775: 774: 770: 764: 761: 756: 755: 750: 747: 746:External MSDS 744: 741: 738: 737: 730: 723: 716: 692: 689: 688: 684: 683: 657: 654: 650: 649: 623: 620: 616: 615: 612: 609: 606: 602: 601: 597: 593: 590: 586: 585: 581: 579: 574: 569: 565: 557: 549: 543: 542: 538: 530: 522: 516: 515: 510: 506: 503: 502:Dipole moment 499: 498: 494: 491: 487: 486: 482: 479: 475: 474: 469: 466: 462: 458: 454: 452: 449: 448: 444: 441: 437: 436: 432: 430: 429:Boiling point 427: 426: 422: 420: 419:Melting point 417: 416: 412: 410: 407: 406: 402: 399: 398: 391: 389: 386: 385: 367: 364: 360: 359: 354: 345: 344: 341: 334: 320: 319: 316: 309: 301: 297: 293: 292: 290: 280: 276: 275: 271: 269: 266: 265: 258: 254: 253: 251: 245: 241: 240: 236: 232: 230: 227: 226: 223:3798, 562210 222: 219: 215: 214: 207: 206: 204: 202: 197: 196: 192: 188: 185: 183: 181:ECHA InfoCard 178: 177: 170: 166: 165: 163: 161: 158: 157: 150: 146: 145: 143: 141: 138: 137: 130: 126: 125: 123: 119: 114: 113: 106: 102: 101: 99: 96: 92: 91: 86: 78: 74: 68: 64: 59: 55: 50: 39: 35: 29: 25: 24: 20: 1787: 1672: 1604: 1600: 1575: 1571: 1552: 1546: 1499:(3): 55–89. 1496: 1492: 1486: 1467: 1461: 1444: 1441:Inorg. Chem. 1439: 1427: 1421: 1410:the original 1405: 1393: 1364: 1358: 1336:(1): 33–37. 1333: 1327: 1305: 1268: 1264: 1254: 1210: 1206: 1199: 1181:10261/236866 1159: 1152: 1143: 1134: 1113: 1101: 1069: 1048: 1035: 1030: 1013:(piperidine) 1000: 979:gives Mo(CO) 963:reacts with 958: 935: 932: 908: 876: 857: 827: 823: 822: 766: 686: 610: 577: 555: 528: 465:acetonitrile 88:Identifiers 1322:, and W(CO) 1288:10773/40120 605:Signal word 495:Octahedral 483:Orthogonal 400:Appearance 356:Properties 187:100.034.271 149:CHEBI:30508 2030:Categories 1938:Molybdates 1384:0471936235 1271:: 214983. 1126:References 1040:isomerizes 1007:piperidine 905:Occurrence 877:Like many 862:adopts an 848:seaborgium 589:Pictograms 548:combustion 471:Structure 451:Solubility 445:insoluble 413:1.96 g cm 388:Molar mass 160:ChemSpider 116:3D model ( 105:13939-06-5 95:CAS Number 67:IUPAC name 1297:255329673 1243:206558746 942:catalysts 915:landfills 830:) is the 580:labelling 521:formation 268:UN number 208:237-713-3 200:EC Number 1621:95405500 1521:93769658 1350:11529076 1318:, Mo(CO) 1314:, Fe(CO) 1235:25237098 1038:complex 1034:-. This 952:and the 881:, Mo(CO) 844:tungsten 840:chromium 687:NFPA 704 571:Hazards 169:21428397 1739:Mo(III) 1580:Bibcode 1548:Synlett 1501:Bibcode 1430:-Mo(CO) 1215:Bibcode 1207:Science 1044:toluene 1023:boiling 983:(THF). 868:ligands 805:what is 803: ( 461:diglyme 409:Density 244:PubChem 1931:Mo(VI) 1807:Mo(IV) 1696:Mo(II) 1673:Mo(CO) 1619:  1519:  1474:  1381:  1348:  1295:  1241:  1233:  1187:  1070:Mo(CO) 1059:": --> 990:": --> 959:Mo(CO) 919:sewage 909:Mo(CO) 897:or WCl 893:, MoCl 858:Mo(CO) 846:, and 800:verify 797:  742:(SDS) 611:Danger 393:264.01 340:SMILES 61:Names 1972:MoOCl 1892:Mo(V) 1666:Mo(0) 1617:S2CID 1543:(PDF) 1517:S2CID 1413:(PDF) 1402:(PDF) 1293:S2CID 1239:S2CID 1165:Wiley 1049:trans 1005:with 315:InChI 272:3466 257:98885 140:ChEBI 118:JSmol 1964:MoOF 1956:MoCl 1899:MoCl 1880:MoAs 1862:MoTe 1854:MoSe 1822:MoCl 1814:MoBr 1754:MoCl 1746:MoBr 1727:MoSi 1711:MoCl 1703:MoBr 1553:2005 1472:ISBN 1379:ISBN 1346:PMID 1231:PMID 1185:ISBN 1082:and 1061:edit 1036:cis- 992:edit 917:and 679:P501 675:P405 667:P280 663:P271 659:P261 645:H413 641:H330 637:H319 633:H315 629:H310 625:H300 507:0 D 229:MeSH 2012:MoS 2004:MoF 1992:MoO 1980:MoF 1948:MoO 1907:MoF 1871:MoP 1846:MoS 1838:MoO 1830:MoF 1798:MoP 1790:Bu) 1762:MoI 1719:MoI 1609:doi 1605:350 1588:doi 1557:doi 1509:doi 1449:doi 1428:cis 1371:doi 1338:doi 1283:hdl 1273:doi 1269:478 1223:doi 1211:345 1177:hdl 1169:doi 1090:is 1080:KTp 1052:-. 1046:to 1042:in 1031:cis 1021:in 973:THF 944:in 578:GHS 559:298 532:298 457:THF 284:EPA 247:CID 2032:: 1996:Cl 1915:Mo 1786:(O 1782:Mo 1770:Mo 1682:Mo 1615:. 1603:. 1586:. 1576:31 1574:. 1551:. 1545:. 1515:. 1507:. 1497:31 1495:. 1445:17 1404:. 1377:. 1344:. 1332:. 1291:. 1281:. 1267:. 1263:. 1237:. 1229:. 1221:. 1209:. 1183:. 1175:. 1167:. 1163:. 1142:. 1122:. 1120:CO 1094:. 956:. 925:. 842:, 677:, 673:, 669:, 665:, 661:, 643:, 639:, 635:, 631:, 627:, 582:: 551:(Δ 524:(Δ 463:, 459:, 375:Mo 2014:3 2006:6 1998:2 1994:2 1986:2 1984:O 1982:2 1974:4 1966:4 1958:6 1950:3 1921:5 1919:O 1917:2 1909:5 1901:5 1882:2 1873:2 1864:2 1856:2 1848:2 1840:2 1832:4 1824:4 1816:4 1792:6 1788:t 1784:2 1776:3 1774:O 1772:2 1764:3 1756:3 1748:3 1729:2 1721:2 1713:2 1705:2 1686:P 1684:3 1675:6 1651:e 1644:t 1637:v 1623:. 1611:: 1594:. 1590:: 1582:: 1565:. 1559:: 1523:. 1511:: 1503:: 1480:. 1455:. 1451:: 1436:2 1434:L 1432:4 1387:. 1373:: 1352:. 1340:: 1334:1 1324:6 1320:6 1316:5 1312:4 1299:. 1285:: 1275:: 1245:. 1225:: 1217:: 1193:. 1179:: 1171:: 1116:6 1088:3 1076:3 1072:6 1065:] 1015:2 1011:4 1003:6 996:] 981:5 977:6 969:4 961:6 938:6 923:6 911:6 899:6 895:5 891:3 883:6 860:6 836:6 795:N 728:0 721:1 714:4 561:) 556:H 553:c 534:) 529:H 526:f 381:6 378:O 372:6 369:C 286:) 282:( 120:)

Index

Stereo, skeletal formula of molybdenum hexacarbonyl
Ball and stick model of molybdenum hexacarbonyl
Sample of molybdenum hexacarbonyl
IUPAC name
Systematic IUPAC name
CAS Number
13939-06-5
JSmol
Interactive image
ChEBI
CHEBI:30508
ChemSpider
21428397
ECHA InfoCard
100.034.271
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EC Number
Gmelin Reference
MeSH
Hexacarbonylmolybdenum
PubChem
98885
UN number
CompTox Dashboard
DTXSID70894074
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InChI
SMILES
Chemical formula
Molar mass

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