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Paleoceanography

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than Th: Pa has a residence time ~100–200 years while Th has one ~20–40 years. In today's Atlantic Ocean and current overturning circulation, Th transport to the Southern Ocean is minimal due to its short residence time, and Pa transport is high. This results in relatively low Pa / Th ratios found by McManus et al. in a core at 33N 57W, and a depth of 4.5 km. When the overturning circulation shuts down (as hypothesized) during glacial periods, the Pa / Th ratio becomes elevated due to the lack of removal of Pa to the Southern Ocean. McManus et al. also note a small raise in the Pa / Th ratio during the
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core-scanning methods. These  methods have enabled research similar to that conducted with ice core records in Antarctica. These records can inform on the relative abundance of organisms present at a given time using paleoproductivity methods such as measuring the total diatom abundance. Records can also inform on historic weather patterns and ocean circulation such as Deschamps et al. described with their research into sediment records from the Chukchi-Alaskan and Canadian Beaufort Margins.
1559: 1571: 32: 2430: 1455:(fraction of deep-sea sediment between 10 and 63 μm). Carbon isotope and cadmium/calcium ratio proxies are used because variability in their ratios is due partly to changes in bottom-water chemistry, which is in turn related the source of deep-water formation. These ratios, however, are influenced by biological, ecological, and geochemical processes which complicate circulation inferences. 1230:
precipitate, they sink and form sediments on the ocean floor whose δO can be used to infer past SSTs. Oxygen isotope ratios are not perfect proxies, however. The volume of ice trapped in continental ice sheets can have an impact of the δO. Freshwater characterized by lower values of δO becomes trapped in the continental ice sheets, so that during glacial periods seawater δO is elevated and
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isotopes (Pa and Th) to show that the Atlantic Meridional Overturning Circulation had been nearly (or completely) shut off during the last glacial period. Pa and Th are both formed from the radioactive decay of dissolved uranium in seawater, with Pa able to remain supported in the water column longer
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Deschamps, Charles-Edouard & Montero-Serrano, Jean & St-Onge, Guillaume & Poirier, André. (2019). Holocene changes in deep-water circulation inferred from authigenic Nd and Hf isotopes in sediment records from the Chukchi-Alaskan and Canadian Beaufort margins Key points. Paleoceanography
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excess in core records can provide a better inference of sea-surface salinity than oxygen isotopes, and certain species, such as diatoms, can provide a semiquantitative salinity record due to the relative abundances of diatoms that are limited to certain salinity regimes. There have been changes to
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et al. who worked to calibrate bottom water temperature to Mg/Ca ratios in 9 locations covering a variety of depths from up to six different benthic foraminifera (depending on location). The authors found an equation calibrating bottom water temperature of Mg/Ca ratios that takes on an exponential
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are long-chain, complex organic molecules produced by photosynthetic algae. They are temperature sensitive and can be extracted from marine sediments. Use of alkenones represents a more direct relationship between SST and algae and does not rely on knowing biotic and physical-chemical thermodynamic
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are useful in reconstructing SST because of the influence temperature has on the isotope ratio. Plankton take up oxygen in building their shells and will be less enriched in their δO when formed in warmer waters, provided they are in thermodynamic equilibrium with the seawater. When these shells
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can be used as a proxy for the SST in which the shells formed. Mg/Ca ratios have several other influencing factors other than temperature, such as vital effects, shell-cleaning, and postmortem and post-depositional dissolution effects, to name a few. Other influences aside, Mg/Ca ratios have
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and the salinity balance of the oceans with the North Atlantic and becoming more saline and the sub-tropical Indian and pacific oceans becoming less so. With changes to the water cycle, there have also been variations with the vertical distribution of salt and haloclines. Large incursions of
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Sediment records can tell us a great deal about our past and help make inferences towards the future. Though this area of Paleoceanography is nothing new with some research going back to the 1930s and earlier.    Modern time scale reconstructive research has advanced using sediment
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S.L. Jaccard, E.D. Galbraith, D.M. Sigman, G.H. Haug, A pervasive link between Antarctic ice core and subarctic Pacific sediment records over the past 800kyrs, Quaternary Science Reviews, Volume 29, Issues 1–2, 2010, Pages 206-212, ISSN 0277-3791,
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Sjunneskog, C., F. Taylor 2002.  Postglacial marine diatom record of the Palmer Deep, Antarctic Peninsula (ODP Leg 178, Site 1098) 1. Total diatom abundance.  VL  - 17.  DO  - 10.1029/2000PA000563. 
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studies. Another advantage of using alkenones is that they are a product of photosynthesis, necessitating formation in the sunlight of the upper surface layers. As such, it better records near-surface SST.
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and the ratio of magnesium to calcium (Mg/Ca) in shell secretions from plankton, from long-chain organic molecules such as alkenone, from tropical corals near the sea surface, and from mollusk shells.
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McManus, J. F.; Francois, R.; Gherardi, J.-M.; Keigwin, L. D.; Brown-Leger, S. (22 April 2004). "Collapse and rapid resumption of Atlantic meridional circulation linked to deglacial climate changes".
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and biological productivity. Paleoceanographic studies using environment models and different proxies enable the scientific community to assess the role of the oceanic processes in the global
1285:. The temperatures inferred from the Mg/Ca ratios have confirmed an up to 3 °C cooling of the deep ocean during the late Pleistocene glacial periods. One notable study is that by 1195:
methods as a way to infer information about the past state and evolution of the world's oceans. Several geochemical proxy tools include long-chain organic molecules (e.g.
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ion concentration in the ocean. δB has been identified in corals from the southwestern Pacific to vary with ocean pH, and shows that climate variabilities such as the
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Olausson, Eric (January 1963). "Evidence of climatic changes in North Atlantic deep-sea cores, with remarks on isotopic paleotemperature analysis".
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Goosse, H. and Zunz, V.: Decadal trends in the Antarctic sea ice extent ultimately controlled by ice–ocean feedback, The Cryosphere, 8, 453–470,
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Billups, K.; Schrag, D.P. (April 2003). "Application of benthic foraminiferal Mg/Ca ratios to questions of Cenozoic climate change".
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Lea, D. W. (5 September 2003). "Synchroneity of Tropical and High-Latitude Atlantic Temperatures over the Last Glacial Termination".
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Pearson, Paul N.; Palmer, Martin R. (17 August 2000). "Atmospheric carbon dioxide concentrations over the past 60 million years".
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Lehman, Scott J.; Keigwin, Lloyd D. (30 April 1992). "Sudden changes in North Atlantic circulation during the last deglaciation".
1969:; Rosenthal, Yair; Slowey, Niall (October 2002). "Benthic foraminiferal Mg/Ca-paleothermometry: a revised core-top calibration". 1491: 201: 2061:"Diatom-inferred salinity records from the Arctic Siberian Margin: Implications for fluvial runoff patterns during the Holocene" 96: 2594: 68: 2216:; Lehman, S. J. (19 February 1993). "Mid-Depth Circulation of the Subpolar North Atlantic During the Last Glacial Maximum". 2659: 2448: 75: 2434: 1915: 1663: 115: 155:
by the re-construction of past climate at various intervals. Paleoceanographic research is also intimately tied to
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Vinogradova, N. & Ponte, R. In search of fingerprints of the recent intensification of the ocean water cycle.
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concentrations. Another application of δB in plankton shells can be used as an indirect proxy for atmospheric CO
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isotope ratios (δB) can be used to infer both recent as well as millennial time scale changes in the acidity,
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Herbert, T. D. (2003). "Alkenone paleotemperature determinations". In Holland, H.D.; Turekian, K.K. (eds.).
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event, another period in climate history thought to have experienced a weakening overturning circulation.
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where Mg/Ca is the Mg/Ca ratio found in the benthic foraminifera and BWT is the bottom water temperature.
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Shackleton, Nicholas (1 July 1967). "Oxygen Isotope Analyses and Pleistocene Temperatures Re-assessed".
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Pelejero, C. (30 September 2005). "Preindustrial to Modern Interdecadal Variability in Coral Reef pH".
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Several proxy methods have been used to infer past ocean circulation and changes to it. They include
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successfully quantified the tropical cooling that occurred during the last glacial period.
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Sea-surface temperature (SST) records can be extracted from deep-sea sediment cores using
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freshwater and changing salinity can also contribute to a reduction in sea ice extent.
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Yu, L. A global relationship between the ocean water cycle and near-surface salinity.
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Piggot, Charles Snowden. “Core Samples of the Ocean Bottom and Their Significance.”
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Urey, Harold C. (1947). "The thermodynamic properties of isotopic substances".
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Vertical redistribution of salt and layered changes in global ocean salinity.
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Henderson, Gideon M. (October 2002). "New oceanic proxies for paleoclimate".
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Paleoclimates : understanding climate change past and present
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All proxies included are useful in inferring the behavior of the
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shells formed during these times will have a larger δO value.
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is a more challenging quantity to infer from paleorecords.
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Bauch, Henning A.; Polyakova, Yelena I. (June 2003).
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concentrations over the past several million years.
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For example, McManus et al. used 180: 1678: 1418: 1144: 1120: 1099: 1079: 1058: 1038: 1018: 997: 977: 957: 937: 917: 897: 876: 856: 835: 815: 795: 775: 755: 735: 715: 169: 25: 1933:Earth and Planetary Science Letters 1838: 1610:Earth and Planetary Science Letters 1451:isotopes (Nd and Nd), and sortable 1388: 131:is the study of the history of the 13: 1460:meridional overturning circulation 1362: 1359: 1356: 1315: 1312: 1304: 1301: 14: 2671: 2422: 1505:(PDO) can modulate the impact of 163:Source and methods of information 139:past with regard to circulation, 2428: 2132:Liu, C., Liang, X., Ponte, R.M. 1581: 1569: 1557: 1277:are the Mg/Ca ratios in benthic 30: 2588:Journal of Geophysical Research 2367: 2316: 2206: 2146: 2126: 2110: 2094: 2052: 2042: 2032: 2027:10.1016/j.quascirev.2009.10.007 2014: 1997: 1971:Geochimica et Cosmochimica Acta 1959: 1924: 1908:10.1016/B0-08-043751-6/06115-6 1883: 1832: 1789: 1754: 1703: 1672: 1601: 1366: 1340: 714: 1: 2238:10.1126/science.259.5098.1148 1991:10.1016/S0016-7037(02)00941-9 1953:10.1016/S0012-821X(03)00067-0 1630:10.1016/S0012-821X(02)00809-9 1594: 54:secondary or tertiary sources 2581:Geophysical Research Letters 1783:10.1016/0079-6611(65)90020-0 1509:due to rising atmospheric CO 1275:deep-sea temperature history 7: 2660:Oceanographical terminology 1520: 1503:Pacific decadal oscillation 1479:Acidity, pH, and alkalinity 1397: 1169: 929:Earliest multicellular life 399: 10: 2676: 2472:American Geophysical Union 1654:Cronin, Thomas M. (2010). 1227:Oxygen isotope ratios (δO) 1199:), stable and radioactive 147:, geology and patterns of 21:Paleoceanography (journal) 18: 2565: 2499: 2478: 2623:Water Resources Research 2552:Charles A. Whitten Medal 2537:James B. Macelwane Medal 2102:J. Geophys. Res. -Oceans 1892:Treatise on geochemistry 1763:Progress in Oceanography 1269:Bottom-water temperature 1257:relationships needed in 355:−1000 — 335:−1500 — 315:−2000 — 295:−2500 — 275:−3000 — 255:−3500 — 235:−4000 — 215:−4500 — 212: 2345:10.1126/science.1113692 1945:2003E&PSL.209..181B 1861:10.1126/science.1088470 1622:2002E&PSL.203....1H 1241:in place of calcium in 1215:Sea-surface temperature 375:−500 — 2527:Robert E. Horton Medal 2512:Walter H. Bucher Medal 2005:The Scientific Monthly 1443:isotopes (Pa and Th), 1376: 41:relies excessively on 2609:Reviews of Geophysics 2522:William Gilbert Award 2158:10.5194/tc-8-453-2014 1425:carbon isotope ratios 1377: 1221:oxygen isotope ratios 19:For the journal, see 2547:Waldo E. Smith Award 2437:at Wikimedia Commons 2088:10.1029/2002PA000847 1689:10.1039/JR9470000562 1297: 1237:The substitution of 2542:Roger Revelle Medal 2517:Maurice Ewing Medal 2507:William Bowie Medal 2388:2000Natur.406..695P 2337:2005Sci...309.2204P 2331:(5744): 2204–2207. 2294:10.1038/nature02494 2286:2004Natur.428..834M 2230:1993Sci...259.1148O 2224:(5098): 1148–1152. 2184:1992Natur.356..757L 2123:, 5513–5528 (2017). 2080:2003PalOc..18.1027B 1983:2002GeCoA..66.3375L 1900:2003TrGeo...6..391H 1853:2003Sci...301.1361L 1847:(5638): 1361–1364. 1810:1967Natur.215...15S 1775:1963PrOce...3..221O 1724:1955JG.....63..538E 1507:ocean acidification 1497:concentrations and 909:Sexual reproduction 888:Huronian glaciation 2532:Inge Lehmann Medal 1712:Journal of Geology 1372: 1156:Quaternary ice age 1091:Earliest tetrapods 1050:Cambrian explosion 1009:Cryogenian ice age 868:Atmospheric oxygen 847:Pongola glaciation 475:Multicellular life 427:Single-celled life 65:"Paleoceanography" 2632: 2631: 2433:Media related to 2382:(6797): 695–699. 2280:(6985): 834–837. 2178:(6372): 757–762. 1977:(19): 3375–3387. 1419:Ocean circulation 1189: 1188: 1173:million years ago 1164: 1163: 1143: 1142: 1119: 1118: 1098: 1097: 1078: 1077: 1070:Andean glaciation 1057: 1056: 1037: 1036: 1017: 1016: 996: 995: 976: 975: 956: 955: 936: 935: 916: 915: 896: 895: 875: 874: 855: 854: 834: 833: 814: 813: 794: 793: 774: 773: 754: 753: 734: 733: 126: 125: 118: 100: 2667: 2645:Paleoceanography 2465: 2458: 2451: 2442: 2441: 2435:Paleoceanography 2432: 2416: 2415: 2396:10.1038/35021000 2371: 2365: 2364: 2320: 2314: 2313: 2269: 2258: 2257: 2210: 2204: 2203: 2192:10.1038/356757a0 2167: 2161: 2150: 2144: 2130: 2124: 2114: 2108: 2107:, C10025 (2011). 2098: 2092: 2091: 2068:Paleoceanography 2065: 2056: 2050: 2046: 2040: 2039:Paleoceanography 2036: 2030: 2018: 2012: 2001: 1995: 1994: 1967:Lear, Caroline H 1963: 1957: 1956: 1939:(1–2): 181–195. 1928: 1922: 1921: 1887: 1881: 1880: 1836: 1830: 1829: 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443:Photosynthesis 441: 440: 439: 434: 433: 432: 425: 424: 423: 418: 417: 416: 409: 408: 407: 402: 401: 400: 398: 395:0 — 393: 388: 383: 378: 373: 368: 363: 358: 353: 348: 343: 338: 333: 328: 323: 318: 313: 308: 303: 298: 293: 288: 283: 278: 273: 268: 263: 258: 253: 248: 243: 238: 233: 228: 223: 218: 213: 210: 209: 207: 206: 199: 192: 181: 178: 177: 170: 164: 161: 124: 123: 38: 36: 29: 15: 9: 6: 4: 3: 2: 2672: 2661: 2658: 2656: 2653: 2651: 2648: 2646: 2643: 2642: 2640: 2625: 2624: 2620: 2618: 2617: 2616:Space Weather 2613: 2611: 2610: 2606: 2604: 2603: 2602:Radio Science 2599: 2597: 2596: 2592: 2590: 2589: 2585: 2583: 2582: 2578: 2576: 2575: 2571: 2570: 2568: 2564: 2558: 2557:Whipple Award 2555: 2553: 2550: 2548: 2545: 2543: 2540: 2538: 2535: 2533: 2530: 2528: 2525: 2523: 2520: 2518: 2515: 2513: 2510: 2508: 2505: 2504: 2502: 2498: 2492: 2489: 2487: 2484: 2483: 2481: 2477: 2473: 2466: 2461: 2459: 2454: 2452: 2447: 2446: 2443: 2436: 2431: 2427: 2426: 2413: 2409: 2405: 2401: 2397: 2393: 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W. 1769:: 221–252. 1616:(1): 1–13. 1499:bicarbonate 1445:radiocarbon 1412:water cycle 183:This box: 2639:Categories 2486:Presidents 2479:Membership 2138:Nat Commun 2074:(2): n/a. 1683:: 562–81. 1595:References 1283:ostracodes 519:Arthropods 459:Eukaryotes 76:newspapers 43:references 2412:205008176 2361:129883047 2310:205210064 1748:225042939 1449:neodymium 1407:Deuterium 1353:∗ 1347:± 1338:⁡ 1332:∗ 1326:± 1254:Alkenones 1239:magnesium 1197:alkenones 540:Dinosaurs 141:chemistry 2404:10963587 2353:16195458 2302:15103371 2254:23996710 2246:17794395 2118:J. Clim. 1877:28169540 1869:12958356 1740:30080906 1697:20249764 1521:See also 1403:Salinity 1398:Salinity 1201:isotopes 1181:Ice Ages 574:Primates 522:Molluscs 137:geologic 2491:Fellows 2384:Bibcode 2333:Bibcode 2325:Science 2282:Bibcode 2226:Bibcode 2218:Science 2200:4351664 2180:Bibcode 2160:, 2014. 2076:Bibcode 1979:Bibcode 1941:Bibcode 1896:Bibcode 1849:Bibcode 1841:Science 1826:4221046 1806:Bibcode 1771:Bibcode 1720:Bibcode 1618:Bibcode 1564:Geology 1550:Portals 1468:thorium 1441:thorium 1433:calcium 1429:cadmium 1410:global 1232:calcite 1149:← 1125:← 1104:← 1084:← 1063:← 1043:← 1023:← 1002:← 982:← 962:← 942:← 922:← 902:← 881:← 861:← 840:← 820:← 800:← 780:← 760:← 740:← 720:← 556:Mammals 531:Flowers 390:– 385:— 380:– 370:– 365:— 360:– 350:– 345:— 340:– 330:– 325:— 320:– 310:– 305:— 300:– 290:– 285:— 280:– 270:– 265:— 260:– 250:– 245:— 240:– 230:– 225:— 220:– 153:climate 145:biology 135:in the 90:scholar 2500:Awards 2410:  2402:  2376:Nature 2359:  2351:  2308:  2300:  2274:Nature 2252:  2244:  2198:  2172:Nature 2134:et al. 1914:  1875:  1867:  1824:  1798:Nature 1746:  1738:  1695:  1662:  1576:Oceans 1290:form: 1247:shells 1136:humans 709:  702:  548:  511:  483:  467:  451:  435:  419:  403:  133:oceans 92:  85:  78:  71:  63:  2408:S2CID 2357:S2CID 2306:S2CID 2250:S2CID 2196:S2CID 2064:(PDF) 2009:JSTOR 1873:S2CID 1822:S2CID 1744:S2CID 1736:JSTOR 1484:Boron 1350:0.007 1344:0.109 1329:0.049 1323:0.867 1193:proxy 565:Birds 411:Water 97:JSTOR 83:books 2400:PMID 2349:PMID 2298:PMID 2242:PMID 1912:ISBN 1865:PMID 1693:PMID 1660:ISBN 1453:silt 1287:Lear 1281:and 1259:CaCO 1243:CaCO 1207:and 767:LUCA 203:edit 196:talk 189:view 69:news 2574:Eos 2392:doi 2380:406 2341:doi 2329:309 2290:doi 2278:428 2234:doi 2222:259 2188:doi 2176:356 2154:doi 2141:10, 2105:116 2084:doi 2023:doi 1987:doi 1949:doi 1937:209 1904:doi 1857:doi 1845:301 1814:doi 1802:215 1779:doi 1728:doi 1685:doi 1626:doi 1614:203 1335:exp 45:to 2641:: 2406:. 2398:. 2390:. 2378:. 2355:. 2347:. 2339:. 2327:. 2304:. 2296:. 2288:. 2276:. 2262:^ 2248:. 2240:. 2232:. 2220:. 2194:. 2186:. 2174:. 2121:30 2082:. 2072:18 2070:. 2066:. 1985:. 1975:66 1973:. 1947:. 1935:. 1910:. 1902:. 1871:. 1863:. 1855:. 1843:. 1820:. 1812:. 1800:. 1777:. 1765:. 1742:. 1734:. 1726:. 1716:63 1714:. 1691:. 1638:^ 1624:. 1612:. 1488:pH 1427:, 1211:. 1134:/ 159:. 143:, 56:. 2464:e 2457:t 2450:v 2414:. 2394:: 2386:: 2363:. 2343:: 2335:: 2312:. 2292:: 2284:: 2256:. 2236:: 2228:: 2202:. 2190:: 2182:: 2156:: 2090:. 2086:: 2078:: 2029:. 2025:: 1993:. 1989:: 1981:: 1955:. 1951:: 1943:: 1920:. 1906:: 1898:: 1879:. 1859:: 1851:: 1828:. 1816:: 1808:: 1785:. 1781:: 1773:: 1767:3 1750:. 1730:: 1722:: 1699:. 1687:: 1668:. 1632:. 1628:: 1620:: 1552:: 1515:2 1511:2 1494:2 1466:/ 1439:/ 1431:/ 1370:: 1367:) 1363:T 1360:W 1357:B 1341:( 1320:= 1316:a 1313:C 1309:/ 1305:g 1302:M 1261:3 1245:3 1178:* 1175:) 1171:( 1158:* 1113:* 1072:* 1011:* 890:* 849:* 693:c 691:i 689:o 687:z 685:o 683:r 681:e 679:n 677:a 675:h 673:P 662:c 660:i 658:o 656:z 654:o 652:r 650:e 648:t 646:o 644:r 642:P 623:n 621:a 619:e 617:h 615:c 613:r 611:A 595:n 593:a 591:e 589:d 587:a 585:H 502:s 500:t 498:n 496:a 494:l 492:P 119:) 113:( 108:) 104:( 94:· 87:· 80:· 73:· 50:. 23:.

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