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Pre-exponential factor

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at a particular temperature and fitting the data to the Arrhenius equation. The pre-exponential factor is generally not exactly constant, but rather depends on the specific reaction being studied and the temperature at which the reaction is occurring.
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The units of the pre-exponential factor A are identical to those of the rate constant and will vary depending on the order of the reaction. For a first-order reaction, it has units of s. For that reason, it is often called
267: 283:, the frequency factor, A, depends on how often molecules collide when all concentrations are 1 mol/L and on whether the molecules are properly oriented when they collide. Values of A for some reactions can be found at 151:. The pre-exponential factor can be thought of as a measure of the frequency of properly oriented collisions. It is typically determined experimentally by measuring the rate constant 177: 169: 315: 89: 61: 390: 42: 68: 75: 108: 414: 57: 46: 383: 409: 82: 291: 284: 35: 364: 140: 376: 144: 295: 147:. It is usually designated by A when determined from experiment, while Z is usually left for 8: 148: 154: 122: 356: 128: 280: 360: 316:"How do you calculate the pre-exponential factor from the Arrhenius equation?" 262:{\displaystyle A={\frac {k}{e^{-{\frac {E_{a}}{RT}}}}}=ke^{\frac {E_{a}}{RT}}} 403: 348: 143:(equation shown below), an empirical relationship between temperature and 334: 24: 16:
Numerical constant in the Arrhenius equation in Chemical Kinetics
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IUPAC Gold Book definition of pre-exponential factor
49:. Unsourced material may be challenged and removed. 261: 163: 401: 384: 391: 377: 109:Learn how and when to remove this message 139:is the pre-exponential constant in the 402: 294:, A can be expressed in terms of the 343: 47:adding citations to reliable sources 18: 13: 14: 426: 347: 23: 34:needs additional citations for 308: 1: 301: 363:. You can help Knowledge by 7: 10: 431: 342: 120: 58:"Pre-exponential factor" 415:Chemical reaction stubs 292:transition state theory 263: 165: 133:pre-exponential factor 296:entropy of activation 264: 166: 178: 155: 43:improve this article 149:collision frequency 259: 161: 141:Arrhenius equation 123:Arrhenius equation 410:Chemical kinetics 372: 371: 357:chemical reaction 298:of the reaction. 256: 224: 220: 164:{\displaystyle k} 129:chemical kinetics 119: 118: 111: 93: 422: 393: 386: 379: 351: 344: 327: 326: 324: 322: 312: 285:Collision theory 281:collision theory 274:frequency factor 268: 266: 265: 260: 258: 257: 255: 247: 246: 237: 225: 223: 222: 221: 219: 211: 210: 201: 188: 170: 168: 167: 162: 145:rate coefficient 114: 107: 103: 100: 94: 92: 51: 27: 19: 430: 429: 425: 424: 423: 421: 420: 419: 400: 399: 398: 397: 340: 331: 330: 320: 318: 314: 313: 309: 304: 248: 242: 238: 236: 232: 212: 206: 202: 200: 196: 192: 187: 179: 176: 175: 156: 153: 152: 125: 115: 104: 98: 95: 52: 50: 40: 28: 17: 12: 11: 5: 428: 418: 417: 412: 396: 395: 388: 381: 373: 370: 369: 352: 338: 337: 329: 328: 306: 305: 303: 300: 254: 251: 245: 241: 235: 231: 228: 218: 215: 209: 205: 199: 195: 191: 186: 183: 160: 121:Main article: 117: 116: 31: 29: 22: 15: 9: 6: 4: 3: 2: 427: 416: 413: 411: 408: 407: 405: 394: 389: 387: 382: 380: 375: 374: 368: 366: 362: 359:article is a 358: 353: 350: 346: 345: 341: 336: 333: 332: 317: 311: 307: 299: 297: 293: 290:According to 288: 286: 282: 279:According to 277: 275: 269: 252: 249: 243: 239: 233: 229: 226: 216: 213: 207: 203: 197: 193: 189: 184: 181: 173: 158: 150: 146: 142: 138: 134: 130: 124: 113: 110: 102: 91: 88: 84: 81: 77: 74: 70: 67: 63: 60: –  59: 55: 54:Find sources: 48: 44: 38: 37: 32:This article 30: 26: 21: 20: 365:expanding it 354: 339: 319:. Retrieved 310: 289: 278: 273: 270: 174: 136: 132: 126: 105: 96: 86: 79: 72: 65: 53: 41:Please help 36:verification 33: 321:December 8, 404:Categories 302:References 69:newspapers 198:− 99:June 2018 137:A factor 83:scholar 131:, the 85:  78:  71:  64:  56:  355:This 90:JSTOR 76:books 361:stub 323:2022 62:news 135:or 127:In 45:by 406:: 287:. 276:. 392:e 385:t 378:v 367:. 325:. 253:T 250:R 244:a 240:E 234:e 230:k 227:= 217:T 214:R 208:a 204:E 194:e 190:k 185:= 182:A 159:k 112:) 106:( 101:) 97:( 87:· 80:· 73:· 66:· 39:.

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"Pre-exponential factor"
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Arrhenius equation
chemical kinetics
Arrhenius equation
rate coefficient
collision frequency
collision theory
Collision theory
transition state theory
entropy of activation
"How do you calculate the pre-exponential factor from the Arrhenius equation?"
IUPAC Gold Book definition of pre-exponential factor
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chemical reaction
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