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Robert Gilliard

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that are responsive to external stimuli, such as light, heat and mechanical force. Gilliard has proposed thermochromic materials that could be used in combat uniforms when soldiers adapt to different temperatures or terrains. The thermochromic materials developed by Gilliard contain thermoluminescent
116:. His research involves the synthesis of molecules for energy storage, molecular materials, and main-group element mediated bond activation. He is a member of the editorial advisory board at Inorganic Chemistry, Chemical Communications, and Angewandte Chemie, among other scientific journals. 279: 660:
Gilliard, Robert J.; Abraham, Mariham Y.; Wang, Yuzhong; Wei, Pingrong; Xie, Yaoming; Quillian, Brandon; Schaefer, Henry F.; Schleyer, Paul v. R.; Robinson, Gregory H. (20 June 2012).
1070:"A Multidimensional Approach to CarbodiphosphoraneBismuth Coordination Chemistry: Cationization, Redox-Flexibility, and Stabilization of a Crystalline Bismuth Hydridoborate" 225:
complexes with redox- and coordination-state flexibility that offer new possibilities for bond activation, and bismuth-containing small molecules for C-H activation.
964:"Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone" 392:"Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone" 1411: 774:
Gilliard, Robert J.; Suter, Riccardo; Schrader, Erik; Benkő, Zoltán; Rheingold, Arnold L.; Grützmacher, Hansjörg; Protasiewicz, John D. (14 November 2017).
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Hollister, Kimberly; Molino, Andrew; Breiner, Grace; Walley, Jacob; Wentz, Kelsie; Conley, Ashley; Dickie, Diane; Wilson, David; Gilliard, Robert (2022).
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Hollister, Kimberly K.; Molino, Andrew; Breiner, Grace; Walley, Jacob E.; Wentz, Kelsie E.; Conley, Ashley M.; Dickie, Diane A.; Wilson, David J. D.;
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Gilliard, Robert J.; Heift, Dominikus; Benkő, Zoltán; Keiser, Jerod M.; Rheingold, Arnold L.; Grützmacher, Hansjörg; Protasiewicz, John D. (2018).
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Wentz, Kelsie E.; Molino, Andrew; Weisflog, Sarah L.; Kaur, Aishvaryadeep; Dickie, Diane A.; Wilson, David J. D.; Gilliard, Robert J. (May 2021).
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atoms into polycyclic aromatic hydrocarbons and investigates the optical and electronic properties. He has shown that the introduction of
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Wentz, Kelsie E.; Molino, Andrew; Freeman, Lucas A.; Dickie, Diane A.; Wilson, David J. D.; Gilliard, Robert J. (14 September 2022).
636:"Group 2 organometallic chemistry : an excursion into the chemistry of highly reactive organoberyllium complexes | WorldCat.org" 857: 250: 1421: 1416: 1157: 1131: 1360: 610: 1401: 191: 113: 67: 349:"Approaching Dianionic Tetraoxadiborecine Macrocycles: 10-Membered Bora-Crown Ethers Incorporating Borafluorenate Units" 1406: 1017:
Obi, Akachukwu D.; Frey, Nathan C.; Dickie, Diane A.; Webster, Charles Edwin; Gilliard, Robert J. (12 September 2022).
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Group 2 organometallic chemistry : an excursion into the chemistry of highly reactive organoberyllium complexes
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Wentz, Kelsie; Molino, Andrew; Freeman, Lucas; Dickie, Diane; Wilson, David; Gilliard, Robert (2022).
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Wentz, Kelsie; Molino, Andrew; Freeman, Lucas; Dickie, Diane; David, Wilson; Gilliard, Robert (2023).
1208:"UVa Chemistry Professor Robert J. Gilliard, Jr. Named a 2021 Sloan Fellow | Department of Chemistry" 286: 472:
Wang, Guocang; Walley, Jacob; Dickie, Diane; Pan, Sudip; Frenking, Gernot; Gilliard, Robert (2020).
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can facilitate modulation of electronic structure or the ability to activate gas molecules such as
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National Organization for the Professional Advancement of Black Chemists and Chemical Engineers
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Gilliard investigates molecular systems for energy storage and catalysis. He has investigated
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is an American chemist and researcher who is the Novartis Associate Professor of Chemistry at
144: 46: 1030: 1019:"N-Heterocyclic Carbene-Assisted Reversible Migratory Coupling of Aminoborane at Magnesium" 920: 308:"Boron-Doped Pentacenes: Isolation of Crystalline 5,12- and 5,7-Diboratapentacene Dianions" 222: 833: 8: 1069: 148: 1034: 924: 1132:"Gilliard Receives 2021 Thieme Chemistry Journals Award | Gilliard Research Laboratory" 999: 944: 882: 776:"Synthesis of P2C2O2 and P2CO via NHC-mediated coupling of the phosphaethynolate anion" 756: 501: 460: 419: 378: 335: 265: 210: 137: 50: 140:, where he studied chemistry and worked on organometallic transition metal compounds. 1064:
Obi, Akachukwu D.; Dickie, Diane A.; Tiznado, William; Frenking, Gernot; Pan, Sudip;
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Barker, Joshua; Obi, Akachukwu; Dickie, Diane; Gilliard, Robert (2023).
1258:"UVA Chemist Robert Gilliard's Research Earns Him a Packard Fellowship" 1233:"Beckman Foundation Announces 2021 Beckman Young Investigator Awardees" 792: 775: 725: 708: 163: 75: 677: 246:
2021 Negative Emissions Science Scialog Collaborative Innovation Award
556:"Robert Gilliard Biography | Booking Info for Speaking Engagements" 1359:
Advancement, Research Corporation for Science (15 February 2023).
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Lloyd N. Ferguson Young Scientist Award for Excellence in Research
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Advancement, Research Corporation for Science (25 January 2021).
909:"Stabilization of the Elusive 9-Carbene-9-Borafluorene Monoanion" 853:"Air-Stable Thermoluminescent Carbodicarbene-Borafluorenium Ions" 585:"Meet Organometallics' 2021 Distinguished Author Award Recipient" 433:"Air-Stable Thermoluminescent Carbodicarbene-Borafluorenium Ions" 1158:"Eight Projects Win Scialog: Negative Emissions Science Funding" 86: 1361:"RCSA's 1st Holland Awards Celebrate 6 Distinguished Scholars" 214: 846: 430: 156: 773: 289:
Harry Gray Award for Creative Work in Inorganic Chemistry
1063: 961: 706: 389: 346: 1284:"UVA Honors Faculty for Their Research and Scholarship" 906: 305: 659: 147:
for his doctoral research, where he worked alongside
1016: 174:, and worked on highly reactive phosphorus species. 709:"An isolable magnesium diphosphaethynolate complex" 471: 255:2021 Alfred P. Sloan Research Fellow in Chemistry 202:air-stable, colour-tuneable borafluorenium ions. 1383: 474:"A Stable, Crystalline Beryllium Radical Cation" 258:2021 Organometallics Distinguished Author Award 1412:Massachusetts Institute of Technology faculty 1365:Research Corporation for Science Advancement 1162:Research Corporation for Science Advancement 294:Research Corporation for Science Advancement 182:In 2017, Gilliard joined the faculty at the 1358: 1155: 119: 1310:"Dr. Lloyd N. Ferguson Professional Award" 662:"Carbene-Stabilized Beryllium Borohydride" 801: 791: 734: 724: 364: 968:Journal of the American Chemical Society 858:Journal of the American Chemical Society 834:"Visiting Assistant Professor 2021-2022" 666:Journal of the American Chemical Society 478:Journal of the American Chemical Society 437:Journal of the American Chemical Society 396:Journal of the American Chemical Society 312:Journal of the American Chemical Society 299: 251:National Science Foundation CAREER Award 353:Angewandte Chemie International Edition 1397:People from Hartsville, South Carolina 1384: 608: 177: 582: 261:2021 Beckman Young Investigator Award 209:for energy conversion. He introduces 192:Massachusetts Institute of Technology 136:. He was an undergraduate student at 114:Massachusetts Institute of Technology 68:Massachusetts Institute of Technology 578: 576: 525: 523: 243:2021 Thieme Chemistry Journals Award 228: 1237:Arnold and Mabel Beckman Foundation 151:. His doctoral research considered 13: 14: 1433: 1335:"ACS 2023 National Award winners" 573: 520: 609:Melvin, Jim (7 September 2020). 531:"| Gilliard Research Laboratory" 207:polycyclic aromatic hydrocarbons 153:Group 2 organometallic chemistry 132:, where he was president of the 1352: 1327: 1302: 1276: 1250: 1225: 1200: 1175: 1149: 1136:gilliardgroup.chem.virginia.edu 1124: 1099: 1057: 1010: 955: 900: 840: 535:gilliardgroup.chem.virginia.edu 292:2023 Robert Holland Jr. Award, 237:Chemical & Engineering News 205:Gilliard has also investigated 172:Case Western Reserve University 80:Case Western Reserve University 1422:Scientists from South Carolina 1417:21st-century American chemists 826: 767: 700: 653: 628: 602: 548: 1: 1086:10.1021/acs.inorgchem.2c03337 583:Reeve, Erin (10 March 2021). 513: 16:American chemist and academic 1402:University of Georgia alumni 589:ACS Axial | ACS Publications 7: 560:www.allamericanspeakers.com 268:for Science and Engineering 194:, and moved there in 2022. 10: 1438: 126:Hartsville, South Carolina 36:Hartsville, South Carolina 1407:Clemson University alumni 1212:chemistry.as.virginia.edu 287:American Chemical Society 275:Research Excellence Award 103: 85: 63: 56: 42: 30: 23: 120:Early life and education 1066:Gilliard, Robert J. Jr. 849:Gilliard, Robert J. Jr. 780:Chemical Communications 110:Robert J. Gilliard, Jr. 1043:10.1002/ange.202211496 933:10.1002/ange.202103628 366:10.1002/anie.202215772 273:University of Virginia 221:. He has demonstrated 190:Visiting professor at 188:Martin Luther King Jr. 184:University of Virginia 130:Hartsville High School 72:University of Virginia 300:Selected publications 145:University of Georgia 47:University of Georgia 1187:give.as.virginia.edu 980:10.1021/jacs.2c06845 871:10.1021/jacs.1c11861 490:10.1021/jacs.9b13777 449:10.1021/jacs.1c11861 408:10.1021/jacs.2c06845 324:10.1021/jacs.2c11494 1080:(48): 19452–19462. 1035:2022AngCh.13411496O 974:(36): 16276–16281. 925:2021AngCh.13313175W 919:(23): 13175–13182. 803:20.500.11850/220073 786:(91): 12325–12328. 736:20.500.11850/235643 713:Dalton Transactions 402:(36): 16276–16281. 178:Research and career 149:Gregory H. Robinson 793:10.1039/C7CC07654A 726:10.1039/c7dt04539e 266:Packard Fellowship 138:Clemson University 51:Clemson University 25:Robert J. Gilliard 1290:. 28 January 2022 1264:. 20 October 2021 1023:Angewandte Chemie 913:Angewandte Chemie 678:10.1021/ja304514f 672:(24): 9953–9955. 484:(10): 4560–4564. 359:(5): e202215772. 229:Awards and honors 124:Gilliard is from 107: 106: 58:Scientific career 1429: 1376: 1375: 1373: 1371: 1356: 1350: 1349: 1347: 1345: 1331: 1325: 1324: 1322: 1320: 1306: 1300: 1299: 1297: 1295: 1280: 1274: 1273: 1271: 1269: 1254: 1248: 1247: 1245: 1243: 1229: 1223: 1222: 1220: 1218: 1204: 1198: 1197: 1195: 1193: 1179: 1173: 1172: 1170: 1168: 1153: 1147: 1146: 1144: 1142: 1128: 1122: 1121: 1119: 1117: 1103: 1097: 1096: 1094: 1092: 1061: 1055: 1054: 1014: 1008: 1007: 959: 953: 952: 904: 898: 897: 895: 893: 844: 838: 837: 830: 824: 823: 805: 795: 771: 765: 764: 738: 728: 704: 698: 697: 657: 651: 650: 648: 646: 640:www.worldcat.org 632: 626: 625: 623: 621: 606: 600: 599: 597: 595: 580: 571: 570: 568: 566: 552: 546: 545: 543: 541: 527: 509: 468: 427: 386: 368: 343: 318:(4): 2028–2034. 143:He moved to the 99: 21: 20: 1437: 1436: 1432: 1431: 1430: 1428: 1427: 1426: 1382: 1381: 1380: 1379: 1369: 1367: 1357: 1353: 1343: 1341: 1333: 1332: 1328: 1318: 1316: 1314:www.nobcche.org 1308: 1307: 1303: 1293: 1291: 1282: 1281: 1277: 1267: 1265: 1256: 1255: 1251: 1241: 1239: 1231: 1230: 1226: 1216: 1214: 1206: 1205: 1201: 1191: 1189: 1181: 1180: 1176: 1166: 1164: 1154: 1150: 1140: 1138: 1130: 1129: 1125: 1115: 1113: 1105: 1104: 1100: 1090: 1088: 1062: 1058: 1015: 1011: 960: 956: 905: 901: 891: 889: 845: 841: 832: 831: 827: 772: 768: 705: 701: 658: 654: 644: 642: 634: 633: 629: 619: 617: 607: 603: 593: 591: 581: 574: 564: 562: 554: 553: 549: 539: 537: 529: 528: 521: 516: 302: 231: 199:smart materials 180: 168:Ford Foundation 122: 97: 78: 74: 70: 49: 43:Alma mater 38: 26: 17: 12: 11: 5: 1435: 1425: 1424: 1419: 1414: 1409: 1404: 1399: 1394: 1378: 1377: 1351: 1326: 1301: 1275: 1249: 1224: 1199: 1174: 1148: 1123: 1098: 1056: 1009: 954: 899: 865:(1): 590–598. 839: 825: 766: 719:(3): 666–669. 699: 652: 627: 601: 572: 547: 518: 517: 515: 512: 511: 510: 469: 443:(1): 590–598. 428: 387: 344: 301: 298: 297: 296: 290: 283: 276: 269: 262: 259: 256: 253: 247: 244: 241: 230: 227: 223:alkaline earth 219:carbon dioxide 179: 176: 128:. He attended 121: 118: 105: 104: 101: 100: 89: 83: 82: 65: 61: 60: 54: 53: 44: 40: 39: 34: 32: 28: 27: 24: 15: 9: 6: 4: 3: 2: 1434: 1423: 1420: 1418: 1415: 1413: 1410: 1408: 1405: 1403: 1400: 1398: 1395: 1393: 1392:Living people 1390: 1389: 1387: 1366: 1362: 1355: 1340: 1336: 1330: 1315: 1311: 1305: 1289: 1285: 1279: 1263: 1259: 1253: 1238: 1234: 1228: 1213: 1209: 1203: 1188: 1184: 1178: 1163: 1159: 1152: 1137: 1133: 1127: 1112: 1108: 1102: 1087: 1083: 1079: 1075: 1071: 1067: 1060: 1052: 1048: 1044: 1040: 1036: 1032: 1028: 1024: 1020: 1013: 1005: 1001: 997: 993: 989: 985: 981: 977: 973: 969: 965: 958: 950: 946: 942: 938: 934: 930: 926: 922: 918: 914: 910: 903: 888: 884: 880: 876: 872: 868: 864: 860: 859: 854: 850: 843: 835: 829: 821: 817: 813: 809: 804: 799: 794: 789: 785: 781: 777: 770: 762: 758: 754: 750: 746: 742: 737: 732: 727: 722: 718: 714: 710: 703: 695: 691: 687: 683: 679: 675: 671: 667: 663: 656: 641: 637: 631: 616: 612: 605: 590: 586: 579: 577: 561: 557: 551: 536: 532: 526: 524: 519: 507: 503: 499: 495: 491: 487: 483: 479: 475: 470: 466: 462: 458: 454: 450: 446: 442: 438: 434: 429: 425: 421: 417: 413: 409: 405: 401: 397: 393: 388: 384: 380: 376: 372: 367: 362: 358: 354: 350: 345: 341: 337: 333: 329: 325: 321: 317: 313: 309: 304: 303: 295: 291: 288: 284: 281: 277: 274: 270: 267: 263: 260: 257: 254: 252: 248: 245: 242: 239: 238: 233: 232: 226: 224: 220: 216: 212: 208: 203: 200: 195: 193: 189: 185: 175: 173: 169: 165: 161: 158: 154: 150: 146: 141: 139: 135: 131: 127: 117: 115: 111: 102: 95: 94: 90: 88: 84: 81: 77: 73: 69: 66: 62: 59: 55: 52: 48: 45: 41: 37: 33: 29: 22: 19: 1368:. 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Chem 892:18 February 645:18 February 620:18 February 594:18 February 565:18 February 540:18 February 240:Talented 12 155:. He was a 1386:Categories 514:References 211:main-group 164:ETH Zurich 162:Fellow at 76:ETH Zurich 1288:UVA Today 1262:UVA Today 1051:0044-8249 1004:251931742 988:0002-7863 949:241226260 941:0044-8249 887:245733434 812:1364-548X 745:1477-9226 686:0002-7863 506:211262005 465:245713340 424:251931742 383:254043076 340:256192152 1370:14 March 1068:(2022). 996:36037435 879:35016509 851:(2022). 820:29095454 753:29242885 694:22670857 498:32088963 457:35016509 416:36037435 375:36437238 332:36689632 1031:Bibcode 921:Bibcode 836:. 2021. 761:4045258 170:Fellow 1049:  1029:(43). 1002:  994:  986:  947:  939:  885:  877:  818:  810:  759:  751:  743:  692:  684:  504:  496:  463:  455:  422:  414:  381:  373:  338:  330:  98:(2014) 96:  87:Thesis 1000:S2CID 945:S2CID 883:S2CID 757:S2CID 502:S2CID 461:S2CID 420:S2CID 379:S2CID 336:S2CID 285:2023 278:2022 271:2022 264:2021 249:2021 234:2020 215:boron 160:Merck 1372:2023 1346:2023 1321:2023 1296:2023 1270:2023 1244:2023 1219:2023 1194:2023 1169:2023 1143:2023 1118:2023 1093:2023 1047:ISSN 992:PMID 984:ISSN 937:ISSN 894:2023 875:PMID 816:PMID 808:ISSN 749:PMID 741:ISSN 690:PMID 682:ISSN 647:2023 622:2023 596:2023 567:2023 542:2023 494:PMID 453:PMID 412:PMID 371:PMID 328:PMID 166:and 157:UNCF 31:Born 1082:doi 1039:doi 1027:134 976:doi 972:144 929:doi 917:133 867:doi 863:144 798:hdl 788:doi 731:hdl 721:doi 674:doi 670:134 486:doi 482:142 445:doi 441:144 404:doi 400:144 361:doi 320:doi 316:145 1388:: 1363:. 1337:. 1312:. 1286:. 1260:. 1235:. 1210:. 1185:. 1160:. 1134:. 1109:. 1078:61 1076:. 1072:. 1045:. 1037:. 1025:. 1021:. 998:. 990:. 982:. 970:. 966:. 943:. 935:. 927:. 915:. 911:. 881:. 873:. 861:. 855:. 814:. 806:. 796:. 784:53 782:. 778:. 755:. 747:. 739:. 729:. 717:47 715:. 711:. 688:. 680:. 668:. 664:. 638:. 613:. 587:. 575:^ 558:. 533:. 522:^ 500:. 492:. 480:. 476:. 459:. 451:. 439:. 435:. 418:. 410:. 398:. 394:. 377:. 369:. 357:62 355:. 351:. 334:. 326:. 314:. 310:. 1374:. 1348:. 1323:. 1298:. 1272:. 1246:. 1221:. 1196:. 1171:. 1145:. 1120:. 1095:. 1084:: 1053:. 1041:: 1033:: 1006:. 978:: 951:. 931:: 923:: 896:. 869:: 822:. 800:: 790:: 763:. 733:: 723:: 696:. 676:: 649:. 624:. 598:. 569:. 544:. 508:. 488:: 467:. 447:: 426:. 406:: 385:. 363:: 342:. 322::

Index

Hartsville, South Carolina
University of Georgia
Clemson University
Massachusetts Institute of Technology
University of Virginia
ETH Zurich
Case Western Reserve University
Thesis
Group 2 organometallic chemistry : an excursion into the chemistry of highly reactive organoberyllium complexes
Massachusetts Institute of Technology
Hartsville, South Carolina
Hartsville High School
student body
Clemson University
University of Georgia
Gregory H. Robinson
Group 2 organometallic chemistry
UNCF
Merck
ETH Zurich
Ford Foundation
Case Western Reserve University
University of Virginia
Martin Luther King Jr.
Massachusetts Institute of Technology
smart materials
polycyclic aromatic hydrocarbons
main-group
boron
carbon dioxide

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