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24:
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398:
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587:. Salen ligands are notable for coordinating a wide range of different metals, which they can often stabilise in various oxidation states. For this reason salen-type compounds are used as
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782:
460:
832:
733:
Shaw, Subrata; White, James D. (11 June 2019). "Asymmetric
Catalysis Using Chiral Salen–Metal Complexes: Recent Advances".
583:). It may also refer to a class of compounds, which are structurally related to the classical salen ligand, primarily bis-
522:
908:
279:
InChI=1S/C16H16N2O2/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20/h1-8,11-12,19-20H,9-10H2/b17-11+,18-12+
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Cozzi, Pier
Giorgio (2004). "Metal–Salen Schiff base complexes in catalysis: practical aspects".
868:
Pier
Giorgio Cozzi (2004). "Metal-Salen Schiff base complexes in catalysis: Practical aspects".
649:
Complexes of salen with metal cations can often be made in situ, i.e., without isolating the H
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778:"Nebenvalenzringverbindungen. IV. Über einige innerkomplexe Kobaltsalze der Oxyaldimine"
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This article is about Salen. For
Complexes of salen and related ligands, see
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Except where otherwise noted, data are given for materials in their
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815:'-Disalicylalethylenediamine)-μ - Aquodicobalt(II)".
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867:
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201:
811:Diehl, Harvey; Hach, Clifford C. (1950). "Bis(
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38:2,2′-Ethylenebis(nitrilomethylidene)diphenol,
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795:
783:Bulletin of the Chemical Society of Japan
732:
637:Salcomine, a complex of salen with cobalt
221:
640:
632:
621:of ethylenediamine and salicylaldehyde.
303:C1=CC=C(C(=C1)/C=N/CC/N=C/C2=CC=CC=C2O)O
250:
901:
360:126 °C (259 °F; 399 K)
152:
697:
282:Key: VEUMANXWQDHAJV-JYFOCSDGSA-N
119:
861:
192:
13:
674:, a structurally related class of
14:
930:
819:. Vol. 3. pp. 196–201.
625:
617:salen may be synthesized by the
512:
388:
22:
661:salen + M → M(salen) + 2 H
508:(at 25 °C , 100 kPa).
804:
769:
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691:
680:-symmetric imine based ligands
1:
685:
645:Jacobsen's salen-Mn catalyst
7:
747:10.1021/acs.chemrev.9b00074
665:
46:′-Ethylenebis(salicylimine)
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825:10.1002/9780470132340.ch53
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603:Synthesis and complexation
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909:Organometallic chemistry
435:Precautionary statements
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672:Bisthiosemicarbazones
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609:Metal salen complexes
593:Metal salen complexes
548:Metal salen complexes
919:Tetradentate ligands
776:Tsumaki, T. (1938).
350:268.32
79: (non-specific)
817:Inorganic Syntheses
797:10.1246/bcsj.13.252
18:
647:
639:
589:metal deactivators
535:Infobox references
16:
834:978-0-470-13234-0
741:(16): 9381–9426.
595:also find use as
567:synthesized from
565:-symmetric ligand
543:Chemical compound
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540:
413:Hazard statements
235:CompTox Dashboard
101:Interactive image
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569:salicylaldehyde
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17:Salen ligand
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619:condensation
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585:Schiff bases
580:
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558:tetradentate
556:refers to a
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552:
404:
371:
121:ChEMBL594100
52:Identifiers
43:
39:
36:Other names
399:Signal word
312:Properties
159:100.002.161
69:129409-01-4
903:Categories
686:References
383:Pictograms
346:Molar mass
223:M122L9EGR6
132:ChemSpider
88:3D model (
59:CAS Number
853:ignored (
843:cite book
763:184486101
597:catalysts
489:P403+P233
481:P337+P313
477:P332+P313
461:P304+P340
457:P302+P352
374:labelling
180:202-376-3
172:EC Number
890:15354222
755:31184109
720:15354222
666:See also
653:salen.
365:Hazards
141:10484366
528:what is
526: (
405:Warning
340:
190:PubChem
76:94-93-9
888:
831:
761:
753:
718:
575:) and
523:verify
520:
296:SMILES
112:ChEMBL
31:Names
759:S2CID
554:Salen
271:InChI
203:26518
90:JSmol
886:PMID
855:help
829:ISBN
751:PMID
716:PMID
497:P501
493:P405
485:P362
473:P321
469:P312
453:P280
449:P271
445:P264
441:P261
427:H335
423:H319
419:H315
214:UNII
878:doi
821:doi
813:N,N
792:doi
743:doi
739:119
708:doi
573:sal
372:GHS
240:EPA
193:CID
905::
884:.
874:33
872:.
847::
845:}}
841:{{
827:.
788:13
780:.
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749:.
737:.
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704:33
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581:en
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330:16
326:16
892:.
880::
857:)
837:.
823::
800:.
794::
765:.
745::
722:.
710::
678:2
676:C
659:2
657:H
651:2
615:2
613:H
579:(
571:(
563:2
561:C
550:.
518:N
338:2
336:O
334:2
332:N
328:H
324:C
242:)
238:(
92:)
44:N
42:,
40:N
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