Knowledge

Saponification value

Source πŸ“

22: 232: 466:, rather than KOH (caustic potash) which produces soft paste, gel or liquid soaps. In order to calculate the lye amount needed to make bar soap, KOH values of SV can be converted to NaOH values by dividing KOH values by the ratio of the molecular weights of KOH and NaOH (1.403). 88:. The higher the saponification value, the lower the fatty acids average length, the lighter the mean molecular weight of triglycerides and vice versa. Practically, fats or oils with high saponification value (such as coconut and palm oil) are more suitable for 550: 788:, texturing etc. On the other hand, when proportion of unsaponifiables is too high (> 3%), or the specific unsaponifiables present do not provide significant benefits, a defective or inferior soap product can result. For example, 666: 604:, the SV of a given fat is inversely proportional to its molecular weight. Actually, as fats and oils contain a mix of different triglycerides species, the average MW can be calculated according to the following relation: 775:
Unsaponifiable constituents are an important consideration when selecting oil mixtures for the manufacture of soaps. Unsaponifiables can be beneficial to a soap formula because they may have properties such as
149: 370: 692:
saponifiable functions were present per g of coconut oil, which means more KOH is required to saponify the same amount of matter, and thus a higher SV. The calculated molecular weight (Eq.
136:
indicator, which indicates the consumption of strong base (KOH) by the acid, not the weak base (potassium carboxylates). The SV (mg KOH/ g of sample) is calculated as following:
487: 323: 297: 271: 617: 802:
Determination of unsaponifiables involves a saponification step of the sample followed by extraction of the unsaponifiable using an organic solvent (i.e.
593:
with a total MW of 885.4 (g / mol). Therefore, its SV equals 190 mg KOH / g sample. In comparison, trilaurin with three shorter fatty acid residues (
1412: 811: 399: 227:{\displaystyle {\textrm {SV}}={\frac {({\textrm {B}}-{\textrm {S}})\times {\textrm {M}}\times 56.106}{{\textrm {W}}_{\textrm {oil/fat}}}}} 474:
The theoretical SV of a pure triglyceride molecule can be calculated by the following equation (where MW is its molecular weight):
684:
with an abundance of medium chain fatty acids (mainly lauric acid) contain more fatty acids per unit of weight than, for example,
1683: 760:(sterols esters, wax esters, tocopherols esters, ...). This fraction may also contain environmental contaminants and residues of 795:
For edible oils, the tolerated limit of unsaponifiable matter is 1.5% (olive, refined soybean), while inferior quality crude or
1837: 1782: 1755: 1667: 1640: 1605: 1565: 1538: 1422: 696:) is not applicable to fats and oils containing high amounts of unsaponifiable material, free fatty acids (> 0.1%), or 340: 1319: 1392: 815: 444: 732:
contains, by weight, 1.5 – 2.5% of unsaponifiable matter. Unsaponifiables include nonvolatile components :
728:
when treated with alkali and remain insoluble in water but soluble in organic solvents. For instance, typical
1956: 545:{\displaystyle {\textrm {MW}}_{\textrm {oil/fat}}={\frac {3\times 1000\times 56.106}{\textrm {SV}}}+38.049} 1343: 1447: 1879: 1372: 376:
For example, standard methods for determination of SV of vegetable and animal fats are as follows:
304: 278: 252: 125: 1798: 124:
consume one equivalent of base At the end of the reaction the quantity of KOH is determined by
112:. The KOH is consumed by reaction with triglycerides, which consume three equivalents of base. 1827: 1772: 1630: 1528: 1745: 1657: 1891: 792:
is not suitable for soap making as it may contain more than 10% of unsaponifiable matter.
8: 1495: 326: 61: 1895: 1684:"Trade standard applying to olive oils and olive pomace oils (COI/T.15/NC No 3/Rev. 14)" 661:{\displaystyle {\textrm {MW}}_{\textrm {oil/fat}}={\frac {168318}{\textrm {SV}}}+38.049} 1477: 807: 440: 1712: 1907: 1833: 1778: 1751: 1663: 1636: 1611: 1601: 1571: 1561: 1534: 1469: 1428: 1418: 1388: 821: 129: 1481: 1899: 1459: 1380: 781: 757: 459: 101: 77: 65: 1595: 1555: 1066: 789: 133: 1292: 1286: 1274: 1256: 935: 777: 439:
The SV can also be calculated from the fatty acid composition as determined by
69: 26: 1464: 1950: 1911: 1615: 1575: 1473: 1432: 1384: 1199: 803: 745: 697: 412: 117: 806:). Official methods for animal and vegetable fats and oils are described by 1925: 1280: 878: 469: 100:
To determine saponification value, the sample is treated with an excess of
85: 30: 21: 1903: 1268: 1250: 1180: 1161: 1030: 1011: 897: 785: 769: 761: 729: 701: 681: 594: 425: 113: 1247: β€“ Milligrams of a base needed to neutralize 1 gram of a given acid 1829:
Fish Oil Replacement and Alternative Lipid Sources in Aquaculture Feeds
1826:
Turchini, Giovanni M.; Ng, Wing-Keong; Tocher, Douglas Redford (2010).
1298: 1277: β€“ Mass of KOH needed to neutralize 1 gram of acetylized substance 1244: 1104: 859: 753: 749: 741: 586: 81: 1448:"Structure indices in FA chemistry. How relevant is the iodine value?" 1295: β€“ Process that converts fat, oil, or lipid into soap and alcohol 451: 1218: 1142: 1047: 765: 685: 1774:
Food Lipids: Chemistry, Nutrition, and Biotechnology, Third Edition
1262: 1123: 1085: 954: 916: 590: 582: 455: 34: 1880:"The estimation of unsaponifiable matter in oils, fats, and waxes" 1259: β€“ Mass of bromine absorbed by 100 grams of a given substance 822:
Saponification values and unsaponifiables of various oils and fats
1926:"SECTION 3. Codex Standard for Fats and Oils from Animal Sources" 1283: β€“ Mass of iodine absorbed by 100 grams of a given substance 973: 840: 121: 105: 299:
is the volume of HCl solution used for the tested sample, in mL;
1853: 796: 756:
as well as those that mainly result from the saponification of
737: 733: 109: 76:
under the conditions specified. It is a measure of the average
1713:"USDA commodity requirements document for bulk oil and tallow" 689: 585:, a triglyceride occurring in many fats and oils, has three 273:
is the volume of HCl solution used for the blank run, in mL;
1370: 992: 725: 417: 404: 89: 38: 1656:
Fryer, Percival J.; Weston, Frank E. (December 19, 2013).
1600:(Third ed.). Boca Raton, FL: CRC Press. p. 424. 1560:(Third ed.). Boca Raton, FL: CRC Press. p. 424. 1629:
Belitz, H.-D.; Grosch, Werner; Schieberle, Peter (2013).
1253: β€“ Measure of an organic compound's nitrogen content 721: 717: 713: 463: 430: 394: 390: 120:
and free fatty acids, as well as by other esters such as
73: 568:
3 is the number of fatty acids residues per triglyceride
470:
Calculation of average molecular weight of fats and oils
108:
solution of potassium hydroxide) for half an hour under
33:
molecule (left) with potassium hydroxide (KOH) yielding
1628: 1230: 1223: 1210: 1204: 1191: 1185: 1172: 1166: 1154: 1147: 1134: 1128: 1115: 1109: 1097: 1090: 1078: 1071: 1058: 1052: 1040: 1035: 1022: 1016: 1004: 997: 984: 978: 965: 959: 947: 940: 927: 921: 908: 902: 889: 883: 871: 864: 852: 845: 332: 712:
Unsaponifiables are components of a fatty substance (
620: 571:
1000 is the conversion factor for milligrams to grams
490: 343: 307: 281: 255: 152: 1289: β€“ Measure of peroxide content of a fat or oil 1271: β€“ Measure of the epoxy content of a substance 365:{\displaystyle {{\textrm {W}}_{\textrm {oil/fat}}}} 16:
Milligrams of a base required to saponify 1g of fat
660: 544: 364: 317: 291: 265: 226: 577:38.049 is the molecular mass of glycerol backbone 1948: 1825: 1593: 1553: 1806:Deutsche Gesellschaft fΓΌr Fettwissenschaft e.V 1377:Ullmann's Encyclopedia of Industrial Chemistry 1452:Journal of the American Oil Chemists' Society 1301:— Small scale process of producing soap 1655: 1547: 1414:Chemistry and Technology of Oils & Fats 1410: 335:is the molecular weight of KOH, in g / mol; 60:) represents the number of milligrams of 1659:Technical Handbook of Oils, Fats and Waxes 1635:. Springer Science & Business Media. 1533:. Springer Science & Business Media. 1522: 1520: 1518: 1516: 1463: 1379:. Weinheim: Wiley-VCH. pp. a24_247. 832:Saponification value (mg KOH / g sample) 1771:Akoh, Casimir C.; Min, David B. (2008). 1743: 688:(mainly oleic acid). Consequently, more 132:(HCl). Key to the method is the use of 20: 1770: 1526: 1411:Chakrabarty, M. M. (November 9, 2003). 1320:"Saponification Value of Fats and Oils" 1949: 1877: 1799:"Physical Properties of fats and Oils" 1594:Gunstone, F.D.; Harwood, J.L. (2007). 1554:Gunstone, F.D.; Harwood, J.L. (2007). 1527:Nielsen, Suzanne (September 4, 2014). 1513: 1445: 1371:Klaus Schumann; Kurt Siekmann (2005). 1739: 1737: 1344:"Saponification value of Fat and Oil" 589:residues esterified to a molecule of 1589: 1587: 1585: 1406: 1404: 1338: 1336: 611: 597:) has a MW of 639 and an SV of 263. 481: 143: 1265: β€“ Fuel standard for biodiesel 37:(purple) and salts of fatty acids ( 13: 1747:Oils and Fats in the Food Industry 1734: 707: 14: 1968: 1582: 1401: 1333: 116:consume two equivalents of KOH. 84:present in the sample in form of 1417:. New Delhi: Allied Publishers. 600:As it can be seen from equation 95: 1918: 1871: 1846: 1819: 1791: 1764: 1705: 1676: 1649: 1622: 607: 477: 139: 1662:. Cambridge University Press. 1488: 1439: 1364: 1312: 574:56.1 is the molar mass of KOH. 372:is the weight of sample, in g. 186: 166: 1: 1305: 318:{\displaystyle {\textrm {M}}} 292:{\displaystyle {\textrm {S}}} 266:{\displaystyle {\textrm {B}}} 80:(or chain length) of all the 772:hydrocarbons and aromatics. 329:of HCl solution, in mol / L; 7: 1238: 814:3596: 2000 or 18609: 2000, 128:using standard solution of 10: 1973: 1500:www.fromnaturewithlove.com 835:Unsaponifiable matter (%) 462:(NaOH), commonly known as 1750:. John Wiley & Sons. 1691:internationaloliveoil.org 1465:10.1007/s11746-002-0569-4 1878:Wilkie, John M. (1917). 1744:Gunstone, Frank (2009). 1446:Knothe, Gerhard (2002). 1385:10.1002/14356007.a24_247 1496:"Saponification Chart" 662: 546: 366: 319: 293: 267: 228: 42: 663: 547: 367: 320: 294: 268: 229: 50:saponification number 24: 1957:Analytical chemistry 1904:10.1039/AN9174200200 799:oil could reach 3%. 724:) that fail to form 618: 488: 341: 305: 279: 253: 150: 46:Saponification value 1896:1917Ana....42..200W 68:(NaOH) required to 62:potassium hydroxide 1597:The Lipid Handbook 1557:The Lipid Handbook 658: 542: 441:gas chromatography 413:Petroleum products 362: 315: 289: 263: 224: 43: 1854:"Lanolin - CAMEO" 1839:978-1-4398-0863-4 1784:978-1-4200-4664-9 1757:978-1-4443-0243-1 1669:978-1-107-68731-8 1642:978-3-662-07279-0 1607:978-1-4200-0967-5 1567:978-1-4200-0967-5 1540:978-1-4419-1477-4 1424:978-81-7764-495-1 1236: 1235: 818:method Ca 6a-40. 678: 677: 650: 648: 633: 626: 562: 561: 534: 532: 503: 496: 437: 436: 357: 350: 312: 286: 260: 244: 243: 222: 218: 211: 196: 183: 173: 157: 130:hydrochloric acid 1964: 1941: 1940: 1938: 1936: 1922: 1916: 1915: 1890:(495): 200–202. 1875: 1869: 1868: 1866: 1864: 1850: 1844: 1843: 1823: 1817: 1816: 1814: 1812: 1803: 1795: 1789: 1788: 1768: 1762: 1761: 1741: 1732: 1731: 1729: 1727: 1717: 1709: 1703: 1702: 1700: 1698: 1688: 1680: 1674: 1673: 1653: 1647: 1646: 1626: 1620: 1619: 1591: 1580: 1579: 1551: 1545: 1544: 1524: 1511: 1510: 1508: 1506: 1492: 1486: 1485: 1467: 1443: 1437: 1436: 1408: 1399: 1398: 1368: 1362: 1361: 1359: 1357: 1348: 1340: 1331: 1330: 1328: 1326: 1316: 1232: 1225: 1212: 1206: 1193: 1187: 1174: 1168: 1156: 1149: 1136: 1130: 1117: 1111: 1099: 1092: 1080: 1073: 1060: 1054: 1042: 1037: 1024: 1018: 1006: 999: 986: 980: 967: 961: 949: 942: 929: 923: 910: 904: 891: 885: 873: 866: 854: 847: 826: 825: 708:Unsaponifiables 680:This means that 667: 665: 664: 659: 651: 649: 646: 641: 636: 635: 634: 631: 628: 627: 624: 612: 609: 551: 549: 548: 543: 535: 533: 530: 528: 511: 506: 505: 504: 501: 498: 497: 494: 482: 479: 460:sodium hydroxide 385:Standard method 379: 378: 371: 369: 368: 363: 361: 360: 359: 358: 355: 352: 351: 348: 334: 324: 322: 321: 316: 314: 313: 310: 298: 296: 295: 290: 288: 287: 284: 272: 270: 269: 264: 262: 261: 258: 233: 231: 230: 225: 223: 221: 220: 219: 216: 213: 212: 209: 205: 198: 197: 194: 185: 184: 181: 175: 174: 171: 164: 159: 158: 155: 144: 141: 78:molecular weight 66:sodium hydroxide 1972: 1971: 1967: 1966: 1965: 1963: 1962: 1961: 1947: 1946: 1945: 1944: 1934: 1932: 1924: 1923: 1919: 1876: 1872: 1862: 1860: 1852: 1851: 1847: 1840: 1824: 1820: 1810: 1808: 1801: 1797: 1796: 1792: 1785: 1769: 1765: 1758: 1742: 1735: 1725: 1723: 1715: 1711: 1710: 1706: 1696: 1694: 1686: 1682: 1681: 1677: 1670: 1654: 1650: 1643: 1627: 1623: 1608: 1592: 1583: 1568: 1552: 1548: 1541: 1525: 1514: 1504: 1502: 1494: 1493: 1489: 1444: 1440: 1425: 1409: 1402: 1395: 1369: 1365: 1355: 1353: 1346: 1342: 1341: 1334: 1324: 1322: 1318: 1317: 1313: 1308: 1241: 1067:Palm kernel oil 824: 710: 702:diacylglycerols 645: 640: 630: 629: 623: 622: 621: 619: 616: 615: 529: 512: 510: 500: 499: 493: 492: 491: 489: 486: 485: 472: 403: 354: 353: 347: 346: 345: 344: 342: 339: 338: 309: 308: 306: 303: 302: 283: 282: 280: 277: 276: 257: 256: 254: 251: 250: 215: 214: 208: 207: 206: 193: 192: 180: 179: 170: 169: 165: 163: 154: 153: 151: 148: 147: 134:phenolphthalein 98: 17: 12: 11: 5: 1970: 1960: 1959: 1943: 1942: 1917: 1870: 1845: 1838: 1818: 1790: 1783: 1763: 1756: 1733: 1704: 1675: 1668: 1648: 1641: 1632:Food Chemistry 1621: 1606: 1581: 1566: 1546: 1539: 1512: 1487: 1458:(9): 847–854. 1438: 1423: 1400: 1393: 1363: 1332: 1310: 1309: 1307: 1304: 1303: 1302: 1296: 1293:Saponification 1290: 1287:Peroxide value 1284: 1278: 1275:Hydroxyl value 1272: 1266: 1260: 1257:Bromine number 1254: 1248: 1240: 1237: 1234: 1233: 1227: 1221: 1215: 1214: 1208: 1202: 1196: 1195: 1189: 1183: 1177: 1176: 1170: 1164: 1158: 1157: 1151: 1145: 1139: 1138: 1132: 1126: 1120: 1119: 1113: 1107: 1101: 1100: 1094: 1088: 1082: 1081: 1075: 1069: 1063: 1062: 1056: 1050: 1044: 1043: 1038: 1033: 1027: 1026: 1020: 1014: 1008: 1007: 1001: 995: 989: 988: 982: 976: 970: 969: 963: 957: 951: 950: 944: 938: 936:Cottonseed oil 932: 931: 925: 919: 913: 912: 906: 900: 894: 893: 887: 881: 875: 874: 868: 862: 856: 855: 849: 843: 837: 836: 833: 830: 823: 820: 778:moisturization 746:fatty alcohols 709: 706: 676: 675: 670: 668: 657: 654: 644: 639: 581:For instance, 579: 578: 575: 572: 569: 566: 560: 559: 554: 552: 541: 538: 527: 524: 521: 518: 515: 509: 471: 468: 435: 434: 428: 422: 421: 415: 409: 408: 397: 387: 386: 383: 374: 373: 336: 330: 300: 274: 248: 242: 241: 236: 234: 204: 201: 191: 188: 178: 168: 162: 118:Monoglycerides 97: 94: 29:reaction of a 27:saponification 15: 9: 6: 4: 3: 2: 1969: 1958: 1955: 1954: 1952: 1935:September 14, 1931: 1927: 1921: 1913: 1909: 1905: 1901: 1897: 1893: 1889: 1885: 1881: 1874: 1863:September 14, 1859: 1858:cameo.mfa.org 1855: 1849: 1841: 1835: 1832:. CRC Press. 1831: 1830: 1822: 1811:September 14, 1807: 1800: 1794: 1786: 1780: 1777:. CRC Press. 1776: 1775: 1767: 1759: 1753: 1749: 1748: 1740: 1738: 1726:September 15, 1721: 1714: 1708: 1697:September 15, 1692: 1685: 1679: 1671: 1665: 1661: 1660: 1652: 1644: 1638: 1634: 1633: 1625: 1617: 1613: 1609: 1603: 1599: 1598: 1590: 1588: 1586: 1577: 1573: 1569: 1563: 1559: 1558: 1550: 1542: 1536: 1532: 1531: 1530:Food Analysis 1523: 1521: 1519: 1517: 1505:September 13, 1501: 1497: 1491: 1483: 1479: 1475: 1471: 1466: 1461: 1457: 1453: 1449: 1442: 1434: 1430: 1426: 1420: 1416: 1415: 1407: 1405: 1396: 1394:3-527-30673-0 1390: 1386: 1382: 1378: 1374: 1367: 1352: 1351:kyoto-kem.com 1345: 1339: 1337: 1321: 1315: 1311: 1300: 1297: 1294: 1291: 1288: 1285: 1282: 1279: 1276: 1273: 1270: 1267: 1264: 1261: 1258: 1255: 1252: 1249: 1246: 1243: 1242: 1228: 1222: 1220: 1217: 1216: 1209: 1203: 1201: 1200:Sunflower oil 1198: 1197: 1190: 1184: 1182: 1179: 1178: 1171: 1165: 1163: 1160: 1159: 1152: 1146: 1144: 1143:Safflower oil 1141: 1140: 1133: 1127: 1125: 1122: 1121: 1114: 1108: 1106: 1103: 1102: 1095: 1089: 1087: 1084: 1083: 1076: 1070: 1068: 1065: 1064: 1057: 1051: 1049: 1046: 1045: 1039: 1034: 1032: 1029: 1028: 1021: 1015: 1013: 1010: 1009: 1002: 996: 994: 991: 990: 983: 977: 975: 972: 971: 964: 958: 956: 953: 952: 945: 939: 937: 934: 933: 926: 920: 918: 915: 914: 907: 901: 899: 896: 895: 888: 882: 880: 877: 876: 869: 863: 861: 858: 857: 850: 844: 842: 839: 838: 834: 831: 828: 827: 819: 817: 813: 809: 805: 804:diethyl ether 800: 798: 793: 791: 787: 783: 779: 773: 771: 767: 763: 759: 755: 751: 747: 743: 739: 735: 731: 727: 723: 719: 715: 705: 704:(> 0.1%). 703: 699: 695: 691: 687: 683: 674: 671: 669: 655: 652: 642: 637: 614: 613: 610: 605: 603: 598: 596: 592: 588: 584: 576: 573: 570: 567: 564: 563: 558: 555: 553: 539: 536: 525: 522: 519: 516: 513: 507: 484: 483: 480: 475: 467: 465: 461: 457: 453: 448: 446: 442: 432: 429: 427: 424: 423: 419: 416: 414: 411: 410: 406: 401: 398: 396: 392: 389: 388: 384: 381: 380: 377: 337: 331: 328: 301: 275: 249: 246: 245: 240: 237: 235: 202: 199: 189: 176: 160: 146: 145: 142: 137: 135: 131: 127: 123: 119: 115: 111: 107: 104:(usually an 103: 96:Determination 93: 91: 87: 86:triglycerides 83: 79: 75: 71: 67: 63: 59: 55: 51: 47: 40: 36: 32: 28: 23: 19: 1933:. Retrieved 1929: 1920: 1887: 1883: 1873: 1861:. Retrieved 1857: 1848: 1828: 1821: 1809:. Retrieved 1805: 1793: 1773: 1766: 1746: 1724:. Retrieved 1720:fsa.usda.gov 1719: 1707: 1695:. Retrieved 1690: 1678: 1658: 1651: 1631: 1624: 1596: 1556: 1549: 1529: 1503:. Retrieved 1499: 1490: 1455: 1451: 1441: 1413: 1376: 1366: 1354:. Retrieved 1350: 1323:. Retrieved 1314: 1281:Iodine value 1124:Rapeseed oil 879:Cocoa butter 810:D1065 - 18, 801: 794: 782:conditioning 774: 762:plasticizers 758:fatty esters 711: 693: 679: 672: 606: 601: 599: 580: 556: 476: 473: 454:who aim for 449: 438: 426:Mineral oils 375: 238: 138: 114:Diglycerides 99: 72:one gram of 57: 53: 49: 45: 44: 31:triglyceride 18: 1930:www.fao.org 1325:January 18, 1269:Epoxy value 1251:Amine value 1181:Soybean oil 1162:Shea butter 1031:Mineral oil 1012:Linseed oil 898:Coconut oil 786:antioxidant 770:mineral oil 754:carotenoids 750:tocopherols 742:triterpenes 730:soybean oil 682:coconut oil 595:lauric acid 452:soap makers 447:Cd 3a-94). 82:fatty acids 25:Example of 1306:References 1299:Soapmaking 1245:Acid value 1105:Peanut oil 860:Canola oil 829:Fat / oil 766:pesticides 587:oleic acid 1912:1364-5528 1616:327018169 1576:327018169 1474:1558-9331 1433:771847815 1219:Whale oil 1048:Olive oil 790:shark oil 686:olive oil 523:× 517:× 450:Handmade 402:3657:2020 200:× 190:× 177:− 126:titration 106:ethanolic 64:(KOH) or 1951:Category 1482:53055746 1263:EN 14214 1239:See also 1086:Palm oil 955:Fish oil 917:Corn oil 591:glycerol 583:triolein 456:bar soap 382:Product 327:molarity 122:lactones 92:making. 70:saponify 35:glycerol 1892:Bibcode 1884:Analyst 1373:"Soaps" 1356:July 8, 974:Lanolin 841:Beeswax 738:sterols 734:alkanes 632:oil/fat 502:oil/fat 356:oil/fat 325:is the 217:oil/fat 1910:  1836:  1781:  1754:  1722:. 2013 1693:. 2019 1666:  1639:  1614:  1604:  1574:  1564:  1537:  1480:  1472:  1431:  1421:  1391:  1226:– 202 1213:– 1.2 1207:– 195 1194:– 2.5 1188:– 195 1169:– 190 1150:– 194 1137:– 1.1 1131:– 181 1118:– 4.4 1112:– 196 1093:– 209 1074:– 254 1061:– 1.1 1055:– 196 1019:– 196 1000:– 203 981:– 127 962:– 200 943:– 207 924:– 195 911:– 1.4 905:– 265 886:– 200 867:– 193 848:– 102 797:pomace 656:38.049 643:168318 565:where: 540:38.049 526:56.106 433:51559 407:D5558 247:where: 203:56.106 110:reflux 102:alkali 1802:(PDF) 1716:(PDF) 1687:(PDF) 1478:S2CID 1347:(PDF) 1229:< 1175:– 17 1153:< 1096:< 1077:< 1003:< 987:– 50 946:< 870:< 851:> 726:soaps 698:mono- 690:ester 608:Eq. 3 478:Eq. 2 140:Eq. 1 1937:2020 1908:ISSN 1865:2020 1834:ISBN 1813:2020 1779:ISBN 1752:ISBN 1728:2020 1699:2020 1664:ISBN 1637:ISBN 1612:OCLC 1602:ISBN 1572:OCLC 1562:ISBN 1535:ISBN 1507:2020 1470:ISSN 1429:OCLC 1419:ISBN 1389:ISBN 1358:2016 1327:2018 1025:– 2 993:Lard 968:– 3 930:– 3 892:– 1 816:AOCS 808:ASTM 752:and 700:and 520:1000 458:use 445:AOCS 420:D94 418:ASTM 405:ASTM 395:oils 393:and 391:Fats 333:56.1 90:soap 39:soap 1900:doi 1460:doi 1381:doi 1224:185 1211:0.3 1205:189 1192:1.5 1186:187 1167:170 1155:1.6 1148:188 1135:0.7 1129:168 1116:0.2 1110:187 1098:1.4 1091:190 1072:230 1059:0.4 1053:184 1041:100 1023:0.1 1017:188 998:192 966:0.6 960:179 941:189 922:187 909:0.1 903:248 890:0.2 884:192 872:0.2 865:182 812:ISO 722:wax 718:fat 714:oil 673:(3) 602:(2) 557:(2) 464:lye 431:DIN 400:ISO 239:(1) 74:fat 56:or 48:or 1953:: 1928:. 1906:. 1898:. 1888:42 1886:. 1882:. 1856:. 1804:. 1736:^ 1718:. 1689:. 1610:. 1584:^ 1570:. 1515:^ 1498:. 1476:. 1468:. 1456:79 1454:. 1450:. 1427:. 1403:^ 1387:. 1375:. 1349:. 1335:^ 1005:10 985:40 979:80 853:52 846:60 784:, 780:, 768:, 764:, 748:, 744:, 740:, 736:, 720:, 716:, 647:SV 625:MW 531:SV 495:MW 156:SV 58:SN 54:SV 41:). 1939:. 1914:. 1902:: 1894:: 1867:. 1842:. 1815:. 1787:. 1760:. 1730:. 1701:. 1672:. 1645:. 1618:. 1578:. 1543:. 1509:. 1484:. 1462:: 1435:. 1397:. 1383:: 1360:. 1329:. 1231:2 1173:6 1079:1 1036:0 948:2 928:1 694:3 653:+ 638:= 537:+ 514:3 508:= 443:( 349:W 311:M 285:S 259:B 210:W 195:M 187:) 182:S 172:B 167:( 161:= 52:(

Index

Saponification reaction of a triglyceride
saponification
triglyceride
glycerol
soap
potassium hydroxide
sodium hydroxide
saponify
fat
molecular weight
fatty acids
triglycerides
soap
alkali
ethanolic
reflux
Diglycerides
Monoglycerides
lactones
titration
hydrochloric acid
phenolphthalein
molarity
Fats
oils
ISO
ASTM
Petroleum products
ASTM
Mineral oils

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