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742:. It is detonated by friction, shock, or spark. It remains stable at all temperatures which may be encountered in storage. It is generally used in the form of pressed pellets, and has been approved as the standard bursting charge for small-caliber projectiles, since it gives much better fragmentation than TNT. It has an
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The most toxic ordnance compounds, tetryl and 1,3,5-TNB, are also the most degradable. Therefore, these chemicals are expected to be short-lived in nature, and environmental impacts would not be expected in areas that are not currently subject to chronic inputs of these chemicals. Tetryl decomposes
779:
and acidified to pH < 3. All samples expected to contain tetryl should not be exposed to temperatures above room temperature. In addition, degradation products of tetryl appear as a shoulder on the 2,4,6-TNT peak. Peak heights rather than peak areas should be used when tetryl is present in
852:
Epidemiological data shows that tetryl has most effect on the skin, acting as a strong irritant. Symptoms of skin sensitization such as dermatitis, itch, erythema, etc. may occur. Tetryl can also affect mucous membranes, the upper respiratory tract, and possibly the liver.
848:
Although tetryl is among the most toxic explosive compounds, it is very short-lived. This combined with the fact that the health impacts of this compound are largely unstudied, not much is known about any health problems that this compound may cause.
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714:. Tetryl is a sensitive secondary high explosive used as a booster, a small charge placed next to the detonator in order to propagate detonation into the main explosive charge.
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958:“A Military Guide to Terrorism in the 21st Century.” August 2003. P. 171. U.S. Army Training and Doctrine Command, Fort Leavenworth, Kansas.
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and other solvents. When tetryl is heated, it first melts, then decomposes and explodes. It burns readily and is more easily detonated than
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812:. Tetryl is no longer manufactured or used in the United States, but can still be found in legacy munitions such as the
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and later conflicts. Tetryl is usually used on its own, though can sometimes be found in compositions such as
771:/water solutions, as well as with heat. All aqueous samples expected to contain tetryl should be diluted with
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Tetryl is a yellow crystalline solid powder material, practically insoluble in water but soluble in
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of 23,600–23,900 feet per second (7200–7300 m/s). Tetryl is the basis for the service tetryl
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CDC - Documentation for
Immediately Dangerous To Life or Health Concentrations (IDLHs)
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InChI=1S/C7H5N5O8/c1-8(12(19)20)7-5(10(15)16)2-4(9(13)14)3-6(7)11(17)18/h2-3H,1H3
780:
concentrations that are significant relative to the concentration of 2,4,6-TNT.
327:
InChI=1/C7H5N5O8/c1-8(12(19)20)7-5(10(15)16)2-4(9(13)14)3-6(7)11(17)18/h2-3H,1H3
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shells (dating from circa 1945) showing color code for tetryl filling
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Except where otherwise noted, data are given for materials in their
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booster explosive, though its use has been largely superseded by
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Immediately
Dangerous to Life or Health Concentrations (IDLH)
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http://smallwarsjournal.com/documents/terrorismhandbook.pdf
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is included in the cap to ensure detonation of tetryl.
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necessary for positive detonation of TNT. A mixture of
927:
National
Institute for Occupational Safety and Health
905:
National
Institute for Occupational Safety and Health
1023:
Occupational Safety and Health
Guideline for Tetryl
456:187 °C (369 °F; 460 K) decomposes
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1018:Agency for Toxic Substances and Disease Registry
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1034:Occupational Safety & Health Administration
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983:CDC - NIOSH Pocket Guide to Chemical Hazards
446:129.5 °C (265.1 °F; 402.6 K)
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899:NIOSH Pocket Guide to Chemical Hazards.
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320:Key: AGUIVNYEYSCPNI-UHFFFAOYSA-N
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41:Methyl(2,4,6-trinitrophenyl)nitramide
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828:Tetryl is produced by slowly mixing
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660:2,4,6-Trinitrophenylmethylnitramine
330:Key: AGUIVNYEYSCPNI-UHFFFAOYAF
202:
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14:
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351:CN(c1c(cc(cc1(=O))(=O))(=O))(=O)
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621:(at 25 °C , 100 kPa).
562:5000 mg/kg (dog, subcutaneous)
79:,2,4,6-tetranitrophenyl-1-amine
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911:
800:Tetryl was used mainly during
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996:, New York: Wiley-VCH, 1996.
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572:(US health exposure limits):
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544:or concentration (LD, LC):
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416:Yellow crystalline solid
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962:. Accessed May 11, 2010.
792:Cross-sectional view of
69:,2,4,6-tetranitroaniline
994:Explosives Engineering
797:
695:compound used to make
794:Oerlikon 20 mm cannon
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53:Nitramine (incorrect)
946:"Booster Explosives"
762:Environmental Effect
499:Friction sensitivity
468:Virtually insoluble
37:Preferred IUPAC name
1049:Explosive chemicals
836:in the presence of
718:Chemical properties
509:Detonation velocity
463:Solubility in water
408: g·mol
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1028:2009-02-27 at the
832:with concentrated
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756:potassium chlorate
744:explosive velocity
648:Infobox references
607:(Immediate danger)
478:<1 mmHg (20°C)
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992:Cooper, Paul W.,
752:mercury fulminate
701:explosive booster
656:Chemical compound
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489:Shock sensitivity
273:CompTox Dashboard
129:Interactive image
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773:acetonitrile
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706:Tetryl is a
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224:RTECS number
88:Identifiers
76:
72:
66:
62:
48:Other names
1054:Nitroamines
834:nitric acid
767:rapidly in
740:picric acid
542:Lethal dose
413:Appearance
360:Properties
187:100.006.848
149:CHEBI:28950
1043:Categories
879:References
824:Production
777:filtration
697:detonators
503:Sensitive
493:Sensitive
436:1.73 g/cm
401:Molar mass
249:GJ18911991
160:ChemSpider
116:3D model (
95:CAS Number
873:RE factor
775:prior to
708:nitramine
703:charges.
693:explosive
611:750 mg/m
527:RE factor
426:Odorless
260:UN number
231:BY6300000
56:Tetralite
1026:Archived
929:(NIOSH).
919:"Tetryl"
907:(NIOSH).
857:See also
818:landmine
810:tetrytol
769:methanol
691:) is an
536:Hazards
517:(24,836
105:479-45-8
75:-Methyl-
65:-Methyl-
901:"#0607"
784:History
728:benzene
724:acetone
641:what is
639: (
432:Density
406:287.144
200:PubChem
17:Tetryl
1014:Tetryl
1000:
664:tetryl
636:verify
633:
513:7,570
344:SMILES
59:Tetril
31:Names
569:NIOSH
531:1.25
309:InChI
213:10178
140:ChEBI
118:JSmol
998:ISBN
804:and
754:and
699:and
605:IDLH
422:Odor
265:0208
240:UNII
169:9770
814:M14
736:TNT
734:or
712:RDX
662:or
592:REL
579:PEL
519:f/s
515:m/s
278:EPA
203:CID
1045::
1032:,
1016:,
935:^
925:.
921:.
903:.
887:^
840:.
820:.
806:II
726:,
552:Lo
550:LD
521:)
948:.
689:8
686:O
683:5
680:N
677:5
674:H
671:7
668:C
666:(
631:Y
558:)
554:(
394:8
391:O
388:5
385:N
382:5
379:H
376:7
373:C
280:)
276:(
120:)
77:N
73:N
67:N
63:N
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