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17:
172:
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Schwarzenbach, Gerold; Bßrgi, Hans-Beat; Jensen, William P.; Lawrance, Geoffrey A.; Mønsted, Lene; Sargeson, Alan M. (1983). "Acid
Cleavage of Nickel(Ii) Complexes Containing cis,cis-1,3,5-Cyclohexanetriamine (TACH), Crystal Structure of
236:
201:
319:
Aimee J. Gamble; Jason M. Lynam; Robert J. Thatcher; Paul H. Walton; Adrian C. Whitwood (2013). "cis-1,3,5-Triaminocyclohexane as a
Facially Capping Ligand for Ruthenium(II)".
292:
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74:
185:
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141:
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positions available on the octahedral metal center. When bound to four- and five-coordinate metal centres, these ligands impose C
278:
507:
Parkin, G. (2000). "The
Bioinorganic Chemistry of Zinc: Synthetic Analogues of Zinc Enzymes that Feature Tripodal Ligands".
242:
NTA is a commercially important tripodal ligand. Its three carboxylic acid groups undergo deprotonation upon complexation.
46:. Because the ligands are polydentate, they do not readily dissociate from the metal centre. Many tripodal ligands have C
248:
156:
are also tripodal. Many kinds of donor groups have been incorporated into the arms of tripodal ligands, including amido
120:
because it is cheaply produced and has a high affinity for divalent metal ions. Other tripodal triamine ligands include
480:
Blackman, A. G. (2008). "Tripodal
Tetraamine Ligands Containing Three Pyridine Units: the other polypyridyl ligands".
264:
284:
270:
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207:
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splitting patterns. Tripodal ligands are often able to coordinately saturate metal ions with lower
121:
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165:
62:
39:
460:
318:
105:
43:
419:"M-E and M=E Complexes of Iron and Cobalt that Emphasize Three-Fold Symmetry (E = O, N, NR)"
8:
390:, and a Correlation Between the Structure and Reactivity of Nickel-Polyamine Complexes".
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Structure of (color code: blue = nitrogen, red = oxygen, dark blue = nickel).
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Verkade, J. G. (1993). "Atranes: New
Examples with Unexpected Properties".
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28:
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16:
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Motifs for complexation of tri- and tetradentate tripodal ligands
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301:, when triply deprotonated, is an unsymmetrical tripodal ligand.
35:
416:
171:
85:
tripodal ligands occupy four contiguous sites, leaving two
73:tripod ligands occupy one face, leading to a fixed
104:One tripodal ligand of commercial significance is
527:
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38:. They are popular in research in the areas of
353:
140:) and cis-1,3,5-triaminocyclohexane. Certain
465:: CS1 maint: multiple names: authors list (
210:, a tetradentate tripodal ligand popular in
506:
442:
56:
195:, X can be CR, SiR, Si, BR, B, N, P etc.
170:
15:
528:
230:, an anionic tridentate tripod ligand.
417:Saouma, C. T., Peters, J. C. (2011).
93:symmetry, which can lead to uncommon
258:, a dianionic organometallic ligand.
13:
14:
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285:cis,cis-1,3,5-triaminocyclohexane
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277:
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226:Structure of a metal complex of
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1:
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271:1,1,1-Tris(aminomethyl)ethane
67:octahedral molecular geometry
7:
10:
552:
208:Tris(2-pyridylmethyl)amine
435:10.1016/j.ccr.2011.01.009
180:Tripodal Ligands Examples
509:Chemical Communications
166:N-heterocyclic carbenes
494:10.1002/ejic.200800115
212:bioinorganic chemistry
176:
63:coordination complexes
57:Coordination chemistry
40:coordination chemistry
21:
174:
44:homogeneous catalysis
19:
99:coordination numbers
482:Eur. J. Inorg. Chem
404:10.1021/ic00168a042
392:Inorganic Chemistry
368:10.1021/ar00033a005
228:trispyrazolylborate
177:
22:
511:(20): 1971â1985.
398:(26): 4029â4038.
333:10.1021/ic302819j
106:nitrilotriacetate
81:) geometry. The
543:
536:Tripodal ligands
521:
520:
517:10.1039/B004816J
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429:(7â8): 920â937.
423:Coord. Chem. Rev
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327:(8): 4517â4527.
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25:Tripodal ligands
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144:such as RC(CH
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488:(17): 2633.
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256:Kläui ligand
103:
95:ligand field
86:
83:tetradentate
78:
60:
33:tetradentate
24:
23:
321:Inorg. Chem
299:citric acid
191:A tripodal
362:(9): 483.
307:References
71:tridentate
61:In their
530:Category
453:21625302
341:23517123
65:with an
51:symmetry
444:3103469
36:ligands
451:
441:
339:
164:, and
108:, N(CH
75:facial
124:(N(CH
486:2008
467:link
449:PMID
337:PMID
254:The
122:tren
77:(or
69:the
42:and
31:and
29:tri-
27:are
513:doi
490:doi
439:PMC
431:doi
427:255
400:doi
382:(NO
364:doi
329:doi
148:PPh
87:cis
79:fac
532::
484:.
463:}}
459:{{
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162:N)
158:(R
132:NH
128:CH
112:CO
101:.
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118:3
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114:2
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91:3
48:3
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
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