291:
198:
605:
610:
730:
725:
24:
729:
836:
1725:
1093:
Zinc phosphide is an ideal candidate for thin film photovoltaic applications, for it has strong optical absorption and an almost ideal band gap (1.5eV). In addition to this, both zinc and phosphorus are found abundantly in the Earth's crust, meaning that material extraction cost is low compared with
1125:
with an on/off ratio near 100. These are both acceptable suitability benchmarks for solar cells. Development still needs to be made on optimizing the nanoparticle ink formation and device architecture before commercialization is possible, but commercial spray-on zinc phosphide solar cells may be
731:
1187:, are not sensitive to the smell. The baits have to contain sufficient amount of zinc phosphide in sufficiently attractive food in order to kill rodents in a single serving; a sublethal dose may cause aversion towards zinc phosphide baits encountered by surviving rodents in the future.
728:
1120:
The testing and development of these zinc phosphide thin films is still in its early stages, but early results have been positive. Prototype heterojunction devices fabricated from zinc phosphide nanoparticle ink exhibited a rectification ratio of 600 and
1036:
form at around 845 °C. In the room-temperature form there are discrete P atoms, zinc atoms are tetrahedrally coordinated and phosphorus six coordinate, with zinc atoms at 6 of the vertices of a distorted cube.
753:
1309:
618:
1198:
to cause vomiting if the material is accidentally ingested by humans or domestic animals. However, it is still effective against rats, mice, guinea pigs and rabbits, none of which have a vomiting reflex.
585:
746:
1113:
from bulk zinc phosphide, but their fabrication required temperatures greater than 850 °C or complicated vacuum deposition methods. By contrast, colloidal zinc phosphide
1143:. A mixture of food and zinc phosphide is left where the rodents can eat it. The acid in the digestive system of the rodent reacts with the phosphide to generate toxic
1526:
F. Wagenknecht and R. Juza "Zinc
Phosphides" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1080-1.
3224:
3228:
3245:
1147:
gas. This method of vermin control has possible use in places where rodents are immune to other common poisons. Other pesticides similar to zinc phosphide are
3118:
3769:
3454:
3249:
2497:
1658:
Luber, Erik J. (2013). "Solution-Processed Zinc
Phosphide (α-Zn 3 P 2 ) Colloidal Semiconducting Nanocrystals for Thin Film Photovoltaic Applications".
3418:
3269:
849:
1811:
1208:
1235:
Zinc phosphide is highly toxic, especially when ingested or inhaled. The reason for its toxicity is the release of phosphorus compounds, usually
1765:
1623:
Trukhan, V. M.; Izotov, A. D.; Shoukavaya, T. V. (2014). "Compounds and solid solutions of the Zn-Cd-P-As system in semiconductor electronics".
2375:
3901:
1117:, contained in a zinc phosphide “ink”, allows for inexpensive, easy large-scale production, by means of slot-die coating or spray coating.
340:
1839:
1711:
1586:
Evgeniĭ I︠U︡rʹevich Tonkov, 1992, High
Pressure Phase Transformations: A Handbook, Vol 2, Gordon and Breach Science Publishers,
3950:
1098:. Both zinc and phosphorus are also nontoxic, which is not the case for other common commercial thin film photovoltaics, like
1334:
Teng, F.; Hu, K.; Ouyang, W.; Fang, X. (2018). "Photoelectric
Detectors Based on Inorganic p-Type Semiconductor Materials".
3880:
2970:
1693:
1109:
were the first to successfully synthesize colloidal zinc phosphide. Before this, researchers were able to create efficient
844:
760:
3885:
2368:
1611:
1591:
1515:
1284:
1220:
305:
4371:
1216:
688:
155:
1463:"Photoluminescence-based measurements of the energy gap and diffusion length of Zn[sub 3]P[sub 2]"
1211:
has approved the import and manufacture of
Microencapsulated Zinc Phosphide (MZP Paste) for the ground control of
856:
3875:
1175:
Zinc phosphide is typically added to rodent baits in amount of around 0.75-2%. Such baits have a strong, pungent
1077:
904:
4124:
1445:
556:
2361:
1806:
1190:
Rodenticide-grade zinc phosphide usually comes as a black powder containing 75% of zinc phosphide and 25% of
739:
4361:
1832:
650:
638:
248:
193:
3856:
3686:
2631:
1793:
1462:
1191:
269:
672:
3943:
3851:
2853:
2804:
1536:
Luber, Erik J.; Mobarok, Md Hosnay; Buriak, Jillian M. (2013). "Solution-Processed Zinc
Phosphide (α-Zn
1255:
676:
1029:
205:
3846:
3749:
3388:
2963:
2906:
2824:
2796:
2540:
660:
286:
1183:. The odor attracts rodents, but has a repulsive effect on other animals; However, birds, notably
4366:
4351:
4305:
3806:
3714:
3706:
3702:
3380:
3363:
3216:
2930:
2780:
2772:
2656:
2581:
2555:
2477:
1825:
1212:
891:. It is a grey solid, although commercial samples are often dark or even black. It is used as a
604:
4285:
3774:
3682:
3392:
2848:
2816:
2788:
2693:
2626:
2545:
1428:
Bettermann, G.; Krause, W.; Riess, G.; Hofmann, T. (2002). "Phosphorus
Compounds, Inorganic".
175:
4356:
4129:
3936:
3785:
3403:
3367:
3323:
3204:
2764:
2743:
2605:
2405:
2298:
1869:
1106:
632:
597:
4325:
3976:
3729:
3719:
3522:
3257:
3084:
2894:
2882:
2832:
2616:
2482:
2467:
2384:
1908:
1477:
1385:
Zanin, I. E.; Aleinikova, K. B.; Afanasiev, M. M.; Antipin, M. Yu. (2004). "Structure of Zn
1343:
1224:
1033:
609:
257:
109:
89:
1254:. Phosphine is also denser than air and may remain close to the ground without sufficient
1239:, when it reacts with water and acids. Phosphine is very toxic and, with trace amounts of
60:
8:
4346:
4200:
4175:
3866:
3795:
3790:
3694:
3672:
3459:
3344:
3285:
3184:
3152:
2956:
2870:
2865:
2738:
2713:
2666:
2641:
2576:
2571:
2521:
2492:
1799:
1148:
50:
1481:
1347:
290:
197:
23:
4167:
3990:
3511:
3492:
3318:
3211:
3174:
3157:
2918:
2651:
2646:
2595:
2535:
2400:
2092:
1640:
1410:
1367:
4190:
3744:
3734:
3724:
3549:
3497:
3474:
3427:
3375:
3358:
3331:
3313:
3193:
3161:
3088:
3045:
2708:
2703:
2678:
2566:
2526:
2511:
2506:
2446:
2434:
2420:
2415:
2246:
1675:
1607:
1587:
1569:
1561:
1511:
1493:
1441:
1414:
1359:
1280:
1152:
1099:
1065:
888:
814:
696:
479:
237:
1644:
1461:
Kimball, Gregory M.; Müller, Astrid M.; Lewis, Nathan S.; Atwater, Harry A. (2009).
1371:
1215:. The application was made by Pest Tech Limited, with support from Connovation Ltd,
4238:
4185:
3837:
3739:
3677:
3464:
3444:
3439:
3305:
3109:
2718:
2683:
2516:
2472:
2458:
2156:
2037:
1667:
1632:
1553:
1485:
1433:
1402:
1351:
1223:. It will be used as an additional vertebrate poison in certain situations. Unlike
1122:
1041:
919:
513:
431:
363:
1544:) Colloidal Semiconducting Nanocrystals for Thin Film Photovoltaic Applications".
4295:
4152:
4114:
4077:
3917:
3079:
2410:
2230:
2108:
1510:
Specialist
Periodical Reports, Photochemistry, 1981, Royal Society of Chemistry,
668:
1697:
4215:
4157:
4069:
3541:
3530:
3240:
2487:
2164:
2087:
2061:
2004:
1936:
1848:
981:
827:
489:
1636:
1406:
788:
4340:
4026:
4010:
3971:
3928:
3096:
2120:
2082:
2029:
1980:
1972:
1960:
1952:
1788:
1763:
1565:
1497:
1437:
1095:
1053:
911:
907:
420:
186:
1427:
4320:
4300:
4050:
4040:
3959:
2987:
2314:
2278:
2262:
2218:
2190:
2132:
2074:
2069:
2012:
1988:
1944:
1928:
1789:
Zinc
Phosphide Pesticide Information Profile - Extension Toxicology Network
1679:
1573:
1363:
1355:
1114:
966:
534:
752:
692:
4290:
4087:
4055:
4035:
3963:
2202:
1996:
1240:
1184:
1140:
965:
Another method of preparation include reacting tri-n-octylphosphine with
892:
759:
680:
497:
738:
4310:
4246:
4223:
4119:
4101:
4045:
3166:
2353:
2024:
1916:
1743:
1251:
1180:
1110:
1040:
The crystalline structure of zinc phosphide is very similar to that of
939:
915:
878:
745:
485:
442:
382:
206:
166:
1671:
1557:
1489:
942:; however, for critical applications, additional processing to remove
4315:
4256:
4144:
4109:
2998:
2979:
2840:
2392:
1236:
1144:
973:
885:
826:
Except where otherwise noted, data are given for materials in their
4264:
4005:
3985:
711:
463:
704:
154:
4195:
4180:
4082:
4015:
1817:
943:
664:
452:
448:
410:
224:
4269:
4228:
1384:
1195:
1176:
1694:"Colloidal zinc phosphide for photovoltaics - nanotechweb.org"
656:
2948:
144:
274:
1794:
EPA Proposed Risk
Mitigation Decision for Nine Rodenticides
935:
872:
456:
400:
1279:(87 ed.). Boca Raton, FL: CRC Press. pp. 4–100.
918:. A second compound exists in the zinc-phosphorus system,
4134:
1460:
972:
Zinc phosphide reacts with water to produce highly toxic
2184:
1622:
1862:
1179:-like odor characteristic of phosphine liberated by
1766:"Zinc phosphide pest poison approved with controls"
1764:Environment Risk Management Authority New Zealand.
1535:
1304:
1302:
1300:
1298:
1296:
934:Zinc phosphide can be prepared by the reaction of
4338:
1454:
1333:
642:
236:
1529:
1293:
727:
108:
88:
59:
3958:
1430:Ullmann's Encyclopedia of Industrial Chemistry
1202:
700:
3944:
2964:
2369:
1833:
1807:Zinc phosphide properties and use in Michigan
1227:, it cannot be used for aerial application.
425:1,160 °C (2,120 °F; 1,430 K)
1803:in the Pesticide Properties DataBase (PPDB)
1310:"ThermoFisher Scientific safety data sheet"
3951:
3937:
2971:
2957:
2376:
2362:
1840:
1826:
929:
684:
289:
196:
174:
820:ThermoFisher Scientific, revised 02/2020
256:
2383:
1606:5th edition Oxford Science Publications
1080:exhibit full continuous solid-solution.
1616:
285:
4339:
1580:
1316:. Thermo Fisher Scientific. 2020-02-21
187:
3932:
2952:
2357:
1821:
1726:"Zinc Phosphide Technical Fact Sheet"
1657:
317:Key: NQDYSWQRWWTVJU-UHFFFAOYSA-N
1274:
1268:
1139:Metal phosphides have been used as
327:Key: NQDYSWQRWWTVJU-WGUIJFGEAN
227:
13:
1847:
1378:
1209:Environmental Protection Authority
723:
14:
4383:
4306:1,3-Difluoro-2-propanol (Gliftor)
1782:
1277:Handbook of Chemistry and Physics
1088:
834:
608:
603:
324:InChI=1/2P.3Zn/rP2Zn3/c3-1-5-2-4
22:
1757:
1736:
1718:
1704:
1686:
1651:
1596:
1395:Journal of Structural Chemistry
1129:
1083:
830:(at 25 °C , 100 kPa).
4125:Tetramethylenedisulfotetramine
2978:
1604:Structural Inorganic Chemistry
1520:
1504:
1421:
1327:
1134:
910:with a direct band gap of 1.5
557:Occupational safety and health
1:
1261:
914:and may have applications in
2997:
1814:- Pesticides in the military
1078:Zn-Cd-P-As quaternary system
1015:
523: = 8.0785 Å,
7:
1203:Pest control in New Zealand
1192:antimony potassium tartrate
1126:possible within ten years.
777:or concentration (LD, LC):
527: = 11.3966 Å
10:
4388:
1076:). These compounds of the
387:258.12 g/mol
4278:
4255:
4237:
4214:
4166:
4143:
4100:
4068:
4024:
3998:
3984:
3970:
3910:
3894:
3865:
3836:
3654:
2986:
2757:
2391:
1901:
1855:
1637:10.1134/S0020168514090143
1407:10.1007/s10947-005-0067-9
1230:
946:compounds may be needed.
824:
773:
584:
554:
549:
472:
356:
336:
301:
43:
35:
30:
21:
2185:Organozinc(II) compounds
1438:10.1002/14356007.a19_527
1094:that of other thin film
1032:form that converts to a
651:Precautionary statements
4372:Foul-smelling chemicals
1863:Organozinc(I) compounds
1470:Applied Physics Letters
1432:. Weinheim: Wiley-VCH.
1275:Lide, David R. (1998).
1028:has a room-temperature
930:Synthesis and reactions
1744:"Why rats can't vomit"
1356:10.1002/adma.201706262
734:
4130:Chlorophenylsilatrane
3977:Vitamin K antagonists
1107:University of Alberta
920:zinc diphosphide (ZnP
733:
570:Fatal, acutely toxic
4326:Sodium fluoroacetate
2385:Phosphorus compounds
809:2000 mg/kg (Rabbit)
716:(fire diamond)
468:1.4-1.6 eV (direct)
4362:II-V semiconductors
4176:Aluminium phosphide
4168:Inorganic compounds
1625:Inorganic Materials
1482:2009ApPhL..95k2103K
1348:2018AdM....3006262T
1221:Animal Health Board
1149:aluminium phosphide
1105:Researchers at the
432:Solubility in water
38:trizinc diphosphide
18:
4286:α-Naphthylthiourea
3991:4-Hydroxycoumarins
3895:Quinary phosphides
1602:Wells A.F. (1984)
1336:Advanced Materials
1217:Lincoln University
916:photovoltaic cells
857:Infobox references
735:
576:Inhalation hazards
16:
4334:
4333:
4191:Calcium phosphide
4096:
4095:
4064:
4063:
3926:
3925:
3831:
3830:
2946:
2945:
2351:
2350:
2310:
2309:
1897:
1896:
1746:. Ratbehavior.org
1672:10.1021/nn4034234
1558:10.1021/nn4034234
1490:10.1063/1.3225151
1153:calcium phosphide
1100:cadmium telluride
1066:cadmium phosphide
889:chemical compound
865:Chemical compound
863:
862:
815:Safety data sheet
633:Hazard statements
566:Ingestion hazards
480:Crystal structure
270:CompTox Dashboard
156:Interactive image
4379:
4239:Organophosphorus
4201:Thallium sulfate
4186:Barium carbonate
4025:2nd generation (
3996:
3995:
3982:
3981:
3953:
3946:
3939:
3930:
3929:
3766:
3669:
3450:
2995:
2994:
2973:
2966:
2959:
2950:
2949:
2749:
2699:
2689:
2662:
2637:
2622:
2612:
2601:
2591:
2562:
2551:
2430:
2378:
2371:
2364:
2355:
2354:
2343:
2342:
2341:
2333:
2332:
2324:
2323:
2182:
2181:
2057:
2056:
2055:
2047:
2046:
1860:
1859:
1842:
1835:
1828:
1819:
1818:
1776:
1775:
1773:
1772:
1761:
1755:
1754:
1752:
1751:
1740:
1734:
1733:
1722:
1716:
1715:
1708:
1702:
1701:
1696:. Archived from
1690:
1684:
1683:
1666:(9): 8136–8146.
1655:
1649:
1648:
1620:
1614:
1600:
1594:
1584:
1578:
1577:
1552:(9): 8136–8146.
1533:
1527:
1524:
1518:
1508:
1502:
1501:
1467:
1458:
1452:
1451:
1425:
1419:
1418:
1382:
1376:
1375:
1331:
1325:
1324:
1322:
1321:
1306:
1291:
1290:
1272:
1207:The New Zealand
1123:photosensitivity
1042:cadmium arsenide
847:
841:
838:
837:
807:1123 mg/kg (Rat)
799:42.6 mg/kg (Rat)
764:
763:
755:
748:
741:
726:
706:
702:
698:
694:
690:
686:
682:
678:
674:
670:
666:
662:
658:
644:
640:
612:
607:
514:Lattice constant
364:Chemical formula
294:
293:
278:
276:
260:
240:
229:
208:
200:
189:
178:
158:
133:
132:
131:
123:
122:
112:
104:
103:
102:
92:
84:
83:
82:
74:
73:
63:
26:
19:
15:
4387:
4386:
4382:
4381:
4380:
4378:
4377:
4376:
4337:
4336:
4335:
4330:
4296:Fluoroacetamide
4274:
4251:
4233:
4210:
4162:
4153:Cholecalciferol
4139:
4115:Phenylsilatrane
4092:
4078:Chlorophacinone
4070:1,3-Indandiones
4060:
4020:
3989:
3975:
3966:
3957:
3927:
3922:
3918:Ferrophosphorus
3906:
3890:
3861:
3832:
3778:
3764:
3710:
3705:
3690:
3685:
3667:
3545:
3526:
3515:
3482:
3478:
3449:
3445:
3435:
3431:
3422:
3407:
3396:
3391:
3387:
3384:
3371:
3366:
3352:
3348:
3309:
3304:
3302:
3298:
3289:
3280:
3274:
3265:
3261:
3256:
3253:
3248:
3232:
3227:
3203:
3201:
3197:
3188:
3160:
3126:
3122:
3113:
3087:
3049:
3002:
2982:
2977:
2947:
2942:
2938:
2934:
2926:
2922:
2914:
2910:
2902:
2898:
2890:
2886:
2878:
2874:
2861:
2857:
2844:
2836:
2828:
2820:
2812:
2808:
2800:
2792:
2784:
2776:
2768:
2758:Other compounds
2753:
2748:
2744:
2734:
2730:
2722:
2698:
2694:
2688:
2684:
2674:
2670:
2661:
2657:
2636:
2632:
2621:
2617:
2610:
2606:
2600:
2596:
2590:
2586:
2582:
2560:
2556:
2550:
2546:
2530:
2501:
2462:
2454:
2450:
2442:
2438:
2429:
2425:
2421:
2387:
2382:
2352:
2347:
2340:
2337:
2336:
2335:
2331:
2328:
2327:
2326:
2322:
2319:
2318:
2317:
2315:
2306:
2302:
2294:
2290:
2286:
2282:
2274:
2270:
2266:
2258:
2254:
2250:
2242:
2238:
2234:
2226:
2222:
2214:
2210:
2206:
2198:
2194:
2180:
2176:
2172:
2168:
2160:
2152:
2148:
2140:
2136:
2128:
2124:
2116:
2112:
2104:
2100:
2096:
2078:
2065:
2054:
2051:
2050:
2049:
2045:
2042:
2041:
2040:
2038:
2033:
2020:
2016:
2008:
2000:
1992:
1984:
1976:
1968:
1964:
1956:
1948:
1940:
1932:
1924:
1920:
1912:
1893:
1889:
1885:
1881:
1877:
1873:
1851:
1846:
1785:
1780:
1779:
1770:
1768:
1762:
1758:
1749:
1747:
1742:
1741:
1737:
1724:
1723:
1719:
1710:
1709:
1705:
1692:
1691:
1687:
1656:
1652:
1621:
1617:
1601:
1597:
1585:
1581:
1543:
1539:
1534:
1530:
1525:
1521:
1509:
1505:
1465:
1459:
1455:
1448:
1426:
1422:
1392:
1388:
1383:
1379:
1342:(35): 1706262.
1332:
1328:
1319:
1317:
1308:
1307:
1294:
1287:
1273:
1269:
1264:
1248:
1244:
1233:
1205:
1170:
1167:+ 6H → 3Zn + PH
1166:
1162:
1137:
1132:
1091:
1086:
1075:
1071:
1063:
1059:
1051:
1047:
1027:
1023:
1018:
1011:
1007:
1003:
999:
995:
987:
979:
961:
957:
953:
932:
923:
902:
898:
882:
876:
866:
859:
854:
853:
852: ?)
843:
839:
835:
831:
808:
806:
802:
800:
798:
792:
786:
769:
768:
767:
766:
761:
757:
750:
743:
736:
732:
724:
653:
635:
621:
600:
577:
567:
542:
528:
516:
506:
500:
482:
434:
405:characteristic
376:
372:
366:
352:
349:
344:
343:
332:
329:
328:
325:
319:
318:
315:
314:InChI=1S/2P.3Zn
309:
308:
297:
279:
272:
263:
243:
230:
218:
181:
161:
148:
137:
130:
127:
126:
125:
121:
118:
117:
116:
114:
101:
98:
97:
96:
94:
81:
78:
77:
76:
72:
69:
68:
67:
65:
53:
39:
17:Zinc phosphide
12:
11:
5:
4385:
4375:
4374:
4369:
4367:II-V compounds
4364:
4359:
4354:
4352:Zinc compounds
4349:
4332:
4331:
4329:
4328:
4323:
4318:
4313:
4308:
4303:
4298:
4293:
4288:
4282:
4280:
4276:
4275:
4273:
4272:
4267:
4261:
4259:
4253:
4252:
4250:
4249:
4243:
4241:
4235:
4234:
4232:
4231:
4226:
4220:
4218:
4216:Organochlorine
4212:
4211:
4209:
4208:
4206:Zinc phosphide
4203:
4198:
4193:
4188:
4183:
4178:
4172:
4170:
4164:
4163:
4161:
4160:
4158:Ergocalciferol
4155:
4149:
4147:
4141:
4140:
4138:
4137:
4132:
4127:
4122:
4117:
4112:
4106:
4104:
4098:
4097:
4094:
4093:
4091:
4090:
4085:
4080:
4074:
4072:
4066:
4065:
4062:
4061:
4059:
4058:
4053:
4048:
4043:
4038:
4032:
4030:
4027:Superwarfarins
4022:
4021:
4019:
4018:
4013:
4008:
4002:
4000:
3999:1st generation
3993:
3979:
3972:Anticoagulants
3968:
3967:
3956:
3955:
3948:
3941:
3933:
3924:
3923:
3921:
3920:
3914:
3912:
3908:
3907:
3905:
3904:
3898:
3896:
3892:
3891:
3889:
3888:
3883:
3878:
3872:
3870:
3863:
3862:
3860:
3859:
3854:
3849:
3843:
3841:
3834:
3833:
3829:
3828:
3826:
3824:
3821:
3818:
3815:
3812:
3809:
3804:
3801:
3798:
3793:
3788:
3783:
3780:
3776:
3772:
3767:
3762:
3760:
3757:
3756:
3754:
3752:
3747:
3742:
3737:
3732:
3727:
3722:
3717:
3712:
3708:
3700:
3697:
3692:
3688:
3680:
3675:
3670:
3665:
3663:
3660:
3659:
3657:
3655:
3653:
3651:
3649:
3647:
3645:
3643:
3641:
3639:
3637:
3635:
3633:
3631:
3629:
3626:
3624:
3621:
3620:
3617:
3614:
3611:
3608:
3605:
3602:
3599:
3596:
3593:
3590:
3587:
3584:
3581:
3578:
3575:
3572:
3569:
3566:
3562:
3561:
3558:
3555:
3552:
3547:
3543:
3539:
3536:
3533:
3528:
3524:
3520:
3517:
3513:
3509:
3506:
3503:
3500:
3495:
3490:
3487:
3484:
3480:
3476:
3471:
3470:
3467:
3462:
3457:
3452:
3447:
3442:
3437:
3433:
3429:
3425:
3420:
3416:
3413:
3410:
3405:
3401:
3398:
3394:
3382:
3378:
3373:
3369:
3361:
3356:
3354:
3350:
3346:
3342:
3338:
3337:
3334:
3329:
3326:
3321:
3316:
3311:
3307:
3300:
3296:
3292:
3287:
3283:
3278:
3272:
3267:
3263:
3259:
3251:
3243:
3238:
3235:
3230:
3222:
3219:
3214:
3209:
3207:
3199:
3195:
3191:
3186:
3181:
3180:
3177:
3172:
3169:
3164:
3155:
3150:
3148:
3146:
3144:
3142:
3140:
3138:
3136:
3134:
3132:
3130:
3128:
3124:
3120:
3116:
3111:
3106:
3105:
3102:
3099:
3094:
3091:
3082:
3077:
3075:
3073:
3071:
3069:
3067:
3065:
3063:
3061:
3059:
3057:
3055:
3052:
3047:
3042:
3041:
3038:
3036:
3034:
3032:
3030:
3028:
3026:
3024:
3022:
3020:
3018:
3016:
3014:
3012:
3010:
3008:
3006:
3004:
3000:
2993:
2991:
2984:
2983:
2976:
2975:
2968:
2961:
2953:
2944:
2943:
2941:
2940:
2936:
2932:
2928:
2924:
2920:
2916:
2912:
2908:
2904:
2900:
2896:
2892:
2888:
2884:
2880:
2876:
2872:
2868:
2863:
2859:
2855:
2851:
2846:
2842:
2838:
2834:
2830:
2826:
2822:
2818:
2814:
2810:
2806:
2802:
2798:
2794:
2790:
2786:
2782:
2778:
2774:
2770:
2766:
2761:
2759:
2755:
2754:
2752:
2751:
2746:
2741:
2736:
2732:
2728:
2724:
2720:
2716:
2711:
2706:
2701:
2696:
2691:
2686:
2681:
2676:
2672:
2668:
2664:
2659:
2654:
2649:
2644:
2639:
2634:
2629:
2624:
2619:
2614:
2608:
2603:
2598:
2593:
2588:
2584:
2579:
2574:
2569:
2564:
2558:
2553:
2548:
2543:
2538:
2533:
2528:
2524:
2519:
2514:
2509:
2504:
2499:
2495:
2490:
2485:
2480:
2475:
2470:
2465:
2460:
2456:
2452:
2448:
2444:
2440:
2436:
2432:
2427:
2423:
2418:
2413:
2408:
2403:
2397:
2395:
2389:
2388:
2381:
2380:
2373:
2366:
2358:
2349:
2348:
2346:
2345:
2338:
2329:
2320:
2311:
2308:
2307:
2305:
2300:
2296:
2292:
2288:
2284:
2280:
2276:
2272:
2268:
2264:
2260:
2256:
2252:
2248:
2244:
2240:
2236:
2232:
2228:
2224:
2220:
2216:
2212:
2208:
2204:
2200:
2196:
2192:
2188:
2186:
2179:
2178:
2174:
2170:
2166:
2162:
2158:
2154:
2150:
2146:
2142:
2138:
2134:
2130:
2126:
2122:
2118:
2114:
2110:
2106:
2102:
2098:
2094:
2090:
2085:
2080:
2076:
2072:
2067:
2063:
2059:
2052:
2043:
2035:
2031:
2027:
2022:
2018:
2014:
2010:
2006:
2002:
1998:
1994:
1990:
1986:
1982:
1978:
1974:
1970:
1966:
1962:
1958:
1954:
1950:
1946:
1942:
1938:
1934:
1930:
1926:
1922:
1918:
1914:
1910:
1905:
1903:
1899:
1898:
1895:
1894:
1892:
1891:
1887:
1883:
1879:
1875:
1871:
1866:
1864:
1857:
1853:
1852:
1849:Zinc compounds
1845:
1844:
1837:
1830:
1822:
1816:
1815:
1809:
1804:
1800:Zinc phosphide
1796:
1791:
1784:
1783:External links
1781:
1778:
1777:
1756:
1735:
1717:
1703:
1700:on 2013-09-16.
1685:
1650:
1631:(9): 868–873.
1615:
1595:
1579:
1541:
1537:
1528:
1519:
1503:
1476:(11): 112103.
1453:
1446:
1420:
1401:(5): 844–848.
1390:
1386:
1377:
1326:
1292:
1285:
1266:
1265:
1263:
1260:
1246:
1242:
1232:
1229:
1204:
1201:
1173:
1172:
1168:
1164:
1160:
1136:
1133:
1131:
1128:
1090:
1087:
1085:
1082:
1073:
1069:
1061:
1057:
1049:
1045:
1025:
1021:
1017:
1014:
1013:
1012:
1009:
1005:
1001:
997:
993:
985:
982:zinc hydroxide
977:
963:
962:
959:
955:
951:
931:
928:
921:
900:
896:
880:
874:
869:Zinc phosphide
864:
861:
860:
855:
833:
832:
828:standard state
825:
822:
821:
818:
811:
810:
801:12 mg/kg (Rat)
793:
784:
782:
779:
778:
771:
770:
758:
751:
744:
737:
722:
721:
720:
719:
717:
708:
707:
654:
649:
646:
645:
636:
631:
628:
627:
622:
617:
614:
613:
601:
596:
593:
592:
582:
581:
578:
575:
572:
571:
568:
565:
562:
561:
552:
551:
547:
546:
543:
533:
530:
529:
519:
517:
512:
509:
508:
507:/nmc, No. 137
504:
501:
496:
493:
492:
483:
478:
475:
474:
470:
469:
466:
460:
459:
455:, reacts with
445:
439:
438:
435:
430:
427:
426:
423:
417:
416:
413:
407:
406:
403:
397:
396:
393:
389:
388:
385:
379:
378:
374:
370:
367:
362:
359:
358:
354:
353:
351:
350:
347:
339:
338:
337:
334:
333:
331:
330:
326:
323:
322:
320:
316:
313:
312:
304:
303:
302:
299:
298:
296:
295:
282:
280:
268:
265:
264:
262:
261:
253:
251:
245:
244:
242:
241:
233:
231:
223:
220:
219:
217:
216:
212:
210:
202:
201:
191:
183:
182:
180:
179:
171:
169:
163:
162:
160:
159:
151:
149:
142:
139:
138:
136:
135:
128:
119:
106:
99:
86:
79:
70:
56:
54:
49:
46:
45:
41:
40:
37:
33:
32:
28:
27:
9:
6:
4:
3:
2:
4384:
4373:
4370:
4368:
4365:
4363:
4360:
4358:
4355:
4353:
4350:
4348:
4345:
4344:
4342:
4327:
4324:
4322:
4319:
4317:
4314:
4312:
4309:
4307:
4304:
4302:
4299:
4297:
4294:
4292:
4289:
4287:
4284:
4283:
4281:
4277:
4271:
4268:
4266:
4263:
4262:
4260:
4258:
4254:
4248:
4245:
4244:
4242:
4240:
4236:
4230:
4227:
4225:
4222:
4221:
4219:
4217:
4213:
4207:
4204:
4202:
4199:
4197:
4194:
4192:
4189:
4187:
4184:
4182:
4179:
4177:
4174:
4173:
4171:
4169:
4165:
4159:
4156:
4154:
4151:
4150:
4148:
4146:
4142:
4136:
4133:
4131:
4128:
4126:
4123:
4121:
4118:
4116:
4113:
4111:
4108:
4107:
4105:
4103:
4099:
4089:
4086:
4084:
4081:
4079:
4076:
4075:
4073:
4071:
4067:
4057:
4054:
4052:
4049:
4047:
4044:
4042:
4039:
4037:
4034:
4033:
4031:
4028:
4023:
4017:
4014:
4012:
4011:Coumatetralyl
4009:
4007:
4004:
4003:
4001:
3997:
3994:
3992:
3987:
3983:
3980:
3978:
3973:
3969:
3965:
3961:
3954:
3949:
3947:
3942:
3940:
3935:
3934:
3931:
3919:
3916:
3915:
3913:
3909:
3903:
3900:
3899:
3897:
3893:
3887:
3884:
3882:
3879:
3877:
3874:
3873:
3871:
3868:
3864:
3858:
3855:
3853:
3850:
3848:
3845:
3844:
3842:
3839:
3835:
3827:
3825:
3822:
3819:
3816:
3813:
3810:
3808:
3805:
3802:
3799:
3797:
3794:
3792:
3789:
3787:
3784:
3781:
3779:
3773:
3771:
3768:
3763:
3761:
3759:
3758:
3755:
3753:
3751:
3748:
3746:
3743:
3741:
3738:
3736:
3733:
3731:
3728:
3726:
3723:
3721:
3718:
3716:
3713:
3711:
3704:
3701:
3698:
3696:
3693:
3691:
3684:
3681:
3679:
3676:
3674:
3671:
3666:
3664:
3662:
3661:
3658:
3656:
3652:
3650:
3648:
3646:
3644:
3642:
3640:
3638:
3636:
3634:
3632:
3630:
3627:
3625:
3623:
3622:
3618:
3615:
3612:
3609:
3606:
3603:
3600:
3597:
3594:
3591:
3588:
3585:
3582:
3579:
3576:
3573:
3570:
3567:
3564:
3563:
3559:
3556:
3553:
3551:
3548:
3546:
3540:
3537:
3534:
3532:
3529:
3527:
3521:
3518:
3516:
3510:
3507:
3504:
3501:
3499:
3496:
3494:
3491:
3488:
3485:
3483:
3473:
3472:
3468:
3466:
3463:
3461:
3458:
3456:
3453:
3451:
3443:
3441:
3438:
3436:
3426:
3424:
3417:
3414:
3411:
3409:
3402:
3399:
3397:
3390:
3386:
3379:
3377:
3374:
3372:
3365:
3362:
3360:
3357:
3355:
3353:
3343:
3340:
3339:
3335:
3333:
3330:
3327:
3325:
3322:
3320:
3317:
3315:
3312:
3310:
3303:
3293:
3291:
3284:
3282:
3281:
3275:
3268:
3266:
3255:
3247:
3244:
3242:
3239:
3236:
3234:
3226:
3223:
3220:
3218:
3215:
3213:
3210:
3208:
3206:
3202:
3192:
3190:
3183:
3182:
3178:
3176:
3173:
3170:
3168:
3165:
3163:
3159:
3156:
3154:
3151:
3149:
3147:
3145:
3143:
3141:
3139:
3137:
3135:
3133:
3131:
3129:
3127:
3117:
3115:
3108:
3107:
3103:
3100:
3098:
3095:
3092:
3090:
3086:
3083:
3081:
3078:
3076:
3074:
3072:
3070:
3068:
3066:
3064:
3062:
3060:
3058:
3056:
3053:
3051:
3044:
3043:
3039:
3037:
3035:
3033:
3031:
3029:
3027:
3025:
3023:
3021:
3019:
3017:
3015:
3013:
3011:
3009:
3007:
3005:
3003:
2996:
2992:
2989:
2985:
2981:
2974:
2969:
2967:
2962:
2960:
2955:
2954:
2951:
2939:
2929:
2927:
2917:
2915:
2905:
2903:
2893:
2891:
2881:
2879:
2869:
2867:
2864:
2862:
2852:
2850:
2847:
2845:
2839:
2837:
2831:
2829:
2823:
2821:
2815:
2813:
2803:
2801:
2795:
2793:
2787:
2785:
2779:
2777:
2771:
2769:
2763:
2762:
2760:
2756:
2750:
2742:
2740:
2737:
2735:
2725:
2723:
2717:
2715:
2712:
2710:
2707:
2705:
2702:
2700:
2692:
2690:
2682:
2680:
2677:
2675:
2665:
2663:
2655:
2653:
2650:
2648:
2645:
2643:
2640:
2638:
2630:
2628:
2625:
2623:
2615:
2613:
2604:
2602:
2594:
2592:
2580:
2578:
2575:
2573:
2570:
2568:
2565:
2563:
2554:
2552:
2544:
2542:
2539:
2537:
2534:
2532:
2525:
2523:
2520:
2518:
2515:
2513:
2510:
2508:
2505:
2503:
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1096:photovoltaics
1089:Photovoltaics
1081:
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1054:zinc arsenide
1043:
1038:
1035:
1031:
991:
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535:Formula units
532:
531:
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487:
484:
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454:
451:, soluble in
450:
447:insoluble in
446:
444:
441:
440:
436:
433:
429:
428:
424:
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421:Melting point
419:
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188:ECHA InfoCard
185:
184:
177:
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48:
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42:
34:
29:
25:
20:
4357:Rodenticides
4321:Scilliroside
4301:Flupropadine
4205:
4051:Difethialone
4041:Bromadiolone
3964:Rodenticides
3960:Pest control
3294:
3277:
3271:
2726:
2144:
1798:
1769:. Retrieved
1759:
1748:. Retrieved
1738:
1729:
1720:
1706:
1698:the original
1688:
1663:
1659:
1653:
1628:
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1318:. Retrieved
1313:
1276:
1270:
1234:
1206:
1189:
1185:wild turkeys
1174:
1141:rodenticides
1138:
1130:Pest control
1119:
1104:
1092:
1084:Applications
1039:
1019:
1004:O → 2 PH
971:
967:dimethylzinc
964:
933:
868:
867:
803:
795:
774:
712:
624:
586:
555:
538:
524:
520:
44:Identifiers
36:Other names
4291:Bromethalin
4145:Calciferols
4102:Convulsants
4088:Diphacinone
4056:Flocoumafen
4036:Brodifacoum
1256:ventilation
1225:1080 poison
1135:Rodenticide
1111:solar cells
1008:+ 3 Zn(OH)
950:6 Zn + P
893:rodenticide
789:median dose
775:Lethal dose
619:Signal word
560:(OHS/OSH):
498:Space group
392:Appearance
357:Properties
194:100.013.859
4347:Phosphides
4341:Categories
4311:Norbormide
4257:Carbamates
4247:Phosacetim
4224:Chloralose
4120:Strychnine
4046:Difenacoum
3876:Zn-Cd-P-As
3869:phosphides
3867:Quaternary
3840:phosphides
2990:phosphides
2980:Phosphides
2393:Phosphides
1771:2011-08-14
1750:2013-08-17
1447:3527306730
1320:2020-11-02
1262:References
1252:pyrophoric
1181:hydrolysis
1030:tetragonal
940:phosphorus
598:Pictograms
486:Tetragonal
473:Structure
443:Solubility
415:4.55 g/cm
395:dark gray
383:Molar mass
258:813396S1PC
167:ChemSpider
143:3D model (
110:51810-70-9
90:12037-79-5
51:CAS Number
4316:Pyrinuron
4110:Crimidine
3986:Coumarins
3902:GaInAsSbP
1566:1936-0851
1498:0003-6951
1415:101460207
1237:phosphine
1145:phosphine
1016:Structure
974:phosphine
886:inorganic
697:P402+P404
693:P370+P378
689:P335+P334
677:P301+P310
661:P231+P232
589:labelling
215:234-867-3
207:EC Number
61:1314-84-7
4265:Aldicarb
4006:Warfarin
3911:See also
3628:↓
2231:Zn(CH(CH
1909:Zn(acac)
1902:Zinc(II)
1680:23952612
1660:ACS Nano
1645:94409384
1574:23952612
1546:ACS Nano
1372:47016453
1364:29888448
1219:and the
884:) is an
713:NFPA 704
550:Hazards
464:Band gap
238:25113606
176:11344765
4196:Cyanide
4181:Arsenic
4083:Pindone
4016:Fumarin
3886:AlGaInP
3881:InAsSbP
3838:Ternary
2247:Zn(C(CH
1856:Zinc(I)
1478:Bibcode
1344:Bibcode
1213:possums
984:(Zn(OH)
954:→ 2 Zn
944:arsenic
850:what is
848: (
453:benzene
449:ethanol
437:reacts
411:Density
377:
225:PubChem
113: (
93: (
64: (
4279:Others
4270:T-1152
4229:Endrin
2988:Binary
2062:Zn(OH)
2039:Zn(ClO
1961:Zn(ClO
1945:Zn(CN)
1812:MD0173
1712:"Home"
1678:
1643:
1610:
1590:
1572:
1564:
1514:
1496:
1444:
1413:
1370:
1362:
1283:
1231:Safety
1196:emetic
1177:garlic
1064:) and
1000:+ 6 H
980:) and
845:verify
842:
817:(SDS)
804:Dermal
625:Danger
341:SMILES
31:Names
3857:AlGaP
3852:GaAsP
3847:GaInP
2299:ZnICH
2219:Zn(CH
2191:Zn(CH
2013:Zn(NO
2005:ZnMoO
1973:ZnCrO
1641:S2CID
1466:(PDF)
1411:S2CID
1368:S2CID
1194:, an
1034:cubic
938:with
903:is a
580:High
457:acids
306:InChI
145:JSmol
3319:-GeP
3162:-SiP
2279:Zn(C
2263:Zn(C
2223:COO)
2203:Zn(C
2088:ZnTe
2083:ZnSe
2075:ZnSO
1953:ZnCl
1937:ZnCO
1929:ZnBr
1917:Zn(N
1676:PMID
1608:ISBN
1588:ISBN
1570:PMID
1562:ISSN
1512:ISBN
1494:ISSN
1442:ISBN
1360:PMID
1281:ISBN
1151:and
936:zinc
905:II-V
895:. Zn
796:Oral
705:P501
701:P405
685:P330
681:P321
673:P280
669:P270
665:P264
657:P223
643:H300
639:H260
490:tP40
401:Odor
348:=PP=
249:UNII
4135:RDX
3823:No
3820:Md
3817:Fm
3814:Es
3811:Cf
3807:BkP
3803:Cm
3800:Am
3796:PuP
3791:NpP
3782:Pa
3775:ThP
3770:AcP
3750:YbP
3745:TmP
3740:ErP
3735:HoP
3730:DyP
3725:TbP
3720:GdP
3715:EuP
3707:SmP
3703:SmP
3699:Pm
3695:NdP
3687:PrP
3683:PrP
3678:CeP
3673:LaP
3619:Og
3616:Ts
3613:Lv
3610:Mc
3607:Fl
3604:Nh
3601:Cn
3598:Rg
3595:Ds
3592:Mt
3589:Hs
3586:Bh
3583:Sg
3580:Db
3577:Rf
3574:Lr
3571:**
3568:Ra
3565:Fr
3560:Rn
3557:At
3554:Po
3550:BiP
3542:PbP
3538:Tl
3535:Hg
3531:AuP
3523:PtP
3519:Ir
3512:OsP
3508:Re
3502:Ta
3498:HfP
3493:LuP
3486:Ba
3469:Xe
3460:+Te
3455:SbP
3446:SnP
3440:InP
3415:Pd
3412:Rh
3400:Tc
3393:MoP
3389:MoP
3376:NbP
3368:ZrP
3364:ZrP
3341:Rb
3336:Kr
3332:+Br
3328:Se
3324:AsP
3314:GaP
3306:ZnP
3246:CoP
3241:FeP
3237:Mn
3225:CrP
3217:TiP
3212:ScP
3205:CaP
3179:Ar
3175:+Cl
3158:+Si
3153:AlP
3104:Ne
3054:Be
3040:He
2797:PCl
2789:PCl
2781:PBr
2773:PBr
2765:PBr
2745:ZrP
2739:ZrP
2719:ZnP
2714:YbP
2704:TmP
2695:ThP
2685:SnP
2679:TbP
2658:SmP
2652:SmP
2647:ScP
2642:PuP
2633:PrP
2627:PrP
2618:PtP
2597:OsP
2577:NpP
2572:NdP
2567:NbP
2547:MoP
2541:MoP
2536:LuP
2522:LaP
2517:InP
2512:HoP
2507:HfP
2493:FeP
2488:AuP
2483:GdP
2478:EuP
2473:ErP
2468:DyP
2416:BiP
2406:AsP
2401:AlP
2334:ZnO
2169:(PO
2157:ZnP
2070:ZnS
2030:ZnO
2025:ZnO
1997:ZnI
1989:ZnH
1981:ZnF
1878:(CH
1668:doi
1633:doi
1554:doi
1486:doi
1434:doi
1403:doi
1393:".
1352:doi
1068:(Cd
1056:(Zn
1052:),
1044:(Cd
988:):
976:(PH
587:GHS
275:EPA
228:CID
95:ZnP
4343::
3962::
3786:UP
3765:**
3505:W
3489:*
3475:Cs
3465:+I
3428:Cd
3419:Ag
3404:Ru
3381:Mo
3359:YP
3345:Sr
3295:Zn
3286:Cu
3270:Ni
3258:Co
3250:Co
3229:Cr
3221:V
3194:Ca
3171:S
3119:Mg
3110:Na
3101:F
3097:+O
3093:N
3089:+C
3085:CP
3080:BP
3046:Li
2999:PH
2937:10
2866:PO
2849:PN
2841:PH
2833:PI
2825:PF
2817:PF
2809:Cl
2727:Zn
2709:YP
2667:Sr
2607:Ru
2583:Np
2557:Mo
2527:Li
2498:Fe
2459:Cu
2447:Cd
2435:Ca
2422:Cs
2411:BP
2330:46
2321:24
2165:Zn
2145:Zn
2133:Zn
2125:As
2121:Zn
2113:Sb
2109:Zn
2093:Zn
1874:(C
1870:Zn
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3308:2
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740:4
541:)
539:Z
537:(
525:c
521:a
505:2
375:2
373:P
371:3
277:)
273:(
147:)
134:)
129:x
124:P
120:x
105:)
100:2
85:)
80:2
75:P
71:3
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