User talk:Smokefoot/TalkArch3

2096:

biting sideeffects of neuroleptics, as it is a fireant toxin. I am not a conspiracy theorist and have a very solid background. Next day the edits were reverted without comment by Carebear and some other editor. So I patched the correct information back, again and again. See my comments on the top of the talk page. These editors don't know the difference between a mixture and a chemical compound. They think chemistry is like cooking a chicken soup: If you cook the soup on chicken, it is a chicken soup and tastes like chicken. If you add salt, it becomes more salty. If you add pepper, it becomes spicy hot. etc. So all piperidine compounds carry over the properties of the mother substance. If a piperidine compound is an insecticide, you can rightfully assume, that all other piperidine compounds are insecticidal too, depending on the "mixture". etc. I finally gave up the revert war, friendly and educating explanations on the talk page of Dr. Carebear proved useless, see there. Same for the other editor. Look there. I have talked with them like to a sick horse. Then I added a horrible assortment of piperidine compounds to the page, with colorful description of the effects. (among them, making the brain radioactive with radiolabeled Piperidilbenzilate, and turning people into zombies with psychochemical warfare agents) At least this was factually correct and referenced in the source articles, and everybody was happy. I hoped however that this would lead to a "reductio ad absurdum" of their chemical theories. (from grannies chicken soup)

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large rover to be launched to Mars in late 2009. This rover is powered by a Radioisotope Thermal Generator (RTG) heated by Pu-244. It also carries a pulsed neutron generator (Dynamical Albedo of Neutrons, DAN) used to measure sub-surface properties. DAN produces pulses of 1.E7 14 MEV neutrons in about a microsecond. The X-ray diffraction instrument uses Sulfur hexafluoride as electrical insulation in the 25kV power supply. As a review board member, I asked if the neutron flux from these two sources might affect the dielectric properties of SF6. I have found no information on this. Do you have any information on this, or can you point me to someone who might know? Thanks for your time. PS. I was once a UCLA professor of geophysics, then with the US Geological Survey Astrogeology group, now "retired" and helping NASA with Mars missions. Hugh H. Kieffer ........... Celestial Reasonings 180 Snowshoe Lane ....... Voice & Fax 775-782-0767

2673:, those edits were some time ago and you are correct that it is normal practice to discuss changes in cases where the article is fairly mature. It was clear to me (and remains the case) that the article was in bad shape, judging from the obvious redundancies. So I did not seek advice. I knew that I would get lots of feedback from editors with weak scientific judgement and poor writing skills, which I did not want. My edits were pretty generic. The article remains rough - especially the list of the 'chemical analysis." Is there some part that is amiss? Thanks for the note.-- 2799: 2911: 31: 1837:

my goal in editing the article was to provide an image that was of higher quality than the one that preceded it. I appreciate your kindness and generosity in contacting me--I do believe this is no the first time. Right now, I'm just an undergraduate with an intense passion for all things chemistry and I enjoy applying my knowledge towards editing articles on Knowledge--it tends to reinforce my knowledge. Again, thanks for your contact and I look forward to future contact.

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of the above mentioned possible mechanisms plus others, like change of metabolic pathways due to the steric hindrance of certain metabolic attacks in the open chain analog etc. and things become more complex if we take the possibility of active or toxic metabolites into account. Embedding the active amino group is simply one of the building blocks in drug design and individually leads itself to new SARs to play with. I would not call this "no significance".

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piperidine skeleton, to arrive at derivatives with altered pharmacological profile (keeping the distances to other functional groups constant): The alteration may stem from the semi-rigid conformation, or from the increased lipid solubility due to the 5-C chain, or from details in receptor binding affinity by the bulky ring addition, or from steric hindrance of metabolic attacks, to give examples. Or from a combination of the above and other factors.

1637: 1913:----- I like the artikle from 2001 stating that NF3 is used to avoide CF4 which has a halfe life in the atmosphere of 50000 years not of 750, and that the efficency of the process could be as high as 99% so only 1 % of the used NF3 escapes. But when the stupid journalsists go hunting for the biggest story, information is the last thing what they want. Fear of the last days of man is the minimum what they want to have.-- 913: 118:

this is still superior to oil-based liquid lubricants. Also, I feel the Vietnam War stuff needs to be put under a sub-heading of 'Military and Ballistic' uses, as that paragraph appears then the article switches back to an industrial use. If you like, look at my text and apply edits of your own. Regards, Ian (Beefy_SAFC).

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and without engaging in useful discussions. Same for some other editor. Every discussion lost on them so far. The theory that neuroleptics are a mix of fireant venom and insecticides lives on. I prefer if these editors abstain from further work on chemical articles, but maybe instead contribute some chicken soup recipe.

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edit hardly looks POV, and the ref is hardly credible either. Figured you'd have it on your watchlist, but just in case. I'm really not knowledgeable in this area, otherwise I'd re-word it, or revert accordingly. I'm actually opposed to fluoridation (I learned to brush my teeth), but I'm more opposed

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page. Perhaps that partly a result of the work I did to try and remove/replace the bulk of the primary sources on the PFOA page (net reduction of 20 references). I recently realized I had over wiki-fied the interwiki links on the page (repetitive statement?). Was that part of what you meant by style?

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You are however right, that no common simple property of the piperidine compounds is inherited from the parent compound, as naive editors assume. So there is a common theme of alterations which may be achieved by this embedding; but it has no single, simple and consistent explanation, more like a mix

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This idiocy and hooliganism has been going on for a year now. See talk page Dr Carebear. Everybody talking to him like to a sick horse, to convince that chemical compounds are not merely mixtures and do not carry over the properties of their components. He still reverses everything without a comment,

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I encountered your handle through the Knowledge entry on Sulfur hexafluoride.I have a serious question and am hoping you can point me in the right direction. I have asked my son to help make initial contact, as he has a WP account and is much more fluent in the ways of the web. NASA is now building a

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Mate, I've just found this article. It's a mess, but could do with a chembox - could you do that? (because I don't know how!). I've just spent ages changing it all from maths type into wikified chemical notation, but I'm not sure whether it needs all that synthetic stuff or not. However, having spent

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Hey Smokefoot! I was wondering if we could keep the molecular geometry section in the diatomic article. As much as it may seem irrelevant to the diatomic page, it needs to be somewhere. It is crucial to completing the set on molecular geometry. As there are sources now, I certainly am not making this

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What exactly do you find so misleading and confusing? It seems to me that all you're arguing is that you don't like VSEPR and that you disagree with such things. If you can actually back up your argument with something instead of stating that you don't like it then perhaps something would actually be

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Unfortunately, heavy editing is unlikely to be resumed until Tuesday (the next day I have school) because of Martin Luther King Day. And, since I am indeed a first-year chemistry student (as was relatively apparent), I'm unable to contribute much more to the infobox, though I'm likely one of the best

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I'm acting under someone else's premise. This is a chemistry class project. To be honest I don't know much about hybridisation (though I know enough to correctly label the hybridisation of various geometries) and it wasn't my idea to put it in the infobox. Additionally, my chemistry teacher will cook

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Yes, the presence of the piperidine skeleton is of some pharmacological significance, however not in the way how some editors imagine (giving pharmaceuticals the properties of ant venom). The significance is that frequently a functional amino group is embedded into the semi-rigid conformation of the

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Thank you for your continued correspondence. Your level of knowledge far exceeds mine on the subject of infinite polymers and possibly any subject of chemistry. I had conducted some work in a biochemistry lab with a fertilizing solution that contained sodium molybdate, stumbled over the article, and

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Sure, as chemists we may feel that MSDSs tend to err in the side of exaggeration, because we don't tend to eat the chemicals we work with, and we usually work with small amounts, so NaF doesn't seem like a big deal. But it is toxic. Not as much as botulinum toxin, or even good ol' cyanide, but still

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O are highly unusual species, but their unusual character goes un-noticed because of this kind of imprecision/folklore. Virtually all elements will spontaneously burn in oxygen, most dangerously so, so what is the point of highlighting the alkali metals and alkine earth metals? Many are impressed

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There were, as I recall, referenced sections on the use of urine in the making of gunpowder and its use as a mordant in the dying of cloth. I will attempt to regenerate these as fully referenced and well written sections. If you would like to provide input as to the chemical reactions involved in

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Thanks for adding an article on tren. Overdue and a great start. I added some information and edited some of yours, so I hope that you are okay with that. All organonitrogen compounds when combusted release CO and NOx, so we usually do not mention this aspect (or we'd need to expand the warnings

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I suppose it's unlikely that a chemist, even a botanist, would be that interested in classic 20th Century French literature. And your tidy up seems very worthwhile. But it's a shame that you have now tidied away Marcel Proust entirely from this article, presumably on the grounds of irrelevance. The

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Thanks for the catch on linear binding of O2. I was pretty sure I had seen a talk where the speaker claimed to have linear O2 and I was going to check on it next time I was in the office. But nitric oxide is better example of linear/bent even if I can come up with an obscure speculative report on

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Not that you get me wrong. I did rid the piperidine article of utter nonsense, like: Piperidine increases the bioavailability of phenothiazine in neuroleptics. Phenothiazine is an insecticide and a carbamate, as such causes "anticholinesterase blocking toxicity". Piperidine causes the stinging and

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4000t in 2008 (+/-25%) was the number in the article and the article metioned above states that 90-99% are decomposed in the process it is used for, the plasma cleaning of CVD chambers. The article also gives a estimation of 13 to 56 tonns per year are released into the enviroment, if the produced

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Smokefoot, I award you the Chemistry Bond Star for your unrelenting contribution to Chemistry and Chemicals on Knowledge. Especially for your willingness to get your hands dirty when it comes to getting involved with the more controversial matters that arise from time to time - keep bashing those

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Cl is the one which would be subject to pi electron attack; however, from what I believe, this positive charge on the very electronegative chlorine substantially polarizes the "nuetral" chlorine making it the actual electrophilic species. I will change my additions to account for both ideas on the

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Smokefoot, I'll not reapply any of my edits without discussing with you first - I will await your reply before doing anything. I was trying to tidy up the article and make clear a few points, plus one new development I was aware of. For example, whilst oxidation of MoS2 does restrict it's use,

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Hi, could you have a look at the changes I have made to copper sulfide and copper(I) sulfide, in particular the oxidation state section in copper sulfide which I have extended to water down the "all copper sulfides are copper(I)" viewpoint. As regards renaming CuS how about the IUPAC name for the

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Interesting you should bring up this "molecule" ... A quick literature search suggests that so far no one has attempted to isolate anything resembling "hexafluorosilicic acid". A quick shot with a mass spec shows a peak at 143 with the proper Si peak at 144, but there are lots of +(HF) and -(HF)

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Thanks for the reply. I missed that Marcel and his pot had slipped down to the bottom. Asparagus trivia must be even harder to find than a perfumed French chamber-pot! So who knows. I must admit that the line on its own sounds like a very odd accusation indeed, so maybe a reference back up to the

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Smokefoot, I've reintorduced the 'Future Developments' in MoS2. As I commented earlier, I've been heavily involved in wear science and feel that perhaps a mention of the oxide phenomena I talked about should be made. One of the reasons it was pursued is because of the upper limit of 350°C for

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hey Smokez, thanks for your contributions/advice. I am a high school student, so i suppose my edits are on the amature level. I have taken up the task of editing the agostic interaction page for a project. Can you please send me the Kubas article. My email is amarkov@rams.micds.org. Cheers mate!

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I think it's just a matter of precision. It seems to me that Nergaal is using "oxide" loosely to include superoxides, peroxides, etc. I don't think that's necessarily wrong, but perhaps the phrasing could be made more explicit. Regarding spontaneity, it may be a case of saying the truth but not

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are also formed. One has to really beat on some of these reactions to complete the conversion to the oxides. And my point about "spontaneously" is that to the normal ear, this word means fast, but to a chemist's ear, it means thermodynamically favorable (and possibly excruciatingly slow). Yes,

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To be honest, I can't even find the edit the user was referencing. I'm a little new to this so when you get the chance could you link the edit below? I'll check back soon but we may have C-F bond page fun before I get around to doing anything. I appreciate the implicit admission of accepting the

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1 g could reasonably called "mild", it is an arbitrary distinction. Who sets the limits between nontoxic, mildly toxic, toxic, highly toxic, extremely toxic, etc.? My suggestion is to avoid any such labels and just give the numbers, unless you are getting the label from an authority such as a

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Well, I don't see KCN as a polymer, but as a crystalline structure, and as a ionic compound if it is in water. I draw that structure cause I saw a similar structure on commons for HCN, but it isn't the same. So, what do you suggest me to draw a picture of KCN? Can be a good idea to draw the

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You deleted material dealing with the hypothesized effect of ammonia on nicotine in cigarettes. As this subject is quite topical, and as the material you deleted was fully referenced to the scientific literature, I feel that the material you deleted ought to be reinstated. JosephPriestley

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I am not a great fan of traditional naming of manganese compounds as the old timers didn't understand oxidation numbers or all of oxidation states of Mn when they went for the -ous -ic, -ite -ate style of nomenclature-- in this case IUPAC did us all a favour, so for me the series of

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I'm happy to make images for the other compounds, but I'll only do so if it's OK with you and won't interfere negatively with the projects. If any of your students find papers with structural data in, you can of course send me a link or the data itself and I'll whip up a 3D pic.

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It's just two different conventions for computing formal charges. In coordination chemistry, the electrons in a bond "belong" to the ligand. In organic chemistry, the electrons are "shared equally". Both are arbitrary, but we should follow them where appropriate to the context.

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might appear yellow or brown, but tren is colourless. I'd appreciate it if you'd look over the coordination chem part that I added for clarity and typo's. It would be nice to say something more about ATR, but I dont think that tren is really used as much as the permethylated

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LOL, I agree that policing the chem pages for advice on how to get high could be a Sisyphian task. IMHO, the sentence in question is simply making a important distinction that KI is not the commonly available tincture of iodine. Confusing the two will most likely be fatal.

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What made you think I overwikified Pyrite article? When chemical marks are wikified people can easily see what they are by touching them. I didn't wikify same things twice except Fe and S because they appeared again far down in another section with other marks. Best regards

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Absolutely not offensive at all. I understand the reasoning that the "electron pushing" demonstration can fool one into thinking that the resonance is an actual process that is occurring. I appreciate your input. I will update the image to remove the arrows.

299:. The idea, firmly instilled into many enthusiasts - me at one time - is that sodium and potassium quickly and simply convert to binary oxides (nonsense at RT), whereas most of the reactivity and the fireworks is associated with water. The article is about 663:

That said, you're right in that it's not the place to discuss the issue and the compacted oxide phenomena does have it's own page with comprehensive discussion. Therefore mention of it is now as brief as possible with link to page if anyone wants to look.

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I use a Mac for everything except making the raw images - I use an old PC for that. It's a bit frustrating that they don't have a Mac version of DS Visualizer. I have Spartan for Mac, but the images it generates are not as clear, unless you want to show

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Hi Smokefoot, my father has asked me to forward the following to you since I have a Knowledge account already set up. If you could please respond to him at "hkieffer(at)charter.net", any help you might have in this matter would be appreciated. Thanks!

1276:). Perhaps you are worried that Proust will have us rambling off through the asparagus patch into World War One and various sexual perversions, unless you put your organic chemist's foot down? But I feel the article is now the poorer for that deletion. 2566:

N. The reason that I named it Trilithium(1+) Ion Azanetriide, is because it is its correct IUPAC name according to them, rather than an accepted name. Besides, simply "lithium nitride" does not convey any information concerning the structure of the

1564:- I thought vanadium and molybdenum had all the pretty colours. BTW I enjoyed your antimony tetroxide article, (I made a few tweaks on grammar etc couldn't resist it), yet another interesting structure that I knew nothing about! Oh have a look at 228:

Are you sure? The situation is probably more complicated than indicated by the statement. Also, "spontaneously" has a tricky meaning. Etc etc. It might be worth reading up on M + O2 reactions. Describing the reality can get complicated though, I

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feature to your user account, and to those other trusted Knowledge chemists. I hope this helps with reverting any vandalism or other inappropriate edits you come across. (If you do not want rollback, just let me know, and I'll remove it.) --

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Thanks for your support. Please, please let me know if you have misgivings about my editing. Some of the articles on really big chemicals have become lists of very minor stuff, distorting reality, but I can get slightly strident. I rely on

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I searched Google Scholar for the crystal structure of the compound but could not find it. I also tried to look at the references provided in the article, but those particular ones are not accessible online through my university network.

281:"the whole truth", as indeed most metals react spontaneously with oxygen in the thermodynamic sense. Yet the alkali metals are special in that they react readily enough that one needs to worry about it and keep them away from oxygen... -- 523:

me if those boxes aren't up. I'm not sure of your reference material, but my textbook at least makes mention of orbital hybridisation. What in particular are you suggesting we list instead? I can make the template edit any time.

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Tis okay, I'll restore my edits in that case. I've done more wear science than I care to admit (to the point it's boring me senseless, TBH). I just felt the item needed updating and tidying up. Regards, Ian (Beefy_SAFC).

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toxic. About a couple of orders of magnitude more toxic than table salt, for example. Table salt has also been used for suicide, but it is way less likely to cause accidental deaths, because it is much less toxic than NaF. --

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Do you have a reference confirming that DIBAL is dimeric? Might be easier to just reference, rather than starting a revert war. If you find the crystal structure on your travels, I'll be happy to make an image based on it.

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It appears that all potential angles on PFOA are being covered by you in considerable detail. So you should be able recover any removed material without much effort. I still think that the PFOA article is problematic in

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I am not sure where did you learn chemistry, but they actually do. Even Aluminum reacts spontaneously with oxygen, forming a protective oxide layer, and aluminum is not even close as reactive as any of the group 1 or 2

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FYI, AeronM is the same editor who inserted the material you (rightly) removed from the fluoride article. AeronM's claim that you vandalized the article is spurious, and is one in a pattern of similar accusations.

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on why you removed an edit on Sodium Fluoride. I un-reverted it because it seemed odd that an paragraph with citations was removed, but now that you explained your reasoning, I completely agree with you. Thanks,

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You recently removed a section on fluorotelomer alcohols from the article. However, there is substantial evidence that these substances contribute to a large extent to the environmental concentrations: see e.g.

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I was curious about this article. Since you edited it, you might have some insights. Since this couple is just copper and zinc, might it be possible simply to get a brass object, and file it down to particles?

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is correct. It has a 3 in the NFPA scale from 0 to 4 (although some sources give it a 2; I haven't checked to see if there is an authoritative NFPA source I can check). JT Baker even calls it "severe (poison)".

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I think we can come across a compromise - how about we use the stoichmetric names for binary compounds in "Name =" as in Trilithium Nitride, and the correct IUPAC name Trilithium(1+) Azanetriide in "IUPACName

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Now that is service - and free! I recommend waiting a little to see what happens, because these assignments/suggestions are still changing a little. Also I dont know what their reaction will be this year.--

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N page to "downplay" the ionic nature and imply a "sheet anion" . The refs I have (and they are quite old so there may be more recent stuff), indicate that the bonding is ionic rather than covalent- see

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I've replied to your message in my talk page to try to keep the whole thread in one place. If you don't have it in your watchlist, please let me know and I'll post a notice here if I reply there again.

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I dont think that traditional alloys are active as reagents in the methylene transfer reactions. Apparently, many recipes exist. The role of Cu in the reaction is similar to the role of Cu in the

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done. Besides, those pages are based primarily on VSEPR anyway, so saying that the boxes rely too heavily on VSEPR is basically saying you think all those pages contain primarily wrong information.

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Yes, of course the journalists forgot to mention that, besides being 17 000 times more potent than CO2, it is emitted in amounts that are billions of times smaller! :-) --08:38, 3 July 2008 (UTC)

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Thanks for the message about removing my edits from the TCP article. I was working on finding some good citations at the time. I might just put a short sentence with a link to a page such as

243: 175:. I'd value your critical attention. I also wonder how to better integrate the bits and pieces that are already there on this kind of topics. A lot of it seems rather scattered around. 316:

by a sodium fires but don't take the time to figure out what is really happening. There is also the myth that binary oxides of the alkali metals are pervasive, when they are rarities.

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I think it's great you're taking the time & effort to sort out the articles on these major industrial chemicals. Just wanted you to know your efforts are very much appreciated. --

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Causes severe eye irritation. Skin and respiratory irritant. May be harmful - toxicology not fully investigated. Experimental teratogen. May affect fertility. May cause sensitization.

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chemistry students in my grade. Thank you for your tips as well as insight. I'll keep the freon articles in mind, as they could potentially be workable for me at a later time period.

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Phenmetrazine vs. Methamphetamine similar for Phendimetrazine oops. this are morpholine ring analogs. The piperidine analogs are not commercialized, due to exceedingly long action.

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structure that I added last night. Others teach an structure in which the aromatic pi electrons attack the species and the abstracts the proton to regenrate the catalyst.

69:, after it was recentely demoted from its FA-status. In this, you contributed to the voting process. Would you please be so kind as to provide feedback in its now running 2032:

Hi. Your extensive revisions to Catalysis last week have produced a much improved article. Thanks. I made a few more minor changes today. I have also left 2 questions at

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as an actual molecule, or provide good evidence that such a species does not exist. I think I'm going to try to find someone to sponsor a matrix isolation experiment.

253:, but to be sure of the details. The action of O2 on alkali metals is complicated. These reactions do not always afford the binary oxides, at least not in all cases. 2499:

Disruptive means - so bad that others must clean up after you. You are making other editors work on stamping out bad information. You need to talk to your teacher.--

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page was generally an improvement, is it not customary to discuss such major rewrites in the talk section before removing work that some might consider legitimate?

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standards organization or government (in which case it would be a good idea to cite it). Consider that NaF is called "toxic" by EU standards, if the infobox at

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However, I thought that the "could tax your will power" was a tad harsh for what after all was a good-faith edit to which I was about to add some citations.

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OK, I won't make a big deal about it. But it's not a convention used just by students. You won't find amine oxides drawn any other way in J. Org. Chem.

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most metals react spontaneously with O2, but the process can require eons. E.g. Mg. etc. Oh well, I get the sense this conversation is going nowhere--

147: 2317: 1825: 1251:. I was hesitant to work on such a established page with such a long history. Let me know if you see anythinig that I might be able to help with.-- 1053: 676: 2730:

Your comments about the structure of this innocuous sounding compound are spot on- I had a feeling it was a messy area but when I came across this

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let me know if you have a problem with the current revision. I understand that this is your demesne so I will be open to criticism or advice on the

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With a low toxicity and negligible skin permeability, bisphenols are sufficiently safe that they are used as antioxidants in cosmetics and foods.

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In your opinion 0.025 µg/kg/day is "low toxicity"? And can you tell more about their usage in cosmetics and foods? You did not add references. --

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contain any organic chemical compound that contains copper, or be restricted just to compounds with Cu-C bonds? 16:31, 26 November 2008 (UTC)

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If part of the reason you edit Knowledge is to learn, as it is for me, then can you please point out a few things to me along the way? Thanks. -

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H. Reichardt , A. Frenzel and K. Schober (2001). "Environmentally friendly wafer production: NF3 remote microwave plasma for chamber cleaning".

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Hey Smokefoot, Your edits are great! I'm not trained as a chemist, so I'll defer to your expertise. Thanks for the help. Kindest regards,

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Yes, Tl(I) is what I had in mind. Thanks for catching this mistake because it would be tricky to write an article on an non-existent cmpd.--

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Hi there, we found a bottle of "glyceryl-glass" beads in our lab and are trying to work out what on earth this stuff is. The Sigma ref is

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re:Lithium, sodium, potassium, rubidium, cesium, magnesium... all react spontaneously with oxygen ... to form oxides..." Is that true?

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Perhaps you'd like your students to write one on dppp to complete the important members of the dppx (x = m, e, p, f, etc.) series? --

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What is your argument as to the misleading character of the "electron pushing" demonstration of the imidazole resonance structures?

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I am registered, I simply am sometimes unable to login from work. Does my not signing in somehow invalidate my previous question?

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as described, its a much more complex solution chemistry than I would have expected, I just assumed it was all about insoluble MnO

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heads where needed, de-bunking pseudoscience whenever or whereever it pops-up! - Generally, thanks, and keep up the good work! --

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so long doing it, I'm reluctant to lose most of it! It's been untouched since 2006, which must be some kind of record. Cheers,

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What do you mean disruptive? I try to give true info but, I only give what I found using a source an I don't copy and paste.

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with little charges on the N's. Or DMSO with arrows. This convention is followed by organic students, and I find it lame. --

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Oh, maybe I messed up - it is my responsibility to go back and exhume the gunpowder and mordant parts. Give me some time. --

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in the solid state, which was not surprising as Mn(IV) is traditionally considered to be unstable (notwithstanding MnO

200:. In your efforts to remove froth I believe you also removed a considerable amount of useful and non-trivial content. 2557: 2304: 1482: 1217: 1195:, with an edit summary stating that DIBAL is not a dimer, but they did not give any evidence to support their claim. 1568:- I'm filling the gaps on oxides, their structures and physical properties - I ran out of ideas on uses. Regards.. 1458: 2490: 2470: 992: 769: 754:

Pretty funky! Considering over hundred studies showing serious adverse effects, and also that page you added says:

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As for DMSO, yet another arbitrary convention: it is normal to see sulfur as "hypervalent", but not nitrogen... --

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under Articles for deletion. In other words, no actual discussion page was made. The proper AfD process is listed

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I was looking at your list of topics for writing projects. I've made images for some of them already, for example

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That was an accident and I was going to take it off but you already had. I'm soooooo sorry. Forgive me, please.

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Yes, not signing suggests a rogue editor who would be unresponsive. Responding to your original question about

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I think the article looks much improved by your edits and the Asparagus and urine section now looks just right.

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interest (obsession even) that Charles Swann has with asparagus goes far beyond the chamber pot (see my note in

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to learn more about contributing to this encyclopedia, and if you would like to experiment, please use the

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4000t are used acording to the described process, so we should add this to get it alittle bit balanced.--

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Hi there, I have been adding some Mn oxides and came across this page, and I have a few problems with it.

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sub-section might be useful? Whatever. I'm glad that even organic chemists can have a sense of humour.

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Welcome to Knowledge. It might not have been your intention, but your recent edit removed content from

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It seems that I'm not the only one that has noticed that ... "without Smokefoot there is fire!" :) --

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Why so much emphasis in saying that it is only "mildly" toxic? While I agree that a lethal dose : -->

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Mate, you seem like a sensible chap who knows a little about chemistry(!). Could you have a look at

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N-ethyl-Piperidil-3-benzilate vs. Benactyzine (increased central activity and duration of action)

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Yeah from me too, I happened to notice the grief you'd been given a little while ago. Keep it up.

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The design of this almost completely impersonal (yet hopefully uplifting) message was ripped from

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Do you mean that KCN is a ionic compound so its structure is K CN ? It's so correct or not? --

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OK, we're going on the idea that it is CH3-CH2-O-Si derivatised glass. Thanks for the input.

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Probably a good idea for you to register, before we bother trying to hold a conversation.--

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I'm not sure if you're aware of this page, but this might be of interest to you. Cheers! --

997: 680: 672: 632: 585: 206: 2454: 2369:. Could you please add charges to the N and O atoms or use "N→O", similar to structures 928:. If this was a mistake, don't worry; the text has been restored, as you can see from the 8: 2927: 1701: 1649: 1416: 1399: 1384: 1368: 1311: 1293: 1277: 925: 876:

There are a couple different ways it is thought of. Some textbooks teach the neutral AlCl

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MoS2 and it is of academic interest to wear scientists (I said this in an earlier edit).

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mixed valence formulation: copper(II) dicopper(I) sulfide(2−) disulfide(2−) (joke!) --

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Not pushy at all (I'll resist the urge to say "uncharacteristically so" ;), and thank

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Is it thallium(III) ethoxide or thallium(I) ethoxide? I found no hint for the (III).--

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Hi Smokefoot, I have been adding some content to this page, as well as quite a bit on

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Isn't there something about light and heat going hand in hand? ;) Merry Christmas.

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So welcome back soon! You are one of the backbones of the chemistry in Knowledge!--

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I am very concerned about the questions your edits raise regarding this issue of

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If you wish to start a new discussion or revive an old one, please do so on the

2282:. Therefore, a section on fluorotelomer alcohols deserves being in the article. 841:

states that its F. Z. Roussin, but the reference from 1858 says Roussin, M. L.--

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If you wish to start a new discussion or revive an old one, please do so on the

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to people messing with WP or using it as a vehicle for their POVs :) Cheers,

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Thioridazine vs open chain neuroleptic analogs (increased central activity)

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peaks also. I've been considering what kind of experiment might "isolate" H

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on hundreds of articles on organoN species). Also, tren is colourless.

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and discuss edits that are likely to be controversial on the article's

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If you wish to discuss, I can be contacted at beefnetuk@yahoo.co.uk .

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Thanks for the tips, but my point wass to encourage you not to simply

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Would you care elaborate on your most recent comment on my talk page?

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I think this article is the one where all th stupid things came from

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anions would be manganate(IV) etc - so much simpler and unambiguous

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as a significant PFOA precuror after seeing these sources together

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Please reconsider your recent huge reduction of the article on

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Ok I'll ask for this article to be deleted. I never tried KMnO

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Here's hoping the new year brings you nothing but the best ;)

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and see if you think he's made it all up, like I do? Thanks,

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at any time by removing the {{Talkback}} or {{Tb}} template.

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I've only added one of them to the article, the rest are at

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Thanks for catching that glitch. I'll pass on the info. --

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crystalline structure? Unfortunately, I don't know it... --

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I received a message from you concerning the compound of Li

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Funny how curiosity leads us into such strange pathways.

1112: 920:. When removing text, please specify a reason in the 1247:. I'm also glad that you approve of what I did with 887:

structure, it would indeed seem as if the positively

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Commons:Image:Roussin's-black-salt-anion-3D-balls.png

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so much for taking the time to improve the article.

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O gives a series of so-called "manganites" e.g. KMnO

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Commons:Image:Roussin's-red-salt-anion-3D-balls.png

1506:of course!) and not many are known. Dissolving MnO 749:http://ptcl.chem.ox.ac.uk/MSDS/BI/bisphenol_A.html 126:I might have messed up, sorry for the deletion on 2149:Pethidine and derivatives vs. open chain analogs 148:Beefy_SAFC Revision of 'molybdenum disulfide' (2) 2688:these processes, that would be great. Thanks! 1061:Dicarbonyltris(triphenylphosphine)ruthenium (0) 1005:I've finally uploaded all the images I made of 814:Just a note to tell you that I've responded at 1591:deserved it to have a good article! Thanks!!-- 113:Beefy_SAFC Revision of 'molybdenum disulfide' 2804:Hello, Smokefoot. You have new messages at 2265:. Have you read this archived diskussion 2365:I noticed that you created an image for 2126:Piperidine, pharmacological significance 442:Commons:Category:Chlorodiphenylphosphine 342:Two weeks too late, you say? Not in the 295:It's a matter, not of precision, but of 1634: 14: 2924:Do not edit the contents of this page. 44:Do not edit the contents of this page. 2137:Phencyclidine vs. open chain analogs 1735:and {doi|10.1006/jssc.1996.7196 }} -- 892:mechanism. I appreciate your contact. 97:Done. Good luck with this project.-- 2905: 2308:] about this under "353..." Thanks - 2257:Hi. I noticed your contributions to 2071:copper sulfide and copper(I) sulfide 742:fix chemistry and copy edit the rest 61:Hi, Smokefoot, I've copy-edited the 25: 2388:I'll think about it. We dont write 23: 2797: 1609:(Permanent) Leave is not an option 518:Re re Molecular Geometry Infoboxes 454:Commons:Category:Methyl isocyanide 24: 2942: 1367:. Just thought I'd let you know. 2909: 2523:. Any ideas what this could be? 1635: 911: 883:At any rate, in the nuetral AlCl 837:Hi smokefoot, the article about 334: 29: 2784:Category:Organocopper compounds 2712:18:14, 23 September 2008 (UTC) 2698:13:44, 23 September 2008 (UTC) 2683:13:24, 23 September 2008 (UTC) 2665:12:55, 23 September 2008 (UTC) 2651:23:44, 17 September 2008 (UTC) 2635:22:44, 17 September 2008 (UTC) 2606:06:54, 19 September 2008 (UTC) 2592:05:23, 17 September 2008 (UTC) 2577:02:19, 17 September 2008 (UTC) 2550:00:11, 11 September 2008 (UTC) 2533:22:38, 10 September 2008 (UTC) 1383:You got all the steps in now. 13: 1: 2901:00:52, 29 December 2008 (UTC) 2885:00:26, 29 December 2008 (UTC) 2865:13:34, 24 December 2008 (UTC) 2844:15:47, 14 December 2008 (UTC) 2769:00:46, 14 November 2008 (UTC) 2733:I was completely convinced.-- 2509:21:32, 6 September 2008 (UTC) 2495:21:28, 6 September 2008 (UTC) 2479:21:18, 6 September 2008 (UTC) 2445:18:47, 6 September 2008 (UTC) 2431:18:46, 6 September 2008 (UTC) 2416:18:30, 6 September 2008 (UTC) 2402:18:07, 6 September 2008 (UTC) 2383:17:50, 6 September 2008 (UTC) 2292:19:22, 2 September 2008 (UTC) 2197:for the Si + MeCl reaction.-- 1937:10.1016/j.jhazmat.2008.02.023 1892:10.1016/S0167-9317(00)00505-0 1722:I see you have altered the Li 1494:I can find no references to K 1328:Dielectric Properties of SF6? 1017:Commons:Category:Sodium amide 828:04:17, 28 February 2008 (UTC) 802:02:29, 16 February 2008 (UTC) 770:01:18, 16 February 2008 (UTC) 721:07:40, 12 February 2008 (UTC) 689:12:20, 10 February 2008 (UTC) 140:15:25, 30 December 2007 (UTC) 91:19:13, 31 December 2007 (UTC) 57:Lead(II) nitrate, back to FA? 2743:09:36, 3 November 2008 (UTC) 2353:01:30, 5 November 2008 (UTC) 2333:20:21, 19 October 2008 (UTC) 2318:16:12, 19 October 2008 (UTC) 1907:Text "pages 73-76" ignored ( 649:17:37, 25 January 2008 (UTC) 619:15:49, 21 January 2008 (UTC) 604:20:45, 20 January 2008 (UTC) 581:19:27, 21 January 2008 (UTC) 557:06:04, 20 January 2008 (UTC) 533:04:50, 20 January 2008 (UTC) 513:15:52, 19 January 2008 (UTC) 490:04:57, 17 January 2008 (UTC) 475:18:20, 16 January 2008 (UTC) 427:04:57, 17 January 2008 (UTC) 412:09:07, 15 January 2008 (UTC) 374: 364:01:42, 14 January 2008 (UTC) 7: 2248:19:52, 27 August 2008 (UTC) 1880:Microelectronic Engineering 1193:diisobutylaluminium hydride 291:19:05, 6 January 2008 (UTC) 272:18:43, 6 January 2008 (UTC) 244:18:17, 6 January 2008 (UTC) 215:03:13, 4 January 2008 (UTC) 185:19:51, 3 January 2008 (UTC) 107:17:56, 1 January 2008 (UTC) 10: 2947: 2225:10:20, 1 August 2008 (UTC) 2207:09:33, 1 August 2008 (UTC) 2188:07:10, 1 August 2008 (UTC) 1667:Illegitimi non carborundum 1483:06:02, 29 April 2008 (UTC) 1459:18:25, 21 April 2008 (UTC) 1434:00:26, 20 April 2008 (UTC) 1421:19:45, 19 April 2008 (UTC) 1394:19:08, 13 April 2008 (UTC) 1378:18:27, 13 April 2008 (UTC) 1350:22:12, 11 April 2008 (UTC) 1238:17:14, 29 March 2008 (UTC) 1218:21:51, 25 March 2008 (UTC) 1171:10:22, 27 March 2008 (UTC) 1155:15:56, 25 March 2008 (UTC) 1125:13:30, 12 March 2008 (UTC) 1106:08:26, 12 March 2008 (UTC) 333: 2778:I see you reverted me at 2558:Naming of Lithium Nitride 2163:13:09, 31 July 2008 (UTC) 2121:09:41, 30 July 2008 (UTC) 2106:02:46, 30 July 2008 (UTC) 2086:09:25, 24 July 2008 (UTC) 2066:17:42, 18 July 2008 (UTC) 1847:03:54, 23 June 2008 (UTC) 1826:17:10, 22 June 2008 (UTC) 1810:13:51, 22 June 2008 (UTC) 1733:10.1107/S0567739478002041 1641: 1359:You didn't properly list 1320:19:31, 6 April 2008 (UTC) 1302:16:07, 6 April 2008 (UTC) 1286:15:29, 6 April 2008 (UTC) 1261:05:46, 1 April 2008 (UTC) 1245:Transition metal hydrides 1077:22:10, 2 March 2008 (UTC) 1054:22:09, 2 March 2008 (UTC) 1034:18:38, 2 March 2008 (UTC) 993:16:26, 2 March 2008 (UTC) 973:03:50, 2 March 2008 (UTC) 950:02:43, 2 March 2008 (UTC) 902:18:18, 1 March 2008 (UTC) 866:18:54, 1 March 2008 (UTC) 851:16:54, 1 March 2008 (UTC) 779:Thanks for your detailed 747:==Safety aspects== See 498:Let me know if and when! 2046:02:38, 9 July 2008 (UTC) 2022:22:43, 8 July 2008 (UTC) 2006:14:51, 8 July 2008 (UTC) 1979:06:29, 4 July 2008 (UTC) 1949:07:05, 3 July 2008 (UTC) 1923:06:35, 3 July 2008 (UTC) 1870:04:59, 3 July 2008 (UTC) 1856:Didn't take 'em long... 1786:20:21, 8 June 2008 (UTC) 1745:08:07, 5 June 2008 (UTC) 1710:13:05, 4 June 2008 (UTC) 1695:07:48, 4 June 2008 (UTC) 1681:20:16, 2 June 2008 (UTC) 1658:19:24, 2 June 2008 (UTC) 1642:The Chemistry Bond Star 1623:21:33, 27 May 2008 (UTC) 1601:00:04, 11 May 2008 (UTC) 1510:in conc alkali gives MnO 2615:While your work on the 1578:18:06, 2 May 2008 (UTC) 1551:14:14, 2 May 2008 (UTC) 737:on 2008-01-06T03:36:13 2802: 2749:Hexafluorosilicic acid 2487:Syntheticalconnections 2467:Syntheticalconnections 2299:fluorotelomer alcohols 2263:Perfluorooctanoic acid 2253:Perfluorooctanoic acid 1012:'s crystal structure. 744:. However, you added: 67:Chemicals wikiproject 2922:of past discussions. 2801: 1795:Greetings Smokefoot, 1720:Good to see you back! 1522:in fused oxide e.g. K 1361:Venketa Parthasarathy 1355:Venketa Parthasarathy 1243:Thanks for improving 1115:article. Many thanks. 932:. Take a look at the 158:Solid-state chemistry 42:of past discussions. 2806:RockManQ's talk page 2233:Ammonia and nicotine 2174:Hey there Smokefoot 2134:Substance examples: 1852:Nitrogen trifluoride 1566:Manganese(III) oxide 2726:Sodium metasilicate 1791:Imidazole resonance 1628:Chemistry Bond Star 1488:potassium manganite 1185:User:130.160.28.217 1082:Tricresyl phosphate 495:OK, not a problem. 18:User talk:Smokefoot 2813:remove this notice 2803: 2169:Zinc-copper couple 1860:came out today :) 839:Roussin's Red Salt 173:magnetic structure 2934: 2933: 2928:current talk page 2863: 2842: 2625:comment added by 2481: 2465:comment added by 2028:Catalysis article 1663: 1662: 1444:I have added the 1391: 1375: 1191:a paragraph from 1131:Fluoride toxicity 940:. Thank you. -- 691: 675:comment added by 651: 635:comment added by 395: 394: 370: 369: 362: 89: 65:article from the 54: 53: 48:current talk page 2938: 2913: 2912: 2906: 2871:Re:About KCN ... 2853: 2832: 2816: 2774:Copper compounds 2637: 2460: 2367:pyridine-N-oxide 2361:Pyridine-N-oxide 2215:Okay, thanks! -- 1912: 1905: 1903: 1895: 1639: 1632: 1631: 1431: 1389: 1387: 1386:Ten Pound Hammer 1373: 1371: 1370:Ten Pound Hammer 969: 962: 915: 794: 791: 788: 717: 710: 704: 670: 630: 577: 570: 553: 546: 437:Happy new year! 433:Writing projects 372: 371: 352: 338: 331: 330: 87: 83: 79: 63:lead(II) nitrate 33: 32: 26: 2946: 2945: 2941: 2940: 2939: 2937: 2936: 2935: 2910: 2873: 2822: 2817: 2810: 2795: 2780:copper benzoate 2776: 2754:Hey Smokefoot, 2752: 2728: 2620: 2613: 2598:Plasmic Physics 2584:Plasmic Physics 2569:Plasmic Physics 2565: 2560: 2517: 2457: 2363: 2338:content on the 2259:Perfluorocarbon 2255: 2240:Josephpriestley 2235: 2172: 2128: 2093: 2073: 2053: 2030: 1991: 1906: 1897: 1896: 1858:that news story 1854: 1834: 1793: 1772: 1768: 1762: 1760: 1756: 1725: 1718: 1716:lithium nitride 1630: 1611: 1589:Wilhelm Michler 1586: 1584:Wilhelm Michler 1563: 1559: 1540: 1533: 1529: 1525: 1521: 1513: 1509: 1505: 1501: 1497: 1490: 1468: 1442: 1429: 1402: 1385: 1369: 1357: 1338: 1330: 1269: 1225: 1179: 1139:sodium fluoride 1133: 1084: 1064: 1010: 1000: 981: 967: 960: 909: 907:Gentle reminder 886: 879: 874: 872:Re: FeCl3 + Cl2 835: 809: 792: 789: 786: 777: 752: 728: 715: 708: 702: 697: 692: 657: 626: 588: 579: 575: 568: 555: 551: 544: 520: 435: 400: 344:Julian calendar 329: 314: 310: 225: 207:Terry Bollinger 194: 161: 150: 124: 115: 85: 77: 71:FA re-candidacy 59: 30: 22: 21: 20: 12: 11: 5: 2944: 2932: 2931: 2914: 2904: 2903: 2872: 2869: 2868: 2867: 2821: 2818: 2809: 2796: 2794: 2788: 2775: 2772: 2751: 2746: 2727: 2724: 2723: 2722: 2721: 2720: 2719: 2718: 2717: 2716: 2715: 2714: 2612: 2609: 2563: 2559: 2556: 2555: 2554: 2553: 2552: 2516: 2515:Glyceryl glass 2513: 2512: 2511: 2497: 2456: 2453: 2452: 2451: 2450: 2449: 2448: 2447: 2433: 2362: 2359: 2358: 2357: 2356: 2355: 2320: 2254: 2251: 2234: 2231: 2230: 2229: 2228: 2227: 2210: 2209: 2195:Direct process 2171: 2166: 2155:70.137.164.136 2127: 2124: 2113:70.137.181.232 2098:70.137.181.232 2092: 2089: 2072: 2069: 2052: 2049: 2034:Talk:Catalysis 2029: 2026: 2025: 2024: 1993:Hey Smokefoot 1990: 1989:KOH, DCM, etc. 1987: 1986: 1985: 1984: 1983: 1982: 1981: 1961: 1960: 1959: 1958: 1952: 1951: 1928: 1927: 1926: 1925: 1853: 1850: 1833: 1830: 1829: 1828: 1792: 1789: 1770: 1766: 1761: 1758: 1754: 1751: 1749: 1723: 1721: 1717: 1714: 1713: 1712: 1702:Quantockgoblin 1661: 1660: 1650:Quantockgoblin 1644: 1643: 1640: 1629: 1626: 1610: 1607: 1605: 1585: 1582: 1581: 1580: 1561: 1557: 1538: 1535: 1531: 1527: 1523: 1519: 1518:. Reacting MnO 1511: 1507: 1503: 1499: 1495: 1493: 1489: 1486: 1470:Hey Smokefoot 1467: 1462: 1441: 1438: 1437: 1436: 1401: 1398: 1397: 1396: 1390:and his otters 1374:and his otters 1356: 1353: 1335: 1329: 1326: 1325: 1324: 1323: 1322: 1312:Martinevans123 1305: 1304: 1294:Martinevans123 1278:Martinevans123 1274:Asparagus talk 1268: 1265: 1264: 1263: 1224: 1221: 1178: 1175: 1174: 1173: 1132: 1129: 1128: 1127: 1095: 1083: 1080: 1063: 1058: 1057: 1056: 1042: 1041: 1008: 999: 996: 980: 977: 976: 975: 908: 905: 884: 877: 873: 870: 869: 868: 834: 833:Roussin, M. L. 831: 808: 805: 776: 773: 746: 727: 724: 696: 693: 669: 656: 653: 625: 622: 587: 584: 573: 549: 519: 516: 493: 492: 434: 431: 430: 429: 399: 396: 393: 392: 368: 367: 347: 339: 328: 321: 320: 319: 318: 317: 312: 308: 293: 275: 274: 224: 221: 219: 193: 188: 160: 155: 149: 146: 144: 123: 120: 114: 111: 110: 109: 58: 55: 52: 51: 34: 15: 9: 6: 4: 3: 2: 2943: 2929: 2925: 2921: 2920: 2915: 2908: 2907: 2902: 2898: 2894: 2889: 2888: 2887: 2886: 2882: 2878: 2866: 2861: 2857: 2852: 2851:Fvasconcellos 2848: 2847: 2846: 2845: 2840: 2836: 2831: 2830:Fvasconcellos 2827: 2820:Molybdopterin 2814: 2807: 2800: 2793: 2787: 2785: 2781: 2771: 2770: 2766: 2762: 2757: 2750: 2745: 2744: 2740: 2736: 2732: 2713: 2709: 2705: 2701: 2700: 2699: 2695: 2691: 2690:Patris Magnus 2686: 2685: 2684: 2680: 2676: 2672: 2668: 2667: 2666: 2662: 2658: 2657:Patris Magnus 2654: 2653: 2652: 2648: 2644: 2640: 2639: 2638: 2636: 2632: 2628: 2624: 2618: 2608: 2607: 2603: 2599: 2594: 2593: 2589: 2585: 2579: 2578: 2574: 2570: 2551: 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