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261:. One of the double bonds connects two parts of an organic molecule. The other double bond connects a metal-based catalyst to a fragment of an organic molecule. In metathesis, these two double bonds combine and split to make four single bonds. The single bonds form a ring that connects the metal catalyst, the organic fragment, and the two parts of the organic molecule. The metal catalyst then breaks off from the ring, carrying away part of the organic molecule. This process leaves the fragment attached to the remainder of the
1143:
250:, which involves organic (carbon-based) compounds. In metathesis, chemists break double bonds more easily by introducing a catalyst—that is, a substance that starts or speeds up a chemical reaction. Chemists began performing metathesis in the 1950s without knowing exactly how the reaction worked. This lack of understanding hindered the search for more efficient catalysts.
206:. He began working in the chemical industry but was frustrated there. He is quoted as saying, "If you want to find something new, look for something new...there is a certain amount of risk in this attitude, as even the slightest failure tends to be resounding, but you are so happy when you succeed that it is worth taking the risk." In 1960, Chauvin began working for the
277:
to develop catalysts that carried out the reaction more efficiently. The three chemists' work has enabled manufacturers to make organic compounds, including some plastics and medicines, using less energy because the required reaction pressures and temperatures became lower, and using fewer harmful
238:. Chauvin was embarrassed to receive his award and initially indicated that he might not accept it. He did however receive his award from the King of Sweden and deliver his Nobel lecture. He was elected a member of the French Academy of Sciences in 2005.
415:
Magna, L.; Niccolai, G. P.; Chauvin, Y.; Basset, J.-M. (2003). "The importance of imidazolium substituents in the use of imidazolium based room temperature ionic liquids as solvents for palladium catalyzed telomerization of butadiene with methanol".
214:. He became honorary director of research there following his retirement from the institute in 1995. Chauvin also served as an emeritus (retired) director of research at the Lyon School of Chemistry, Physics, and Electronics.
265:
with a double bond, forming a new organic compound. Scholars have compared this reaction to a dance in which two sets of partners join hands to form a ring and then split apart again to form two new partnerships.
257:
bound to a carbon atom in one group of atoms causes the group to shift places with a group of atoms in another molecule and explained metathesis in detail. He showed that the reaction involves two
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Martinato, A.; Chauvin, Y.; Lefebvre, G. (1964). "Kinetic aspects of the "period of adjustment" during polymerization (of propylene) with titanium trichloride-triethylaluminium, "Title".
203:
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Herisson, J. L.; Chauvin, Y. (1971). "Catalysis of olefin transformations by tungsten complexes. II. Telomerization of cyclic olefins in the presence of acyclic olefins".
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Chauvin, Y.; Gilbert, B.; Guibard, I. (1990). "Catalytic dimerization of alkenes by nickel complexes in organochloroaluminate molten salts".
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382:(This article is occasionally cited as 1970 as the year of publication due to a typographical error in the original publication.)
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that must be extracted from the desired synthetic. It was for this process they were awarded with 2005 Chemistry Nobel Prize.
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544:"Nobel Prize in Chemistry, 2005. Yves Chauvin, Robert H. Grubbs and Richard R. Schrock. Metathesis and catalysis honored"
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Chang, Kenneth, Yves
Chauvin, chemist sharing Nobel Prize, dies at 84, New York Times, 31 January 2015, p. B13
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202:, to French parents; his father worked as an electrical engineer. He graduated in 1954 from the
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Uchino, M.; Chauvin, Y.; Lefebvre, G. (1967). "Dimerization of propylene by nickel complexes".
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In the early 1970s
Chauvin achieved a breakthrough when he described the mechanism by which a
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457:"Yves Chauvin (1930–2015) Nobel-prizewinning chemist who rearranged carbon–carbon bonds"
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Yves
Chauvin (2006). "Olefin Metathesis: The Early Days (Nobel Lecture)".
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Chauvin, Yves." World Book
Student. World Book, 2011. Web. 21 March 2011.
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Information relating to recent work in the CNRS CPE-Lyon laboratory
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and Nobel Prize laureate. He was honorary research director at the
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and expensive chemicals, and creating fewer contaminant reaction
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838:"Yves Chauvin, 'Green' Chemist and Nobel Laureate, Dies at 84"
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630:"Keine Freude: Nobelpreisträger findet Auszeichnung peinlich"
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170:. He was known for his work for deciphering the process of
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204:École supérieure de chimie physique électronique de Lyon
94:École supérieure de chimie physique électronique de Lyon
294:
Chauvin died, at the age of 84, on 27 January 2015 in
385:
350:
819:"Chemistry Nobel laureate Yves Chauvin dies aged 84"
628:SPIEGEL ONLINE, Hamburg, Germany (5 October 2005).
234:, for his work from the early 1970s in the area of
353:Comptes Rendus de l'Académie des Sciences, Série C
156:; 10 October 1930 – 27 January 2015) was a French
786:"Addio a Yves Chauvin, Nobel per la chimica 2005"
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867:including the Nobel Lecture on 8 December 2005
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879:General information about the Nobel Prize 2005
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194:Yves Chauvin was born on 10 October 1930 in
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800:"Le Nobel de chimie Yves Chauvin est mort"
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35:Nobel Laureates in Chemistry 2005 on stage
29:
2611:Members of the French Academy of Sciences
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269:Chauvin's description of metathesis led
507:Angewandte Chemie International Edition
16:French chemist and Nobel Prize laureate
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2398:International Atomic Energy Agency
836:Chang, Kenneth (31 January 2015).
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174:for which he was awarded the 2005
14:
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869:Olefin Metathesis: The Early Days
852:
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817:Stoye, Emma (30 January 2015).
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874:Details about his Nobel Prize
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133:French Institute of Petroleum
2601:21st-century French chemists
2596:20th-century French chemists
2591:Nobel laureates in Chemistry
163:Institut français du pétrole
7:
2586:Belgian emigrants to France
697:"Humantouchofchemistry.com"
378:10.1002/macp.1971.021410112
241:
103:Deciphering the process of
10:
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647:Karl Grandin, ed. (2005).
561:10.1051/medsci/20052111995
503:"Yves Chauvin (1930-2015)"
246:Chauvin's work centred on
208:French Petroleum Institute
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2065:Venkatraman Ramakrishnan
1344:Wendell Meredith Stanley
924:Nobel Prize in Chemistry
649:"Yves Chauvin Biography"
289:
224:Nobel Prize in Chemistry
222:He was awarded the 2005
176:Nobel Prize in Chemistry
115:Nobel Prize in Chemistry
218:Awards and recognitions
189:
2606:French Nobel laureates
2499:Nobel Prize recipients
2445:Physiology or Medicine
2229:Emmanuelle Charpentier
2217:M. Stanley Whittingham
1188:Hans von Euler-Chelpin
655:. The Nobel Foundation
520:10.1002/anie.201501336
323:10.1002/anie.200601234
1599:Christian B. Anfinsen
1239:Frédéric Joliot-Curie
2261:Karl Barry Sharpless
1758:Dudley R. Herschbach
1583:Luis Federico Leloir
675:"ChemistryViews.org"
499:Olivier-Bourbigou, H
400:10.1039/c39900001715
311:Angew. Chem. Int. Ed
166:and a member of the
2253:Carolyn R. Bertozzi
2165:Jean-Pierre Sauvage
1902:Jens Christian Skou
1870:F. Sherwood Rowland
1782:Charles J. Pedersen
1746:Herbert A. Hauptman
1439:Vincent du Vigneaud
1056:Richard Willstätter
940:Jacobus van 't Hoff
2344:Richard R. Schrock
2213:John B. Goodenough
2141:William E. Moerner
2021:Richard R. Schrock
1993:Roderick MacKinnon
1965:K. Barry Sharpless
1790:Johann Deisenhofer
1619:Geoffrey Wilkinson
1615:Ernst Otto Fischer
1539:Robert S. Mulliken
1475:Jaroslav Heyrovský
1423:Hermann Staudinger
1243:Irène Joliot-Curie
861:on Nobelprize.org
842:The New York Times
806:. 28 January 2015.
788:. 29 January 2015.
703:on 2 February 2015
542:Mansuy, D (2005).
453:Basset, Jean-Marie
275:Richard R. Schrock
232:Richard R. Schrock
184:Richard R. Schrock
2616:People from Menen
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2470:Economic Sciences
2434:Theodor W. Hänsch
2403:Mohamed ElBaradei
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2269:Moungi G. Bawendi
2189:Richard Henderson
2033:Roger D. Kornberg
2001:Aaron Ciechanover
1834:Rudolph A. Marcus
1738:Robert Merrifield
1674:Peter D. Mitchell
1447:Cyril Hinshelwood
1208:Friedrich Bergius
1132:Richard Zsigmondy
1048:Theodore Richards
996:Ernest Rutherford
765:"Eluniversal.com"
677:. 30 January 2015
548:Médecine/Sciences
430:10.1021/om021057s
424:(22): 4418–4425.
394:(23): 1715–1716.
317:(23): 3740–3747.
236:olefin metathesis
172:olefin metathesis
153:[ivʃovɛ̃]
142:
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123:Scientific career
105:olefin metathesis
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1725:
1717:
1714:Roald Hoffmann
1705:
1698:Walter Gilbert
1689:
1677:
1669:
1666:Ilya Prigogine
1661:
1652:
1650:
1646:
1645:
1643:
1642:
1635:John Cornforth
1630:
1622:
1610:
1603:Stanford Moore
1594:
1586:
1578:
1566:
1558:
1551:Ronald Norrish
1542:
1534:
1526:
1518:
1506:
1494:
1486:
1478:
1470:
1462:
1459:Alexander Todd
1454:
1442:
1434:
1426:
1418:
1406:
1399:Edwin McMillan
1393:
1391:
1387:
1386:
1384:
1383:
1371:
1363:
1355:
1347:
1331:
1323:
1315:
1307:
1300:
1293:
1286:
1274:
1266:
1259:Norman Haworth
1254:
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1234:
1226:
1219:
1211:
1199:
1191:
1179:
1171:
1163:
1154:
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1148:
1147:
1140:
1138:
1136:
1135:
1127:
1120:
1112:
1104:
1096:
1093:Walther Nernst
1088:
1081:
1073:
1066:
1059:
1051:
1043:
1035:
1023:
1015:
1007:
999:
991:
988:Eduard Buchner
983:
975:
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964:William Ramsay
959:
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928:
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854:
853:External links
851:
848:
847:
828:
809:
791:
777:
756:
735:
714:
688:
666:
653:Les Prix Nobel
639:
634:SPIEGEL ONLINE
620:
608:
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575:
534:
490:
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366:Makromol. Chem
361:
348:
340:Comptes Rendus
335:
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100:Known for
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70:(aged 84)
64:
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42:
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2242:
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2221:Akira Yoshino
2218:
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2185:Joachim Frank
2182:
2177:
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2166:
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2158:
2154:
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2149:Tomas Lindahl
2145:
2142:
2138:
2134:
2129:
2126:
2125:Arieh Warshel
2122:
2118:
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2110:
2109:Brian Kobilka
2106:
2101:
2098:
2097:Dan Shechtman
2093:
2090:
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2077:
2074:
2073:Ada E. Yonath
2070:
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2037:
2034:
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2026:
2022:
2018:
2013:
2010:
2006:
2005:Avram Hershko
2002:
1997:
1994:
1990:
1985:
1982:
1981:Kurt Wüthrich
1978:
1977:Koichi Tanaka
1974:
1969:
1966:
1962:
1958:
1953:
1952:
1950:
1946:
1939:
1935:
1931:
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1894:Paul D. Boyer
1890:
1887:
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1863:
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1855:
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1847:
1846:Michael Smith
1843:
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1822:
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1814:
1811:
1807:
1806:Sidney Altman
1802:
1799:
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1710:Kenichi Fukui
1706:
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1607:William Stein
1604:
1600:
1595:
1592:
1587:
1584:
1579:
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1564:
1559:
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1555:George Porter
1552:
1548:
1547:Manfred Eigen
1543:
1540:
1535:
1532:
1527:
1524:
1519:
1516:
1512:
1507:
1504:
1500:
1495:
1492:
1491:Melvin Calvin
1487:
1484:
1483:Willard Libby
1479:
1476:
1471:
1468:
1463:
1460:
1455:
1452:
1448:
1443:
1440:
1435:
1432:
1431:Linus Pauling
1427:
1424:
1419:
1416:
1415:Richard Synge
1412:
1411:Archer Martin
1407:
1404:
1400:
1395:
1394:
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1377:
1372:
1369:
1364:
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1360:Arne Tiselius
1356:
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1348:
1345:
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1340:John Northrop
1337:
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1316:
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1308:
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1294:
1287:
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1264:
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1227:
1220:
1217:
1212:
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1200:
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1192:
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1185:
1184:Arthur Harden
1180:
1177:
1176:Adolf Windaus
1172:
1169:
1164:
1161:
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1133:
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1121:
1118:
1113:
1110:
1109:Francis Aston
1105:
1102:
1097:
1094:
1089:
1082:
1079:
1074:
1067:
1060:
1057:
1052:
1049:
1044:
1041:
1040:Alfred Werner
1036:
1033:
1032:Paul Sabatier
1029:
1024:
1021:
1016:
1013:
1008:
1005:
1000:
997:
992:
989:
984:
981:
980:Henri Moissan
976:
973:
968:
965:
960:
957:
952:
949:
944:
941:
936:
935:
933:
929:
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921:
914:
909:
907:
902:
900:
895:
894:
891:
885:
882:
880:
877:
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870:
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857:
856:
843:
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824:
820:
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805:
801:
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745:
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718:
702:
698:
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635:
631:
624:
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603:
588:
582:
580:
571:
567:
562:
557:
554:(11): 995–6.
553:
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538:
530:
526:
521:
516:
512:
508:
504:
500:
494:
486:
482:
477:
472:
469:(7542): 159.
468:
464:
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458:
454:
448:
444:
431:
427:
423:
419:
413:
409:
405:
401:
397:
393:
389:
384:
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375:
371:
367:
362:
359:(2): 103–106.
358:
354:
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328:
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226:, along with
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27:
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2529:
2459:Robin Warren
2428:John L. Hall
2350:Yves Chauvin
2349:
2205:George Smith
2085:Akira Suzuki
2041:Gerhard Ertl
2025:Yves Chauvin
2024:
1973:John B. Fenn
1961:Ryoji Noyori
1948:2001–present
1922:Ahmed Zewail
1882:Harold Kroto
1866:Mario Molina
1794:Robert Huber
1766:John Polanyi
1750:Jerome Karle
1686:Georg Wittig
1571:Derek Barton
1563:Lars Onsager
1515:Giulio Natta
1511:Karl Ziegler
1503:John Kendrew
1271:Richard Kuhn
1196:Hans Fischer
1012:Otto Wallach
948:Emil Fischer
868:
859:Yves Chauvin
841:
831:
822:
812:
803:
794:
780:
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759:
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738:
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717:
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701:the original
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669:
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652:
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590:. Retrieved
587:"Britannica"
551:
547:
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510:
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466:
460:
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391:
387:
369:
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356:
352:
343:
339:
314:
310:
302:Publications
293:
268:
259:double bonds
252:
245:
221:
193:
161:
145:Yves Chauvin
144:
143:
129:Institutions
122:
68:(2015-01-27)
23:Yves Chauvin
2581:2015 deaths
2576:1930 births
2461:(Australia)
2455:(Australia)
2321:Nobel Prize
2173:Ben Feringa
2157:Aziz Sancar
2137:Stefan Hell
2133:Eric Betzig
1910:Walter Kohn
1878:Robert Curl
1854:George Olah
1842:Kary Mullis
1818:Elias Corey
1810:Thomas Cech
1762:Yuan T. Lee
1730:Henry Taube
1263:Paul Karrer
1251:Peter Debye
1231:Harold Urey
1117:Fritz Pregl
1078:Fritz Haber
1020:Marie Curie
804:Le Monde.fr
372:: 161–176.
280:by-products
178:along with
82:Nationality
2570:Categories
2361:Literature
2009:Irwin Rose
1989:Peter Agre
1914:John Pople
1722:Aaron Klug
1627:Paul Flory
1575:Odd Hassel
1499:Max Perutz
1380:Kurt Alder
1376:Otto Diels
1204:Carl Bosch
770:31 January
749:31 January
728:31 January
707:31 January
681:3 February
592:3 February
439:References
388:Chem. Comm
298:, France.
255:metal atom
248:metathesis
47:1930-10-10
2436:(Germany)
2330:Chemistry
2323:laureates
1694:Paul Berg
1649:1976–2000
1390:1951–1975
1320:Otto Hahn
1151:1926–1950
931:1901–1925
920:Laureates
90:Education
57:, Belgium
2480:(Israel)
2352:(France)
570:16274653
529:25754448
501:(2015).
485:25762275
455:(2015).
408:94961900
331:16724296
242:Research
76:, France
2414:Physics
2405:(Egypt)
922:of the
659:29 July
200:Belgium
158:chemist
149:French:
2267:2023:
2251:2022:
2239:2021:
2227:2020:
2211:2019:
2195:2018:
2179:2017:
2163:2016:
2147:2015:
2131:2014:
2115:2013:
2103:2012:
2095:2011:
2079:2010:
2063:2009:
2047:2008:
2039:2007:
2031:2006:
2015:2005:
1999:2004:
1987:2003:
1971:2002:
1955:2001:
1928:2000:
1920:1999:
1908:1998:
1892:1997:
1876:1996:
1860:1995:
1852:1994:
1840:1993:
1832:1992:
1824:1991:
1816:1990:
1804:1989:
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1772:1987:
1756:1986:
1744:1985:
1736:1984:
1728:1983:
1720:1982:
1708:1981:
1692:1980:
1680:1979:
1672:1978:
1664:1977:
1656:1976:
1633:1975:
1625:1974:
1613:1973:
1597:1972:
1589:1971:
1581:1970:
1569:1969:
1561:1968:
1545:1967:
1537:1966:
1529:1965:
1521:1964:
1509:1963:
1497:1962:
1489:1961:
1481:1960:
1473:1959:
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1421:1953:
1409:1952:
1397:1951:
1374:1950:
1366:1949:
1358:1948:
1350:1947:
1334:1946:
1326:1945:
1318:1944:
1310:1943:
1277:1939:
1269:1938:
1257:1937:
1249:1936:
1237:1935:
1229:1934:
1214:1932:
1202:1931:
1194:1930:
1182:1929:
1174:1928:
1166:1927:
1158:1926:
1130:1925:
1115:1923:
1107:1922:
1099:1921:
1091:1920:
1076:1918:
1054:1915:
1046:1914:
1038:1913:
1026:1912:
1018:1911:
1010:1910:
1002:1909:
994:1908:
986:1907:
978:1906:
970:1905:
962:1904:
954:1903:
946:1902:
938:1901:
723:"NNDB"
568:
527:
483:
462:Nature
406:
329:
117:(2005)
111:Awards
85:French
2530:2005
2385:Peace
2319:2005
404:S2CID
296:Tours
290:Death
196:Menen
74:Tours
55:Menen
2555:2010
2550:2009
2545:2008
2540:2007
2535:2006
2525:2004
2520:2003
2515:2002
2510:2001
2505:2000
2389:2005
2365:2005
1304:1942
1297:1941
1290:1940
1223:1933
1124:1924
1085:1919
1070:1917
1063:1916
772:2015
751:2015
730:2015
709:2015
683:2015
661:2008
594:2015
566:PMID
525:PMID
481:PMID
327:PMID
282:and
273:and
230:and
190:Life
182:and
63:Died
41:Born
556:doi
515:doi
471:doi
467:519
426:doi
396:doi
374:doi
370:141
357:265
344:258
319:doi
210:in
2572::
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2259:/
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2231:/
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2203:/
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2119:/
2107:/
2087:/
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2023:/
2019:/
2007:/
2003:/
1991:/
1979:/
1975:/
1963:/
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1936:/
1932:/
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1030:/
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376::
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