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configuration and is kinetically inert. For this reason the formation of is initiated by installing TAME on a platinum(II) precursor. The resulting square planar complex is oxidized with to produce the target Pt(IV) derivatives.
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coordinates facially to metal ions. This stereochemical feature has been exploited in the preparation of platinum(IV) cage complexes, e.g., , which is a six coordinate Pt(IV) complex. Platinum in its +4 oxidation state has a
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K. N. Brown; D. C. R. Hockless; A. M. Sargeson (1999). "Synthesis and
Electrochemistry of : Crystallographic Analysis of Bis Platinum(II) Bis(tetrachlorozincate) Dihydrate".
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L. J. Zompa and J.-P. Anselme, "Catalytic
Reduction of 1,1,1 tris(azidomethyl)ethane to 1,1,1 tris(Aminomethyl)ethane" Org. Prep. Proced. lnt, 6, 103 (1974).
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TAME is synthesized by the Pd/C-catalyzed hydrogenation of 1,1,1-tris(azidomethyl)ethane. Although
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are potentially explosive, they are excellent and practical source of
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Except where otherwise noted, data are given for materials in their
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420:. The required tris(azidomethyl)ethane is obtained from the tri
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393:. It is a colorless liquid. It is classified as a
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217:InChI=1S/C5H15N3/c1-5(2-6,3-7)4-8/h2-4,6-8H2,1H3
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227:InChI=1/C5H15N3/c1-5(2-6,3-7)4-8/h2-4,6-8H2,1H3
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341:128.6 °C (263.5 °F; 401.8 K)
326:264.0 °C (507.2 °F; 537.1 K)
41:2-(Aminomethyl)-2-methylpropane-1,3-diamine
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220:Key: UGDSCHVVUPHIFM-UHFFFAOYSA-N
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230:Key: UGDSCHVVUPHIFM-UHFFFAOYAE
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351:(at 25 °C , 100 kPa).
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17:1,1,1-Tris(aminomethyl)ethane
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367:1,1,1-Tris(aminomethyl)ethane
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432:. These two steps are:
298:117.20
37:Preferred IUPAC name
377:with the formula CH
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519:The tripodal TAME
355:Infobox references
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515:Complexes of TAME
363:Chemical compound
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306:Colorless liquid
173:CompTox Dashboard
97:Interactive image
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595:Tripodal ligands
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569:10.1039/A901725I
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402:chelating ligand
375:organic compound
267:Chemical formula
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563:: 2171-2176.
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430:sodium azide
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251:CC(CN)(CN)CN
56:Identifiers
48:Other names
408:Preparation
337:Flash point
303:Appearance
260:Properties
135:100.149.897
590:Polyamines
584:Categories
533:References
468:+ 3 NaOTs
294:Molar mass
108:ChemSpider
84:3D model (
73:15995-42-3
63:CAS Number
395:polyamine
316:1.0 g/cm
422:tosylate
373:) is an
331:Hazards
312:Density
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161:4526530
148:PubChem
117:3721461
521:ligand
507:+ 3 N
491:→ CH
452:→ CH
428:using
414:azides
244:SMILES
31:Names
475:+ CH
440:+ CH
436:3 NaN
209:InChI
86:JSmol
495:C(CH
479:C(CH
456:C(CH
448:OTs)
444:C(CH
381:C(CH
371:TAME
276:C(CH
50:TAME
565:doi
561:105
471:3 H
424:by
178:EPA
151:CID
586::
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499:NH
385:NH
280:NH
272:CH
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485:3
483:N
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460:N
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Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
ethane.svg)
