91:
33:
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425:, being bound to six oxygen ligands, including a triply bridging oxide at the center of the equilateral triangle. The compound was an early example of a molecular complex of iron that features an oxide ligand. The cation has idealized D
448:. Many different salts are known by exchanging the anion, e.g. Cl. Reduction of the cation affords the neutral mixed-valence derivative that contains one ferrous and two ferric centers. Mixed metal species are known such as .
771:
Blake, Antony B.; Yavari, Ahmad; Hatfield, William E.; Sethulekshmi, C. N. (1985). "Magnetic and spectroscopic properties of some heterotrinuclear basic acetates of chromium(III), iron(III), and divalent metal ions".
456:
Chromium(III), ruthenium(III), vanadium(III), manganese(III) and rhodium(III) form analogous compounds. Iron(III) acetate (lacking the oxo ligand) has been claimed as a red coloured compound from the reaction of
418:
Basic iron acetate forms on treating aqueous solutions of iron(III) sources with acetate salts. A typical precursor is freshly precipitated iron oxide/hydroxide, which is halide-free.
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406:). Commonly the salt is known as "basic iron acetate". The formation of the red-brown complex was once used as a test for
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Materials prepared by heating iron, acetic acid, and air, loosely described as basic iron acetates, are used as
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Figgis, B. N.; Robertson, G. B. (13 February 1965). "Crystal-Molecular
Structure and Magnetic Properties of Cr
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90:
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The terminal aqua ligands on the trimetallic framework can be substituted with other ligands, such as
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799:, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter,
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Early work showed that the cation is trinuclear. The Fe centres are equivalent, each being
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819:
Paul, Ram C.; Narula, Ramesh C.; Vasisht, Sham K. (December 1978). "Iron(III) acetates".
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coordination complex: O1(C)O6(23)()(O(C)O4)O(C)O24()(O(C)O5)O(C)O135()OC(C)O6
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Iron acetate is often brushed upon untreated wood to give it an aged appearance.
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Holleman, Arnold
Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.),
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J., Burgess; M. V., Twigg (2005). R. Bruce, King; J., Wiley (eds.).
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Except where otherwise noted, data are given for materials in their
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This paper describes the isostructure chromium and iron compounds.
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160:
882:
665:
H. Lux (1963). "Basic Iron(III) Acetate". In Georg Brauer (ed.).
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201:
81:
115:
basic iron(III) acetate, iron(III) oxyacetate, iron(III) Acetate
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150:
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682:"Über Salze einer Hexaacetato(formiato)-trichrombase. II"
257:
InChI=1/3C2H4O2.Fe/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
774:
Journal of the
Chemical Society, Dalton Transactions
679:
625:. London; New York: Longmans, Green. Archived from
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213:
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136:
46:Is iron (III) acetate actually soluble or not?.
794:
686:Berichte der Deutschen Chemischen Gesellschaft
866:
680:Weinland, R.; Dinkelacker, P. (July 1909).
667:Handbook of Preparative Inorganic Chemistry
42:needs attention from an expert in Chemicals
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14:
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57:may be able to help recruit an expert.
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622:The Analysis of Steel-Works Materials
536:CRC Handbook of Chemistry and Physics
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532:
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26:
619:H., Brearley; F., Ibbotson (1902).
596:Encyclopedia of inorganic chemistry
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260:Key: PVFSDGKDKFSOTB-DFZHHIFOAZ
204:
24:
639:
25:
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598:(2nd ed.). New York: Wiley.
539:(87th ed.). Boca Raton, FL:
881:Acetyl halides and salts of the
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376:(at 25 °C , 100 kPa).
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533:Lide, David R., ed. (2006).
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644:. Read Books. p. 474.
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394:is the acetate salt of the
167:coordination complex:
44:. The specific problem is:
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333:650.9 g/mol
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698:10.1002/cber.19090420318
640:W., Simon (March 2007).
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414:Structure and synthesis
509:Manganese(III) acetate
514:Chromium(III) acetate
281:CC(=O).CC(=O).CC(=O).
55:WikiProject Chemicals
782:10.1039/DT9850002509
396:coordination complex
341:brownish-red powder
1780:Iron(III) compounds
797:Inorganic Chemistry
741:1965Natur.205..694F
642:Manual of Chemistry
565:"Iron(III) Acetate"
504:Rhodium(II) acetate
348:Solubility in water
76:
833:10.1007/BF01393501
499:Cobalt(II) acetate
463:iron(III) chloride
380:Infobox references
75:Iron(III) acetate
74:
18:Basic iron acetate
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776:(12): 2509–2520.
735:(4972): 694–695.
629:on 18 April 2015.
605:978-0-470-86078-6
543:. pp. 4–63.
452:Related compounds
446:dimethylformamide
388:Chemical compound
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170:Interactive image
162:Interactive image
107:iron(III) acetate
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16:(Redirected from
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494:Iron(II) acetate
302:Chemical formula
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627:the original
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572:. Retrieved
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121:Identifiers
113:Other names
60:
52:for details.
45:
41:
363:soluble in
338:Appearance
295:Properties
63:August 2024
1769:Categories
520:References
423:octahedral
398:(OAc is CH
359:Solubility
353:Insoluble
329:Molar mass
235:CZZ8832SI5
181:ChemSpider
149:3D model (
128:CAS Number
104:IUPAC name
541:CRC Press
436:Reactions
138:1834-30-6
50:talk page
1775:Acetates
998:NaH(OAc)
841:94447648
574:18 April
488:See also
479:mordants
442:pyridine
430:symmetry
48:See the
1701:Th(OAc)
1693:Ac(OAc)
1680:Yb(OAc)
1672:Tm(OAc)
1664:Er(OAc)
1656:Ho(OAc)
1648:Dy(OAc)
1640:Tb(OAc)
1632:Gd(OAc)
1624:Eu(OAc)
1616:Sm(OAc)
1605:Nd(OAc)
1597:Pr(OAc)
1589:Ce(OAc)
1581:La(OAc)
1572:
1493:Bi(OAc)
1485:Pb(OAc)
1478:Pb(OAc)
1470:Tl(OAc)
1458:Hg(OAc)
1439:Au(OAc)
1431:Pt(OAc)
1405:Lu(OAc)
1394:Ba(OAc)
1357:Sb(OAc)
1349:Sn(OAc)
1342:Sn(OAc)
1334:In(OAc)
1326:Cd(OAc)
1313:Pd(OAc)
1293:Ru(OAc)
1270:Mo(OAc)
1259:Zr(OAc)
1241:Sr(OAc)
1211:As(OAc)
1200:Ga(OAc)
1192:Zn(OAc)
1184:Cu(OAc)
1172:Ni(OAc)
1164:Co(OAc)
1156:Fe(OAc)
1149:Fe(OAc)
1141:Mn(OAc)
1134:Mn(OAc)
1126:Cr(OAc)
1119:Cr(OAc)
1111:VO(OAc)
1103:Ti(OAc)
1095:Sc(OAc)
1085:Ca(OAc)
1025:Al(OAc)
1014:Al(OAc)
1006:Mg(OAc)
919:Be(OAc)
883:acetate
757:4283321
737:Bibcode
569:EndMemo
365:ethanol
323:
202:PubChem
1376:I(OAc)
1251:Y(OAc)
1033:Al(OH)
949:O(OAc)
938:B(OAc)
930:O(OAc)
839:
803:
755:
729:Nature
723:OCl.5H
648:
602:
547:
410:ions.
408:ferric
274:SMILES
215:164887
190:144555
98:Names
1716:(OAc)
1466:TlOAc
1451:(OAc)
1389:CsOAc
1321:AgOAc
1305:(OAc)
1285:(OAc)
1236:RbOAc
1226:BrOAc
1180:CuOAc
1070:ClOAc
1049:(OAc)
1021:ALSOL
994:NaOAc
975:AcOOH
957:AcOAc
914:LiOAc
837:S2CID
753:S2CID
249:InChI
151:JSmol
1372:IOAc
1222:BrAc
1080:KOAc
1066:ClAc
984:FOAc
961:ROAc
898:AcOH
801:ISBN
727:O".
719:COO)
646:ISBN
600:ISBN
576:2015
545:ISBN
477:and
475:dyes
469:Uses
461:and
444:and
226:UNII
1750:No
1747:Md
1744:Fm
1741:Es
1738:Cf
1735:Bk
1732:Cm
1729:Am
1726:Pu
1723:Np
1708:Pa
1689:**
1612:Pm
1565:Og
1562:Ts
1559:Lv
1556:Mc
1553:Fl
1550:Nh
1547:Cn
1544:Rg
1541:Ds
1538:Mt
1535:Hs
1532:Bh
1529:Sg
1526:Db
1523:Rf
1520:Lr
1517:**
1514:Ra
1511:Fr
1506:Rn
1503:At
1500:Po
1427:Ir
1424:Os
1421:Re
1415:Ta
1412:Hf
1383:Xe
1368:IAc
1364:Te
1277:Tc
1266:Nb
1230:Kr
1218:Se
1207:Ge
1074:Ar
1056:Si
1037:OAc
988:Ne
980:FAc
970:OAc
908:He
885:ion
829:doi
778:doi
745:doi
733:205
715:(CH
694:doi
205:CID
1771::
1712:UO
1577:*
1447:Hg
1418:W
1401:*
1301:Rh
1289:Cl
1281:Ru
1062:S
1059:P
1045:SO
1041:Al
1029:OH
966:NH
926:Be
835:.
823:.
751:.
743:.
731:.
690:42
688:.
684:.
584:^
567:.
481:.
465:.
432:.
427:3h
402:CO
321:18
315:Fe
313:27
309:14
1718:2
1714:2
1703:4
1695:3
1682:3
1674:3
1666:3
1658:3
1650:3
1642:3
1634:3
1626:3
1618:3
1607:3
1599:3
1591:3
1583:3
1495:3
1487:4
1480:2
1472:3
1460:2
1453:2
1449:2
1441:3
1433:2
1407:3
1396:2
1378:3
1359:3
1351:4
1344:2
1336:3
1328:2
1315:2
1307:4
1303:2
1295:3
1287:4
1283:2
1272:2
1261:4
1253:3
1243:2
1213:3
1202:3
1194:2
1186:2
1174:2
1166:2
1158:3
1151:2
1143:3
1136:2
1128:3
1121:2
1113:3
1105:4
1097:3
1087:2
1051:4
1047:4
1043:2
1035:2
1027:2
1016:3
1008:2
1000:2
968:4
951:4
947:2
945:B
940:3
932:6
928:4
921:2
874:e
867:t
860:v
843:.
831::
825:3
784:.
780::
759:.
747::
739::
725:2
721:6
717:3
713:3
700:.
696::
654:.
608:.
578:.
553:.
404:2
400:3
319:O
317:3
311:H
307:C
153:)
65:)
61:(
20:)
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