299:
291:
31:
621:
and four formula units per unit cell. At 30 GPa the unit cell has a=4.736 b=8.175 c=7.140 Å and β=91.34°. The unit cell volume is 276.3 Å and density 4.61. The double Sr=O bonds have lengths of 1.22, 1.24, and 1.25 Å. The single Sr-O bonds have lengths of 1.36 and 1.41 Å. The angles
784:
Spahr, Dominik; König, Jannes; Bayarjargal, Lkhamsuren; Luchitskaia, Rita; Milman, Victor; Perlov, Alexander; Liermann, Hanns-Peter; Winkler, Björn (22 June 2022). "Synthesis and
Structure of Pb: An Inorganic Pyrocarbonate Salt".
828:
Spahr, Dominik; König, Jannes; Bayarjargal, Lkhamsuren; Milman, Victor; Perlov, Alexander; Liermann, Hanns-Peter; Winkler, Björn (23 February 2022). "Sr is an
Inorganic Pyrocarbonate Salt with 2– Complex Anions".
706:
754:
Zeller, Klaus-Peter; Schuler, Paul; Haiss, Peter (2005). "The hidden equilibrium in aqueous sodium carbonate solutions: Evidence for the formation of the dicarbonate anion".
1297:
1314:
596:
and four formula units per unit cell. At 30 GPa the unit cell has a=4.771 b=8.079 c=7.070 Å and β=91.32°. The unit cell volume is 272.4 Å and density 7.59.
510:. Dicarbonate salts are apparently unstable at ambient conditions, but can be made under pressure and may have a fleeting existence in carbonate solutions.
208:
696:
Plácido García; Helge
Willner; Maximiliano Burgos Paci; Gustavo A. Argüello; Thorsten Berends (2005). "Bis(trifluoromethyl)dicarbonate, CF
1183:
890:
1225:
1211:
101:
475:
1177:
183:
1353:
1197:
349:
278:
609:(strontium dicarbonate) is very similar to the lead compound, and also has monoclinic structure with space group
1267:
883:
118:
298:
537:. It is also sometimes used for chemicals that contain two carbonate units in their covalent structure or
152:
1398:
1239:
1393:
876:
695:
441:
169:
112:
622:
subtended at the carbon atoms are slightly less than 120°, and the angle at the C-O-C is larger.
732:
353:
1403:
43:
77:
1078:
387:
8:
1148:
1134:
1120:
1092:
410:
319:
67:
1388:
1253:
1106:
1064:
1039:
1033:
1029:
854:
810:
1367:
1173:
979:
858:
846:
814:
802:
636:
140:
1004:
959:
949:
838:
794:
763:
718:
714:
380:
337:
231:
798:
1050:
969:
939:
913:
651:
483:
1333:
1292:
990:
918:
571:
564:
272:
1382:
1338:
676:
671:
666:
538:
1361:
1309:
850:
806:
767:
631:
1343:
842:
661:
646:
582:
518:
17:
656:
578:
290:
257:
1348:
899:
341:
271:
Except where otherwise noted, data are given for materials in their
30:
315:
100:
641:
127:
783:
753:
487:
345:
868:
90:
157:
827:
560:
302:
Molecular structure of bis(trifluoromethyl) dicarbonate
533:
or esters of the hydrogencarbonate functional group
192:InChI=1S/C2H2O5/c3-1(4)7-2(5)6/h(H,3,4)(H,5,6)/p-2
521:, the common name of the hydrogencarbonate anion
1380:
559:(lead(II) dicarbonate) can be formed at 30
139:
76:
884:
294:The general structure of dicarbonate esters
891:
877:
517:is sometimes used erroneously to refer to
831:Journal of the American Chemical Society
297:
289:
779:
777:
168:
117:
1381:
872:
195:Key: ZFTFAPZRGNKQPU-UHFFFAOYSA-L
774:
1178:Ethylenetetracarboxylic dianhydride
352:. These compounds can be viewed as
130:
13:
544:
486:, consisting solely of oxygen and
14:
1415:
29:
733:"CHEBI:48501 - dicarbonic acid"
350:polycarbonate functional groups
275:(at 25 °C , 100 kPa).
898:
821:
747:
725:
719:10.1016/j.jfluchem.2005.05.002
689:
1:
1327:Compounds derived from oxides
799:10.1021/acs.inorgchem.2c01507
682:
356:of the hypothetical compound
490:. The anion has the formula
7:
625:
383:containing this group are:
10:
1420:
15:
1326:
1285:
932:
906:
269:
224:
204:
179:
60:
52:
42:
37:
28:
340:, which consists of two
16:Not to be confused with
768:10.1002/ejic.200400445
539:stoichiometric formula
303:
295:
301:
293:
843:10.1021/jacs.2c00351
388:dimethyl dicarbonate
787:Inorganic Chemistry
756:Eur. J. Inorg. Chem
411:diethyl dicarbonate
362:HO−C(=O)−O−C(=O)−OH
348:atom. It is one of
323:−O−C(=O)−O−C(=O)−O−
265: g·mol
25:
1368:Peroxydicarbonates
1034:1,3-Dioxetanedione
1030:1,2-Dioxetanedione
446:-butyl dicarbonate
379:. Three important
344:groups sharing an
310:, also known as a
304:
296:
279:Infobox references
23:
1399:Functional groups
1376:
1375:
1174:Cyclohexanehexone
793:(26): 9855–9859.
707:J. Fluorine Chem.
637:Peroxodicarbonate
577:. It forms white
492:O−C(=O)−O−C(=O)−O
482:It is one of the
381:organic compounds
287:Chemical compound
285:
284:
153:CompTox Dashboard
102:Interactive image
1411:
1394:Carbonate esters
1277:
1263:
1249:
1235:
1221:
1207:
1193:
1171:
1158:
1144:
1130:
1116:
1102:
1088:
1074:
1060:
1046:
1027:
1014:
1000:
986:
975:
965:
955:
945:
924:
893:
886:
879:
870:
869:
863:
862:
837:(7): 2899–2904.
825:
819:
818:
781:
772:
771:
751:
745:
744:
742:
740:
729:
723:
722:
693:
608:
558:
536:
532:
531:
530:
527:
509:
508:
507:
504:
493:
484:oxocarbon anions
474:, also known as
473:
438:
407:
378:
363:
338:functional group
336:
324:
264:
251:
250:
249:
246:
232:Chemical formula
172:
161:
159:
143:
132:
121:
104:
80:
33:
26:
24:Dicarbonate ion
22:
1419:
1418:
1414:
1413:
1412:
1410:
1409:
1408:
1379:
1378:
1377:
1372:
1334:Metal carbonyls
1322:
1318:
1305:
1301:
1281:
1276:
1272:
1268:
1262:
1258:
1254:
1248:
1244:
1240:
1234:
1230:
1226:
1220:
1216:
1212:
1206:
1202:
1198:
1192:
1188:
1184:
1170:
1166:
1162:
1157:
1153:
1149:
1143:
1139:
1135:
1129:
1125:
1121:
1115:
1111:
1107:
1101:
1097:
1093:
1087:
1083:
1079:
1073:
1069:
1065:
1059:
1055:
1051:
1044:
1040:
1026:
1022:
1018:
1013:
1009:
1005:
999:
995:
991:
984:
980:
974:
970:
964:
960:
954:
950:
944:
940:
928:
923:
919:
902:
897:
867:
866:
826:
822:
782:
775:
752:
748:
738:
736:
731:
730:
726:
703:
699:
694:
690:
685:
652:Peroxydisulfate
628:
616:
607:
603:
599:
591:
581:crystals, with
575:
568:
563:and 2000K from
557:
553:
549:
547:
545:Inorganic salts
534:
528:
525:
524:
522:
505:
502:
501:
499:
495:
491:
472:
468:
464:
460:
456:
452:
448:
437:
433:
429:
425:
421:
417:
413:
406:
402:
398:
394:
390:
377:
373:
369:
365:
361:
358:dicarbonic acid
334:
330:
326:
322:
318:containing the
288:
281:
276:
262:
247:
244:
243:
241:
237:
234:
220:
217:
212:
211:
200:
197:
196:
193:
187:
186:
175:
162:
155:
146:
133:
107:
94:
83:
70:
56:
48:
21:
12:
11:
5:
1417:
1407:
1406:
1401:
1396:
1391:
1374:
1373:
1371:
1370:
1365:
1354:Polycarbonates
1351:
1346:
1341:
1336:
1330:
1328:
1324:
1323:
1321:
1320:
1316:
1312:
1307:
1303:
1299:
1295:
1293:Graphite oxide
1289:
1287:
1283:
1282:
1280:
1279:
1274:
1270:
1265:
1260:
1256:
1251:
1246:
1242:
1237:
1232:
1228:
1223:
1218:
1214:
1209:
1204:
1200:
1195:
1190:
1186:
1181:
1168:
1164:
1160:
1155:
1151:
1146:
1141:
1137:
1132:
1127:
1123:
1118:
1113:
1109:
1104:
1099:
1095:
1090:
1085:
1081:
1076:
1071:
1067:
1062:
1057:
1053:
1048:
1042:
1037:
1024:
1020:
1016:
1011:
1007:
1002:
997:
993:
988:
982:
977:
972:
967:
962:
957:
952:
947:
942:
936:
934:
930:
929:
927:
926:
921:
916:
910:
908:
904:
903:
896:
895:
888:
881:
873:
865:
864:
820:
773:
762:(1): 168–172.
746:
724:
713:(6): 984–990.
701:
697:
687:
686:
684:
681:
680:
679:
674:
669:
664:
659:
654:
649:
644:
639:
634:
627:
624:
614:
605:
601:
589:
573:
566:
555:
551:
546:
543:
497:
480:
479:
470:
466:
462:
458:
454:
450:
439:
435:
431:
427:
423:
419:
415:
408:
404:
400:
396:
392:
375:
371:
367:
332:
328:
286:
283:
282:
277:
273:standard state
270:
267:
266:
260:
254:
253:
239:
235:
230:
227:
226:
222:
221:
219:
218:
215:
207:
206:
205:
202:
201:
199:
198:
194:
191:
190:
182:
181:
180:
177:
176:
174:
173:
170:DTXSID30570367
165:
163:
151:
148:
147:
145:
144:
136:
134:
126:
123:
122:
115:
109:
108:
106:
105:
97:
95:
88:
85:
84:
82:
81:
73:
71:
66:
63:
62:
58:
57:
54:
50:
49:
46:
40:
39:
35:
34:
9:
6:
4:
3:
2:
1416:
1405:
1402:
1400:
1397:
1395:
1392:
1390:
1387:
1386:
1384:
1369:
1366:
1363:
1362:Tricarbonates
1359:
1355:
1352:
1350:
1347:
1345:
1342:
1340:
1339:Carbonic acid
1337:
1335:
1332:
1331:
1329:
1325:
1319:
1313:
1311:
1308:
1306:
1296:
1294:
1291:
1290:
1288:
1284:
1278:
1266:
1264:
1252:
1250:
1238:
1236:
1224:
1222:
1210:
1208:
1196:
1194:
1182:
1179:
1175:
1161:
1159:
1147:
1145:
1133:
1131:
1119:
1117:
1105:
1103:
1091:
1089:
1077:
1075:
1063:
1061:
1049:
1047:
1038:
1035:
1031:
1017:
1015:
1003:
1001:
989:
987:
978:
976:
968:
966:
958:
956:
948:
946:
938:
937:
935:
933:Exotic oxides
931:
925:
917:
915:
912:
911:
909:
907:Common oxides
905:
901:
894:
889:
887:
882:
880:
875:
874:
871:
860:
856:
852:
848:
844:
840:
836:
832:
824:
816:
812:
808:
804:
800:
796:
792:
788:
780:
778:
769:
765:
761:
757:
750:
734:
728:
720:
716:
712:
709:
708:
700:OC(O)OC(O)OCF
692:
688:
678:
677:Polyphosphate
675:
673:
672:Pyrophosphate
670:
668:
667:Tetrathionate
665:
663:
660:
658:
655:
653:
650:
648:
645:
643:
640:
638:
635:
633:
630:
629:
623:
620:
612:
597:
595:
587:
584:
580:
576:
569:
562:
542:
540:
520:
516:
511:
489:
485:
477:
447:
445:
440:
412:
409:
389:
386:
385:
384:
382:
359:
355:
351:
347:
343:
339:
321:
317:
313:
312:pyrocarbonate
309:
300:
292:
280:
274:
268:
261:
259:
256:
255:
236:
233:
229:
228:
223:
216:C(=O)()OC(=O)
214:
213:
210:
203:
189:
188:
185:
178:
171:
167:
166:
164:
154:
150:
149:
142:
138:
137:
135:
129:
125:
124:
120:
119:pyrocarbonate
116:
114:
111:
110:
103:
99:
98:
96:
92:
87:
86:
79:
75:
74:
72:
69:
65:
64:
59:
55:Pyrocarbonate
51:
45:
41:
36:
32:
27:
19:
1404:Dicarbonates
1358:Dicarbonates
1357:
1344:Bicarbonates
834:
830:
823:
790:
786:
759:
755:
749:
737:. Retrieved
727:
710:
705:
691:
632:Tricarbonate
618:
610:
598:
593:
585:
548:
514:
512:
481:
443:
357:
311:
307:
305:
61:Identifiers
53:Other names
662:Trithionate
647:Pyrosulfate
583:space group
535:−O−C(=O)−OH
519:bicarbonate
515:dicarbonate
354:derivatives
308:dicarbonate
225:Properties
78:214335-04-3
47:Dicarbonate
18:Bicarbonate
1383:Categories
1349:Carbonates
900:Oxocarbons
683:References
657:Dithionate
579:monoclinic
478:anhydride.
258:Molar mass
89:3D model (
68:CAS Number
44:IUPAC name
1389:Oxyanions
859:246678040
815:249922854
513:The term
342:carbonate
1286:Polymers
851:35134291
807:35730801
626:See also
320:divalent
316:chemical
141:15238643
739:30 June
735:. ChEBI
642:Oxalate
314:, is a
263:104.017
252:
128:PubChem
857:
849:
813:
805:
488:carbon
465:−C(−CH
346:oxygen
209:SMILES
38:Names
855:S2CID
811:S2CID
184:InChI
91:JSmol
1360:and
1176:and
1032:and
847:PMID
803:PMID
760:2005
741:2024
570:and
565:PbCO
444:tert
113:MeSH
839:doi
835:144
795:doi
764:doi
715:doi
711:126
704:".
600:SrC
561:GPa
550:PbC
523:HCO
494:or
476:Boc
457:C−C
453:C−)
442:di-
403:−CH
395:C−C
364:or
325:or
158:EPA
131:CID
1385::
1315:CO
1310:CO
1275:12
1271:12
1257:12
1243:12
1233:10
1229:10
1215:10
971:CO
961:CO
951:CO
941:CO
920:CO
914:CO
853:.
845:.
833:.
809:.
801:.
791:61
789:.
776:^
758:.
572:CO
541:.
503:2−
449:(H
430:−C
422:−C
360:,
327:−C
306:A
245:2−
1364:)
1356:(
1317:2
1304:2
1302:O
1300:3
1298:C
1273:O
1269:C
1261:9
1259:O
1255:C
1247:6
1245:O
1241:C
1231:O
1227:C
1219:8
1217:O
1213:C
1205:9
1203:O
1201:9
1199:C
1191:8
1189:O
1187:8
1185:C
1180:)
1172:(
1169:6
1167:O
1165:6
1163:C
1156:5
1154:O
1152:5
1150:C
1142:2
1140:O
1138:5
1136:C
1128:6
1126:O
1124:4
1122:C
1114:4
1112:O
1110:4
1108:C
1100:2
1098:O
1096:4
1094:C
1086:6
1084:O
1082:3
1080:C
1072:3
1070:O
1068:3
1066:C
1058:2
1056:O
1054:3
1052:C
1045:O
1043:3
1041:C
1036:)
1028:(
1025:4
1023:O
1021:2
1019:C
1012:3
1010:O
1008:2
1006:C
998:2
996:O
994:2
992:C
985:O
983:2
981:C
973:6
963:5
953:4
943:3
922:2
892:e
885:t
878:v
861:.
841::
817:.
797::
770:.
766::
743:.
721:.
717::
702:3
698:3
619:c
617:/
615:1
613:2
611:P
606:5
604:O
602:2
594:c
592:/
590:1
588:2
586:P
574:2
567:3
556:5
554:O
552:2
529:3
526:−
506:5
500:O
498:2
496:C
471:3
469:)
467:3
463:5
461:O
459:2
455:3
451:3
436:5
434:H
432:2
428:5
426:O
424:2
420:5
418:H
416:2
414:C
405:3
401:5
399:O
397:2
393:3
391:H
376:5
374:O
372:2
370:C
368:2
366:H
335:−
333:5
331:O
329:2
248:5
242:O
240:2
238:C
160:)
156:(
93:)
20:.
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
-dicarbonate-from-xtal-2005-3D-balls.png)