1096:
1899:
1793:. Herbert G. McPherson, a Berkeley trained physicist at National Carbon, a division of Union Carbide, was key in confirming a conjecture of Leo Szilard that boron impurities even in "pure" graphite were responsible for a neutron absorption cross-section in graphite that compromised U-235 chain reactions. McPherson was aware of the presence of impurities in graphite because, with the use of Technicolor in cinematography, the spectra of graphite electrode arcs used in movie projectors required impurities to enhance emission of light in the red region to display warmer skin tones on the screen. Thus, had it not been for color movies, chances are that the first sustained natural U chain reaction would have required a heavy water moderated reactor.
2150:
1923:
1112:
out. In an 1877 patent, the two brothers Bessel (Adolph and August) of
Dresden, Germany, took this "floating" process a step further and added a small amount of oil to the tanks and boiled the mix – an agitation or frothing step – to collect the graphite, the first steps toward the future flotation process. Adolph Bessel received the Wohler Medal for the patented process that upgraded the recovery of graphite to 90% from the German deposit. In 1977, the German Society of Mining Engineers and Metallurgists organized a special symposium dedicated to their discovery and, thus, the 100th anniversary of flotation.
2386:
1132:
2158:
777:
789:
801:
762:
755:), differing in terms of the stacking of the graphene layers: stacking in alpha graphite is ABA, as opposed to ABC stacking in the energetically less stable beta graphite. Rhombohedral graphite cannot occur in pure form. Natural graphite, or commercial natural graphite, contains 5 to 15% rhombohedral graphite and this may be due to intensive milling. The alpha form can be converted to the beta form through shear forces, and the beta form reverts to the alpha form when it is heated to 1300 °C for four hours.
820:
1014:
45:
5337:
1420:
1575:
883:
1915:
2045:: No inhalation hazard in manufactured and shipped state. Dust and fumes generated from the material can enter the body by inhalation. High concentrations of dust and fumes may irritate the throat and respiratory system and cause coughing. Frequent inhalation of fume/dust over a long period of time increases the risk of developing lung diseases. Prolonged and repeated overexposure to dust can lead to
2588:
1080:, a major factor in the expansion of educational tools during the first great rise of education for the masses. The British Empire controlled most of the world's production (especially from Ceylon), but production from Austrian, German, and American deposits expanded by mid-century. For example, the Dixon Crucible Company of Jersey City, New Jersey, founded by
1954:
from the different fractions, each with a certain flake size distribution and carbon content. Custom blends can also be made for individual customers who want a certain flake size distribution and carbon content. If flake size is unimportant, the concentrate can be ground more freely. Typical end products include a fine powder for use as a slurry in
1478:
produces a clean, professional look. It is also relatively inexpensive and widely available. Many artists use graphite in conjunction with other media, such as charcoal or ink, to create a range of effects and textures in their work. Graphite of various hardness or softness results in different qualities and tones when used as an
2129:
lime-rich slag, and some iron. The iron is recycled on-site, leaving a mixture of graphite and slag. The best recovery process uses hydraulic classification (which utilizes a flow of water to separate minerals by specific gravity: graphite is light and settles nearly last) to get a 70% graphite rough concentrate.
2305:, unlike in well-explored areas, where they will have strong technology accumulation and large patent portfolios. The innovation focus of these three emerging areas is highly scattered and can be diverse, even for a single applicant. However, recent inventions are seen to leverage the development of graphite
1345:
Graphite is 'predominant anode material used today in lithium-ion batteries'. EV batteries contain four basic components: anode, cathode, electrolyte, and separator. While there is much focus on the cathode materials – lithium, nickel, cobalt, manganese, etc. – the predominant anode material used in
1259:
and some plants had their equipment auctioned off. Since much of the lost capacity was for carbon-magnesite brick, graphite consumption within the refractories area moved towards alumina-graphite shapes and
Monolithics, and away from the brick. The major source of carbon-magnesite brick is now China.
2128:
A high-quality flake graphite product that closely resembles natural flake graphite can be made from steelmaking kish. Kish is a large-volume near-molten waste skimmed from the molten iron feed to a basic oxygen furnace and consists of a mix of graphite (precipitated out of the supersaturated iron),
2117:
are sometimes also recycled, but often are not due to their low graphite content: the largest-volume items, such as carbon-magnesite bricks that contain only 15–25% graphite, usually contain too little graphite to be worthwhile to recycle. However, some recycled carbon–magnesite brick is used as the
2109:
The most common way of recycling graphite occurs when synthetic graphite electrodes are either manufactured and pieces are cut off or lathe turnings are discarded for reuse, or the electrode (or other materials) are used all the way down to the electrode holder. A new electrode replaces the old one,
1477:
In art, graphite is typically used to create detailed and precise drawings, as it allows for a wide range of values (light to dark) to be achieved. It can also be used to create softer, more subtle lines and shading. Graphite is popular among artists because it is easy to control, easy to erase, and
1400:
are specialty items for use at very high or very low temperatures, as forging die lubricant, an antiseize agent, a gear lubricant for mining machinery, and to lubricate locks. Having low-grit graphite, or even better, no-grit graphite (ultra high purity), is highly desirable. It can be used as a dry
536:
any impurities that may be present, including hydrogen, nitrogen, sulfur, organics, and metals. This is why synthetic graphite is highly pure in excess of 99.9% C purity, but typically has lower density, conductivity and a higher porosity than its natural equivalent. Synthetic graphite can also be
2227:
Global patenting activity relating to ultrasonic exfoliation has decreased over the years, indicating that this low-cost technique has become well established. Thermal exfoliation is a more recent process. Compared to ultrasonic exfoliation, this fast and solvent-free thermal approach has attracted
906:
propagate quickly along the tightly bound planes, but are slower to travel from one plane to another. Graphite's high thermal stability and electrical and thermal conductivity facilitate its widespread use as electrodes and refractories in high temperature material processing applications. However,
1942:. This makes the "marked" gangue particles float off with the graphite, yielding impure concentrate. There are two ways of obtaining a commercial concentrate or product: repeated regrinding and floating (up to seven times) to purify the concentrate, or by acid leaching (dissolving) the gangue with
1742:
above the temperature of graphitization, sometimes with minor modifications. The graphite scrap comes from pieces of unusable electrode material (in the manufacturing stage or after use) and lathe turnings, usually after crushing and sizing. Most synthetic graphite powder goes to carbon raising in
1111:
article on the Dixon
Crucible Company is a sketch of the "floating tanks" used in the age-old process of extracting graphite. Because graphite is so light, the mix of graphite and waste was sent through a final series of water tanks where a cleaner graphite "floated" off, which left waste to drop
1072:
material to line molds for cannonballs, resulting in rounder, smoother balls that could be fired farther, contributing to the strength of the
English navy. This particular deposit of graphite was extremely pure and soft, and could easily be cut into sticks. Because of its military importance, this
997:
of 70° approximately), and it becomes hydrophobic (contact angle of 95° approximately) due to airborne pollutants (hydrocarbons) present in the atmosphere. Those contaminants also alter the electric equipotential surface of graphite by creating domains with potential differences of up to 200 mV as
1953:
In milling, the incoming graphite products and concentrates can be ground before being classified (sized or screened), with the coarser flake size fractions (below 8 mesh, 8–20 mesh, 20–50 mesh) carefully preserved, and then the carbon contents are determined. Some standard blends can be prepared
1242:
Crucibles began using very large flake graphite, and carbon-magnesite bricks requiring not quite so large flake graphite; for these and others there is now much more flexibility in the size of flake required, and amorphous graphite is no longer restricted to low-end refractories. Alumina-graphite
2239:
applications. With over 8,000 patent families filed from 2012 to 2021, battery applications were a key driver of global graphite-related inventions. Innovations in this area are led by battery manufacturers or anode suppliers who have amassed sizable patent portfolios focused strongly on battery
2223:
layers within graphite, has been extensively studied between 2012 and 2021. Specifically, ultrasonic and thermal exfoliation have been the two most popular approaches worldwide, with 4,267 and 2,579 patent families, respectively, significantly more than for either the chemical or electrochemical
1559:
which keeps them cool while saving weight, and is made into a foil laminate that can be used in valve packings or made into gaskets. Old-style packings are now a minor member of this grouping: fine flake graphite in oils or greases for uses requiring heat resistance. A GAN estimate of current US
1550:
or in sheet metal collars surrounding plastic pipe (during a fire, the graphite expands and chars to resist fire penetration and spread), or to make high-performance gasket material for high-temperature use. After being made into graphite foil, the foil is machined and assembled into the bipolar
1115:
In the United States, in 1885, Hezekiah
Bradford of Philadelphia patented a similar process, but it is uncertain if his process was used successfully in the nearby graphite deposits of Chester County, Pennsylvania, a major producer by the 1890s. The Bessel process was limited in use, primarily
2207:
At the same time, innovations exploring new synthesis methods and uses for artificial graphite are gaining interest worldwide, as countries seek to exploit the superior material qualities associated with this man-made substance and reduce reliance on the natural material. Patenting activity is
3468:
Li, Zhiting; Wang, Yongjin; Kozbial, Andrew; Shenoy, Ganesh; Zhou, Feng; McGinley, Rebecca; Ireland, Patrick; Morganstein, Brittni; Kunkel, Alyssa; Surwade, Sumedh P.; Li, Lei; Liu, Haitao (October 2013). "Effect of airborne contaminants on the wettability of supported graphene and graphite".
1358:
mostly goes into raising the carbon content in molten steel; it can also serve to lubricate the dies used to extrude hot steel. Carbon additives face competitive pricing from alternatives such as synthetic graphite powder, petroleum coke, and other forms of carbon. A carbon raiser is added to
1703:(pitch). This is finally graphitized by heating it to temperatures approaching 3,000 °C (5,430 °F), at which the carbon atoms arrange into graphite. They can vary in size up to 3.5 m (11 ft) long and 75 cm (30 in) in diameter. An increasing proportion of global
1589:
with some metals and small molecules. In these compounds, the host molecule or atom gets "sandwiched" between the graphite layers, resulting in a type of compound with variable stoichiometry. A prominent example of an intercalation compound is potassium graphite, denoted by the formula
2251:
applications was an innovation hot topic from 2012 to 2021, with over 8,000 patent families recorded worldwide. However, in recent years, in the top countries of applicant origin in this area, including China, Japan and the United States of
America (US), patent filings have decreased.
1383:. This use has been important for quite some time, but nonasbestos organic (NAO) compositions are beginning to reduce graphite's market share. A brake-lining industry shake-out with some plant closures has not been beneficial, nor has an indifferent automotive market. According to the
4259:
Kato, Tomofumi; Yamada, Yasuhiro; Nishikawa, Yasushi; Otomo, Toshiya; Sato, Hayato; Sato, Satoshi (October 2021). "Origins of peaks of graphitic and pyrrolic nitrogen in N1s X-ray photoelectron spectra of carbon materials: quaternary nitrogen, tertiary amine, or secondary amine?".
1405:
graphite consumption statistics indicates that 2,200 tonnes were used in this fashion in 2005. Metal can also be impregnated into graphite to create a self-lubricating alloy for application in extreme conditions, such as bearings for machines exposed to high or low temperatures.
1938:. This may be carried out by hand-picking the pieces of gangue (rock) and hand-screening the product or by crushing the rock and floating out the graphite. Beneficiation by flotation encounters the difficulty that graphite is very soft and "marks" (coats) the particles of
1243:
shapes are used as continuous casting ware, such as nozzles and troughs, to convey the molten steel from ladle to mold, and carbon magnesite bricks line steel converters and electric-arc furnaces to withstand extreme temperatures. Graphite blocks are also used in parts of
3505:
3440:
Martinez-Martin, David; Longuinhos, Raphael; Izquierdo, Jesus G.; Marele, Antonela; Alexandre, Simone S.; Jaafar, Miriam; Gómez-Rodríguez, Jose M.; Bañares, Luis; Soler, Jose M.; Gomez-Herrero, Julio (September 2013). "Atmospheric contaminants on graphitic surfaces".
4418:
Arregui-Mena, José David; Edmondson, Philip D.; Margetts, Lee; Griffiths, D.V.; Windes, William E.; Carroll, Mark; Mummery, Paul M. (December 2018). "Characterisation of the spatial variability of material properties of
Gilsocarbon and NBG-18 using random fields".
1542:, which forces the crystal lattice planes apart, thus expanding the graphite. The expanded graphite can be used to make graphite foil or used directly as a "hot top" compound to insulate molten metal in a ladle or red-hot steel ingots and decrease heat loss, or as
1395:
A foundry-facing mold wash is a water-based paint of amorphous or fine flake graphite. Painting the inside of a mold with it and letting it dry leaves a fine graphite coat that will ease the separation of the object cast after the hot metal has cooled. Graphite
2610:
3051:
Latychevskaia, Tataiana; Son, Seok-Kyun; Yang, Yaping; Chancellor, Dale; Brown, Michael; Ozdemir, Servet; Madan, Ivan; Berruto, Gabriele; Carbone, Fabrizio; Mishchenko, Artem; Novoselov, Kostya (2019-08-17). "Stacking transition in rhombohedral graphite".
1247:
linings where the high thermal conductivity of the graphite is critical to ensuring adequate cooling of the bottom and hearth of the furnace. High-purity monolithics are often used as a continuous furnace lining instead of carbon-magnesite bricks.
936:). These valence electrons are free to move, so are able to conduct electricity. However, the electricity is primarily conducted within the plane of the layers. The conductive properties of powdered graphite allow its use as pressure sensor in
3224:
Hanaor, Dorian; Michelazzi, Marco; Chenu, Jeremy; Leonelli, Cristina; Sorrell, Charles C. (December 2011). "The effects of firing conditions on the properties of electrophoretically deposited titanium dioxide films on graphite substrates".
1609:, and it further increases under applied pressure (15.1 K at 8 GPa). Graphite's ability to intercalate lithium ions without significant damage from swelling is what makes it the dominant anode material in lithium-ion batteries.
1473:
Today, pencils are still a small but significant market for natural graphite. Around 7% of the 1.1 million tonnes produced in 2011 was used to make pencils. Low-quality amorphous graphite is used and sourced mainly from China.
2278:
represent a long-explored graphite application area. There have been few inventions in this area over the last decade, with less than 300 patent families filed from 2012 to 2021, very significantly less than between 1992 and 2011.
4231:
Kato, Tomofumi; Yamada, Yasuhiro; Nishikawa, Yasushi; Ishikawa, Hiroki; Sato, Satoshi (June 2021). "Carbonization mechanisms of polyimide: Methodology to analyze carbon materials with nitrogen, oxygen, pentagons, and heptagons".
986:, thus it will float in mid-air above a strong magnet. (If it is made in a fluidized bed at 1000–1300 °C then it is isotropic turbostratic, and is used in blood-contacting devices like mechanical heart valves and is called
3526:
1966:
industry (Synthetic graphite powder and powdered petroleum coke can also be used as carbon raiser). Environmental impacts from graphite mills consist of air pollution including fine particulate exposure of workers and also
1238:
brick became important, and a bit later the alumina-graphite shape. As of 2017 the order of importance is: alumina-graphite shapes, carbon-magnesite brick, Monolithics (gunning and ramming mixes), and then crucibles.
1630:(also called silicon carbide). He discovered that overheating carborundum, as opposed to pure carbon, produced almost pure graphite. While studying the effects of high temperature on carborundum, he had found that
2263:
accounted for over one-third of ceramics-related graphite patent families in China and about one-fifth in the rest of the world. Other important graphite applications include high-value ceramic materials such as
1095:
1088:
in 1845, opened mines in the Lake
Ticonderoga district of New York, built a processing plant there, and a factory to manufacture pencils, crucibles and other products in New Jersey, described in the
2293:
are emerging application areas for graphite that have attracted interest from both academia and commercial entities, including renowned universities and multinational corporations. Typically for an
537:
formed into very large flakes (cm) while maintaining its high purity unlike almost all sources of natural graphite. Synthetic graphite has also been known to be formed by other methods including by
1314:, and smartphone products have increased the demand for batteries. Electric-vehicle batteries are anticipated to increase graphite demand. As an example, a lithium-ion battery in a fully electric
4038:
2177:
was the top contributor with more than 47,000 patent families, accounting for four in every five graphite patent families filed worldwide in the last decade. Among other leading countries were
3139:
Bundy, P.; Bassett, W. A.; Weathers, M. S.; Hemley, R. J.; Mao, H. K.; Goncharov, A. F. (1996). "The pressure-temperature phase and transformation diagram for carbon; updated through 1994".
2204:
from its commercial entities and research institutions, China is the country most actively exploiting flake graphite and has contributed to 85 percent of global patent filings in this area.
831:
The equilibrium pressure and temperature conditions for a transition between graphite and diamond is well established theoretically and experimentally. The pressure changes linearly between
1839:
are strongly influenced by the role of graphite in these materials. In this context, the term "(100%) graphite" is often loosely used to refer to a pure mixture of carbon reinforcement and
4798:
736:, which allows the graphene-like layers to be easily separated and to glide past each other. Electrical conductivity perpendicular to the layers is consequently about 1000 times lower.
993:
For a long time graphite has been considered to be hydrophobic. However, recent studies using highly ordered pyrolytic graphite have shown that freshly clean graphite is hydrophilic (
1450:
From the 16th century, all pencils were made with leads of
English natural graphite, but modern pencil lead is most commonly a mix of powdered graphite and clay; it was invented by
2065:: Not relevant, due to the form of the product in its manufactured and shipped state. However, ingestion of dusts generated during working operations may cause nausea and vomiting.
2110:
but a sizeable piece of the old electrode remains. This is crushed and sized, and the resulting graphite powder is mostly used to raise the carbon content of molten steel.
4503:
1005:
Natural and crystalline graphites are not often used in pure form as structural materials, due to their shear-planes, brittleness, and inconsistent mechanical properties.
4385:
3174:
Wang, C. X.; Yang, G. W. (2012). "Thermodynamic and kinetic approaches of diamond and related nanomaterials formed by laser ablation in liquid". In Yang, Guowei (ed.).
1260:
Almost all of the above refractories are used to make steel and account for 75% of refractory consumption; the rest is used by a variety of industries, such as cement.
3841:
Li, Yiwei; Li, Yawei; Sang, Shaobai; Chen, Xilai; Zhao, Lei; Li, Yuanbing; Li, Shujing (January 2014). "Preparation of
Ceramic-Bonded Carbon Block for Blast Furnace".
1641:. In 1896, Acheson received a patent for his method of synthesizing graphite, and in 1897 started commercial production. The Acheson Graphite Co. was formed in 1899.
3326:
1707:
is made using electric arc furnaces, and the electric arc furnace itself is becoming more efficient, making more steel per tonne of electrode. An estimate based on
716:
exploded or low to intermediate-sized stars expelled their outer envelopes late in their lives. Graphite may be the second or third oldest mineral in the Universe.
3903:
Zhang, Hao; Yang, Yang; Ren, Dongsheng; Wang, Li; He, Xiangming (April 2021). "Graphite as anode materials: Fundamental mechanism, recent progress and advances".
1116:
because of the abundant cleaner deposits found around the globe, which needed not much more than hand-sorting to gather the pure graphite. The state of the art,
2068:
Potential physical / chemical effects: Bulk material is non-combustible. The material may form dust and can accumulate electrostatic charges, which may cause an
1123:, is described in the Canadian Department of Mines report on graphite mines and mining when Canadian deposits began to become important producers of graphite.
2090:
2089:) for graphite exposure in the workplace as a time weighted average (TWA) of 15 million particles per cubic foot (1.5 mg/m) over an 8-hour workday. The
5603:
426:. Synthetic and natural graphite are consumed on a large scale (1.3 million metric tons per year in 2022) for uses in many critical industries including
5593:
5561:
4045:
1655:(HOPG) is the highest-quality synthetic form of graphite. It is used in scientific research, in particular, as a length standard for the calibration of
1321:
Radioactive graphite removed from nuclear reactors has been investigated as a source of electricity for low-power applications. This waste is rich in
1255:
of steel underlying firm buyouts and many plant closures. Many of the plant closures resulted from the acquisition of Harbison-Walker Refractories by
3367:
3018:
2244:
innovation. Besides industry players, academia and research institutions have been an essential source of innovation in graphite anode technologies.
1251:
The US and European refractories industry had a crisis in 2000–2003, with an indifferent market for steel and a declining refractory consumption per
2572:
Robinson, Gilpin R.; Hammarstrom, Jane M.; Olson, Donald W. (2017). Schulz, Klaus J.; Deyoung, John H.; Seal, Robert R.; Bradley, Dwight C. (eds.).
959:
between dissimilar metals (due to its electrical conductivity). It is also corrosive to aluminium in the presence of moisture. For this reason, the
3262:
Deprez, N.; McLachlan, D. S. (1988). "The analysis of the electrical conductivity of graphite conductivity of graphite powders during compaction".
2394:
978:
When a large number of crystallographic defects bind these planes together, graphite loses its lubrication properties and becomes what is known as
4808:
2657:
4096:
3930:
2675:
2173:
by applicants from over 60 countries and regions. However, graphite-related patent families originated predominantly from just a few countries.
1898:
4870:
4013:
3392:
2259:
represents another area of intensive research, with over 6,000 patent families registered in the last decade alone. Specifically, graphite for
1634:
vaporizes at about 4,150 °C (7,500 °F), leaving the carbon behind in graphitic carbon. This graphite became valuable as a lubricant.
4474:
2082:
1214:
Natural graphite is mostly used for refractories, batteries, steelmaking, expanded graphite, brake linings, foundry facings, and lubricants.
4314:
Lapshin, Rostislav V. (March 2019). "Drift-insensitive distributed calibration of probe microscope scanner in nanometer range: Real mode".
4553:
3944:
532:. The high temperatures are maintained for weeks, and are required not only to form the graphite from the precursor carbons but to also
1294:, caused a growth in demand for graphite in the late 1980s and early 1990s – a growth driven by portable electronics, such as portable
1076:
During the 19th century, graphite's uses greatly expanded to include stove polish, lubricants, paints, crucibles, foundry facings, and
866:, diamond rapidly converts to graphite. Rapid conversion of graphite to diamond requires pressures well above the equilibrium line: at
761:
963:
banned its use as a lubricant in aluminium aircraft, and discouraged its use in aluminium-containing automatic weapons. Even graphite
2545:
2352:
1747:, US synthetic graphite powder and scrap production were 95,000 t (93,000 long tons; 105,000 short tons) in 2001 (latest data).
4009:
2193:. Together, these top five countries of applicant origin accounted for 95 percent of global patenting output related to graphite.
1514:
or linseed oil to create a heat-resistant protective coating for the exposed portions of a steam locomotive's boiler, such as the
5686:
4492:
732:
with a bond length of 0.142 nm, and the distance between planes is 0.335 nm. Bonding between layers is relatively weak
728:. In each layer, each carbon atom is bonded to three other atoms forming a continuous layer of sp bonded carbon hexagons, like a
3309:
4782:
4763:
4744:
4723:
3576:
3264:
2930:
2641:
2059:
Skin contact: Under normal conditions of intended use, this material does not pose a risk to health. Dust may irritate skin.
1044:
Sometime before 1565 (some sources say as early as 1500), an enormous deposit of graphite was discovered on the approach to
858:, 20 °C (293 K) and 1 standard atmosphere (0.10 MPa), the stable phase of carbon is graphite, but diamond is
5721:
5716:
4121:
2717:"Is the Central Cordillera of Colombia a potential source of graphite?: Implications for the energy transition in Colombia"
3337:
1785:
graphite-based nuclear reactors. Since they could not isolate the difficulty they were forced to use far more expensive
1781:, widely used as the seed electrode in commercial graphite deposition systems – this caused the failure of the Germans'
1190:
in 1778 proved that these were at least three different minerals. Scheele's analysis showed that the chemical compounds
990:, and is not diamagnetic. Pyrolytic graphite and pyrolytic carbon are often confused but are very different materials.)
776:
5588:
4863:
4455:
3642:
3520:
2528:
2522:
2337:
2200:
has the highest number of patent families, with more than 5,600 filed worldwide from 2012 to 2021. Supported by active
1652:
422:
typically in the excess of hundred(s) of layers. Graphite occurs naturally and is the most stable form of carbon under
2268:
for specific industries, ranging from electrical and electronics, aerospace and precision engineering to military and
4360:
3419:
3208:
3183:
2992:
2903:
2878:
2783:
1744:
855:
800:
4585:
3659:
788:
5681:
4142:
1427:
The ability to leave marks on paper and other objects gave graphite its name, given in 1789 by German mineralogist
1287:
1186:("writing stone") in 1789. He attempted to clear up the confusion between molybdena, plumbago and black lead after
471:
96:
3608:
2149:
5416:
4570:
4521:
3808:
Almeida, Bruno Vidal de; Neves, Elton Silva; Silva, Sidiney Nascimento; Vernilli Junior, Fernando (15 May 2017).
2056:
Eye contact: Dust in the eyes will cause irritation. Exposed may experience eye tearing, redness, and discomfort.
1979:
1809:
1586:
1569:
1264:
5193:
5188:
2301:
by various organizations without any players dominating. As a result, the top applicants have a small number of
1002:. Such contaminants can be desorbed by increasing the temperature of graphite to approximately 50 °C or higher.
708:. They are one of about 12 known types of minerals that predate the Solar System and have also been detected in
5706:
5696:
5269:
4726:, Asbury Graphite Mill, 2426–2500 Kirkham Street, Oakland, California, Earth Metrics report 10292.001 (Report).
1719:
574:
257:
2716:
1275:
The use of graphite in batteries has increased since the 1970s. Natural and synthetic graphite are used as an
5701:
4856:
4384:
Arregui-Mena, José David; Bodel, William; Worth, Robert N.; Margetts, Lee; Mummery, Paul M. (December 2016).
1903:
1622:
In 1893, Charles Street of Le Carbone discovered a process for making artificial graphite. In the mid-1890s,
1401:
powder, in water or oil, or as colloidal graphite (a permanent suspension in a liquid). An estimate based on
999:
767:
670:
290:
4287:
Lapshin, Rostislav V. (1 September 1998). "Automatic lateral calibration of tunneling microscope scanners".
2097:(REL) of TWA 2.5 mg/m respirable dust over an 8-hour workday. At levels of 1250 mg/m, graphite is
5731:
129:
3371:
2118:
basis for furnace-repair materials, and also crushed carbon–magnesite brick is used in slag conditioners.
1718:
also uses graphitic carbon electrodes. On a much smaller scale, synthetic graphite electrodes are used in
5711:
3975:
2130:
1743:
steel (competing with natural graphite), with some used in batteries and brake linings. According to the
752:
115:
4639:
1165:, gave its name to the English term for this grey metallic-sheened mineral and even to the leadworts or
442:(5%), among others (17%). Under extremely high pressures and extremely high temperatures it converts to
5608:
5236:
3746:
2094:
2086:
1890:
Graphite rods when filed into shape are used as a tool in glassworking to manipulate hot molten glass.
3106:
943:
Graphite and graphite powder are valued in industrial applications for their self-lubricating and dry
5406:
4089:
3995:
2984:
Handbook of carbon, graphite, diamond, and fullerenes : properties, processing, and applications
2896:
Handbook of carbon, graphite, diamond, and fullerenes : properties, processing, and applications
2689:
2605:
2505:
1656:
538:
20:
4154:
3731:
Handbuch des oryktognostischen Theils der Mineralogie: Mit einer Farbentabelle und einer Kupfertafel
3396:
2799:
Hazen, R. M.; Downs, R. T.; Kah, L.; Sverjensky, D. (13 February 2013). "Carbon Mineral Evolution".
1711:
data indicates that graphite electrode consumption was 197,000 t (217,000 short tons) in 2005.
5726:
5659:
Note: Peat is considered a precursor to coal. Graphite is only technically considered a coal type.
5478:
5391:
5386:
5002:
4471:
4071:
3544:
1922:
1862:
1813:
744:
111:
3885:
2026:. U.S. production of synthetic graphite in 2010 was 134,000 t valued at $ 1.07 billion.
1451:
5691:
5638:
4777:. Industrial Minerals and Rocks (7th ed.). Littleton, CO: AIME-Society of Mining Engineers.
3566:
2367:
1623:
1503:
1081:
86:
4813:
3176:
Laser ablation in liquids : principles and applications in the preparation of nanomaterials
2385:
1777:. Care must be taken that reactor-grade graphite is free of neutron absorbing materials such as
1510:
brushes, and various specialized applications. Railroads would often mix powdered graphite with
5613:
5421:
5062:
4542:
3107:"Recommended terminology for the description of carbon as a solid (IUPAC Recommendations 1995)"
1626:(1856–1931) accidentally invented another way to produce synthetic graphite after synthesizing
1519:
1428:
1179:
1131:
169:
4353:
Handbook of Carbon, Graphite, Diamonds and Fullerenes: Properties, Processing and Applications
3787:
3729:
3594:
The Statutes at Large: From the ... Year of the Reign of ... to the ... Year of the Reign of .
3592:
2920:
5468:
5366:
4889:
2758:
2294:
1884:
1821:
1770:
1291:
1049:
585:
which project is supported by grants from interested parties including a forestry company in
431:
247:
237:
4824:
2517:. Vol. I (Elements, Sulfides, Sulfosalts). Chantilly, VA: Mineralogical Society of America.
2125:
have a high graphite content, the volume of crucibles used and then recycled is very small.
2053:, may possibly be aggravated by prolonged exposure to high concentrations of graphite dusts.
1835:. The mechanical properties of carbon fiber graphite-reinforced plastic composites and grey
5473:
5448:
4940:
4879:
4838:
4819:
4692:
4172:
3850:
3273:
3148:
3071:
2843:
2808:
2429:
2208:
strongly led by commercial entities, particularly world-renowned battery manufacturers and
1680:
1523:
1379:
for heavier (nonautomotive) vehicles, and became important with the need to substitute for
1187:
915:
862:
and its rate of conversion to graphite is negligible. However, at temperatures above about
545:
at temperatures above 2,500 K (2,230 °C), by decomposition of thermally unstable
459:
Graphite occurs naturally in ores that can be classified into one of two categories either
2506:
Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1990).
2022:
is in the development stages of creating a pilot plant for their Coosa Graphite Mine near
2014:, but there are many historical mine sites including ones in Alabama, Montana, and in the
8:
5551:
5411:
5311:
2256:
2232:
2019:
1873:
1844:
1832:
1761:
Special grades of synthetic graphite, such as Gilsocarbon, also find use as a matrix and
1676:
733:
423:
348:
280:
270:
209:
4696:
4176:
3991:
3854:
3277:
3152:
3075:
2847:
2812:
2624:
Marsh, Harry; Rodríguez-Reinoso, Francisco (2006). "Production and Reference Material".
2433:
724:
Graphite consists of sheets of trigonal planar carbon. The individual layers are called
5623:
5566:
5536:
5526:
5483:
5262:
4977:
4959:
4710:
4323:
4193:
4184:
4156:
4017:
3866:
3714:
3354:
3289:
3248:
3234:
3087:
3061:
2963:
2633:
2447:
2298:
2170:
2023:
1968:
1883:
Graphite composites are used as absorber for high-energy particles, for example in the
1715:
1330:
1191:
979:
967:
marks on aluminium parts may facilitate corrosion. Another high-temperature lubricant,
956:
227:
2157:
501:
is the typical source of amorphous graphite. Crystalline flake graphite is mined from
5676:
5628:
5556:
5503:
5356:
4778:
4759:
4740:
4733:
4451:
4356:
4198:
3870:
3638:
3572:
3516:
3486:
3415:
3293:
3285:
3204:
3179:
3160:
3091:
2998:
2988:
2967:
2926:
2899:
2874:
2779:
2637:
2518:
2451:
2134:
1983:
1947:
1943:
1869:
1825:
1762:
1700:
1148:
1085:
948:
937:
854:). However, the phases have a wide region about this line where they can coexist. At
729:
505:
490:
415:
4714:
3028:
1359:
increase the carbon content of the steel to a specified level. An estimate based on
5618:
5371:
5216:
5146:
5052:
4700:
4651:
4428:
4400:
4333:
4296:
4269:
4241:
4188:
4180:
4155:
Emery, Nicolas; Hérold, Claire; Marêché, Jean-François; Lagrange, Philippe (2008).
3912:
3858:
3826:
3821:
3809:
3710:
3478:
3450:
3306:
3281:
3244:
3156:
3118:
3079:
3032:
3023:
2955:
2851:
2816:
2730:
2629:
2577:
2437:
2372:
2275:
2269:
2236:
2213:
1851:
1790:
1756:
1556:
1467:
1267:, US natural graphite consumption in refractories comprised 12,500 tonnes in 2010.
1199:
987:
689:
614:
606:
570:
377:
300:
217:
70:
4432:
4039:"Electric Graphite Growing Demand From Electric Vehicles & Mobile Electronics"
1151:
mineral form. Both of these names arise from confusion with the similar-appearing
947:
properties. However, the use of graphite is limited by its tendency to facilitate
5316:
5101:
5057:
5023:
4965:
4829:
4478:
4404:
4366:
4337:
4245:
3686:. Spons' Workshop Receipts Vol. II: Dyeing to Japanning. Spon. 1921. p. 132.
3454:
3313:
2332:
1931:
1877:
1805:
1766:
1638:
1627:
1595:
1479:
1334:
1311:
1104:
952:
709:
693:
554:
550:
529:
4803:
3931:"EV batteries need graphite – here's what's forecast for supply | Electrek"
2488:
1820:, golf club shafts, bicycle frames, sports car body panels, the fuselage of the
1816:(RCC). Commercial structures made from carbon fiber graphite composites include
1644:
Synthetic graphite can also be prepared from polyimide and then commercialized.
5498:
5426:
5401:
5198:
5007:
4971:
4273:
3916:
2721:
2327:
2290:
2197:
2069:
2046:
1801:
1774:
1739:
1723:
1692:
1688:
1507:
1491:
929:
908:
521:
106:
63:
4843:
4605:
3862:
3083:
2959:
2855:
512:
regions. There are serious negative environmental impacts to graphite mining.
5670:
5255:
5231:
5085:
4984:
4950:
4834:
4758:. Financial Times Executive Commodity Reports. London: Mining Journal Books.
4217:
3027:, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "
2735:
2592:
2310:
2306:
2186:
2035:
2011:
1935:
1865:. It was mixed with rubber in Sumpf and Schornsteinfeger, which were used on
1855:
1684:
1539:
1444:
1387:, US natural graphite consumption in brake linings was 6,510 tonnes in 2005.
1244:
1034:
994:
968:
834:
824:
819:
498:
475:
407:
203:
122:
3970:
3122:
3036:
3002:
2869:
Delhaes, Pierre (2000). "Polymorphism of carbon". In Delhaes, Pierre (ed.).
2608:, Acheson, E. G., "Production of Graphite", published 1906-11-20
2507:
1637:
Acheson's technique for producing silicon carbide and graphite is named the
577:. It is produced from forestry waste and similar byproducts by a company in
508:, while lump or chip graphite is mined from veins which occur in high-grade
5643:
5221:
4370:
4202:
3490:
2771:
2390:
2153:
Distribution of graphite-related patent families by source type - 2012-2022
2138:
1972:
1955:
1782:
1535:
1534:
Expanded graphite is made by immersing natural flake graphite in a bath of
1458:, whose ores had a similar appearance, hence the continuation of the name.
1307:
960:
851:
705:
622:
618:
533:
502:
487:
483:
427:
3945:"Graphite/Metal Alloy Extends Material Life in High-Temperature Processes"
2834:
McCoy, T. J. (22 February 2010). "Mineralogical Evolution of Meteorites".
2820:
1176:
usually refers to a powdered or processed graphite, matte black in color.
645:. The principal export sources of mined graphite are in order of tonnage:
5576:
5571:
5513:
5463:
5438:
5183:
5162:
4905:
4637:
2982:
2362:
2357:
2282:
2219:
The exfoliation process for bulk graphite, which involves separating the
2182:
2015:
2007:
1817:
1786:
1470:
is normally restricted to 17th and 18th-century works, mostly portraits.
1376:
1355:
1315:
1195:
1065:
1045:
983:
933:
899:
578:
542:
525:
509:
328:
137:
4730:
4655:
3439:
2442:
2417:
5321:
4848:
3616:
2302:
2260:
2114:
2072:(ignition source). High dust levels may create potential for explosion.
2042:
1828:
1789:
moderators. Graphite used for nuclear reactors is often referred to as
1672:
1617:
1552:
1397:
1375:
Natural amorphous and fine flake graphite are used in brake linings or
1364:
1326:
1299:
1231:
1223:
1069:
1064:, which the locals found useful for marking sheep. During the reign of
1053:
971:, has the same molecular structure as graphite. It is sometimes called
859:
697:
662:
642:
479:
439:
338:
4417:
4300:
2476:
1073:
unique mine and its production were strictly controlled by the Crown.
1017:
Graphite plates and sheets, 10–15 cm high; mineral specimen from
358:
strongly anisotropic, conducts electricity, greasy feel, readily marks
5648:
5633:
5581:
5531:
5521:
5117:
4935:
4705:
4680:
3482:
2464:
2342:
2062:
2050:
1836:
1696:
1668:
1547:
1511:
1466:, typically as a lump of the mineral without a wood casing. The term
1322:
1295:
1280:
1235:
1030:
944:
922:
891:
807:
713:
681:
626:
590:
435:
3698:
2581:
1013:
5598:
5546:
5453:
5431:
5396:
5376:
5351:
5226:
5067:
4930:
4606:"CDC – NIOSH Pocket Guide to Chemical Hazards – Graphite (natural)"
4328:
3727:
3066:
2347:
2314:
2201:
2144:
2122:
1560:
natural graphite consumption in this end-use is 7,500 tonnes.
1543:
1515:
1380:
1227:
1166:
1018:
926:
919:
907:
in oxygen-containing atmospheres graphite readily oxidizes to form
725:
685:
666:
419:
27:
5336:
3239:
2573:
520:
Synthetic graphite is graphite of high purity produced by thermal
44:
5458:
5306:
5178:
4899:
4722:
C.Michael Hogan; Marc Papineau; et al. (December 18, 1989).
4386:"Spatial variability in the mechanical properties of Gilsocarbon"
4075:
3889:
2676:"CarbonScape Renewable Biographite Anode Material Ready to Scale"
2591:
This article incorporates text from this source, which is in the
2265:
2248:
1959:
1727:
1631:
1463:
1161:
1061:
1057:
1038:
903:
701:
634:
586:
546:
482:. All naturally occurring graphite deposits are formed from the
443:
310:
3807:
2235:, graphite has drawn significant attention worldwide for use in
2169:
families in graphite technologies were filed from 2012 to 2021.
1574:
5443:
5361:
2396:
Patent Landscape Report - Graphite and its applications
2286:
2220:
2190:
2166:
2137:
gives a 95% graphite product with a flake size ranging from 10
2003:
1999:
1939:
1914:
1907:
1866:
1303:
1256:
1203:
1156:
1077:
964:
674:
658:
654:
650:
630:
558:
411:
344:
79:
4383:
3050:
2658:"Batteries made from woodchips could clean up the EV industry"
1893:
1107:
process are associated with graphite mining. Included in the
882:
569:
Biographite is a commercial product proposal for reducing the
5296:
4522:"How graphite is used in the glass and fibreglass industries"
3223:
2241:
2209:
2178:
2174:
1995:
1991:
1987:
1963:
1840:
1778:
1704:
1419:
1276:
1252:
646:
610:
4721:
4450:. New York, N.Y.: American Institute of Physics. Figure 11.
3542:
2776:
Stardust From Meteorites: An Introduction To Presolar Grains
1099:
Graphited Wood Grease 1908 ad in the Electric Railway Review
1092:
21 December 1878. The Dixon pencil is still in production.
665:. Significant unexploited graphite resources also exists in
5541:
5493:
5381:
5301:
5278:
4647:
4230:
2098:
1708:
1455:
1402:
1384:
1360:
1152:
895:
638:
494:
395:
4143:
True color/appearance of the "Graphite, or Smokebox colors
3138:
1226:(heat-resistant) material began before 1900 with graphite
704:
compositions, indicating that they were formed before the
5488:
4640:"Patent Landscape Report - Graphite and its applications"
1206:) and graphite were three different soft black minerals.
1026:
468:
389:
383:
4835:
Video lecture on the properties of graphite by M. Heggie
4519:
4258:
2571:
446:. It is a good conductor of both heat and electricity
198:
Iron-black to steel-gray; deep blue in transmitted light
5247:
2798:
2546:"Graphite global consumption share by end use and type"
2212:
material suppliers, with patenting interest focused on
2010:(6,000 t). Graphite is not currently mined in the
1230:
used to hold molten metal; this is now a minor part of
4044:. galaxycapitalcorp.com. July 20, 2011. Archived from
3664:. Ottawa: Canadian Department of Mines. p. passim
3661:
Graphite its Properties, Occurrence, Refining and Uses
3568:
A Pictorial Guide to the Lakeland Fells, Western Fells
2623:
1367:
in the US used 10,500 tonnes in this fashion in 2005.
2091:
National Institute for Occupational Safety and Health
1329:, so it could potentially be used as the basis for a
392:
5604:
Health and environmental impact of the coal industry
3545:"Old Cumbria Gazetteer, black lead mine, Seathwaite"
2393:
work. Licensed under CC-BY. Text taken from
1618:
Invention of a process to produce synthetic graphite
1598:. The highest transition temperature (by June 2009)
1462:
is another older term for natural graphite used for
398:
386:
5594:
Environmental justice and coal mining in Appalachia
4731:Klein, Cornelis; Cornelius S. Hurlbut, Jr. (1985).
3810:"Blast Furnace Hearth Lining: Post Mortem Analysis"
3467:
3410:Marsh, Harry; Reinoso, Francisco Rodríguez (2007).
1926:
World graphite reserves and mine production in 2022
493:, and the ore type is due to its geologic setting.
380:
4732:
4638:World Intellectual Property Organization. (2023).
3564:
3558:
1363:'s graphite consumption statistics indicates that
1008:
528:materials most commonly by a process known as the
4772:
4753:
3744:
2714:
1454:in 1795. It is chemically unrelated to the metal
1390:
1169:, plants with flowers that resemble this colour.
886:Molar volume against pressure at room temperature
295:Opaque, transparent only in extremely thin flakes
5668:
4816:– Map of World Graphite Mines and Producers 2012
4157:"Synthesis and superconducting properties of CaC
3902:
3395:. Lotus Seven Club. 9 April 2003. Archived from
3327:"ASM Tech Notes – TN7-0506 – Galvanic Corrosion"
2682:
2145:Research and innovation in graphite technologies
1934:and underground methods. Graphite usually needs
1854:is coated in graphite to prevent the buildup of
1612:
1490:Graphite is probably the most-used lubricant in
1037:used graphite in a ceramic paint for decorating
712:. These minerals were formed in the ejecta when
467:(flake or lump/chip) which is determined by the
4586:"Westwater Resources acquires Alabama Graphite"
4472:What is the best material for a tennis racquet?
4344:
3513:The Cambridge ancient history, Volume 3, Part 1
3261:
1068:(1558–1603), Borrowdale graphite was used as a
4122:"Top 5 Speed Tips for Your Pinewood Derby Car"
3203:. University Science Books. pp. 257–260.
2604:
2567:
2565:
2563:
2561:
2559:
2557:
2555:
1990:, of which the following major exporters are:
1695:. They are extruded and shaped, then baked to
932:within the carbon layers (a phenomenon called
5263:
4864:
4280:
4031:
3989:
3547:. Geography Department, Portsmouth University
2083:Occupational Safety and Health Administration
925:. It can conduct electricity due to the vast
4844:CDC – NIOSH Pocket Guide to Chemical Hazards
4678:
3840:
3728:Widenmann, Johann Friedrich Wilhelm (1794).
3414:(1st ed.). Elsevier. pp. 497–498.
3409:
2389: This article incorporates text from a
2049:. Pre-existing pulmonary disorders, such as
1594:. Some graphite intercalation compounds are
1526:uses a graphite tip as its heating element.
629:. Minerals associated with graphite include
4082:
3699:"V.— the Meanings and Synonyms of Plumbago"
2946:Chung, D. D. L. (2002). "Review Graphite".
2918:
2598:
2552:
2240:performance improvements based on graphite
1894:Graphite mining, beneficiation, and milling
1812:, and in heat-resistant composites such as
1340:
1209:
700:. Some microscopic grains have distinctive
524:at temperatures in excess of 2,100 °C from
242:Flaky, otherwise rough when not on cleavage
5270:
5256:
4871:
4857:
4583:
4215:Acheson, E. G. "Manufacture of Graphite",
4014:University of Illinois at Urbana–Champaign
3843:Metallurgical and Materials Transactions A
3684:Electro-Plating on Non-Metallic Substances
3192:
2778:. World Scientific. pp. 14, 154–157.
2231:As the most widespread anode material for
1986:of natural graphite in 2016 was 1,200,000
911:at temperatures of 700 °C and above.
4704:
4411:
4377:
4327:
4192:
4145:. List.nwhs.org. Retrieved on 2013-04-15.
4069:
3825:
3628:
3626:
3497:
3238:
3104:
3065:
3046:
3044:
2734:
2441:
2353:Graphitizing and non-graphitizing carbons
1861:Graphite has been used in at least three
1843:, while the term "composite" is used for
4878:
4445:
4439:
4307:
3703:Transactions of the Philological Society
3173:
3134:
3132:
2987:. Park Ridge, N.J.: Noyes Publications.
2156:
2148:
2099:immediately dangerous to life and health
1921:
1913:
1897:
1573:
1563:
1418:
1346:virtually all EV batteries is graphite.
1318:contains nearly 40 kg of graphite.
1130:
1094:
1012:
881:
818:
4350:
4313:
4286:
3883:
3782:
3780:
3778:
3776:
3774:
3772:
3770:
3768:
3766:
3764:
3543:Norgate, Martin; Norgate, Jean (2008).
3536:
3227:Journal of the European Ceramic Society
3014:
3012:
2980:
2893:
2868:
2754:
2752:
2750:
2748:
2746:
2465:Liquid method: pure graphene production
1831:and have been successfully employed in
1773:also recommends it for use in proposed
1738:The powder is made by heating powdered
1555:. The foil is made into heat sinks for
918:, hence useful in such applications as
16:Allotrope of carbon, mineral, substance
5669:
4571:"Wonder 5: Graphite Mines – Boom Town"
3657:
3632:
3623:
3178:. Pan Stanford Pub. pp. 164–165.
3041:
2898:. Noyes Publications. pp. 40–41.
2873:. Gordon & Breach. pp. 1–24.
2801:Reviews in Mineralogy and Geochemistry
2770:
2196:Among the different graphite sources,
2161:Innovation Maturity Matrix of graphite
2029:
1647:
1135:Advert for Crane's Black Lead, c. 1905
739:There are two allotropic forms called
449:
5562:mining disasters in the United States
5251:
4852:
4724:Phase I Environmental Site Assessment
4633:
4631:
4629:
4627:
4625:
4490:
3788:"Graphite Statistics and Information"
3747:"Versuche mit Wasserbley; Molybdaena"
3696:
3435:
3433:
3431:
3393:"Good Engineering Practice/Corrosion"
3265:Journal of Physics D: Applied Physics
3129:
2945:
2833:
2501:
2499:
2497:
2104:
1876:. It was also used in tiles on early
982:. It is also highly anisotropic, and
595:
515:
4550:National Minerals Information Center
4148:
4072:"ART TECHNIQUE-GRAPHITE AS A MEDIUM"
3761:
3503:
3370:. September 16, 2005. Archived from
3198:
3009:
2743:
2715:Bustamante, C.; Cardona, A. (2024).
2696:. Minerals Education Coalition. 2018
2418:"IMA–CNMNC approved mineral symbols"
2415:
1750:
1529:
1286:The demand for batteries, primarily
1147:. Plumbago was commonly used in its
1103:The beginnings of the revolutionary
212:masses, granular to compacted masses
3949:Foundry Management & Technology
3751:Svenska Vetensk. Academ. Handlingar
1733:
1502:Natural graphite has found uses in
877:
454:
13:
5589:Environmental issues in Appalachia
4679:Lipson, H.; Stokes, A. R. (1942).
4672:
4622:
4543:"Mineral Commodity Summaries 2020"
3990:Ritter, Steve (October 15, 2001).
3968:
3715:10.1111/j.1467-968X.1908.tb00513.x
3428:
3249:10.1016/j.jeurceramsoc.2011.07.007
3024:Compendium of Chemical Terminology
2494:
2338:Exfoliated graphite nano-platelets
1653:Highly oriented pyrolytic graphite
1139:Historically, graphite was called
898:properties of graphite are highly
14:
5743:
4792:
4520:Olmec Advanced Materials (2019).
3506:"The Neolithic-Eneolithic Period"
3368:"Weapons Lubricant in the Desert"
2761:. Encyclopædia Britannica Online.
1971:from powder spillages leading to
1745:United States Geographical Survey
1683:, which are the vast majority of
1671:carry the electricity that melts
1485:
975:, due to its similar properties.
814:
5335:
4735:Manual of Mineralogy: after Dana
4559:from the original on 2017-02-09.
4509:from the original on 2015-09-10.
4493:"Protecting the LHC from itself"
4289:Review of Scientific Instruments
2634:10.1016/B978-008044463-5/50023-6
2586:
2534:from the original on 2013-10-04.
2384:
2085:(OSHA) has set the legal limit (
2076:
1810:carbon fiber reinforced plastics
1605:= 11.5 K is achieved in CaC
1370:
1325:, which emits electrons through
1090:Engineering & Mining Journal
1033:Age in southeastern Europe, the
799:
787:
775:
760:
673:in the form of graphite-bearing
410:allotrope (form) of the element
376:
127:Dihexagonal dipyramidal (6/mmm)
43:
4906:Lonsdaleite (hexagonal diamond)
4598:
4577:
4563:
4535:
4513:
4484:
4464:
4252:
4224:
4209:
4136:
4114:
4102:from the original on 2012-08-09
4063:
4002:
3983:
3962:
3937:
3923:
3896:
3877:
3834:
3801:
3738:
3721:
3690:
3676:
3651:
3601:
3585:
3461:
3403:
3385:
3360:
3355:Better Lubricants than Graphite
3347:
3319:
3300:
3255:
3217:
3167:
3105:E. Fitzer; et al. (1995).
3098:
2974:
2939:
2912:
2887:
2862:
2827:
2792:
2764:
2708:
2668:
2650:
1980:United States Geological Survey
1796:
1570:Graphite intercalation compound
1409:
1333:. This concept is known as the
1283:in major battery technologies.
1234:. In the mid-1980s, the carbon-
1217:
1009:History of natural graphite use
856:normal temperature and pressure
782:Side view of ABA layer stacking
692:. Small graphitic crystals in
583:thermo-catalytic graphitisation
5687:Non-petroleum based lubricants
4070:Not known (January 29, 2018).
3827:10.1590/1980-5373-mr-2016-0875
3635:Colloidal Science of Flotation
2617:
2538:
2482:
2470:
2458:
2409:
1720:electrical discharge machining
1391:Foundry facings and lubricants
1349:
1126:
564:
414:. It consists of many stacked
1:
4433:10.1016/j.jnucmat.2018.09.008
4090:"Module 6: Media for 2-D Art"
2402:
2228:greater commercial interest.
1904:Naturalis Biodiversity Center
1847:with additional ingredients.
1662:
1613:History of synthetic graphite
1497:
1117:
1000:kelvin probe force microscopy
850:(the diamond/graphite/liquid
768:Scanning tunneling microscope
600:
581:using a novel process called
252:Flexible non-elastic, sectile
4646:. Patent Landscape Reports.
4421:Journal of Nuclear Materials
4405:10.1016/j.carbon.2016.09.051
4338:10.1016/j.apsusc.2018.10.149
4262:Journal of Materials Science
4246:10.1016/j.carbon.2021.02.090
4221:, issued September 29, 1896.
4185:10.1088/1468-6996/9/4/044102
3455:10.1016/j.carbon.2013.04.056
3161:10.1016/0008-6223(96)00170-4
2948:Journal of Materials Science
1962:molds, carbon raiser in the
1270:
794:Plane view of layer stacking
719:
7:
5722:Minerals in space group 194
5717:Minerals in space group 186
4681:"A New Structure of Carbon"
4446:Weinberg, Alvin M. (1994).
4010:"The History of the Pencil"
3992:"Pencils & Pencil Lead"
3976:Online Etymology Dictionary
3884:Targray (August 27, 2020).
3571:. London: Frances Lincoln.
3565:Wainwright, Alfred (2005).
3353:Jones, Rick (USAF-Retired)
2320:
1946:(for a silicate gangue) or
1159:. The Latin word for lead,
573:of lithium iron phosphate
10:
5748:
5609:Health effects of coal ash
5417:power in the United States
5237:Aggregated diamond nanorod
4773:Taylor, Harold A. (2005).
4754:Taylor, Harold A. (2000).
4274:10.1007/s10853-021-06283-5
3917:10.1016/j.ensm.2020.12.027
3886:"Graphite Anode Materials"
3745:Scheele, C. W. K. (1779).
3286:10.1088/0022-3727/21/1/015
3111:Pure and Applied Chemistry
2467:. Phys.org (May 30, 2010).
2379:
2299:patent families were filed
2095:recommended exposure limit
2087:permissible exposure limit
1950:(for a carbonate gangue).
1930:Graphite is mined by both
1754:
1657:scanning probe microscopes
1567:
1414:
25:
18:
5657:
5512:
5344:
5333:
5285:
5207:
5137:
5076:
5043:
5035:(cyclo[18]carbon)
4993:
4914:
4886:
4825:giant covalent structures
4814:Mineral & Exploration
4584:Jeremy Law (2018-05-16).
4351:Pierson, Hugh O. (1993).
3996:American Chemical Society
3863:10.1007/s11661-013-1976-4
3637:. CRC Press. p. 11.
3613:Dixon Ticonderoga Company
3084:10.1007/s11467-018-0867-y
2981:Pierson, Hugh O. (1993).
2894:Pierson, Hugh O. (2012).
2856:10.2113/gselements.6.1.19
1902:Large graphite specimen.
1880:stealth strike fighters.
1863:radar absorbent materials
1675:and steel, and sometimes
1222:The use of graphite as a
770:image of graphite surface
539:chemical vapor deposition
362:
354:
337:
327:
319:
309:
299:
289:
279:
269:
256:
246:
236:
232:Basal – perfect on {0001}
226:
216:
202:
194:
189:
168:
136:
121:
105:
95:
85:
69:
59:
54:
42:
37:
21:Graphite (disambiguation)
5479:Greenhouse gas emissions
5277:
5019:(cyclo[6]carbon)
5003:Linear acetylenic carbon
4804:Graphite at Minerals.net
4739:(20th ed.). Wiley.
4165:Sci. Technol. Adv. Mater
3905:Energy Storage Materials
2736:10.5027/andgeoV51n2-3728
2309:, particularly graphite
1814:reinforced carbon-carbon
1722:(EDM), commonly to make
1341:Graphite Anode Materials
1210:Uses of natural graphite
823:Theoretically predicted
617:carbon compounds during
497:that has been thermally
130:Hermann–Mauguin notation
26:Not to be confused with
5682:Native element minerals
5639:Problems in coal mining
4316:Applied Surface Science
3734:. Crusius. p. 653.
3697:Evans, John W. (1908).
3201:Chemical Thermodynamics
3199:Rock, Peter A. (1983).
3123:10.1351/pac199567030473
3037:10.1351/goldbook.R05385
2960:10.1023/A:1014915307738
2922:Graphite and Precursors
2871:Graphite and precursors
2368:Passive fire protection
1975:contamination of soil.
1918:Graphite output in 2005
1802:Graphite (carbon) fiber
1691:after it is mixed with
1624:Edward Goodrich Acheson
1587:intercalation compounds
969:hexagonal boron nitride
684:, graphite occurs with
589:and a battery maker in
5614:History of coal mining
5063:Carbide-derived carbon
4945:(buckminsterfullerene)
4799:Battery Grade Graphite
4355:. Noyes Publications.
3658:Cirkel, Fritz (1907).
3334:Atlas Specialty Metals
2515:Handbook of Mineralogy
2422:Mineralogical Magazine
2257:manufacturing ceramics
2165:Globally, over 60,000
2162:
2154:
2133:this concentrate with
1927:
1919:
1911:
1582:
1429:Abraham Gottlob Werner
1424:
1279:material to construct
1180:Abraham Gottlob Werner
1136:
1100:
1025:In the 4th millennium
1022:
887:
828:
463:(microcrystalline) or
5707:Electrical conductors
5697:Visual arts materials
5469:Fossil fuel phase-out
5367:Black coal equivalent
4448:The First Nuclear Era
3399:on 16 September 2009.
3029:Rhombohedral graphite
2821:10.2138/rmg.2013.75.4
2233:lithium-ion batteries
2160:
2152:
1925:
1917:
1901:
1885:Large Hadron Collider
1822:Boeing 787 Dreamliner
1771:neutron cross-section
1687:. They are made from
1681:electric arc furnaces
1577:
1564:Intercalated graphite
1518:or lower part of the
1504:zinc-carbon batteries
1452:Nicolas-Jacques Conté
1422:
1292:lithium-ion batteries
1134:
1098:
1016:
885:
822:
432:lithium-ion batteries
355:Other characteristics
97:Strunz classification
5702:Refractory materials
5474:Great Smog of London
5407:pollution mitigation
4880:Allotropes of carbon
4839:University of Sussex
4124:. S&W Crafts Mfg
3633:Nguyen, Ahn (2003).
3532:on 25 February 2013.
3054:Frontiers of Physics
2919:Delhaes, P. (2001).
2664:. February 26, 2024.
2628:. pp. 454–508.
2270:nuclear applications
2216:anode applications.
2113:Graphite-containing
2006:(32,000 t) and
1538:, then concentrated
1524:Scope soldering iron
1433:γράφειν ("graphein")
1354:Natural graphite in
1288:nickel–metal hydride
1188:Carl Wilhelm Scheele
916:electrical conductor
621:. It also occurs in
19:For other uses, see
5732:Industrial minerals
5392:fired power station
5387:combustion products
5312:Sub-bituminous coal
5289:(lowest to highest)
5286:Coal types by grade
4820:Mindat w/ locations
4697:1942Natur.149Q.328L
4656:10.34667/tind.47589
4268:(28): 15798–15811.
4218:U.S. patent 568,323
4177:2008STAdM...9d4102E
3855:2014MMTA...45..477L
3278:1988JPhD...21..101D
3153:1996Carbo..34..141B
3076:2019FrPhy..1413608L
2848:2010Eleme...6...19M
2813:2013RvMG...75...79H
2443:10.1180/mgm.2021.43
2434:2021MinM...85..291W
2416:Warr, L.N. (2021).
2295:emerging technology
2030:Occupational safety
2020:Westwater Resources
1874:radar cross section
1845:composite materials
1833:reinforced concrete
1677:direct-reduced iron
1648:Scientific research
1155:ores, particularly
1048:from the hamlet of
734:van der Waals bonds
609:as a result of the
605:Graphite occurs in
450:Types and varieties
424:standard conditions
349:chlorosulfuric acid
208:Tabular, six-sided
5712:Hexagonal minerals
5527:Black lung disease
5504:Toxic heavy metals
5484:Metallurgical coal
5158:(cyclopropatriene)
5139:hypothetical forms
4960:Fullerene whiskers
4491:Yurkewicz, Katie.
4481:. tennis.about.com
4477:2011-07-07 at the
4051:on October 4, 2013
3814:Materials Research
3597:1764. p. 415.
3515:. pp. 31–32.
3312:2009-03-10 at the
3307:Galvanic Corrosion
2191:Russian Federation
2171:Patents were filed
2163:
2155:
2141:(2 mm) down.
2105:Graphite recycling
2093:(NIOSH) has set a
2024:Sylacauga, Alabama
1998:(170,000 t),
1994:(780,000 t),
1969:soil contamination
1928:
1920:
1912:
1716:aluminium smelting
1583:
1425:
1331:betavoltaic device
1192:molybdenum sulfide
1137:
1101:
1023:
980:pyrolytic graphite
957:galvanic corrosion
938:carbon microphones
888:
829:
671:Cordillera Central
516:Synthetic graphite
343:Soluble in molten
320:Optical properties
5664:
5663:
5422:preparation plant
5357:Asian brown cloud
5290:
5245:
5244:
5113:(diatomic carbon)
5045:mixed sp/sp forms
4830:The Graphite Page
4809:Mineral galleries
4784:978-0-87335-233-8
4765:978-1-84083-332-4
4746:978-0-471-80580-9
4500:Symmetry Magazine
4301:10.1063/1.1149091
3969:Harper, Douglas.
3578:978-0-7112-2460-5
3316:. keytometals.com
3233:(15): 2877–2885.
2932:978-90-5699-228-6
2694:Minerals Database
2643:978-0-08-044463-5
2491:. Webmineral.com.
2183:Republic of Korea
2135:hydrochloric acid
2002:(80,000 t),
1978:According to the
1958:and coatings for
1948:hydrochloric acid
1944:hydrofluoric acid
1808:are also used in
1763:neutron moderator
1751:Neutron moderator
1530:Expanded graphite
1263:According to the
1086:Orestes Cleveland
1054:Borrowdale parish
955:, and to promote
949:pitting corrosion
806:Alpha graphite's
730:honeycomb lattice
690:silicate minerals
607:metamorphic rocks
553:from metal melts
506:metamorphic rocks
491:sedimentary rocks
369:
368:
49:Graphite specimen
5739:
5619:Hydrogen sulfide
5339:
5288:
5272:
5265:
5258:
5249:
5248:
5217:Activated carbon
5173:
5172:
5171:
5157:
5156:
5155:
5128:
5127:
5126:
5112:
5111:
5110:
5096:
5095:
5094:
5053:Amorphous carbon
5034:
5033:
5032:
5018:
5017:
5016:
4873:
4866:
4859:
4850:
4849:
4788:
4769:
4750:
4738:
4727:
4718:
4708:
4706:10.1038/149328a0
4666:
4665:
4663:
4662:
4635:
4620:
4619:
4617:
4616:
4602:
4596:
4595:
4593:
4592:
4581:
4575:
4574:
4573:. 24 March 2015.
4567:
4561:
4560:
4558:
4547:
4539:
4533:
4532:
4530:
4528:
4517:
4511:
4510:
4508:
4497:
4488:
4482:
4468:
4462:
4461:
4443:
4437:
4436:
4415:
4409:
4408:
4390:
4381:
4375:
4374:
4348:
4342:
4341:
4331:
4311:
4305:
4304:
4295:(9): 3268–3276.
4284:
4278:
4277:
4256:
4250:
4249:
4228:
4222:
4220:
4213:
4207:
4206:
4196:
4152:
4146:
4140:
4134:
4133:
4131:
4129:
4118:
4112:
4111:
4109:
4107:
4101:
4094:
4086:
4080:
4079:
4067:
4061:
4060:
4058:
4056:
4050:
4043:
4035:
4029:
4028:
4026:
4025:
4016:. Archived from
4006:
4000:
3999:
3987:
3981:
3980:
3966:
3960:
3959:
3957:
3956:
3941:
3935:
3934:
3927:
3921:
3920:
3900:
3894:
3893:
3881:
3875:
3874:
3838:
3832:
3831:
3829:
3805:
3799:
3798:
3796:
3795:
3784:
3759:
3758:
3742:
3736:
3735:
3725:
3719:
3718:
3694:
3688:
3687:
3680:
3674:
3673:
3671:
3669:
3655:
3649:
3648:
3630:
3621:
3620:
3619:on 7 April 2018.
3615:. Archived from
3605:
3599:
3598:
3589:
3583:
3582:
3562:
3556:
3555:
3553:
3552:
3540:
3534:
3533:
3531:
3525:. Archived from
3510:
3504:Boardman, John.
3501:
3495:
3494:
3483:10.1038/nmat3709
3471:Nature Materials
3465:
3459:
3458:
3437:
3426:
3425:
3412:Activated carbon
3407:
3401:
3400:
3389:
3383:
3382:
3380:
3379:
3364:
3358:
3351:
3345:
3344:
3342:
3336:. Archived from
3331:
3323:
3317:
3304:
3298:
3297:
3259:
3253:
3252:
3242:
3221:
3215:
3214:
3196:
3190:
3189:
3171:
3165:
3164:
3136:
3127:
3126:
3102:
3096:
3095:
3069:
3048:
3039:
3016:
3007:
3006:
2978:
2972:
2971:
2954:(8): 1475–1489.
2943:
2937:
2936:
2916:
2910:
2909:
2891:
2885:
2884:
2866:
2860:
2859:
2831:
2825:
2824:
2796:
2790:
2789:
2768:
2762:
2756:
2741:
2740:
2738:
2712:
2706:
2705:
2703:
2701:
2686:
2680:
2679:
2672:
2666:
2665:
2654:
2648:
2647:
2626:Activated Carbon
2621:
2615:
2614:
2613:
2609:
2602:
2596:
2590:
2589:
2585:
2569:
2550:
2549:
2542:
2536:
2535:
2533:
2512:
2503:
2492:
2486:
2480:
2474:
2468:
2462:
2456:
2455:
2445:
2413:
2388:
2373:Pyrolytic carbon
2070:electrical spark
1984:world production
1872:to reduce their
1852:smokeless powder
1806:carbon nanotubes
1791:nuclear graphite
1767:nuclear reactors
1757:Nuclear graphite
1734:Powder and scrap
1578:Structure of CaC
1557:laptop computers
1546:fitted around a
1492:pinewood derbies
1468:plumbago drawing
1431:. It stems from
1423:Graphite pencils
1200:lead(II) sulfide
1182:coined the name
1122:
1119:
988:pyrolytic carbon
878:Other properties
873:
870:, a pressure of
869:
865:
849:
845:
841:
837:
803:
791:
779:
764:
710:molecular clouds
596:Natural graphite
571:carbon footprint
455:Natural graphite
405:
404:
401:
400:
397:
394:
391:
388:
385:
382:
301:Specific gravity
275:Metallic, earthy
262:
76:
75:(repeating unit)
47:
35:
34:
5747:
5746:
5742:
5741:
5740:
5738:
5737:
5736:
5727:Shades of black
5667:
5666:
5665:
5660:
5653:
5508:
5345:Coal combustion
5340:
5331:
5317:Bituminous coal
5287:
5281:
5276:
5246:
5241:
5203:
5194:Metallic carbon
5170:
5167:
5166:
5165:
5163:
5154:
5151:
5150:
5149:
5147:
5133:
5125:
5122:
5121:
5120:
5118:
5109:
5106:
5105:
5104:
5102:
5097:(atomic carbon)
5093:
5090:
5089:
5088:
5086:
5072:
5058:Carbon nanofoam
5039:
5031:
5028:
5027:
5026:
5024:
5015:
5012:
5011:
5010:
5008:
4989:
4954:
4944:
4910:
4900:Diamond (cubic)
4882:
4877:
4795:
4785:
4766:
4747:
4675:
4673:Further reading
4670:
4669:
4660:
4658:
4636:
4623:
4614:
4612:
4604:
4603:
4599:
4590:
4588:
4582:
4578:
4569:
4568:
4564:
4556:
4545:
4541:
4540:
4536:
4526:
4524:
4518:
4514:
4506:
4495:
4489:
4485:
4479:Wayback Machine
4469:
4465:
4458:
4444:
4440:
4416:
4412:
4388:
4382:
4378:
4363:
4349:
4345:
4312:
4308:
4285:
4281:
4257:
4253:
4229:
4225:
4216:
4214:
4210:
4160:
4153:
4149:
4141:
4137:
4127:
4125:
4120:
4119:
4115:
4105:
4103:
4099:
4092:
4088:
4087:
4083:
4068:
4064:
4054:
4052:
4048:
4041:
4037:
4036:
4032:
4023:
4021:
4008:
4007:
4003:
3988:
3984:
3967:
3963:
3954:
3952:
3943:
3942:
3938:
3929:
3928:
3924:
3901:
3897:
3882:
3878:
3839:
3835:
3806:
3802:
3793:
3791:
3786:
3785:
3762:
3743:
3739:
3726:
3722:
3695:
3691:
3682:
3681:
3677:
3667:
3665:
3656:
3652:
3645:
3631:
3624:
3607:
3606:
3602:
3591:
3590:
3586:
3579:
3563:
3559:
3550:
3548:
3541:
3537:
3529:
3523:
3508:
3502:
3498:
3477:(10): 925–931.
3466:
3462:
3438:
3429:
3422:
3408:
3404:
3391:
3390:
3386:
3377:
3375:
3366:
3365:
3361:
3352:
3348:
3340:
3329:
3325:
3324:
3320:
3314:Wayback Machine
3305:
3301:
3260:
3256:
3222:
3218:
3211:
3197:
3193:
3186:
3172:
3168:
3137:
3130:
3103:
3099:
3049:
3042:
3017:
3010:
2995:
2979:
2975:
2944:
2940:
2933:
2917:
2913:
2906:
2892:
2888:
2881:
2867:
2863:
2832:
2828:
2797:
2793:
2786:
2769:
2765:
2757:
2744:
2713:
2709:
2699:
2697:
2688:
2687:
2683:
2674:
2673:
2669:
2656:
2655:
2651:
2644:
2622:
2618:
2611:
2603:
2599:
2587:
2582:10.3133/pp1802J
2570:
2553:
2544:
2543:
2539:
2531:
2525:
2510:
2504:
2495:
2487:
2483:
2475:
2471:
2463:
2459:
2414:
2410:
2405:
2382:
2377:
2333:Carbon nanotube
2323:
2147:
2107:
2079:
2032:
1896:
1878:F-117 Nighthawk
1799:
1775:fusion reactors
1759:
1753:
1736:
1724:injection molds
1665:
1650:
1639:Acheson process
1620:
1615:
1608:
1604:
1596:superconductors
1593:
1585:Graphite forms
1581:
1572:
1566:
1532:
1500:
1488:
1480:artistic medium
1417:
1412:
1393:
1373:
1352:
1343:
1335:diamond battery
1273:
1220:
1212:
1129:
1120:
1105:froth flotation
1011:
953:stainless steel
914:Graphite is an
880:
871:
867:
863:
847:
843:
839:
832:
817:
810:
804:
795:
792:
783:
780:
771:
765:
722:
694:meteoritic iron
603:
598:
575:(LFP) batteries
567:
530:Acheson process
518:
457:
452:
379:
375:
260:
181:= 6.708 ;
159:
148:
132:: (6/m 2/m 2/m)
128:
74:
73:
50:
31:
24:
17:
12:
11:
5:
5745:
5735:
5734:
5729:
5724:
5719:
5714:
5709:
5704:
5699:
5694:
5692:Dry lubricants
5689:
5684:
5679:
5662:
5661:
5658:
5655:
5654:
5652:
5651:
5646:
5641:
5636:
5631:
5626:
5624:Mining regions
5621:
5616:
5611:
5606:
5601:
5596:
5591:
5586:
5585:
5584:
5579:
5574:
5569:
5564:
5559:
5554:
5552:homogenization
5549:
5539:
5534:
5529:
5524:
5518:
5516:
5510:
5509:
5507:
5506:
5501:
5499:Sulfur dioxide
5496:
5491:
5486:
5481:
5476:
5471:
5466:
5461:
5456:
5451:
5446:
5441:
5436:
5435:
5434:
5429:
5424:
5419:
5414:
5412:power in China
5409:
5404:
5399:
5394:
5389:
5379:
5374:
5369:
5364:
5359:
5354:
5348:
5346:
5342:
5341:
5334:
5332:
5330:
5329:
5324:
5319:
5314:
5309:
5304:
5299:
5293:
5291:
5283:
5282:
5275:
5274:
5267:
5260:
5252:
5243:
5242:
5240:
5239:
5234:
5229:
5224:
5219:
5213:
5211:
5205:
5204:
5202:
5201:
5199:Penta-graphene
5196:
5191:
5186:
5181:
5176:
5168:
5160:
5152:
5143:
5141:
5135:
5134:
5132:
5131:
5123:
5115:
5107:
5099:
5091:
5082:
5080:
5074:
5073:
5071:
5070:
5065:
5060:
5055:
5049:
5047:
5041:
5040:
5038:
5037:
5029:
5021:
5013:
5005:
4999:
4997:
4991:
4990:
4988:
4987:
4982:
4952:
4942:
4933:
4928:
4920:
4918:
4912:
4911:
4909:
4908:
4903:
4895:
4893:
4884:
4883:
4876:
4875:
4868:
4861:
4853:
4847:
4846:
4841:
4832:
4827:
4822:
4817:
4811:
4806:
4801:
4794:
4793:External links
4791:
4790:
4789:
4783:
4770:
4764:
4751:
4745:
4728:
4719:
4674:
4671:
4668:
4667:
4621:
4597:
4576:
4562:
4534:
4512:
4483:
4470:Cooper, Jeff.
4463:
4457:978-1563963582
4456:
4438:
4410:
4376:
4361:
4343:
4306:
4279:
4251:
4223:
4208:
4158:
4147:
4135:
4113:
4095:. Saylor.org.
4081:
4062:
4030:
4001:
3982:
3961:
3936:
3922:
3895:
3876:
3849:(1): 477–481.
3833:
3820:(3): 814–818.
3800:
3760:
3737:
3720:
3709:(2): 133–179.
3689:
3675:
3650:
3644:978-0824747824
3643:
3622:
3600:
3584:
3577:
3557:
3535:
3522:978-0521224963
3521:
3496:
3460:
3427:
3420:
3402:
3384:
3359:
3346:
3343:on 2009-02-27.
3318:
3299:
3272:(1): 101–107.
3254:
3216:
3209:
3191:
3184:
3166:
3147:(2): 141–153.
3128:
3117:(3): 473–506.
3097:
3040:
3008:
2993:
2973:
2938:
2931:
2911:
2904:
2886:
2879:
2861:
2826:
2791:
2784:
2763:
2742:
2729:(2): 413–420.
2722:Andean Geology
2707:
2681:
2667:
2649:
2642:
2616:
2597:
2551:
2537:
2524:978-0962209703
2523:
2493:
2481:
2469:
2457:
2428:(3): 291–320.
2407:
2406:
2404:
2401:
2399:, WIPO.
2381:
2378:
2376:
2375:
2370:
2365:
2360:
2355:
2350:
2345:
2340:
2335:
2330:
2324:
2322:
2319:
2311:nanocomposites
2297:area, related
2291:conductive ink
2276:Carbon brushes
2224:alternatives.
2198:flake graphite
2146:
2143:
2106:
2103:
2078:
2075:
2074:
2073:
2066:
2060:
2057:
2054:
2047:pneumoconiosis
2036:health effects
2031:
2028:
1910:, Netherlands.
1895:
1892:
1798:
1795:
1755:Main article:
1752:
1749:
1740:petroleum coke
1735:
1732:
1693:coal tar pitch
1689:petroleum coke
1685:steel furnaces
1664:
1661:
1649:
1646:
1619:
1616:
1614:
1611:
1606:
1602:
1591:
1579:
1568:Main article:
1565:
1562:
1531:
1528:
1508:electric motor
1499:
1496:
1487:
1486:Pinewood derby
1484:
1416:
1413:
1411:
1408:
1392:
1389:
1372:
1369:
1351:
1348:
1342:
1339:
1272:
1269:
1219:
1216:
1211:
1208:
1128:
1125:
1035:Marița culture
1010:
1007:
998:measured with
973:white graphite
930:delocalization
909:carbon dioxide
879:
876:
816:
815:Thermodynamics
813:
812:
811:
805:
798:
796:
793:
786:
784:
781:
774:
772:
766:
759:
721:
718:
602:
599:
597:
594:
566:
563:
555:supersaturated
522:graphitization
517:
514:
456:
453:
451:
448:
367:
366:
364:
360:
359:
356:
352:
351:
341:
335:
334:
331:
325:
324:
321:
317:
316:
315:2.09–2.23 g/cm
313:
307:
306:
303:
297:
296:
293:
287:
286:
283:
277:
276:
273:
267:
266:
263:
254:
253:
250:
244:
243:
240:
234:
233:
230:
224:
223:
220:
214:
213:
206:
200:
199:
196:
192:
191:
190:Identification
187:
186:
185: = 4
172:
166:
165:
157:
146:
140:
134:
133:
125:
119:
118:
109:
107:Crystal system
103:
102:
99:
93:
92:
89:
83:
82:
77:
67:
66:
64:Native mineral
61:
57:
56:
52:
51:
48:
40:
39:
15:
9:
6:
4:
3:
2:
5744:
5733:
5730:
5728:
5725:
5723:
5720:
5718:
5715:
5713:
5710:
5708:
5705:
5703:
5700:
5698:
5695:
5693:
5690:
5688:
5685:
5683:
5680:
5678:
5675:
5674:
5672:
5656:
5650:
5647:
5645:
5642:
5640:
5637:
5635:
5632:
5630:
5627:
5625:
5622:
5620:
5617:
5615:
5612:
5610:
5607:
5605:
5602:
5600:
5597:
5595:
5592:
5590:
5587:
5583:
5580:
5578:
5575:
5573:
5570:
5568:
5567:mining region
5565:
5563:
5560:
5558:
5555:
5553:
5550:
5548:
5545:
5544:
5543:
5540:
5538:
5535:
5533:
5530:
5528:
5525:
5523:
5520:
5519:
5517:
5515:
5511:
5505:
5502:
5500:
5497:
5495:
5492:
5490:
5487:
5485:
5482:
5480:
5477:
5475:
5472:
5470:
5467:
5465:
5462:
5460:
5457:
5455:
5452:
5450:
5447:
5445:
5442:
5440:
5437:
5433:
5430:
5428:
5425:
5423:
5420:
5418:
5415:
5413:
5410:
5408:
5405:
5403:
5400:
5398:
5395:
5393:
5390:
5388:
5385:
5384:
5383:
5380:
5378:
5375:
5373:
5370:
5368:
5365:
5363:
5360:
5358:
5355:
5353:
5350:
5349:
5347:
5343:
5338:
5328:
5325:
5323:
5320:
5318:
5315:
5313:
5310:
5308:
5305:
5303:
5300:
5298:
5295:
5294:
5292:
5284:
5280:
5273:
5268:
5266:
5261:
5259:
5254:
5253:
5250:
5238:
5235:
5233:
5230:
5228:
5225:
5223:
5220:
5218:
5215:
5214:
5212:
5210:
5206:
5200:
5197:
5195:
5192:
5190:
5187:
5185:
5182:
5180:
5177:
5175:
5174:(prismane C8)
5161:
5159:
5145:
5144:
5142:
5140:
5136:
5130:
5116:
5114:
5100:
5098:
5084:
5083:
5081:
5079:
5075:
5069:
5066:
5064:
5061:
5059:
5056:
5054:
5051:
5050:
5048:
5046:
5042:
5036:
5022:
5020:
5006:
5004:
5001:
5000:
4998:
4996:
4992:
4986:
4985:Glassy carbon
4983:
4980:
4979:
4974:
4973:
4968:
4967:
4962:
4961:
4956:
4955:
4947:
4946:
4937:
4934:
4932:
4929:
4927:
4926:
4922:
4921:
4919:
4917:
4913:
4907:
4904:
4902:
4901:
4897:
4896:
4894:
4892:
4891:
4885:
4881:
4874:
4869:
4867:
4862:
4860:
4855:
4854:
4851:
4845:
4842:
4840:
4836:
4833:
4831:
4828:
4826:
4823:
4821:
4818:
4815:
4812:
4810:
4807:
4805:
4802:
4800:
4797:
4796:
4786:
4780:
4776:
4771:
4767:
4761:
4757:
4752:
4748:
4742:
4737:
4736:
4729:
4725:
4720:
4716:
4712:
4707:
4702:
4698:
4694:
4691:(3777): 328.
4690:
4686:
4682:
4677:
4676:
4657:
4653:
4649:
4645:
4641:
4634:
4632:
4630:
4628:
4626:
4611:
4607:
4601:
4587:
4580:
4572:
4566:
4555:
4551:
4544:
4538:
4523:
4516:
4505:
4501:
4494:
4487:
4480:
4476:
4473:
4467:
4459:
4453:
4449:
4442:
4434:
4430:
4426:
4422:
4414:
4406:
4402:
4398:
4394:
4387:
4380:
4372:
4368:
4364:
4362:0-8155-1339-9
4358:
4354:
4347:
4339:
4335:
4330:
4325:
4322:: 1122–1129.
4321:
4317:
4310:
4302:
4298:
4294:
4290:
4283:
4275:
4271:
4267:
4263:
4255:
4247:
4243:
4239:
4235:
4227:
4219:
4212:
4204:
4200:
4195:
4190:
4186:
4182:
4178:
4174:
4171:(4): 044102.
4170:
4166:
4162:
4151:
4144:
4139:
4123:
4117:
4098:
4091:
4085:
4077:
4073:
4066:
4047:
4040:
4034:
4020:on 2015-03-17
4019:
4015:
4011:
4005:
3997:
3993:
3986:
3978:
3977:
3972:
3965:
3950:
3946:
3940:
3932:
3926:
3918:
3914:
3910:
3906:
3899:
3891:
3887:
3880:
3872:
3868:
3864:
3860:
3856:
3852:
3848:
3844:
3837:
3828:
3823:
3819:
3815:
3811:
3804:
3789:
3783:
3781:
3779:
3777:
3775:
3773:
3771:
3769:
3767:
3765:
3756:
3752:
3748:
3741:
3733:
3732:
3724:
3716:
3712:
3708:
3704:
3700:
3693:
3685:
3679:
3663:
3662:
3654:
3646:
3640:
3636:
3629:
3627:
3618:
3614:
3610:
3604:
3596:
3595:
3588:
3580:
3574:
3570:
3569:
3561:
3546:
3539:
3528:
3524:
3518:
3514:
3507:
3500:
3492:
3488:
3484:
3480:
3476:
3472:
3464:
3456:
3452:
3448:
3444:
3436:
3434:
3432:
3423:
3421:9780080455969
3417:
3413:
3406:
3398:
3394:
3388:
3374:on 2007-10-15
3373:
3369:
3363:
3357:. graflex.org
3356:
3350:
3339:
3335:
3328:
3322:
3315:
3311:
3308:
3303:
3295:
3291:
3287:
3283:
3279:
3275:
3271:
3267:
3266:
3258:
3250:
3246:
3241:
3236:
3232:
3228:
3220:
3212:
3210:9781891389320
3206:
3202:
3195:
3187:
3185:9789814241526
3181:
3177:
3170:
3162:
3158:
3154:
3150:
3146:
3142:
3135:
3133:
3124:
3120:
3116:
3112:
3108:
3101:
3093:
3089:
3085:
3081:
3077:
3073:
3068:
3063:
3059:
3055:
3047:
3045:
3038:
3034:
3030:
3026:
3025:
3020:
3015:
3013:
3004:
3000:
2996:
2994:0-8155-1739-4
2990:
2986:
2985:
2977:
2969:
2965:
2961:
2957:
2953:
2949:
2942:
2934:
2928:
2925:. CRC Press.
2924:
2923:
2915:
2907:
2905:9780815517399
2901:
2897:
2890:
2882:
2880:9789056992286
2876:
2872:
2865:
2857:
2853:
2849:
2845:
2841:
2837:
2830:
2822:
2818:
2814:
2810:
2807:(1): 79–107.
2806:
2802:
2795:
2787:
2785:9789814481373
2781:
2777:
2773:
2772:Lugaro, Maria
2767:
2760:
2755:
2753:
2751:
2749:
2747:
2737:
2732:
2728:
2724:
2723:
2718:
2711:
2695:
2691:
2685:
2677:
2671:
2663:
2659:
2653:
2645:
2639:
2635:
2631:
2627:
2620:
2607:
2601:
2594:
2593:public domain
2583:
2579:
2575:
2568:
2566:
2564:
2562:
2560:
2558:
2556:
2547:
2541:
2530:
2526:
2520:
2516:
2509:
2502:
2500:
2498:
2490:
2485:
2479:. Mindat.org.
2478:
2473:
2466:
2461:
2453:
2449:
2444:
2439:
2435:
2431:
2427:
2423:
2419:
2412:
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2398:
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2329:
2326:
2325:
2318:
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2312:
2308:
2307:nanomaterials
2304:
2300:
2296:
2292:
2288:
2284:
2280:
2277:
2273:
2271:
2267:
2262:
2258:
2255:Graphite for
2253:
2250:
2247:Graphite for
2245:
2243:
2238:
2234:
2229:
2225:
2222:
2217:
2215:
2211:
2205:
2203:
2199:
2194:
2192:
2188:
2187:United States
2184:
2180:
2176:
2172:
2168:
2159:
2151:
2142:
2140:
2136:
2132:
2126:
2124:
2119:
2116:
2111:
2102:
2100:
2096:
2092:
2088:
2084:
2077:United States
2071:
2067:
2064:
2061:
2058:
2055:
2052:
2048:
2044:
2041:
2040:
2039:
2037:
2027:
2025:
2021:
2017:
2013:
2012:United States
2009:
2005:
2001:
1997:
1993:
1989:
1985:
1981:
1976:
1974:
1970:
1965:
1961:
1957:
1951:
1949:
1945:
1941:
1937:
1936:beneficiation
1933:
1924:
1916:
1909:
1905:
1900:
1891:
1888:
1886:
1881:
1879:
1875:
1871:
1868:
1864:
1859:
1857:
1856:static charge
1853:
1848:
1846:
1842:
1838:
1834:
1830:
1827:
1823:
1819:
1815:
1811:
1807:
1803:
1794:
1792:
1788:
1784:
1780:
1776:
1772:
1768:
1764:
1758:
1748:
1746:
1741:
1731:
1729:
1725:
1721:
1717:
1714:Electrolytic
1712:
1710:
1706:
1702:
1698:
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1690:
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1541:
1540:sulfuric acid
1537:
1527:
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1521:
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1513:
1509:
1505:
1495:
1493:
1483:
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1475:
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1469:
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1461:
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1453:
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1446:
1445:Ancient Greek
1442:
1438:
1434:
1430:
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1404:
1399:
1388:
1386:
1382:
1378:
1371:Brake linings
1368:
1366:
1362:
1357:
1347:
1338:
1336:
1332:
1328:
1324:
1319:
1317:
1313:
1309:
1308:mobile phones
1305:
1301:
1297:
1293:
1289:
1284:
1282:
1278:
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1261:
1258:
1254:
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1246:
1245:blast furnace
1240:
1237:
1233:
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1215:
1207:
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1197:
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1028:
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1003:
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995:contact angle
991:
989:
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981:
976:
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966:
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853:
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825:phase diagram
821:
809:
802:
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623:igneous rocks
620:
616:
612:
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560:
556:
552:
551:crystallizing
548:
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500:
499:metamorphosed
496:
492:
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476:crystallinity
473:
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205:
204:Crystal habit
201:
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184:
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176:
173:
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123:Crystal class
120:
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5644:Refined coal
5557:liquefaction
5449:Energy value
5326:
5232:Carbon fiber
5222:Carbon black
5208:
5189:Cubic carbon
5138:
5077:
5044:
4994:
4976:
4970:
4964:
4958:
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4644:www.wipo.int
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4084:
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4046:the original
4033:
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4018:the original
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2693:
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2540:
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2472:
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2395:
2391:free content
2383:
2328:Carbon fiber
2281:
2274:
2254:
2246:
2230:
2226:
2218:
2206:
2195:
2164:
2127:
2120:
2115:refractories
2112:
2108:
2080:
2033:
1977:
1956:oil drilling
1952:
1929:
1889:
1882:
1860:
1849:
1818:fishing rods
1800:
1783:World War II
1760:
1737:
1713:
1666:
1651:
1643:
1636:
1621:
1599:
1584:
1536:chromic acid
1533:
1501:
1489:
1476:
1472:
1459:
1449:
1440:
1436:
1432:
1426:
1410:Everyday use
1394:
1374:
1353:
1344:
1320:
1285:
1274:
1262:
1250:
1241:
1232:refractories
1221:
1218:Refractories
1213:
1183:
1178:
1173:
1171:
1160:
1144:
1140:
1138:
1127:Other names
1114:
1108:
1102:
1089:
1084:and partner
1082:Joseph Dixon
1075:
1043:
1024:
1004:
992:
977:
972:
961:US Air Force
942:
913:
889:
852:triple point
830:
753:rhombohedral
748:
740:
738:
723:
706:Solar System
679:
619:metamorphism
604:
582:
568:
543:hydrocarbons
519:
503:carbonaceous
488:carbonaceous
484:metamorphism
464:
460:
458:
428:refractories
371:
370:
323:Uniaxial (−)
182:
178:
174:
161:
153:
149:
142:
116:Rhombohedral
32:
5514:Coal mining
5464:Fossil fuel
5184:Haeckelites
5129:(tricarbon)
5078:other forms
4978:Nanoscrolls
4610:www.cdc.gov
4399:: 497–517.
3911:: 147–170.
2363:Lonsdaleite
2358:Intumescent
2016:Adirondacks
2008:North Korea
1973:heavy metal
1887:beam dump.
1787:heavy water
1628:carborundum
1377:brake shoes
1365:steelmakers
1356:steelmaking
1350:Steelmaking
1316:Nissan Leaf
1300:power tools
1196:molybdenite
1121: 1900
1066:Elizabeth I
1046:Grey Knotts
984:diamagnetic
945:lubricating
934:aromaticity
900:anisotropic
874:is needed.
872:35 GPa
868:2000 K
864:4500 K
848:5000 K
844:12 GPa
696:are called
615:sedimentary
579:New Zealand
565:Biographite
526:hydrocarbon
510:metamorphic
465:crystalline
408:crystalline
329:Pleochroism
291:Diaphaneity
138:Space group
5671:Categories
5537:Coalfields
5322:Anthracite
4936:Fullerenes
4661:2023-11-13
4615:2015-11-03
4591:2020-02-22
4527:19 January
4427:: 91–108.
4329:1501.06679
4024:2013-02-15
3971:"graphite"
3955:2019-06-20
3794:2009-09-09
3551:2008-05-19
3378:2009-06-06
3067:1908.06284
2700:9 December
2690:"Graphite"
2574:"Graphite"
2508:"Graphite"
2403:References
2303:inventions
2283:Biomedical
2261:refractory
2043:Inhalation
2038:include:
2034:Potential
1829:cue sticks
1797:Other uses
1769:. Its low
1679:(DRI), in
1673:scrap iron
1669:electrodes
1663:Electrodes
1553:fuel cells
1551:plates in
1498:Other uses
1435:, meaning
1398:lubricants
1327:beta decay
1296:CD players
1281:electrodes
1224:refractory
1174:black lead
1141:black lead
1070:refractory
1050:Seathwaite
923:electrodes
860:metastable
714:supernovae
698:cliftonite
682:meteorites
663:Madagascar
643:tourmaline
627:meteorites
601:Occurrence
480:grain size
472:morphology
440:lubricants
363:References
339:Solubility
258:Mohs scale
152:(buckled)
87:IMA symbol
5649:Whitedamp
5634:Peak coal
5629:Outbursts
5532:Coal dust
5522:Blackdamp
5427:seam fire
5402:phase-out
4966:Nanotubes
4240:: 58–80.
3871:137571156
3609:"History"
3449:: 33–39.
3294:250886376
3240:1303.2757
3092:125322808
2968:189839788
2606:US 836355
2452:235729616
2343:Fullerene
2123:crucibles
2063:Ingestion
2051:emphysema
1837:cast iron
1697:carbonize
1667:Graphite
1548:fire door
1544:firestops
1512:waste oil
1323:carbon-14
1271:Batteries
1236:magnesite
1228:crucibles
1172:The term
1167:plumbagos
1031:Neolithic
833:1.7
827:of carbon
808:unit cell
745:hexagonal
720:Structure
611:reduction
591:Hong Kong
461:amorphous
436:foundries
177:= 2.461,
170:Unit cell
112:Hexagonal
5677:Graphite
5599:Firedamp
5454:Flue gas
5377:Charcoal
5352:Ash pond
5327:Graphite
5227:Charcoal
5068:Q-carbon
4995:sp forms
4972:Nanobuds
4931:Graphene
4925:Graphite
4916:sp forms
4775:Graphite
4756:Graphite
4715:36502694
4554:Archived
4552:. USGS.
4504:Archived
4475:Archived
4371:8048799M
4203:27878015
4128:July 28,
4097:Archived
3491:23872731
3310:Archived
3003:49708274
2836:Elements
2774:(2005).
2759:graphite
2662:euronews
2529:Archived
2489:Graphite
2477:Graphite
2348:Graphene
2321:See also
2315:graphene
2266:carbides
2202:research
2189:and the
2131:Leaching
2018:of NY.
1982:(USGS),
1932:open pit
1870:snorkels
1728:plastics
1516:smokebox
1460:Plumbago
1437:to write
1381:asbestos
1184:graphite
1145:plumbago
1109:E&MJ
1021:, Canada
1019:Kimmirut
951:in some
927:electron
920:arc lamp
902:, since
892:acoustic
840:0 K
726:graphene
702:isotopic
686:troilite
667:Colombia
547:carbides
534:vaporize
420:graphene
372:Graphite
261:hardness
248:Tenacity
238:Fracture
228:Cleavage
218:Twinning
210:foliated
101:1.CB.05a
60:Category
38:Graphite
28:Graphene
5459:Fly ash
5307:Lignite
5209:related
5179:Chaoite
4693:Bibcode
4194:5099629
4173:Bibcode
4106:2 April
4076:Sybaris
3890:Targray
3851:Bibcode
3668:6 April
3274:Bibcode
3149:Bibcode
3072:Bibcode
2844:Bibcode
2809:Bibcode
2430:Bibcode
2380:Sources
2249:polymer
2237:battery
2214:battery
1960:foundry
1850:Modern
1765:within
1632:silicon
1520:firebox
1464:drawing
1415:Pencils
1312:tablets
1304:Laptops
1162:plumbum
1149:massive
1078:pencils
1062:England
1058:Cumbria
1039:pottery
904:phonons
896:thermal
675:schists
635:calcite
625:and in
587:Finland
444:diamond
438:(10%),
434:(18%),
430:(50%),
406:) is a
347:, warm
311:Density
305:1.9–2.3
222:Present
71:Formula
55:General
5577:slurry
5572:refuse
5444:Coking
5362:Asthma
4781:
4762:
4743:
4713:
4685:Nature
4454:
4393:Carbon
4369:
4359:
4234:Carbon
4201:
4191:
3869:
3790:. USGS
3757:: 238.
3641:
3575:
3519:
3489:
3443:Carbon
3418:
3292:
3207:
3182:
3141:Carbon
3090:
3001:
2991:
2966:
2929:
2902:
2877:
2782:
2640:
2612:
2521:
2450:
2289:, and
2287:sensor
2221:carbon
2185:, the
2181:, the
2167:patent
2121:While
2004:Turkey
2000:Brazil
1988:tonnes
1940:gangue
1908:Leiden
1867:U-boat
1701:binder
1522:. The
1257:RHI AG
1204:galena
1157:galena
965:pencil
747:) and
661:, and
659:Brazil
655:Canada
651:Mexico
631:quartz
559:carbon
549:or by
478:, and
416:layers
412:carbon
345:nickel
333:Strong
281:Streak
271:Luster
164:(flat)
5297:Xylit
4890:forms
4711:S2CID
4557:(PDF)
4546:(PDF)
4507:(PDF)
4496:(PDF)
4389:(PDF)
4324:arXiv
4100:(PDF)
4093:(PDF)
4049:(PDF)
4042:(PDF)
3867:S2CID
3530:(PDF)
3509:(PDF)
3341:(PDF)
3330:(PDF)
3290:S2CID
3235:arXiv
3088:S2CID
3062:arXiv
3019:IUPAC
2964:S2CID
2532:(PDF)
2511:(PDF)
2448:S2CID
2242:anode
2210:anode
2179:Japan
2175:China
1996:India
1992:China
1964:steel
1841:resin
1779:boron
1705:steel
1277:anode
1253:tonne
741:alpha
647:China
639:micas
557:with
541:from
285:Black
195:Color
5582:town
5542:Coal
5494:Smog
5439:Coke
5382:Coal
5372:Char
5302:Peat
5279:Coal
4779:ISBN
4760:ISBN
4741:ISBN
4648:WIPO
4529:2019
4452:ISBN
4357:ISBN
4199:PMID
4130:2022
4108:2012
4057:2013
3670:2018
3639:ISBN
3573:ISBN
3517:ISBN
3487:PMID
3416:ISBN
3205:ISBN
3180:ISBN
2999:OCLC
2989:ISBN
2927:ISBN
2900:ISBN
2875:ISBN
2780:ISBN
2702:2018
2638:ISBN
2519:ISBN
2313:and
2139:mesh
2081:The
1826:pool
1824:and
1804:and
1726:for
1709:USGS
1699:the
1456:lead
1441:draw
1403:USGS
1385:USGS
1361:USGS
1298:and
1290:and
1265:USGS
1153:lead
894:and
890:The
842:and
749:beta
688:and
641:and
495:Coal
5547:gas
5489:NOx
5432:tar
5397:gas
4888:sp
4701:doi
4689:149
4652:doi
4429:doi
4425:511
4401:doi
4397:110
4334:doi
4320:470
4297:doi
4270:doi
4242:doi
4238:178
4189:PMC
4181:doi
3913:doi
3859:doi
3822:doi
3711:doi
3479:doi
3451:doi
3282:doi
3245:doi
3157:doi
3119:doi
3080:doi
3033:doi
3031:".
2956:doi
2852:doi
2817:doi
2731:doi
2630:doi
2578:doi
2438:doi
1443:in
1439:or
1198:),
1143:or
1052:in
1027:BCE
846:at
838:at
835:GPa
680:In
669:'s
613:of
486:of
469:ore
418:of
265:1–2
162:mmc
114:or
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