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amplified photoresists for micro and nanofabrication. This widely used patented technology which enables the extreme miniaturization of microelectronic devices is now ubiquitous for the fabrication of the very powerful computing and communication equipment in worldwide use. The addition of photogenerated bases led to additional advances in chemically amplified resists. In 1990 working with Craig Hawker at
Cornell, he developed the convergent synthesis of dendrimers as well as approaches to hyperbranched polymers. In 1992, working with F. Svec at Cornell, he reported the first preparation of macroporous polymer monoliths that are now used in a variety of chemical separations. Later work at Berkeley saw the development of polymers and dendrimers as carriers for targeted therapeutics and successful approaches to new organic materials for transistors and solar cells.
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and
Forestry, and at Syracuse University (Ph.D. 1971). He was on the Chemistry Faculty at the University of Ottawa in Canada from 1973 to 1987, when he became the IBM Professor of Polymer Chemistry at Cornell University. In 1997 Fréchet joined Chemistry faculty at the University of California, Berkeley and was named the Henry Rapoport Chair of Organic Chemistry in 2003 and Professor of Chemical and Biological Engineering in 2005. From 2010 to 2019 he served as the first Vice President for Research, then Senior Vice-President for Research, Innovation, and Economic Development at the King Abdullah University of Science and Technology.
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477:. He is best known for his work on polymers including polymer-supported chemistry, chemically amplified photoresists, dendrimers, macroporous separation media, and polymers for therapeutics. Ranked among the top 10 chemists in 2021, he has authored nearly 900 scientific paper and 200 patents including 96 US patents. His research areas include
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Fréchet received his first university degree at the Institut de Chimie et
Physique Industrielles (now CPE) in Lyon, France, before coming to the US for studies in organic and polymer chemistry under Conrad Schuerch at the State University of New York College of Environmental Science
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Fréchet’s early work focused on polymer-supported chemistry with the first approach to the solid-phase synthesis of oligosaccharides and pioneering work on polymeric reagents and polymer protecting groups. In 1979 Working with C.G. Willson at IBM during a sabbatical leave, he invented chemically
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Ito, H., Willson. C.G., Fréchet, J.M.J Positive and
Negative Working Resist Compositions with Acid-Generating Photoinitiator and Polymer with Acid-Labile Groups Pendant From Polymer Backbone. US Patent No. 4,491,628 issued January 1,
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Fréchet, J.M.J.; Schuerch, C. Solid-Phase
Synthesis of Oligosaccharides. III. Preparation of Some Derivatives of di- and tri- saccharides via a simple Alcoholysis Reaction. Carbohyd. Res., 1972, 22, 399–412
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Beaujuge, P.M.; Frechet, J.M.J. Molecular Design and
Ordering Effects in pi-Functional Materials for Transistor and Solar Cell Applications – A Perspective. J. Am. Chem. Soc. 2011, 133, 20009-20029
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Tomalia, D. A.; Fréchet, J.M. J. Discovery of dendrimers and dendritic polymers: a brief historical perspective. 2002, Journal of
Polymer Science, Part A: Polymer Chemistry 40, 2719–2728
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Hawker, C.J.; Fréchet, J.M.J. Preparation of
Polymers with Controlled Molecular Architecture: A New Convergent Approach to Dendritic Macromolecules. J. Am. Chem. Soc. 1990, 112, 7638–47
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Fox, M.E.; Szoka, F.C.; Fréchet, J.M.J.; Soluble polymer carriers for the treatment of cancer: the importance of molecular architecture. Accounts Chem Res. 2009. 42, 1141–1151
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Svec, F.; Fréchet, J.M.J. Novel continuous rods of macroporous polymer as High-Performance Liquid
Chromatography Separation Media. Analytical Chemistry 1992, 64, 820–822
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Fréchet, J.M.J.; Ito, H.; Willson, C.G. Sensitive Deep UV Resist
Incorporating Chemical Amplification. Proceedings Microcircuit Engineering 1982, Grenoble, 260–261
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2006 Macro Group UK Medal (joint Royal Society for Chemistry and Society of Chemical Industry) for Outstanding Achievement in the field of Macromolecular Chemistry
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2009 Society of Polymer Science of Japan, International Award for the "Development of functional polymers from fundamentals to applications".
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Fréchet, J.M.J. Synthesis and Applications of Organic Polymers as Supports and Protecting Groups. Tetrahedron, 1981, 37, 663–83
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for the "Development of chemically amplified resist polymer materials for innovative semiconductor manufacturing process"
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with emphasis on the design, fundamental understanding, synthesis, and applications of functional
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Tobin, Dave. (2013, January 30). "SUNY ESF alumnus Jean Fréchet wins Japan Prize,"
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1996 American Chemical Society, ACS Award in Applied Polymer Science
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1999 Society of Imaging Science and Technology, Kosar Memorial Award
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2010 University of California Department of Chemistry Teaching Award
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Berkeley College of Chemistry, Emeriti Faculty, Jean M. J. Fréchet
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1995 Peter J. Debye Chair of Chemistry, Cornell University, NY
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2000 American Chemical Society, ACS Award in Polymer Chemistry
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from the article and its talk page, especially if potentially
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Members of the United States National Academy of Engineering
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Frechet, J.M.J. Pure & Appl. Chem., 1992, 64, 1239–1248
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2001 American Chemical Society, Salute to Excellence Award
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2002 Docteur (Honoris Causa), Université de Lyon I, France
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Members of the United States National Academy of Sciences
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2004 Docteur de L'Université, Université d'Ottawa, Canada
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2009 Arun Guthikonda Memorial Award, Columbia University.
702:& Muriel S. Bender Distinguished Summer Lectureship
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2001 American Chemical Society, A.C. Cope Scholar Award
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2008 D.Sc. (Honoris Causa), University of Liverpool, UK
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2005 Chemical Communications 40th Anniversary Award
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American Association for the Advancement of Science
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730:1983 IUPAC Canadian National Committee Award
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