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Maillard reaction

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is an entirely different process from Maillard browning, though the results of the two processes are sometimes similar to the naked eye (and taste buds). Caramelization may sometimes cause browning in the same foods in which the Maillard reaction occurs, but the two processes are distinct. They are
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In the cooking process, Maillard reactions can produce hundreds of different flavor compounds depending on the chemical constituents in the food, the temperature, the cooking time, and the presence of air. These compounds, in turn, often break down to form yet more flavor compounds.
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Stadler, Richard H.; Robert, Fabien; Riediker, Sonja; Varga, Natalia; Davidek, Tomas; Devaud, Stéphanie; Goldmann, Till; Hau, Jörg; Blank, Imre (August 2004). "In-Depth Mechanistic Study on the Formation of Acrylamide and Other Vinylogous Compounds by the Maillard Reaction".
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The browning reactions that occur when meat is roasted or seared are complex and occur mostly by Maillard browning with contributions from other chemical reactions, including the breakdown of the tetrapyrrole rings of the muscle protein
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or browning of skin tones and can turn hair to a red or ginger tone. The chemical mechanism is the same as in the browning of food, but it develops slowly over time due to the acidic action on the
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of the amino acid and forms a complex mixture of poorly characterized molecules responsible for a range of aromas and flavors. This process is accelerated in an alkaline environment (e.g.,
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steaks, fried dumplings, cookies and other kinds of biscuits, breads, toasted marshmallows, falafel and many other foods undergo this reaction. It is named after French chemist
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Harrison, T. J.; v, G. R. (2005). "An expeditious, high-yielding construction of the food aroma compounds 6-acetyl-1,2,3,4-tetrahydropyridine and 2-acetyl-1-pyrroline".
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is responsible for the biscuit or cracker-like flavor present in baked goods such as bread, popcorn, and tortilla products. The structurally related compound
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Tareke, E.; Rydberg, P.; Karlsson, Patrik; Eriksson, Sune; Törnqvist, Margareta (2002). "Analysis of acrylamide, a carcinogen formed in heated foodstuffs".
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have used the Maillard reaction over the years to make artificial flavors, the majority of patents being related to the production of meat-like flavors.
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bodies and was described by Painter in 1991 as the interaction of anaerobic, acidic, and cold (typically 4 °C (39 °F)) sphagnum acid on the
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In a dry environment, the Maillard reaction—the same chemical process that browns a steak—causes feces to develop a protective outer shell.
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Mottram, Donald S.; Wedzicha, Bronislaw L.; Dodson, Andrew T. (October 2002). "Acrylamide is formed in the Maillard reaction".
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has a similar smell and also occurs naturally without heating. The compound gives varieties of cooked rice and the herb
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published a paper describing the reaction between amino acids and sugars at elevated temperatures. In 1953, chemist
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products undergo further dehydration and deamination to produce dicarbonyls. This is a crucial intermediate.
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call for an oven temperature high enough to ensure that a Maillard reaction occurs. At higher temperatures,
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both promoted by heating, but the Maillard reaction involves amino acids, whereas caramelization is the
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Hodge, J. E. (1953). "Dehydrated Foods, Chemistry of Browning Reactions in Model Systems".
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which typically proceeds rapidly from around 140 to 165 °C (280 to 330 °F). Many
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Champagne: The Essential Guide to the Wines, Producers, and Terroirs of the Iconic Region
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The Maillard reaction is responsible for many colors and flavors in foods, such as the
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Virk-Baker, Mandeep K.; Nagy, Tim R.; Barnes, Stephen; Groopman, John (29 May 2014).
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of the sugar reacts with the amino group of the amino acid, producing N-substituted
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The preparation of French fries at high temperature can lead to the formation of
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can form. This can be discouraged by heating at a lower temperature, adding
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In archaeology, the Maillard process occurs when bodies are preserved in
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Dicarbonyls react with amines to produce Strecker aldehydes through
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Miranda, Gonzalo; Berna, Angel; Mulet, Antonio (4 February 2019).
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Nursten, Harry (2007). "The Chemistry of Nonenzymic Browning".
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Several ways are known for the ketosamines to react further:
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The Maillard reaction also contributes to the preservation of
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of various meats when seared or grilled, the browning and
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On Food and Cooking: The Science and Lore of the Kitchen
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Danehy, James P. (May 19, 1986). Chicester, C.O. (ed.).
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and other crisps, browning of malted barley as found in
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industry's recipes. At high temperatures, a probable
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The acidic peat environment causes a 14: 1920: 1205:. Cancer.org. Retrieved on 2016-07-24. 1077: 882: 814: 708: 1365: 949: 855: 770: 724:International Journal of Food Science 446:The unstable glycosylamine undergoes 429: 230: 88: 1103: 1025: 1320:Nutritional Ecology of the Ruminant 659: 365:. Maillard reactions also occur in 317:6-Acetyl-2,3,4,5-tetrahydropyridine 239:6-Acetyl-2,3,4,5-tetrahydropyridine 24: 1311: 25: 1944: 1343: 885:"The Maillard Reaction Turns 100" 883:Everts, Sarah (October 1, 2012). 1902: 1901: 1482: 1349: 544: 530: 502: 488: 459:Produce two water molecules and 337:below 0.06 nanograms per liter. 155:applied to darken pretzels; see 52: 1257: 1208: 1196: 1160: 1127: 1104:Dove, Alan (11 February 2016). 1097: 1071: 1030:. Ten Speed Press. p. 66. 1019: 968: 907: 889:Chemical & Engineering News 718:Tamanna, N; Mahmood, N (2015). 635:Chichester, C. O., ed. (1986). 476:fission products can be formed. 199:, or injecting carbon dioxide. 808: 679: 653: 628: 566:Advanced glycation end-product 394: 225:U.S. Department of Agriculture 179:, and hence have an increased 13: 1: 1051:Krystal, Becky (2020-01-31). 591: 144:of the sugar reacts with the 1317:Van Soest, Peter J. (1982). 1233:10.1080/01635581.2014.916323 693:. 2021-09-06. Archived from 271:, the golden-brown color of 121:. The reaction is a form of 7: 1144:10.1039/9781847552570-00005 1078:Cooper, Phil (2 May 2017). 581: 561:Akabori amino-acid reaction 537: 10: 1949: 901:10.1021/cen-09040-scitech2 660:Bui, Andrew (2017-09-29). 411:. It is typically seen on 210: 1899: 1818: 1777: 1716: 1653:Chorleywood bread process 1628: 1562: 1491: 1480: 1399: 1391: 824:Advances in Food Research 637:Advances in Food Research 472:, and other short-chain 159:), as the amino groups ( 830:. Academic Press: 107. 330:Pandanus amaryllifolius 1106:"Hard-core sequencing" 950:McGee, Harold (2004). 357: 345: 248: 240: 217:Louis Camille Maillard 123:non-enzymatic browning 115:Louis Camille Maillard 43: 1136:The Maillard Reaction 448:Amadori rearrangement 351: 343: 246: 238: 33: 1358:at Wikimedia Commons 1221:Nutrition and Cancer 1026:Liem, Peter (2017). 994:10.3390/foods8020056 511:Strecker degradation 321:2-acetyl-1-pyrroline 307:toasted marshmallows 1278:2002Natur.419..448M 1058:The Washington Post 870:10.1021/jf60015a004 782:J. Agric. Food Chem 737:10.1155/2015/526762 519:, a possible human 384:of certain sugars. 373:ages in the bottle 34:The crusts of most 1509:Calcium propanoate 430:Chemical mechanism 358: 346: 249: 241: 231:Foods and products 44: 1915: 1914: 1831:Brand name breads 1668:Maillard reaction 1514:Dough conditioner 1356:Maillard reaction 1354:Media related to 1272:(6906): 448–449. 1182:10.1021/jf0495486 1176:(17): 5550–5558. 1153:978-0-85404-964-6 1138:. pp. 5–30. 961:978-0-684-80001-1 929:10.1021/jo051940a 794:10.1021/jf020302f 788:(17): 4998–5006. 247:2-Acetylpyrroline 205:Flavor scientists 119:protein synthesis 95:chemical reaction 48:Maillard reaction 18:Maillard browning 16:(Redirected from 1940: 1905: 1904: 1876:Sourdough breads 1866:Pakistani breads 1810:History of bread 1795:Baker percentage 1693:Sponge and dough 1486: 1386: 1379: 1372: 1363: 1362: 1353: 1306: 1305: 1261: 1255: 1254: 1244: 1212: 1206: 1200: 1194: 1193: 1164: 1158: 1157: 1131: 1125: 1124: 1119: 1117: 1101: 1095: 1094: 1092: 1090: 1084:Farm Consultancy 1075: 1069: 1068: 1066: 1065: 1048: 1042: 1041: 1023: 1017: 1016: 1006: 996: 972: 966: 965: 947: 941: 940: 923:(26): 10872–74. 911: 905: 904: 880: 874: 873: 853: 847: 846: 844: 842: 821: 812: 806: 805: 777: 768: 767: 757: 739: 715: 706: 705: 703: 702: 683: 677: 676: 674: 672: 657: 651: 650: 632: 626: 625: 604: 586: 554: 549: 548: 534: 506: 492: 174: 169: 168: 165: 92: 87: 81: 75: 74: 71: 70: 67: 64: 61: 58: 21: 1948: 1947: 1943: 1942: 1941: 1939: 1938: 1937: 1918: 1917: 1916: 1911: 1895: 1826:American breads 1814: 1805:Bread in Europe 1773: 1712: 1630: 1624: 1620:Weighing scales 1558: 1534:Leavening agent 1487: 1478: 1395: 1390: 1346: 1314: 1312:Further reading 1309: 1286:10.1038/419448a 1262: 1258: 1213: 1209: 1201: 1197: 1165: 1161: 1154: 1132: 1128: 1115: 1113: 1102: 1098: 1088: 1086: 1076: 1072: 1063: 1061: 1049: 1045: 1038: 1024: 1020: 973: 969: 962: 948: 944: 912: 908: 881: 877: 854: 850: 840: 838: 819: 813: 809: 778: 771: 716: 709: 700: 698: 691:Home Cook World 685: 684: 680: 670: 668: 658: 654: 647: 633: 629: 608:Maillard, L. C. 605: 598: 594: 589: 550: 543: 540: 495:The open-chain 432: 417:polysaccharides 397: 335:odor thresholds 311:roasted peanuts 265:coffee roasting 233: 213: 181:nucleophilicity 173: 166: 163: 162: 160: 103:reducing sugars 90:[majaʁ] 85: 79: 55: 51: 38:, such as this 28: 23: 22: 15: 12: 11: 5: 1946: 1936: 1935: 1933:Name reactions 1930: 1928:Food chemistry 1913: 1912: 1900: 1897: 1896: 1894: 1893: 1888: 1883: 1878: 1873: 1868: 1863: 1858: 1853: 1848: 1846:British breads 1843: 1838: 1833: 1828: 1822: 1820: 1816: 1815: 1813: 1812: 1807: 1802: 1800:Bread and salt 1797: 1792: 1787: 1781: 1779: 1775: 1774: 1772: 1771: 1766: 1761: 1756: 1751: 1746: 1741: 1736: 1731: 1726: 1720: 1718: 1714: 1713: 1711: 1710: 1708:Vienna process 1705: 1703:Straight dough 1700: 1695: 1690: 1685: 1680: 1675: 1673:No-knead bread 1670: 1665: 1660: 1655: 1650: 1645: 1640: 1634: 1632: 1626: 1625: 1623: 1622: 1617: 1612: 1607: 1602: 1597: 1592: 1587: 1582: 1577: 1572: 1566: 1564: 1560: 1559: 1557: 1556: 1551: 1546: 1541: 1536: 1531: 1526: 1521: 1516: 1511: 1506: 1501: 1495: 1493: 1489: 1488: 1481: 1479: 1477: 1476: 1471: 1466: 1461: 1456: 1451: 1446: 1444:Sandwich bread 1441: 1436: 1431: 1426: 1421: 1416: 1411: 1405: 1403: 1397: 1396: 1389: 1388: 1381: 1374: 1366: 1360: 1359: 1345: 1344:External links 1342: 1341: 1340: 1313: 1310: 1308: 1307: 1256: 1227:(5): 774–790. 1207: 1195: 1159: 1152: 1126: 1096: 1070: 1043: 1037:978-1784724474 1036: 1018: 967: 960: 942: 906: 875: 864:(15): 928–43. 848: 807: 769: 707: 678: 652: 645: 627: 617:Comptes Rendus 595: 593: 590: 588: 587: 578: 576:Caramelization 573: 568: 563: 557: 556: 555: 539: 536: 486: 485: 484: 483: 477: 463: 454: 444: 437:carbonyl group 431: 428: 396: 393: 377:Caramelization 290:dulce de leche 285:condensed milk 232: 229: 212: 209: 171: 142:carbonyl group 131:caramelization 26: 9: 6: 4: 3: 2: 1945: 1934: 1931: 1929: 1926: 1925: 1923: 1910: 1909: 1898: 1892: 1889: 1887: 1884: 1882: 1879: 1877: 1874: 1872: 1869: 1867: 1864: 1862: 1861:Indian breads 1859: 1857: 1856:French breads 1854: 1852: 1849: 1847: 1844: 1842: 1839: 1837: 1834: 1832: 1829: 1827: 1824: 1823: 1821: 1819:List articles 1817: 1811: 1808: 1806: 1803: 1801: 1798: 1796: 1793: 1791: 1788: 1786: 1783: 1782: 1780: 1776: 1770: 1767: 1765: 1762: 1760: 1757: 1755: 1752: 1750: 1747: 1745: 1742: 1740: 1739:Bread pudding 1737: 1735: 1732: 1730: 1727: 1725: 1722: 1721: 1719: 1715: 1709: 1706: 1704: 1701: 1699: 1696: 1694: 1691: 1689: 1686: 1684: 1681: 1679: 1676: 1674: 1671: 1669: 1666: 1664: 1661: 1659: 1656: 1654: 1651: 1649: 1646: 1644: 1641: 1639: 1636: 1635: 1633: 1629:Processes and 1627: 1621: 1618: 1616: 1613: 1611: 1608: 1606: 1603: 1601: 1598: 1596: 1593: 1591: 1588: 1586: 1585:Dough scraper 1583: 1581: 1578: 1576: 1575:Bread machine 1573: 1571: 1568: 1567: 1565: 1561: 1555: 1552: 1550: 1547: 1545: 1542: 1540: 1537: 1535: 1532: 1530: 1527: 1525: 1522: 1520: 1517: 1515: 1512: 1510: 1507: 1505: 1502: 1500: 1499:Baker's yeast 1497: 1496: 1494: 1490: 1485: 1475: 1472: 1470: 1467: 1465: 1462: 1460: 1457: 1455: 1452: 1450: 1447: 1445: 1442: 1440: 1437: 1435: 1432: 1430: 1427: 1425: 1422: 1420: 1417: 1415: 1412: 1410: 1407: 1406: 1404: 1402: 1398: 1394: 1387: 1382: 1380: 1375: 1373: 1368: 1367: 1364: 1357: 1352: 1348: 1347: 1338: 1334: 1330: 1329:9780801427725 1326: 1322: 1321: 1316: 1315: 1303: 1299: 1295: 1291: 1287: 1283: 1279: 1275: 1271: 1267: 1260: 1252: 1248: 1243: 1238: 1234: 1230: 1226: 1222: 1218: 1211: 1204: 1199: 1191: 1187: 1183: 1179: 1175: 1171: 1163: 1155: 1149: 1145: 1141: 1137: 1130: 1123: 1111: 1107: 1100: 1085: 1081: 1074: 1060: 1059: 1054: 1047: 1039: 1033: 1029: 1022: 1014: 1010: 1005: 1000: 995: 990: 986: 982: 978: 971: 963: 957: 953: 946: 938: 934: 930: 926: 922: 919: 918: 917:J. Org. Chem. 910: 902: 898: 895:(40): 58–60. 894: 890: 886: 879: 871: 867: 863: 859: 852: 837: 833: 829: 825: 818: 811: 803: 799: 795: 791: 787: 783: 776: 774: 765: 761: 756: 751: 747: 743: 738: 733: 729: 725: 721: 714: 712: 697:on 2022-01-27 696: 692: 688: 682: 667: 666:Tasting Table 663: 656: 648: 646:0-12-016430-2 642: 638: 631: 623: 620:(in French). 619: 618: 613: 609: 603: 601: 596: 585: 584: 579: 577: 574: 572: 569: 567: 564: 562: 559: 558: 553: 547: 542: 535: 533: 528: 526: 522: 518: 514: 512: 507: 505: 500: 498: 493: 491: 482: 478: 475: 471: 470:pyruvaldehyde 467: 464: 462: 458: 457: 455: 453: 449: 445: 442: 441:glycosylamine 438: 434: 433: 427: 425: 420: 418: 414: 410: 406: 402: 392: 390: 385: 383: 378: 374: 372: 368: 364: 355: 350: 342: 338: 336: 332: 331: 326: 322: 318: 314: 312: 308: 304: 300: 296: 292: 291: 286: 282: 278: 274: 270: 266: 262: 258: 254: 245: 237: 228: 226: 222: 221:John E. Hodge 218: 208: 206: 200: 198: 194: 190: 186: 182: 178: 158: 154: 150: 147: 143: 140:The reactive 138: 136: 132: 128: 124: 120: 116: 112: 108: 104: 100: 96: 91: 83: 82: 73: 49: 41: 37: 32: 19: 1906: 1891:Toast dishes 1886:Swiss breads 1881:Sweet breads 1871:Quick breads 1836:Bread dishes 1749:French toast 1734:Bread pakora 1724:Bread crumbs 1667: 1319: 1269: 1265: 1259: 1224: 1220: 1210: 1198: 1173: 1169: 1162: 1135: 1129: 1121: 1114:. Retrieved 1109: 1099: 1087:. Retrieved 1083: 1073: 1062:. Retrieved 1056: 1046: 1027: 1021: 984: 980: 970: 951: 945: 920: 915: 909: 892: 888: 878: 861: 857: 851: 839:. Retrieved 827: 823: 810: 785: 781: 727: 723: 699:. Retrieved 695:the original 690: 681: 669:. Retrieved 665: 655: 636: 630: 621: 615: 529: 515: 508: 501: 494: 487: 421: 398: 386: 375: 359: 328: 324: 315: 299:black garlic 288: 273:French fries 261:fried onions 250: 214: 201: 197:asparaginase 177:deprotonated 146:nucleophilic 139: 47: 45: 1841:Bread rolls 1790:Breadmaking 1688:Pre-slicing 1683:Pre-ferment 1605:Stand mixer 1590:Farinograph 1492:Ingredients 1474:Whole wheat 1469:White bread 1439:Salt-rising 1409:Brown bread 552:Food portal 481:melanoidins 452:ketosamines 395:Archaeology 367:dried fruit 269:baked goods 149:amino group 107:melanoidins 99:amino acids 1922:Categories 1764:Sandwiches 1729:Bread bowl 1631:techniques 1464:Unleavened 1449:Soda bread 1424:Multigrain 1203:Acrylamide 1064:2022-07-28 730:: 526762. 701:2022-01-27 671:6 November 592:References 525:asparagine 521:carcinogen 517:Acrylamide 474:hydrolytic 461:reductones 450:, forming 424:paleofeces 387:In making 354:acrylamide 193:acrylamide 189:carcinogen 105:to create 1663:Leavening 1638:Autolysis 1580:Bread pan 1563:Equipment 1454:Sourdough 1434:Rye bread 1419:Flatbread 987:(2): 56. 746:2314-5765 443:and water 401:peat bogs 382:pyrolysis 371:champagne 369:and when 363:myoglobin 303:chocolate 259:taste in 223:with the 215:In 1912, 185:flavoring 135:pyrolysis 1908:Category 1759:Stuffing 1744:Croutons 1698:Steaming 1678:Proofing 1658:Kneading 1459:Sprouted 1337:29909839 1294:12368844 1251:24875401 1190:15315399 1089:2 August 1013:30720722 937:16356012 841:15 March 802:12166997 764:26904661 624:: 66–68. 610:(1912). 538:See also 466:Diacetyl 413:Iron Age 409:bog body 253:browning 157:lye roll 97:between 1615:Toaster 1302:4360610 1274:Bibcode 1242:4164905 1116:16 June 1110:Science 1004:6406843 836:3526830 755:4745522 583:Wok hei 497:Amadori 405:tanning 211:History 191:called 127:recipes 93:) is a 86:French: 40:brioche 1785:Bakery 1643:Baking 1610:Warmer 1335:  1327:  1300:  1292:  1266:Nature 1249:  1239:  1188:  1150:  1034:  1011:  1001:  958:  935:  834:  800:  762:  752:  744:  643:  571:Baking 389:silage 325:pandan 309:, and 295:toffee 175:) are 111:Seared 36:breads 1778:Other 1769:Toast 1754:Rusks 1554:Water 1549:Sugar 1529:Flour 1429:Quick 1401:Types 1393:Bread 1298:S2CID 981:Foods 820:(PDF) 281:dried 257:umami 170:→ RNH 1851:Buns 1717:Uses 1648:Biga 1600:Peel 1595:Lame 1570:Oven 1544:Salt 1539:Milk 1519:Eggs 1504:Barm 1333:OCLC 1325:ISBN 1290:PMID 1247:PMID 1186:PMID 1148:ISBN 1118:2021 1091:2022 1032:ISBN 1009:PMID 956:ISBN 933:PMID 843:2024 832:PMID 798:PMID 760:PMID 742:ISSN 728:2015 673:2017 641:ISBN 435:The 283:and 277:malt 263:and 101:and 46:The 1524:Fat 1414:Bun 1282:doi 1270:419 1237:PMC 1229:doi 1178:doi 1140:doi 999:PMC 989:doi 925:doi 897:doi 866:doi 790:doi 750:PMC 732:doi 622:154 161:RNH 153:lye 80:YAR 78:my- 69:ɑːr 1924:: 1331:. 1296:. 1288:. 1280:. 1268:. 1245:. 1235:. 1225:66 1223:. 1219:. 1184:. 1174:52 1172:. 1146:. 1120:. 1108:. 1082:. 1055:. 1007:. 997:. 983:. 979:. 931:. 921:70 893:90 891:. 887:. 860:. 828:30 826:. 822:. 796:. 786:50 784:. 772:^ 758:. 748:. 740:. 726:. 722:. 710:^ 689:. 664:. 599:^ 513:. 468:, 426:. 419:. 313:. 305:, 301:, 297:, 293:, 287:, 84:; 60:aɪ 1385:e 1378:t 1371:v 1339:. 1304:. 1284:: 1276:: 1253:. 1231:: 1192:. 1180:: 1156:. 1142:: 1093:. 1067:. 1040:. 1015:. 991:: 985:8 964:. 939:. 927:: 903:. 899:: 872:. 868:: 862:1 845:. 804:. 792:: 766:. 734:: 704:. 675:. 649:. 356:. 327:( 172:2 167:3 164:+ 72:/ 66:j 63:ˈ 57:m 54:/ 50:( 20:)

Index

Maillard browning

breads
brioche
/mˈjɑːr/
my-YAR
[majaʁ]
chemical reaction
amino acids
reducing sugars
melanoidins
Seared
Louis Camille Maillard
protein synthesis
non-enzymatic browning
recipes
caramelization
pyrolysis
carbonyl group
nucleophilic
amino group
lye
lye roll
deprotonated
nucleophilicity
flavoring
carcinogen
acrylamide
asparaginase
Flavor scientists

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