709:; Division 5.1(a)1 and Class 5; Division 5.1(a)2. Division 5.1 "means a material that may, generally by yielding oxygen, cause or enhance the combustion of other materials." Division 5.(a)1 of the DOT code applies to solid oxidizers "if, when tested in accordance with the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter), its mean burning time is less than or equal to the burning time of a 3:7 potassium bromate/cellulose mixture." 5.1(a)2 of the DOT code applies to liquid oxidizers "if, when tested in accordance with the UN Manual of Tests and Criteria, it spontaneously ignites or its mean time for a pressure rise from 690 kPa to 2070 kPa gauge is less than the time of a 1:1 nitric acid (65 percent)/cellulose mixture."
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definition of an oxidizing agent is a substance that can cause or contribute to the combustion of other material. By this definition some materials that are classified as oxidizing agents by analytical chemists are not classified as oxidizing agents in a dangerous materials sense. An example is
111:, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are
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In more common usage, an oxidizing agent transfers oxygen atoms to a substrate. In this context, the oxidizing agent can be called an oxygenation reagent or oxygen-atom transfer (OAT) agent. Examples include
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134:(redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen, to a substrate.
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defines oxidizing agents specifically. There are two definitions for oxidizing agents governed under DOT regulations. These two are
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Extensive tabulations of ranking the electron accepting properties of various reagents (redox potentials) are available, see
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N. G. Connelly, W. E. Geiger (1996). "Chemical Redox Agents for
Organometallic Chemistry".
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Tl(I) thallous compounds, in organic lab scale synthesis
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Pages displaying short descriptions of redirect targets
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HAZMAT Class 5 Oxidizing agents and organic peroxides
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1290:(6th ed.), New York: Wiley-Interscience,
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173:Tetracyanoquinodimethane
32:for oxidizing chemicals.
492:Peroxymonosulfuric acid
371:Common oxidizing agents
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103:another substance. The
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1035:antimony pentafluoride
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1340:at Wikimedia Commons
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1044:hexafluoroantimonate
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630:Dinitrogen tetroxide
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1280:Smith, Michael B.;
1089:ruthenium tetroxide
1071:hexafluoroplatinate
929:Hexavalent chromium
555:chromate/dichromate
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1000:permanganate
888:nitric oxide
839:hypochlorite
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668:Lead dioxide
577:Permanganate
506:Hypochlorite
459:black powder
361:permanganate
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286:permanganate
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87:(called the
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922:ultramarine
882:nitric acid
723:Product(s)
553:(PCC), and
541:Hexavalent
518:perchlorate
439:Nitric acid
326:perchlorate
196:ferrocenium
1348:Categories
1208:References
1156:Combustion
1140:compounds
975:dichromate
764:ozonolysis
683:See also:
242:Magic blue
136:Combustion
119:, and the
1123:peroxides
1015:manganate
524:oxyanions
409:peroxides
365:manganate
109:electrons
89:reductant
30:pictogram
1284:(2007),
1267:11848774
1230:Archived
1226:Bitesize
1222:"Metals"
1150:See also
1136:Tl(III)
1121:, other
1025:(basic)
951:chromate
864:chlorate
789:chlorine
775:fluorine
741:O and CO
543:chromium
529:chlorine
514:chlorate
510:chlorite
434:halogens
426:chlorine
418:Fluorine
302:chromate
164:mnemonic
121:halogens
101:oxidizes
79:electron
57:oxidizer
1228:. BBC.
1138:thallic
803:bromine
762:O; see
707:Class 5
533:bromine
522:halogen
447:nitrate
161:OIL RIG
93:reducer
81:from a
75:accepts
53:oxidant
1294:
1265:
1046:or SbF
913:sulfur
817:iodine
733:oxygen
720:Agent
650:(NaBiO
537:iodine
535:, and
445:) and
377:Oxygen
330:oxides
304:), OsO
252:-4-Br)
113:oxygen
1369:Redox
979:Cr, H
868:Cl, H
843:Cl, H
754:ozone
583:(KMnO
466:(KClO
387:Ozone
95:, or
71:redox
63:, or
1292:ISBN
1263:PMID
837:ClO
701:The
689:The
670:(PbO
661:and
624:O),
453:(KNO
441:(HNO
359:,ie
200:Fe(C
198:ion
25:The
1255:doi
1093:OsO
1078:RuO
1066:PtF
1057:PtF
1039:SbF
1030:SbF
1021:MnO
1004:MnO
989:MnO
940:CrO
931:CrO
886:NO
877:HNO
853:ClO
821:I,
807:Br
793:Cl
636:/ N
632:(NO
561:(Na
428:(Cl
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363:to
349:MnO
347:to
337:MnO
314:ClO
290:CrO
288:),
274:MnO
47:An
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983:O
955:Cr
920:,
911:S
902:SO
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847:O
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784:Cl
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620:(N
565:Cr
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531:,
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512:,
508:,
498:SO
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476:(H
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399:(H
389:(O
379:(O
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569:O
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484:O
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480:S
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248:H
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232:H
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218:)
214:5
209:H
205:5
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