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Water-reactive substances

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All chemicals that react vigorously with water or liberate toxic gas when in contact with water are recognized for their hazardous nature in the "Approved Supply List", or the list of substances covered by the international legislation on major hazards many of which are commonly used in manufacturing
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The alkaline earth metals (Be, Mg, Ca, Sr, Ba, and Ra) are the second most reactive metals in the periodic table, and, like the Group 1 metals, have increasing reactivity with increasing numbers of energy levels. Beryllium (Be) is the only alkaline earth metal that does not react with water or
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Magnesium has a mild reaction with cold water. The reaction is short-lived because the magnesium hydroxide layer formed on the magnesium is almost insoluble in water and prevents further reaction.
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directly through reaction with water. The reaction of fluorine with water is especially hazardous, as an addition of fluorine gas to cold water will produce hydrofluoric acid, oxygen gas, and
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A metal reacting with cold water will produce a metal hydroxide and hydrogen gas. However, if a metal reacts with steam, like magnesium, metal oxide is produced as a result of
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are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. Some are highly reducing in nature. Notable examples include
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and sulfuric acid. The use of acid-resistant gloves and face shield is recommended for safe handling; fume hoods are another effective control of such substances.
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The hydroxides of calcium, strontium and barium are only slightly water-soluble but produce sufficient hydroxide ions to make the environment
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and hydrogen gas. Notably, radium hydroxide is the most soluble out of all alkaline earth hydroxide species.
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Raymond, Chang (2010). Chemistry (PDF) (tenth ed.). Americas, New York: McGraw-Hill. pp.897-898.
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reacts similarly to the rest of the alkaline earth metals (other than magnesium), forming
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Magnesium shows insignificant reaction with water, but burns vigorously with steam or
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fire diamond's white square, and in similar contexts, they are denoted as "
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REACTPOOL: A new model for accidental releases of water-reactive chemicals
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Brown, Paul L.; Matyskin, Artem V.; Ekberg, Christian (2022-06-27).
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is always produced when a metal reacts with cold water or steam.
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Water-reactive substances are classified as R2 under the
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Hazardous Waste Operations and Emergency Response Manual
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layer that lowers its reactivity at lower temperatures.
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Slow reaction with cold water, vigorous with hot water
971:"Reaction of Fluorine with Water and with Hydroxides" 53:. Please help to ensure that disputed statements are 877: 283:to produce white magnesium oxide and hydrogen gas: 1009:"Fluoride Salts, Soluble | CAMEO Chemicals | NOAA" 565: 1030: 949:"Reactions of Main Group Elements with Halogens" 634:"MODELLING RELEASES OF WATER REACTIVE CHEMICALS" 241:The Group 1 metals or alkali metals become more 918: 672: 217:The Group 1 metal (M) is oxidised to its metal 813:"Reactions of the Group 2 Elements with Water" 361: 862: 839:"Reactions of Main Group Elements with Water" 712:"Reactions of Main Group Elements with Water" 507:. Interactive Learning Paradigms Incorporated 863:Salutsky, M. L.; Kirby, H. W. (1964-12-01). 455:are so named due to their potential to form 919:Gallagher, RoseMarie; Ingram, Paul (2009). 631: 245:as their number of energy levels inceases. 787:"Reactions of Group 2 Elements with Water" 135:United States Department of Transportation 895: 221:, and water is reduced to hydrogen gas (H 85:Substances that readily reacts with water 73:Learn how and when to remove this message 975:Journal of the American Chemical Society 742:Michael Pilgaard's Table of the Elements 505:"The MSDS HyperGlossary: Metal Reactive" 487:. However, the reaction is fairly slow. 258: 248: 184: 170: 162: 118:Some water-reactive substances are also 49:Relevant discussion may be found on the 969:Cady, George Hamilton (February 1935). 596: 408:Less vigorous reaction with cold water 386:Very vigorous reaction with cold water 14: 1031: 836: 763:"The reaction of magnesium with steam" 709: 603:(1 ed.). Wiley. pp. 48–49. 968: 735: 632:Quinn, D. J.; Davies, P. A. (2003). 26: 24: 397:Vigorous reaction with cold water 198:Reaction of potassium (K) in water 25: 1065: 880:"The aqueous chemistry of radium" 837:Landas, Trevor (2 October 2013). 810: 710:Landas, Trevor (2 October 2013). 673:Kapias, T; Griffiths, RF (2001). 572:Environmental Health & Safety 426:If metals react with cold water, 181:Reaction of sodium (Na) and water 597:Gallant, Brian J. (2006-01-13). 331:, giving a general equation of: 152: 31: 1001: 962: 941: 912: 871: 856: 830: 804: 779: 755: 738:"Beryllium: Chemical Reactions" 921:Chemistry IGCSE Revision Guide 729: 703: 666: 625: 590: 559: 542: 518: 497: 375:Reactions with water or steam 263:Group 2: Alkaline earth metals 13: 1: 556:. Retrieved 27 February 2018. 490: 233:O(l) ⟶ 2 M(aq) + 2 OH(aq) + H 865:THE RADIOCHEMISTRY OF RADIUM 433:If metals react with steam, 7: 447: 362:Reactivity series of metals 10: 1070: 526:"Shipping dangerous goods" 252: 156: 133:and as Hazard 4.3 by the 89:Water-reactive substances 933:: CS1 maint: location ( 566:The University of Iowa. 475:, allowing them to form 324:splitting upon heating. 131:UN classification system 1013:cameochemicals.noaa.gov 897:10.1515/ract-2021-1141 264: 199: 182: 168: 167:Group 1: Alkali metals 1054:Alkaline earth metals 262: 255:Alkaline earth metals 249:Alkaline earth metals 197: 180: 166: 105:alkaline earth metals 843:Chemistry LibreTexts 791:Chemistry LibreTexts 716:Chemistry LibreTexts 568:"Reactive Chemicals" 471:higher than that of 469:reduction potentials 391:Second most reactive 42:factual accuracy is 987:10.1021/ja01305a006 736:Pilgaard, Michael. 654:on 26 February 2018 402:Third most reactive 369:Order of reactivity 609:10.1002/0470007257 291:O(g) ⟶ MgO(s) + H 265: 200: 183: 169: 884:Radiochimica Acta 618:978-0-471-68400-8 481:hydrochloric acid 477:hydrofluoric acid 423: 422: 195: 178: 83: 82: 75: 16:(Redirected from 1061: 1023: 1022: 1020: 1019: 1005: 999: 998: 966: 960: 959: 958:. 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Archived from 563: 557: 546: 540: 539: 537: 536: 522: 516: 515: 513: 512: 501: 366: 365: 356:radium hydroxide 322:metal hydroxides 196: 179: 78: 71: 67: 64: 58: 55:reliably sourced 35: 34: 27: 21: 1069: 1068: 1064: 1063: 1062: 1060: 1059: 1058: 1044:Water chemistry 1039:Chemical safety 1029: 1028: 1027: 1026: 1017: 1015: 1007: 1006: 1002: 967: 963: 947: 946: 942: 926: 925: 917: 913: 876: 872: 861: 857: 847: 845: 835: 831: 821: 819: 809: 805: 796: 794: 785: 784: 780: 771: 769: 761: 760: 756: 746: 744: 734: 730: 720: 718: 708: 704: 694: 692: 690: 679: 671: 667: 657: 655: 651: 636: 630: 626: 619: 595: 591: 581: 579: 578:on 3 March 2018 564: 560: 547: 543: 534: 532: 524: 523: 519: 510: 508: 503: 502: 498: 493: 450: 364: 346: 342: 338: 316: 312: 308: 299: 294: 290: 257: 251: 236: 232: 224: 185: 171: 161: 155: 124:organometallics 86: 79: 68: 62: 59: 48: 40:This article's 36: 32: 23: 22: 15: 12: 11: 5: 1067: 1057: 1056: 1051: 1046: 1041: 1025: 1024: 1000: 981:(2): 246–249. 961: 940: 911: 870: 855: 829: 803: 778: 754: 728: 702: 688: 665: 624: 617: 589: 558: 541: 517: 495: 494: 492: 489: 449: 446: 439: 438: 431: 421: 420: 417: 416:magnesium (Mg) 414: 413:Least reactive 410: 409: 406: 403: 399: 398: 395: 392: 388: 387: 384: 381: 377: 376: 373: 370: 363: 360: 349: 348: 344: 340: 336: 314: 310: 306: 297: 296: 292: 288: 253:Main article: 250: 247: 239: 238: 234: 230: 222: 208:periodic table 157:Main article: 154: 151: 84: 81: 80: 63:September 2024 39: 37: 30: 18:Water-reactive 9: 6: 4: 3: 2: 1066: 1055: 1052: 1050: 1049:Alkali metals 1047: 1045: 1042: 1040: 1037: 1036: 1034: 1014: 1010: 1004: 996: 992: 988: 984: 980: 976: 972: 965: 957: 956: 950: 944: 936: 930: 922: 915: 907: 903: 898: 893: 889: 885: 881: 874: 866: 859: 844: 840: 833: 818: 814: 807: 792: 788: 782: 768: 767:RSC Education 764: 758: 743: 739: 732: 717: 713: 706: 691: 689:0-7176-1995-8 685: 678: 677: 669: 650: 646: 642: 635: 628: 620: 614: 610: 606: 602: 601: 593: 577: 573: 569: 562: 555: 551: 545: 531: 527: 521: 506: 500: 496: 488: 486: 482: 478: 474: 470: 466: 462: 458: 454: 445: 443: 436: 432: 430:are produced. 429: 425: 424: 418: 415: 412: 411: 407: 404: 401: 400: 396: 393: 390: 389: 385: 383:potassium (K) 382: 380:Most reactive 379: 378: 374: 371: 368: 367: 359: 357: 353: 334: 333: 332: 330: 325: 323: 318: 309:O(l) ⟶ Mg(OH) 303: 300: 286: 285: 284: 282: 277: 275: 271: 261: 256: 246: 244: 228: 227: 226: 220: 215: 214:of hydrogen. 213: 209: 205: 204:alkali metals 165: 160: 159:Alkali metals 153:Alkali metals 150: 146: 144: 140: 136: 132: 127: 125: 121: 116: 114: 110: 106: 102: 98: 94: 93:alkali metals 90: 77: 74: 66: 56: 52: 46: 45: 38: 29: 28: 19: 1016:. 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Retrieved 499: 451: 440: 405:calcium (Ca) 350: 339:O(l) ⟶ M(OH) 326: 319: 304: 301: 298: 278: 266: 240: 229:2 M(s) + 2 H 216: 212:displacement 201: 147: 142: 128: 117: 88: 87: 69: 60: 41: 848:16 February 822:16 February 747:16 February 695:25 February 658:25 February 437:are formed. 394:sodium (Na) 281:water vapor 149:processes. 1033:Categories 1018:2024-02-05 955:LibreTexts 953:Chemistry 797:2023-09-08 772:2024-05-11 721:9 February 554:0077274318 535:2024-09-25 511:2007-05-10 491:References 428:hydroxides 335:M(s) + 2 H 305:Mg(s) + 2H 120:pyrophoric 995:0002-7863 929:cite book 906:0033-8230 817:ChemGuide 682:. Crown. 343:(aq) + H 287:Mg(s) + H 109:magnesium 51:talk page 465:chlorine 461:fluorine 453:Halogens 448:Halogens 442:Hydrogen 243:reactive 139:NFPA 704 137:. In an 111:through 99:through 44:disputed 582:2 March 313:(s) + H 122:, like 101:caesium 97:lithium 993:  904:  686:  615:  552:  530:GOV.UK 473:oxygen 435:oxides 352:Radium 113:barium 103:, and 680:(PDF) 652:(PDF) 637:(PDF) 485:ozone 467:have 457:salts 372:Metal 329:basic 274:oxide 270:steam 991:ISSN 935:link 902:ISSN 850:2018 824:2018 749:2018 723:2017 697:2018 684:ISBN 660:2018 613:ISBN 584:2018 550:ISBN 479:and 463:and 317:(g) 237:(g) 219:ions 202:The 983:doi 892:doi 888:110 645:149 605:doi 347:(g) 295:(g) 1035:: 1011:. 989:. 979:57 977:. 973:. 951:. 931:}} 927:{{ 900:. 886:. 882:. 841:. 815:. 789:. 765:. 740:. 714:. 643:. 639:. 611:. 570:. 528:. 115:. 107:, 95:, 1021:. 997:. 985:: 937:) 908:. 894:: 852:. 826:. 800:. 775:. 751:. 725:. 699:. 662:. 621:. 607:: 586:. 538:. 514:. 345:2 341:2 337:2 315:2 311:2 307:2 293:2 289:2 235:2 231:2 223:2 143:W 76:) 70:( 65:) 61:( 57:. 47:. 20:)

Index

Water-reactive
disputed
talk page
reliably sourced
Learn how and when to remove this message
alkali metals
lithium
caesium
alkaline earth metals
magnesium
barium
pyrophoric
organometallics
UN classification system
United States Department of Transportation
NFPA 704
Alkali metals

alkali metals
periodic table
displacement
ions
reactive
Alkaline earth metals

steam
oxide
water vapor
metal hydroxides
basic

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