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Zinc refining

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vapor impurities. In order to remove the lead 2-3% of the vapor is condensed, which draws the majority of the lead out of the vapor; down to the point where it is only 0.003% of the total contents. Finally the vapor is pumped into the cadmium column where it is cooled to an intermediate temperature
68:. Therefore, in the first column the zinc is heated above its boiling point and allowed to rise to a condenser. The iron and aluminium impurities sink to the bottom in the form of a solid or liquid. There are still 77:
below the boiling point zinc, but still above the boiling point of cadmium (767 °C (1,413 °F)). The zinc leaves out the bottom as a refined liquid, while the cadmium leaves out the top as vapor.
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The process take advantage of the relatively low boiling point of zinc (907 °C (1,665 °F)) as compared to the impurities being removed in the first "column":
27:(SHG) zinc, which is at least 99.995% pure. This process is not usually required when smelting of zinc is done through 144: 163: 54: 45:, a slow distortion and cracking of zinc die castings caused by impurities precipitating out. 111: 8: 38:
There are various refining methods, but the refluxing process is the most commonly used.
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Zinc Handbook: Properties, Processing, and Use in Design
41:High purity zinc is required industrially to avoid 31:processes, but is needed when zinc is produced by 155: 112:"London Metal Exchange: LME Zinc Physical" 35:processes, because it is only 98.5% pure. 156: 132: 48: 13: 14: 180: 57:invented this process in 1930. 104: 1: 139:, CRC Press, pp. 21–22, 97: 19:is the process of purifying 7: 80: 10: 185: 126: 164:Metallurgical processes 55:New Jersey Zinc Company 133:Porter, Frank (1991), 25:special high grade 49:Refluxing process 33:pyrometallurgical 176: 149: 120: 119: 108: 184: 183: 179: 178: 177: 175: 174: 173: 154: 153: 147: 129: 124: 123: 110: 109: 105: 100: 83: 51: 12: 11: 5: 182: 172: 171: 166: 152: 151: 145: 128: 125: 122: 121: 102: 101: 99: 96: 95: 94: 89: 82: 79: 50: 47: 9: 6: 4: 3: 2: 181: 170: 167: 165: 162: 161: 159: 148: 146:0-8247-8340-9 142: 138: 137: 131: 130: 117: 113: 107: 103: 93: 90: 88: 87:Zinc smelting 85: 84: 78: 75: 71: 67: 63: 58: 56: 46: 44: 39: 36: 34: 30: 26: 22: 18: 17:Zinc refining 135: 115: 106: 59: 52: 40: 37: 29:electrolysis 24: 16: 15: 116:www.lme.com 158:Categories 98:References 66:aluminium 43:zinc pest 81:See also 127:Sources 74:cadmium 143:  92:ZAMAK 169:Zinc 141:ISBN 72:and 70:lead 64:and 62:iron 53:The 21:zinc 23:to 160:: 114:. 150:. 118:.

Index

zinc
electrolysis
pyrometallurgical
zinc pest
New Jersey Zinc Company
iron
aluminium
lead
cadmium
Zinc smelting
ZAMAK
"London Metal Exchange: LME Zinc Physical"
Zinc Handbook: Properties, Processing, and Use in Design
ISBN
0-8247-8340-9
Categories
Metallurgical processes
Zinc

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