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Hypergolic propellant

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183: 31: 2528: 382:(and optional hypergolic boosters on the Ariane 3 and 4) have been retired and replaced with the Ariane 5, which uses a first stage fueled by liquid hydrogen and liquid oxygen. The Titan II, III and IV, with their hypergolic first and second stages, have also been retired for the Atlas V (RP-1/oxygen) and Delta IV (hydrogen/oxygen). Hypergolic propellants are still used in upper stages, when multiple burn-coast periods are required, and in 395: 437:
As hypergolic rockets do not need an ignition system, they can fire any number of times by simply opening and closing the propellant valves until the propellants are exhausted and are therefore uniquely suited for spacecraft maneuvering and well suited, though not uniquely so, as upper stages of such
79:. The main advantages of hypergolic propellants are that they can be stored as liquids at room temperature and that engines which are powered by them are easy to ignite reliably and repeatedly. Common hypergolic propellants are difficult to handle due to their extreme 266:
as oxidizer. The hypergolic rocket motor had the advantage of fast climb and quick-hitting tactics at the cost of being very volatile and capable of exploding with any degree of inattention. Other proposed combat rocket fighters like the
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has so far limited their practical use to space launch vehicles where they need to be stored only briefly. As the largest issue with the usage of cryogenic propellants in interplanetary space is boil-off, which is largely dependent on
430:. The propellants in turn flow through control valves into the combustion chamber; there, their instant contact ignition prevents a mixture of unreacted propellants from accumulating and then igniting in a potentially catastrophic 845:
are not hypergolic, but concentrated hydrogen peroxide (referred to as high-test peroxide or HTP) run over a catalyst produces free oxygen and steam at over 700 °C (1,300 °F) which is hypergolic with
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of traditional hypergolics necessitate expensive safety precautions. Failure to follow adequate safety procedures with an exceptionally dangerous UDMH-nitric acid propellant mixture nicknamed
328:. But the difficulties of such corrosive and toxic materials, including injury-causing leaks and the explosion of a Titan-II in its silo, led to their near universal replacement with 1589: 414:
Hypergolically-fueled rocket engines are usually simple and reliable because they need no ignition system. Although larger hypergolic engines in some launch vehicles use
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vertical launch expendable fighter was ever flight-tested with the Walter rocket propulsion system as its primary sustaining thrust system for military-purpose aircraft.
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substances, which ignite spontaneously in the presence of air, are also sometimes used as rocket fuels themselves or to ignite other fuels. For example a mixture of
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which required external ignition, and lithergols were solid/liquid hybrids. Hypergolic propellants (or at least hypergolic ignition) were far less prone to
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rocket engine. This propellant combination would have yielded a significant increase in performance, but was ultimately given up due to toxicity concerns.
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like liquid oxygen in a missile that had to be kept launch ready for months or years at a time led to a switch to hypergolic propellants in the U.S.
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The trend among Western space launch agencies is away from large hypergolic rocket engines and toward hydrogen/oxygen engines or methane/oxygen and
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than electric or pyrotechnic ignition. The "hypergole" terminology was coined by Dr. Wolfgang Nöggerath, at the Technical University of
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fuel offers extremely high performance, yet its density only warrants its usage in the largest of rocket stages, while mixtures of
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of 80–83%. He was probably the first to discover this phenomenon, and set to work developing a fuel. Prof. Otto Lutz assisted the
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In contemporary usage, the terms "hypergol" and "hypergolic propellant" usually mean the most common such propellant combination:
1603: 371: 823:(toxic but stable), abandoned due to lack of reliable ignition. No engine with this combination ever went into mass production. 1269: 1216: 1165: 171:
and PBY bombers, but the project was disliked because of the toxic properties of both fuel and oxidizer, as well as the high
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Peenemünde West: Die Erprobungsstelle der Luftwaffe für geheime Fernlenkwaffen und deren Entwicklungsgeschichte
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Peenemünde West: The Luftwaffe's test center for secret guided missiles and the history of their development
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worked on aniline/nitric acid engines in the early 1940s, for small missiles and jet assisted take-off (
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Another advantage of hypergolic propellants is their high density compared to cryogenic propellants.
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Apollo 11 Mission Report - Performance of the Command and Service Module Reaction Control System
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of aniline. The second problem was eventually solved by the addition of small quantities of
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were meant to use the Walter 509 series of rocket motors, but besides the Me 163, only the
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Hypergolic propellants were discovered independently, for the second time, in the U.S. by
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Lutz, O. (1957). "BMW Developments". In Benecke, T. H.; Quick, A.W.; Schulz, W. (eds.).
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Command and control: nuclear weapons, the Damascus Accident, and the illusion of safety
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and Navy Annapolis researchers in 1940. They developed engines powered by aniline and
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History of German Guided Missiles Development (Guided Missiles Seminar. 1956. Munich)
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has a density of 1.14 g/ml, while on the other hand, hypergolic oxidizers such as
260:, a rocket motor which consumed methanol/hydrazine as fuel and high test peroxide 2125: 1929: 1895: 1736: 1469: 1327: 1206: 1189: 1040: 566: 550: 534: 502: 305: 156: 107: 316:. Although they are preferred in space launchers, the difficulties of storing a 30: 2458: 2393: 2094: 1934: 1726: 1032: 986: 978: 715: 699: 347:, employed hypergolic fuels in both the descent and ascent rocket engines. The 344: 325: 268: 230: 211: 172: 160: 152: 1386: 2546: 2468: 2388: 2243: 2212: 1992: 1982: 1977: 1900: 1890: 853: 707: 693: 674: 578: 570: 522: 506: 356: 313: 279: 186:
An early hypergolic-propellant rocket engine, the Walter 109-509A of 1942–45.
84: 61: 1310:"Fuel Propellants - Storable, and Hypergolic vs. Ignitable by Mike Schooley" 497:. They are suitable for use in spacecraft missions lasting many years. The 2473: 2432: 2405: 2164: 1960: 1955: 1604:"Project SPECTRA - Experimental evaluation of a Liquid storable propellant" 927: 865: 849: 769: 600:, for example, resulted in the deadliest rocketry accident in history, the 561:
Relative to their mass, traditional hypergolic propellants possess a lower
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A Summary of NASA and USAF Hypergolic Propellant Related Spills and Fires
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have a density at least ten times higher. This is of great importance in
526: 423: 257: 35: 1840: 2508: 1965: 1028: 909: 593: 498: 431: 317: 238: 167:). The project resulted in the successful assisted take off of several 574: 1559: 1117: 1105: 1016: 816: 729: 645: 538: 478: 415: 297: 95: 44: 39: 1358: 422:, is fed to the propellant tanks under pressure through a series of 1059: 1048: 990: 857: 842: 826: 685: 629: 589: 471: 459: 443: 439: 309: 195: 129: 80: 76: 1240:] (in German), Peene Münde West: Weltbildverlag, p. 220, 628:(NTO) – widely used in historical American rockets, including the 394: 2284: 1917: 1787:
Modern Engineering for Design of Liquid-Propellant Rocket Engines
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Ignition! An Informal History of Liquid Rocket Propellants
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Ignition! An Informal History of Liquid Rocket Propellants
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3rd International Hydrogen Peroxide Propulsion Conference
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Less-common or obsolete hypergolic propellants include:
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have a density of 1.55 g/ml and 1.45 g/ml respectively.
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The only rocket-powered fighter ever deployed was the
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World War II German rocket fighter aircraft, for its
359:(among others) used hypergolic propellants for their 868:derivatives (AK-2x group in the Soviet Union) e.g. 617:Common hypergolic propellant combinations include: 71:The two propellant components usually consist of a 1104:Melof, Brian M.; Grubelich, Mark C. (2000-11-15). 1674:"European space-rocket liquid-propellant engines" 1500:. Archived from the original on February 2, 2013. 1472:Development of the Shuttle, 1972–1981 - Volume 2. 2544: 221:or oil, later influenced by the chemical suffix 967:) presents the same hazards, but offers higher 938:Upper Stages, Isayev-built maneuvering engines. 1103: 336:and then in land-based U.S. and Soviet ICBMs. 1856: 194:, rocket propellants were broadly classed as 68:when they come into contact with each other. 565:than cryogenic propellant combinations like 1801:History of Liquid Propellant Rocket Engines 1518: 1208:History of Liquid Propellant Rocket Engines 942: 128:which contained 30% hydrazine hydrate, 57% 1863: 1849: 1498:"Space Launch Report: Ariane 5 Data Sheet" 1143: 1141: 1139: 1137: 1135: 1133: 1131: 1129: 1127: 752: 607: 38:due to the hazards of the hypergolic fuel 1870: 1259: 993:, was studied by Soviet Rocket Scientist 898:(methanol, hydrazine, water, catalyst) – 2275:Atmosphere-breathing electric propulsion 1348: 514:of spacecraft, for larger craft such as 393: 181: 29: 1124: 916:(flown in French Diamant A first-stage) 14: 2545: 1789:, Huzel & Huang, pub. AIAA, 1992. 1204: 1181: 1015:– A sightly less toxic alternative to 959:is known to burn concrete and gravel. 190:In Germany from the mid-1930s through 1844: 1752: 1413:from the original on 15 November 2014 1231: 1198: 1147: 1023: 334:submarine-launched ballistic missiles 324:and in most Soviet ICBMs such as the 274:and reconnaissance aircraft like the 1592:from the original on 7 January 2022. 1467: 1342: 1187: 1264:. New York, NY: The Penguin Press. 768:(unstable, explosive), used in the 398:Hypergolic propellant tanks of the 378:1 through 4, with their hypergolic 24: 2180:Field-emission electric propulsion 1782:from the original on 10 July 2022. 1720: 1680:from the original on 23 July 2021. 1328:"PROPERTIES OF ROCKET PROPELLANTS" 1316:from the original on 24 July 2021. 1177:from the original on 10 July 2022. 477:The most common hypergolic fuels, 389: 351:used the same combination for the 25: 2569: 2254:Microwave electrothermal thruster 1816: 1716:from the original on 1 July 2022. 1698:from the original on 12 May 2022. 1476:. Smithsonian Institution Press. 1338:from the original on 26 May 2022. 668:Apollo command and service module 2526: 894:(stabilized >80% peroxide) + 556: 1702: 1684: 1666: 1642: 1620: 1596: 1578: 1547: 1490: 1461: 1435: 1417: 1406:The Nedelin Catastrophe, Part 1 1397: 1380: 1365: 1320: 722:Unsymmetrical dimethylhydrazine 487:unsymmetrical dimethylhydrazine 2384:Pulsed nuclear thermal rocket‎ 2280:High Power Electric Propulsion 1586:"WAC Corporal Sounding Rocket" 1302: 1278: 1253: 1225: 1097: 1071: 997:for usage in combination with 13: 1: 2239:Helicon double-layer thruster 2208:Electrodeless plasma thruster 2203:Magnetoplasmadynamic thruster 1803:, G. Sutton, pub. AIAA 2005. 1086: 409: 42:, here being loaded onto the 1829:The Periodic Table of Videos 1563:. 2014-03-23. Archived from 1532:. 2007-12-10. Archived from 1160:. Rutgers University Press. 372:advantages and disadvantages 370:/oxygen engines for various 7: 1468:T.A., Heppenheimer (2002). 781:(dust-sensitive, explosive) 728:(NTO) – frequently used by 712:SpaceX Merlin Engine Family 495:storable liquid propellants 355:. Those spacecraft and the 332:boosters, first in Western 233:, while non-hypergols were 34:The attendant wears a full 10: 2574: 1388:"Toxic Propellant Hazards" 1051:rocket and is used in the 1009:Tetramethylethylenediamine 860:) typically oxidized with 518:this is less of an issue. 400:Orbital Maneuvering System 101: 27:Type of rocket engine fuel 2524: 2441: 2420: 2364: 2311: 2302: 2267: 2221: 2198:Pulsed inductive thruster 2190: 2152: 2143: 2113: 2082: 2039: 2013: 2006: 1943: 1878: 1555:"ISRO tests Vikas engine" 1510:: CS1 maint: unfit URL ( 1079:Oxford English Dictionary 612: 353:Service Propulsion System 2372:Nuclear pulse propulsion 2131:Electric-pump-fed engine 2031:Hybrid-propellant rocket 2021:Liquid-propellant rocket 1834:University of Nottingham 1349:Linstrom, Peter (2021). 1260:Schlosser, Eric (2013). 1065: 943:Proposed, remain unflown 811:white fuming nitric acid 361:reaction control systems 122:with the development of 2428:Beam-powered propulsion 2401:Fission-fragment rocket 2356:Nuclear photonic rocket 2324:Nuclear electric rocket 2090:Staged combustion cycle 2026:Solid-propellant rocket 1628:"Nitric acid/Hydrazine" 753:Less common or obsolete 608:Hypergolic combinations 474:can also be restarted. 438:space launchers as the 380:first and second stages 2479:Non-rocket spacelaunch 2329:Nuclear thermal rocket 2229:Pulsed plasma thruster 1351:NIST Chemistry WebBook 1205:Sutton, G. P. (2006). 961:Chlorine pentafluoride 797:Copenhagen Suborbitals 793:red fuming nitric acid 734:Proton (rocket family) 692:thrusters used by the 406: 187: 149:red fuming nitric acid 60:combination used in a 49: 2145:Electrical propulsion 1872:Spacecraft propulsion 1824:"Hypergolic Reaction" 1232:Botho, Stüwe (1998), 632:; all engines in the 397: 384:launch escape systems 292:, such as the Soviet 185: 54:hypergolic propellant 33: 2377:Antimatter-catalyzed 2175:Hall-effect thruster 1988:Solar thermal rocket 1650:"High Test Peroxide" 1425:"ROCKET PROPELLANTS" 1019:and its derivatives. 957:Chlorine trifluoride 949:Chlorine trifluoride 900:Messerschmitt Me 163 852:(TG-02, approx. 50% 640:is a mixture of 50% 250:Messerschmitt Me 163 210:is a combination of 114:was hypergolic with 92:dinitrogen tetroxide 66:spontaneously ignite 2319:Direct Fusion Drive 2234:Vacuum arc thruster 2121:Pressure-fed engine 2100:Gas-generator cycle 2007:Chemical propulsion 1944:Physical propulsion 1616:on 4 November 2013. 1409:, 28 October 2014, 660:Monomethylhydrazine 634:Apollo Lunar Module 602:Nedelin catastrophe 483:monomethylhydrazine 341:Apollo Lunar Module 217:or work, and Latin 64:, whose components 2533:Spaceflight portal 2499:Reactionless drive 2464:Aerogravity assist 2304:Nuclear propulsion 1735:2009-04-30 at the 1710:"Nitric Acid/UDMH" 1536:on January 4, 2011 1024:Related technology 999:nitrogen tetroxide 983:nitrogen tetroxide 831:high-test peroxide 726:nitrogen tetroxide 664:nitrogen tetroxide 626:nitrogen tetroxide 531:nitrogen tetroxide 491:nitrogen tetroxide 407: 290:ballistic missiles 256:. The Komet had a 229:. Monergols were 188: 116:high-test peroxide 50: 2558:Soviet inventions 2540: 2539: 2494:Atmospheric entry 2449:Orbital mechanics 2416: 2415: 2298: 2297: 2249:Resistojet rocket 2139: 2138: 2114:Intake mechanisms 2047:Liquid propellant 1951:Cold gas thruster 1630:. Astronautix.com 1271:978-1-59420-227-8 1218:978-1-56347-649-5 1167:978-0-8135-0725-5 1037:triethylaluminium 864:or its anhydrous 839:hydrogen peroxide 779:hydrogen peroxide 732:, such as in the 704:triethylaluminium 644:and 50% straight 402:of Space Shuttle 349:Apollo spacecraft 134:hydrogen peroxide 112:hydrazine hydrate 58:rocket propellant 16:(Redirected from 2565: 2530: 2514:Alcubierre drive 2504:Field propulsion 2454:Orbital maneuver 2442:Related concepts 2309: 2308: 2160:Colloid thruster 2150: 2149: 2011: 2010: 1913:Specific impulse 1865: 1858: 1851: 1842: 1841: 1837: 1783: 1781: 1764: 1740: 1724: 1718: 1717: 1706: 1700: 1699: 1688: 1682: 1681: 1670: 1664: 1663: 1661: 1659: 1654: 1646: 1640: 1639: 1637: 1635: 1624: 1618: 1617: 1615: 1609:. 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Walter 104: 28: 23: 22: 15: 12: 11: 5: 2571: 2561: 2560: 2555: 2538: 2537: 2525: 2522: 2521: 2519: 2518: 2517: 2516: 2511: 2501: 2496: 2491: 2486: 2481: 2476: 2471: 2466: 2461: 2459:Gravity assist 2456: 2451: 2445: 2443: 2439: 2438: 2436: 2435: 2430: 2424: 2422: 2421:External power 2418: 2417: 2414: 2413: 2411: 2410: 2409: 2408: 2398: 2397: 2396: 2394:Bussard ramjet 2386: 2381: 2380: 2379: 2368: 2366: 2362: 2361: 2359: 2358: 2353: 2352: 2351: 2346: 2341: 2336: 2326: 2321: 2315: 2313: 2306: 2300: 2299: 2296: 2295: 2293: 2292: 2287: 2282: 2277: 2271: 2269: 2265: 2264: 2262: 2261: 2256: 2251: 2246: 2241: 2236: 2231: 2225: 2223: 2222:Electrothermal 2219: 2218: 2216: 2215: 2210: 2205: 2200: 2194: 2192: 2188: 2187: 2185: 2184: 2183: 2182: 2177: 2172: 2162: 2156: 2154: 2147: 2141: 2140: 2137: 2136: 2134: 2133: 2128: 2123: 2117: 2115: 2111: 2110: 2108: 2107: 2102: 2097: 2095:Expander cycle 2092: 2086: 2084: 2080: 2079: 2077: 2076: 2071: 2066: 2064:Monopropellant 2061: 2060: 2059: 2054: 2043: 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700:Triethylborane 697: 657: 653: 649: 614: 611: 609: 606: 558: 555: 411: 408: 391: 388: 343:, used in the 296:that launched 173:freezing point 161:Curtiss-Wright 153:Robert Goddard 120:Walter Company 103: 100: 26: 9: 6: 4: 3: 2: 2570: 2559: 2556: 2554: 2551: 2550: 2548: 2535: 2534: 2529: 2523: 2515: 2512: 2510: 2507: 2506: 2505: 2502: 2500: 2497: 2495: 2492: 2490: 2487: 2485: 2482: 2480: 2477: 2475: 2472: 2470: 2469:Oberth effect 2467: 2465: 2462: 2460: 2457: 2455: 2452: 2450: 2447: 2446: 2444: 2440: 2434: 2431: 2429: 2426: 2425: 2423: 2419: 2407: 2404: 2403: 2402: 2399: 2395: 2392: 2391: 2390: 2389:Fusion rocket 2387: 2385: 2382: 2378: 2375: 2374: 2373: 2370: 2369: 2367: 2363: 2357: 2354: 2350: 2347: 2345: 2342: 2340: 2337: 2335: 2332: 2331: 2330: 2327: 2325: 2322: 2320: 2317: 2316: 2314: 2312:Closed system 2310: 2307: 2305: 2301: 2291: 2288: 2286: 2283: 2281: 2278: 2276: 2273: 2272: 2270: 2266: 2260: 2257: 2255: 2252: 2250: 2247: 2245: 2244:Arcjet rocket 2242: 2240: 2237: 2235: 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Index

Hypergolic

hazmat suit
hydrazine
MESSENGER
rocket propellant
rocket engine
spontaneously ignite
fuel
oxidizer
toxicity
corrosiveness
dinitrogen tetroxide
hydrazine
Hellmuth Walter
hydrazine hydrate
high-test peroxide
Walter Company
C-Stoff
methanol
hydrogen peroxide
anilines
GALCIT
red fuming nitric acid
Robert Goddard
Reaction Motors
Curtiss-Wright
JATO
Martin PBM
freezing point

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