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Weston cell

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The temperature coefficient can be reduced by shifting to an unsaturated design, the predominant type today. However, an unsaturated cell's output decreases by some 80 microvolts per year, which is compensated by periodic calibration against a saturated cell.
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As shown in the illustration, the cell is set up in an H-shaped glass vessel with the cadmium amalgam in one leg and the pure mercury in the other. Electrical connections to the cadmium amalgam and the mercury are made by
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One of the great advantages of the Weston normal cell is its small change of electromotive force with change of temperature. At any temperature
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by W. E. Ayrton and T. Mather, published by Cassell and Company, London, 1911, pp 198–203
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of pure mercury over which a paste of mercurous sulfate and mercury is placed. The
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Reference cells must be applied in such a way that no current is drawn from them.
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by Walter J. Hamer, National Bureau of Standards Monograph 84, January 15, 1965.
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Drawing from Edward Weston's US Patent 494827 depicting the standard cell.
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This temperature formula was adopted by the London conference of 1908
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Standard Cells, Their Construction, Maintenance, and Characteristics
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The original design was a saturated cadmium cell producing a
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in 1893, it was adopted as the International Standard for
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Introduction to instrumentation and measurements 2nd ed
200:reference and had the advantage of having a lower 16:Wet chemical cell that produces a precise voltage 920: 135:wires fused through the lower ends of the legs. 39:Standard cell, extracted from case. Made in USSR 441: 347:Circular of the National Bureau of Standards 448: 434: 455: 409:Standard Cells for E.M.F. Determinations 34: 26: 18: 921: 59:suitable as a laboratory standard for 429: 13: 184: 75:from 1911 until superseded by the 14: 945: 402: 516: 343:"Electric units and standards" 335: 314: 55:that produces a highly stable 1: 369: 307: 82: 7: 295: 10: 950: 77:Josephson voltage standard 855: 827: 649: 606:Metal–air electrochemical 525: 514: 463: 421:Special-purpose batteries 204:than the previously used 165:(s) + 2e → 2Hg(l) + 202:temperature coefficient 142:Cd(s) → Cd(aq) + 2e 908:Semipermeable membrane 697:Lithium–iron–phosphate 40: 32: 24: 779:Rechargeable alkaline 457:Electrochemical cells 376:Practical Electricity 302:List of battery types 38: 30: 22: 759:Nickel–metal hydride 49:Weston standard cell 769:Polysulfide–bromide 611:Nickel oxyhydroxide 503:Thermogalvanic cell 383:U.S. patent 494,827 320:Robert B. Northrop 532:(non-rechargeable) 476:Concentration cell 414:2011-08-07 at the 113:saturated solution 41: 33: 25: 934:Mercury (element) 916: 915: 125:mercurous sulfate 53:wet-chemical cell 941: 712:Lithium–titanate 657: 533: 520: 481:Electric battery 450: 443: 436: 427: 426: 385: 363: 362: 360: 358: 339: 333: 324:CRC Press, 2005 318: 283: 277: 276: 273: 263: 262: 259: 249: 248: 222: 218: 214: 199: 194: 176: 175: 174: 164: 163: 162: 147:Cathode reaction 949: 948: 944: 943: 942: 940: 939: 938: 919: 918: 917: 912: 851: 830: 823: 744:Nickel–hydrogen 702:Lithium–polymer 658: 655: 654: 645: 534: 531: 530: 521: 512: 459: 454: 416:Wayback Machine 405: 381: 372: 367: 366: 356: 354: 341: 340: 336: 319: 315: 310: 298: 281: 274: 271: 269: 267: 260: 257: 255: 253: 246: 244: 242: 239: 235: 234: 230: 227: 220: 216: 212: 192: 190: 187: 185:Characteristics 173: 170: 169: 168: 166: 161: 158: 157: 156: 154: 153: 117:cadmium sulfate 85: 17: 12: 11: 5: 947: 937: 936: 931: 914: 913: 911: 910: 905: 900: 895: 890: 885: 880: 875: 870: 865: 859: 857: 853: 852: 850: 849: 844: 839: 837:Atomic battery 833: 831: 828: 825: 824: 822: 821: 816: 811: 809:Vanadium redox 806: 801: 796: 791: 786: 784:Silver–cadmium 781: 776: 771: 766: 761: 756: 754:Nickel–lithium 751: 746: 741: 739:Nickel–cadmium 736: 731: 726: 721: 716: 715: 714: 709: 707:Lithium–sulfur 704: 699: 694: 684: 679: 678: 677: 667: 661: 659: 656:(rechargeable) 652:Secondary cell 650: 647: 646: 644: 643: 638: 633: 628: 623: 618: 613: 608: 603: 598: 593: 588: 583: 578: 576:Edison–Lalande 573: 568: 563: 558: 553: 548: 543: 537: 535: 526: 523: 522: 515: 513: 511: 510: 505: 500: 495: 494: 493: 491:Trough battery 488: 478: 473: 467: 465: 461: 460: 453: 452: 445: 438: 430: 424: 423: 418: 404: 403:External links 401: 400: 399: 391: 379: 371: 368: 365: 364: 334: 312: 311: 309: 306: 305: 304: 297: 294: 286: 285: 279: 265: 251: 240: 237: 232: 231: 228: 186: 183: 179: 178: 171: 159: 151: 148: 144: 143: 140: 139:Anode reaction 123:is a paste of 84: 81: 67:. Invented by 15: 9: 6: 4: 3: 2: 946: 935: 932: 930: 929:Battery types 927: 926: 924: 909: 906: 904: 901: 899: 896: 894: 891: 889: 886: 884: 881: 879: 876: 874: 871: 869: 866: 864: 861: 860: 858: 854: 848: 845: 843: 840: 838: 835: 834: 832: 826: 820: 817: 815: 812: 810: 807: 805: 802: 800: 799:Sodium–sulfur 797: 795: 792: 790: 787: 785: 782: 780: 777: 775: 774:Potassium ion 772: 770: 767: 765: 762: 760: 757: 755: 752: 750: 747: 745: 742: 740: 737: 735: 732: 730: 727: 725: 722: 720: 717: 713: 710: 708: 705: 703: 700: 698: 695: 693: 690: 689: 688: 685: 683: 680: 676: 673: 672: 671: 668: 666: 663: 662: 660: 653: 648: 642: 639: 637: 634: 632: 629: 627: 624: 622: 619: 617: 614: 612: 609: 607: 604: 602: 599: 597: 594: 592: 591:Lithium metal 589: 587: 584: 582: 579: 577: 574: 572: 569: 567: 564: 562: 559: 557: 554: 552: 549: 547: 546:Aluminium–air 544: 542: 539: 538: 536: 529: 524: 519: 509: 506: 504: 501: 499: 496: 492: 489: 487: 484: 483: 482: 479: 477: 474: 472: 471:Galvanic cell 469: 468: 466: 462: 458: 451: 446: 444: 439: 437: 432: 431: 428: 422: 419: 417: 413: 410: 407: 406: 397: 396: 392: 389: 384: 380: 377: 374: 373: 352: 348: 344: 338: 331: 330:0-8493-3773-9 327: 323: 317: 313: 303: 300: 299: 293: 289: 226: 225: 224: 209: 207: 203: 198: 182: 149: 146: 145: 141: 138: 137: 136: 134: 128: 126: 122: 118: 114: 110: 106: 102: 98: 94: 90: 80: 78: 74: 70: 69:Edward Weston 66: 62: 58: 54: 50: 46: 37: 29: 21: 814:Zinc–bromine 625: 621:Silver oxide 556:Chromic acid 528:Primary cell 508:Voltaic pile 486:Flow battery 393: 388:Voltaic cell 387: 375: 355:. Retrieved 350: 346: 337: 321: 316: 290: 287: 268:/°C − 20) + 254:/°C − 20) − 210: 188: 180: 129: 86: 48: 44: 42: 903:Salt bridge 888:Electrolyte 819:Zinc–cerium 804:Solid state 789:Silver–zinc 764:Nickel–zinc 749:Nickel–iron 724:Molten salt 692:Dual carbon 687:Lithium ion 682:Lithium–air 641:Zinc–carbon 616:Silicon–air 596:Lithium–air 121:depolarizer 109:electrolyte 61:calibration 45:Weston cell 31:Weston cell 923:Categories 856:Cell parts 847:Solar cell 829:Other cell 794:Sodium ion 665:Automotive 370:Literature 308:References 221:40 Â°C 206:Clark cell 119:, and the 65:voltmeters 893:Half-cell 883:Electrode 842:Fuel cell 719:Metal–air 670:Lead–acid 586:LeclanchĂ© 498:Fuel cell 282:/°C − 20) 217:0 Â°C 83:Chemistry 79:in 1990. 873:Catalyst 734:Nanowire 729:Nanopore 675:gel–VRLA 636:Zinc–air 541:Alkaline 412:Archived 296:See also 215:between 133:platinum 878:Cathode 631:Zamboni 601:Mercury 566:Daniell 357:12 July 332:page 14 105:cathode 103:with a 101:mercury 97:cadmium 93:amalgam 57:voltage 868:Binder 626:Weston 551:Bunsen 328:  195:  91:is an 863:Anode 581:Grove 561:Clark 464:Types 270:0.000 256:0.000 245:0.000 243:/V − 236:/V = 191:1.018 111:is a 99:with 89:anode 51:is a 898:Ions 359:2016 351:1916 326:ISBN 247:0406 219:and 177:(aq) 150:(Hg) 87:The 43:The 571:Dry 386:, " 272:000 258:000 193:638 115:of 95:of 73:EMF 63:of 47:or 925:: 349:. 345:. 275:01 261:95 241:20 223:, 208:. 167:SO 155:SO 127:. 449:e 442:t 435:v 390:" 361:. 284:. 280:t 278:( 266:t 264:( 252:t 250:( 238:E 233:t 229:E 213:t 197:V 172:4 160:4 152:2

Index

Woodcut line drawing of H-shaped cell in an enclosure with electrical terminals at the top.


wet-chemical cell
voltage
calibration
voltmeters
Edward Weston
EMF
Josephson voltage standard
anode
amalgam
cadmium
mercury
cathode
electrolyte
saturated solution
cadmium sulfate
depolarizer
mercurous sulfate
platinum
V
temperature coefficient
Clark cell
List of battery types
ISBN
0-8493-3773-9
"Electric units and standards"
U.S. patent 494,827
Standard Cells, Their Construction, Maintenance, and Characteristics

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