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Paleothermometer

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568:(many species with large leaves with smooth edges and drip tips) and temperate deciduous forests (smaller leaf size classes common, toothed edges common), and is often continuously variable between sites along climatic gradients, such as from hot to cold climates, or high to low precipitation. This variation between sites along environmental gradients reflects adaptive compromises by the species present to balance the need to capture light energy, manage heat gain and loss, while maximising the efficiency of gas exchange, 1587: 1575: 160: 36: 238:
occurs during changes between condensed and vapour phases: the vapour pressure of heavier isotopes is lower, so vapour contains relatively more of the lighter isotopes and when the vapour condenses the precipitation preferentially contains heavier isotopes. The difference from SMOW is expressed as
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is used combining 31 leaf characters, but leaf margin type represented a significant component of the relationship between physiognomic states and temperature. Using CLAMP, MAT is estimated with small standard errors (e.g. CCA ± 0.7–1.0 °C). Additional temperature parameters can be estimated
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is the number of species scored for leaf margin type for the individual fossil leaf flora. LMA calibrations have been derived for major world regions, including North America, Europe, South America, and Australia. Riparian and wetland environments have a slightly different regression equation,
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measurements provide an estimation of the temperature at which a carbonate formed. C-O paleothermometry does not require prior knowledge of the concentration of O in the water (which the δO method does). This allows the C-O paleothermometer to be applied to some samples, including freshwater
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as a trace element. Because the incorporation of Mg as an impurity in calcite is endothermic, more is incorporated into the growing crystal at higher temperatures. Therefore, a high Mg/Ca ratio implies a high temperature, although ecological factors may confound the signal. Mg has a long
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Greenwood, D.R. 2007. North American Eocene Leaves and Climates: From Wolfe and Dilcher to Burnham and Wilf. In: Jarzen, D., Retallack, G., Jarzen, S. & Manchester, S. (Eds.) Advances in Mesozoic and Cenozoic Paleobotany: studies in celebration of David L. Dilcher and Jack A. Wolfe.
619:≤ 1) in vegetation varies proportionately with mean annual temperature (MAT). Requires the fossil flora to be segregated into morphotypes (i.e. ‘species’), but does not require their identification. The original LMA regression equation was derived for East Asian forests, and is: 732: 529:
in the ocean, and so it is possible to largely ignore the effect of changes in seawater Mg/Ca on the signal. Mg/Ca ratios can sometimes underestimate seawater temperatures by way of the dissolution of foraminifer shells, which lowers Mg/Ca values.
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Bernasconi, Stefano M.; Schmid, Thomas W.; Grauel, Anna-Lena; Mutterlose, Joerg (June 2011). "Clumped-isotope geochemistry of carbonates: A new tool for the reconstruction of temperature and oxygen isotope composition of seawater".
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Strontium (Sr) incorporates in coral aragonite, and it is well established that the precise Sr/Ca ratio in the coral skeleton shows an inverse correlation with the seawater temperature during its biomineralization.
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is a methodology that provides an estimate of the ambient temperature at the time of formation of a natural material. Most paleothermometers are based on empirically-calibrated proxy relationships, such as the
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produced from natural carbonates, and by the scarcity of instruments with appropriate detector arrays and sensitivities. The study of these types of isotopic ordering reactions in nature is often called
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SUNDERLIN, D.; LOOPE, G.; PARKER, N. E.; WILLIAMS, C. J. (2011-06-01). "Paleoclimatic and Paleoecological Implications of a Paleocene-Eocene Fossil Leaf Assemblage, Chickaloon Formation, Alaska".
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carbonates and very old rocks, with less ambiguity than other isotope-based methods. The method is presently limited by the very low concentration of isotopologues of mass 47 or higher in CO
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De Villiers, S.; Shen, G. T.; Nelson, B. K (1994). "The Sr/Ca temperature relationship in coralline aragonite—influence of variability in (Sr/Ca) seawater and skeletal growth-parameters".
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using CLAMP, such as the coldest month mean temperature (CMMT) and the warmest month mean temperature (WMMT) which provide estimates for winter and summer mean conditions respectively.
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CLAMP is a multivariate approach largely based on a data set of primarily western hemisphere vegetation, subsequently added to with datasets from additional world regional vegetation.
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is the difference between ocean temperatures where the moisture evaporated and the place where the final precipitation occurred; since ocean temperatures are relatively stable the
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Ruiz-Hernandez, S.E.; Grau-Crespo, R.; Ruiz-Salvador, A.R.; De Leeuw, N.H. (2010). "Thermochemistry of strontium incorporation in aragonite from atomistic simulations".
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Wolfe, J.A. 1979. Temperature parameters of Humid to Mesic Forests of Eastern Asia and relation to forests of other regions of the Northern Hemisphere and Australasia.
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distribution of heavy isotopes. Lab experiments, quantum mechanical calculations, and natural samples (with known crystallization temperatures) all indicate that Δ
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approaches integrate multiple leaf characters and climatic parameters. Temperature has been estimated (to varying degrees of fidelity) using leaf physiognomy for
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Miller, I.M., Brandon, M.T. & Hickey, L.J. 2006. Using leaf margin analysis to estimate the Mid-Cretaceous (Albian) paleolatitude of the Baja BC block.
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Greenwood, D.R., Wilf, P., Wing, S.L. & Christophel, D.C. 2004. Paleotemperature estimates using leaf margin analysis: Is Australia different?
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Branson, Oscar; Redfern, Simon A.T.; Tyliszczak, Tolek; Sadekov, Aleksey; Langer, Gerald; Kimoto, Katsunori; Elderfield, Henry (1 December 2013).
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Traiser, C., Klotz, S., Uhl, D., & Mosbrugger, V. 2005. Environmental signals from leaves – A physiognomic analysis of European vegetation.
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There is a slight thermodynamic tendency for heavy isotopes to form bonds with each other, in excess of what would be expected from a
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of O to O, usually in foram tests or ice cores. High values mean low temperatures. Confounded by ice volume - more ice means higher
576:. Quantitative analyses of modern vegetation leaf physiognomy and climate responses along environmental gradients have been largely 832:), with the isotopic distribution becoming more randomized at higher temperature. Along with the closely related phenomenon of 100: 414:
value mostly reflects the temperature where precipitation occurs. Taking into account that the precipitation forms above the
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Katz, Amitai (June 1973). "The interaction of magnesium with calcite during crystal growth at 25–90°C and one atmosphere".
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Eiler JM (2007). ""Clumped-isotope" geochemistry – The study of naturally-occurring, multiply substituted isotopologues".
512:(Cuffey et al., 1995), implying that glacial-interglacial temperature changes were twice as large as previously believed. 953: 79: 1367:
Kowalski, E.A., 2002. Mean annual temperature estimation based on leaf morphology: a test from tropical South America.
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Wing, S.L. & Greenwood, D.R. 1993. Fossils and fossil climates: the case for equable Eocene continental interiors.
1472: 119: 53: 1030:; Rosenthal, Y.; Slowey, N. (2002). "Benthic foraminiferal Mg/Ca-paleothermometry: A revised core-top calibration". 816:
Certain plants prefer certain temperatures; if their pollen is found one can work out the approximate temperature.
17: 86: 1232: 1195: 1148: 1032: 992: 526: 727:{\displaystyle \sigma \lbrack {\text{LMA}}\rbrack =c{\sqrt {\frac {P_{\text{margin}}(1-P_{\text{margin}})}{r}}}} 1293:
often written as 'annual mean temperature'; the mean of the monthly mean daily air temperatures for a location.
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or random distribution of the same concentration of isotopes. The excess is greatest at low temperature (see
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Bailey, I.W. & Sinnott, E.W. 1916. The climatic distribution of certain kinds of angiosperm leaves.
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gas is analyzed with a mass spectrometer, to determine the abundances of isotopologues. The parameter Δ
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and prevalence of features such as drip tips (‘leaf or foliar physiognomy’) differs between
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Wilf, P. 1997. When are leaves good thermometers? A new case for Leaf Margin Analysis.
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Magnesium (Mg) is incorporated into the calcite shells (tests) of planktic and benthic
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Weber, J.N. (1973). "Incorporation of strontium into reef coral skeletal carbonate".
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Wolfe, J.A. 1993. A method of obtaining climatic parameters from leaf assemblages.
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The error of the estimate for LMA is expressed as the binomial sampling error:
573: 193: 156:, are able to provide, at least in theory, direct measurements of temperature. 1169: 1084: 1601: 1423: 1027: 841: 569: 235: 1105:
Casey, W. H.; Rock P. A.; Chung J. B.; Walling E. M.; McBeath M. K. (1996).
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Distributions of organic molecules in marine sediments reflect temperature.
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approach that is based on the observation that the proportion of woody
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variations in temperature and it was assumed that this corresponded to
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values for precipitation are always negative. The major influence on
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because they have proportionally fewer smooth-margined plants. It is
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which is empirically calibrated from measurements of temperature and
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Philosophical Transactions of the Royal Society of London B
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Encyclopedia of Paleoclimatology and Ancient Environments
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gas by reaction with concentrated phosphoric acid. The CO
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has shown that for glacial-interglacial variations, a =
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where c is the slope from the LMA regression equation,
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variations (Jouzel and Merlivat, 1984). More recently,
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Nearest living relative analogy / coexistence analysis
496:. The calibration was initially done on the basis of 378:{\displaystyle \delta {\ce {^{18}O}}=1000\times \left} 1563: 660: 427: 248: 1457:
Spicer, R.A., 2008. CLAMP. In: V. Gornitz (Editor),
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Lowenstein, Tim K.; Hönisch, Bärbel (21 July 2017).
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is the measured difference in concentration between
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leaf floras, principally using two main approaches:
60:. Unsourced material may be challenged and removed. 1069:"The Use of Mg/Ca as a Seawater Temperature Proxy" 799:CLAMP (Climate leaf analysis multivariate program) 726: 462: 377: 1369:Palaeogeography, Palaeoclimatology, Palaeoecology 1066: 949:"The coordination of Mg in foraminiferal calcite" 1599: 819: 919:List of periods and events in climate history 844:. Carbonate minerals like calcite contain CO 672: 664: 1304:United States Geological Survey Prof. Paper 166: 463:{\displaystyle \delta {\ce {^{18}O}}=aT+b} 1490: 1177: 1130: 974: 836:, this effect arises from differences in 120:Learn how and when to remove this message 1496: 876:is correlated to the inverse square of 608:species with smooth (i.e. non-toothed) 595: 14: 1600: 1282:Courier Forschungsinstitut Senckenberg 418:, we are left with a linear relation: 148:methods. Isotope methods, such as the 1343:Earth & Planetary Science Letters 1192: 989: 770: 651: 621: 58:adding citations to reliable sources 29: 1499:Earth and Planetary Science Letters 1461:. Springer, Dordrecht, pp. 156-158. 954:Earth and Planetary Science Letters 555: 24: 1073:The Paleontological Society Papers 848:groups that can be converted to CO 515: 210:O, with small amounts of HDO and H 158: 25: 1619: 834:equilibrium isotope fractionation 1585: 1573: 34: 1555:10.1016/j.apgeochem.2011.03.080 1525: 1464: 1451: 1446:U.S. Geological Survey Bulletin 1438: 1387: 1374: 1361: 1348: 1335: 1322: 1309: 1296: 1287: 1273: 1233:Geochimica et Cosmochimica Acta 1196:Geochimica et Cosmochimica Acta 1149:Geochimica et Cosmochimica Acta 1033:Geochimica et Cosmochimica Acta 993:Geochimica et Cosmochimica Acta 781:), standard error ± 2.0 °C 632:), standard error ± 2.0 °C 560:The characteristic leaf sizes, 45:needs additional citations for 1260: 1223: 1186: 1139: 1098: 1060: 1020: 983: 940: 892:"clumped-isotope" geochemistry 805:Canonical Correlation Analysis 714: 695: 218:(SMOW) the ratio of D to H is 13: 1: 1054:10.1016/S0016-7037(02)00941-9 934: 27:Study of ancient temperatures 1254:10.1016/0016-7037(94)90457-X 1217:10.1016/0016-7037(73)90015-X 1014:10.1016/0016-7037(73)90091-4 788: 537: 7: 904:Geologic temperature record 897: 759: 740: 639: 10: 1624: 1519:10.1016/j.epsl.2007.08.020 1416:10.2110/palo.2010.p10-077r 1268:American Journal of Botany 976:10.1016/j.epsl.2013.09.037 774:MAT = 2.223 +(36.3 × 625:MAT = 1.141 +(30.6 × 541: 389:and a similar formula for 180: 1170:10.1016/j.gca.2009.10.049 1085:10.1017/S1089332600002564 443: 348: 336: 306: 294: 264: 216:Standard Mean Ocean Water 909:Thermal history of Earth 438: 432: 343: 337: 331: 325: 301: 295: 289: 283: 259: 253: 167:Common paleothermometers 1511:2007E&PSL.262..309E 967:2013E&PSL.383..134B 820:C-O bonds in carbonates 206:Ocean water is mostly H 171: 914:Timeline of glaciation 728: 464: 379: 163: 154:clumped-isotope method 729: 542:Further information: 465: 380: 162: 1535:Applied Geochemistry 830:Van 't Hoff equation 658: 596:Leaf margin analysis 566:tropical rainforests 506:borehole thermometry 425: 246: 54:improve this article 1547:2011ApGC...26S.279B 1408:2011Palai..26..335S 1246:1994GeCoA..58..197D 1209:1973GeCoA..37.2173W 1162:2010GeCoA..74.1320R 1132:10.2475/ajs.296.1.1 1123:1996AmJS..296....1C 1046:2002GeCoA..66.3375L 1006:1973GeCoA..37.1563K 864:with a mass of 47 724: 460: 375: 164: 69:"Paleothermometer" 1040:(19): 3375–3387. 924:Radiative forcing 838:zero point energy 796: 795: 748: 747: 722: 721: 711: 692: 670: 647: 646: 439: 437: 436: 435: 360: 349: 344: 342: 341: 340: 332: 330: 329: 328: 307: 302: 300: 299: 298: 290: 288: 287: 286: 260: 258: 257: 256: 130: 129: 122: 104: 16:(Redirected from 1615: 1608:Paleoclimatology 1590: 1589: 1588: 1578: 1577: 1569: 1559: 1558: 1529: 1523: 1522: 1505:(3–4): 309–327. 1494: 1488: 1487: 1485: 1484: 1475:. Archived from 1468: 1462: 1455: 1449: 1442: 1436: 1435: 1391: 1385: 1378: 1372: 1365: 1359: 1352: 1346: 1339: 1333: 1326: 1320: 1313: 1307: 1300: 1294: 1291: 1285: 1277: 1271: 1264: 1258: 1257: 1227: 1221: 1220: 1203:(9): 2173–2190. 1190: 1184: 1183: 1181: 1156:(4): 1320–1328. 1143: 1137: 1136: 1134: 1102: 1096: 1095: 1093: 1091: 1064: 1058: 1057: 1024: 1018: 1017: 1000:(6): 1563–1586. 987: 981: 980: 978: 944: 929:Paleoclimatology 790: 771: 742: 733: 731: 730: 725: 723: 717: 713: 712: 709: 694: 693: 690: 683: 682: 671: 668: 652: 641: 622: 556:Leaf physiognomy 511: 491: 483: 476: 469: 467: 466: 461: 444: 433: 410: 403: 396: 384: 382: 381: 376: 374: 370: 363: 362: 361: 358: 355: 351: 350: 338: 326: 324: 316: 315: 309: 308: 296: 284: 282: 265: 254: 233: 231: 225: 223: 199: 185: 174: 134:paleothermometer 125: 118: 114: 111: 105: 103: 62: 38: 30: 21: 18:Paleothermometry 1623: 1622: 1618: 1617: 1616: 1614: 1613: 1612: 1598: 1597: 1596: 1586: 1584: 1572: 1564: 1562: 1530: 1526: 1495: 1491: 1482: 1480: 1471: 1469: 1465: 1456: 1452: 1443: 1439: 1392: 1388: 1384:19(2), 129-142. 1379: 1375: 1366: 1362: 1356:New Phytologist 1353: 1349: 1340: 1336: 1327: 1323: 1314: 1310: 1301: 1297: 1292: 1288: 1278: 1274: 1265: 1261: 1228: 1224: 1191: 1187: 1144: 1140: 1103: 1099: 1089: 1087: 1065: 1061: 1025: 1021: 988: 984: 945: 941: 937: 900: 888: 883: 875: 859: 855: 851: 847: 822: 814: 801: 780: 756: 708: 704: 689: 685: 684: 681: 667: 659: 656: 655: 631: 618: 598: 586:Late Cretaceous 558: 550: 540: 518: 516:Mg/Ca and Sr/Ca 509: 489: 481: 479: 474: 431: 426: 423: 422: 416:inversion layer 413: 408: 406: 401: 399: 394: 357: 356: 323: 322: 318: 317: 311: 310: 281: 280: 279: 275: 252: 247: 244: 243: 229: 227: 221: 219: 213: 209: 202: 197: 190: 188: 183: 179: 177: 172: 169: 146: 126: 115: 109: 106: 63: 61: 51: 39: 28: 23: 22: 15: 12: 11: 5: 1621: 1611: 1610: 1595: 1594: 1582: 1561: 1560: 1524: 1489: 1470:CLAMP online. 1463: 1450: 1437: 1402:(6): 335–345. 1386: 1373: 1360: 1347: 1334: 1321: 1308: 1295: 1286: 1284:258: 95 – 108. 1272: 1259: 1240:(1): 197–208. 1222: 1185: 1138: 1097: 1059: 1019: 982: 938: 936: 933: 932: 931: 926: 921: 916: 911: 906: 899: 896: 886: 881: 873: 857: 853: 849: 845: 821: 818: 813: 810: 800: 797: 794: 793: 784: 782: 778: 754: 746: 745: 736: 734: 720: 716: 707: 703: 700: 697: 688: 680: 677: 674: 666: 663: 645: 644: 635: 633: 629: 616: 597: 594: 574:photosynthesis 557: 554: 539: 536: 527:residence time 517: 514: 478: 471: 470: 459: 456: 453: 450: 447: 442: 430: 412: 405: 398: 387: 386: 373: 369: 366: 354: 347: 335: 321: 314: 305: 293: 278: 274: 271: 268: 263: 251: 211: 207: 201: 194:isotopic ratio 187: 181:Main article: 178: 176: 170: 168: 165: 144: 128: 127: 42: 40: 33: 26: 9: 6: 4: 3: 2: 1620: 1609: 1606: 1605: 1603: 1593: 1583: 1581: 1576: 1571: 1570: 1567: 1556: 1552: 1548: 1544: 1541:: S279-S280. 1540: 1536: 1528: 1520: 1516: 1512: 1508: 1504: 1500: 1493: 1479:on 2011-08-13 1478: 1474: 1467: 1460: 1454: 1448:, 2040, 73pp. 1447: 1441: 1433: 1429: 1425: 1421: 1417: 1413: 1409: 1405: 1401: 1397: 1390: 1383: 1377: 1371:188: 141-165. 1370: 1364: 1358:166: 465–484. 1357: 1351: 1344: 1338: 1331: 1325: 1319:341, 243-252. 1318: 1312: 1306:1106, 1 - 37. 1305: 1299: 1290: 1283: 1276: 1269: 1263: 1255: 1251: 1247: 1243: 1239: 1235: 1234: 1226: 1218: 1214: 1210: 1206: 1202: 1198: 1197: 1189: 1180: 1175: 1171: 1167: 1163: 1159: 1155: 1151: 1150: 1142: 1133: 1128: 1124: 1120: 1116: 1112: 1108: 1101: 1086: 1082: 1078: 1074: 1070: 1063: 1055: 1051: 1047: 1043: 1039: 1035: 1034: 1029: 1023: 1015: 1011: 1007: 1003: 999: 995: 994: 986: 977: 972: 968: 964: 960: 956: 955: 950: 943: 939: 930: 927: 925: 922: 920: 917: 915: 912: 910: 907: 905: 902: 901: 895: 893: 879: 871: 867: 863: 862:isotopologues 843: 842:isotopologues 839: 835: 831: 827: 817: 809: 806: 792: 785: 783: 777: 773: 772: 769: 766: 762: 761: 753: 744: 737: 735: 718: 705: 701: 698: 686: 678: 675: 661: 654: 653: 650: 643: 636: 634: 628: 624: 623: 620: 615: 611: 607: 603: 593: 591: 587: 583: 579: 575: 571: 570:transpiration 567: 563: 553: 549: 545: 535: 531: 528: 523: 513: 507: 503: 499: 495: 487: 457: 454: 451: 448: 445: 440: 428: 421: 420: 419: 417: 392: 371: 367: 364: 352: 345: 333: 319: 303: 291: 276: 272: 269: 266: 261: 249: 242: 241: 240: 237: 236:Fractionation 217: 204: 195: 189: 161: 157: 155: 151: 147: 140: 135: 124: 121: 113: 110:February 2008 102: 99: 95: 92: 88: 85: 81: 78: 74: 71: –  70: 66: 65:Find sources: 59: 55: 49: 48: 43:This article 41: 37: 32: 31: 19: 1592:Paleontology 1538: 1534: 1527: 1502: 1498: 1492: 1481:. Retrieved 1477:the original 1473:"CLAMP1.HTM" 1466: 1458: 1453: 1445: 1440: 1399: 1395: 1389: 1381: 1376: 1368: 1363: 1355: 1350: 1345:245: 95–114. 1342: 1337: 1330:Paleobiology 1329: 1324: 1316: 1311: 1303: 1298: 1289: 1281: 1275: 1267: 1262: 1237: 1231: 1225: 1200: 1194: 1188: 1153: 1147: 1141: 1114: 1110: 1100: 1088:. Retrieved 1076: 1072: 1062: 1037: 1031: 1022: 997: 991: 985: 958: 952: 942: 823: 815: 802: 786: 775: 764: 758: 757:as used in ( 751: 749: 738: 648: 637: 626: 613: 610:leaf margins 599: 582:multivariate 559: 551: 532: 522:foraminifera 519: 501: 497: 472: 388: 205: 191: 133: 131: 116: 107: 97: 90: 83: 76: 64: 52:Please help 47:verification 44: 1332:23, 373-90. 1270:3, 24 - 39. 1117:(1): 1–22. 961:: 134–141. 878:temperature 612:(0 ≤ 226:and O/O is 1483:2011-05-18 1111:Am. J. Sci 1079:: 85–100. 1028:Lear, C.H. 935:References 870:stochastic 826:stochastic 602:univariate 578:univariate 494:Antarctica 80:newspapers 1424:0883-1351 1179:1834/4103 702:− 662:σ 538:Alkenones 492:for East 486:Greenland 429:δ 365:− 273:× 250:δ 150:δO method 139:tree ring 1602:Category 1432:54015435 898:See also 880:. Thus Δ 789:1′ 590:Cenozoic 544:Alkenone 510:0.33‰/°C 502:temporal 490:0.76‰/°C 482:0.67‰/°C 203:values. 1580:Geology 1566:Portals 1543:Bibcode 1507:Bibcode 1404:Bibcode 1396:PALAIOS 1382:PALAIOS 1242:Bibcode 1205:Bibcode 1158:Bibcode 1119:Bibcode 1090:14 July 1042:Bibcode 1002:Bibcode 963:Bibcode 763:), and 498:spatial 480:as a = 214:O. 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Index

Paleothermometry

verification
improve this article
adding citations to reliable sources
"Paleothermometer"
news
newspapers
books
scholar
JSTOR
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tree ring
TEX86
δO method
clumped-isotope method

δO
isotopic ratio
Standard Mean Ocean Water
Fractionation
δD
inversion layer
Greenland
Antarctica
borehole thermometry
foraminifera
residence time
Alkenone
TEX86

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