371:. Acid-soluble stone materials such as the calcite in marble, limestone and travertine, as well as the internal cement that binds the resistant grains in sandstone, react with acidic solutions on contact, or on absorbing acid-forming gases in polluted air, such as oxides of sulfur or nitrogen. Acid erodes the stone, leaving dull marks on polished surfaces. In time it may cause deep pitting, eventually totally obliterating the forms of statues, memorials and other sculptures. Even mild household acids, including cola, wine, vinegar, lemon juice and milk, can damage vulnerable types of stone. The milder the acid, the longer it takes to etch calcite-based stone; stronger acids can cause irreparable damage in seconds.
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stone, but still can change the slip characteristics of the surface and do wear relatively quickly. Penetrating sealers often require the use of special cleaners which both clean and top up the repellent ingredient left on the stone surface. These sealers are often breathable to a certain degree, but do not penetrate deeply enough (generally less than 1mm) to be effective against salt attack, such as efflorescence and spalling.
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salt attack, such as efflorescence, spalling, picture framing and freeze-thaw spalling. Some silane stone sealers based on nanotechnology claim to be resistant to UV light and higher pH levels found in new masonry and pointing. A good depth of penetration is also essential for protection from weathering and traffic.
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Natural stone is used in kitchens, floors, walls, bathrooms, dining rooms, around swimming pools, building foyers, public areas and facades. Since ancient times, stone has been popular for building and decorative purposes. It has been valued for its strength, durability, and insulation properties. It
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The most penetrating sealers use siliconates, fluoro-polymers and siloxanes, which repel liquids. These sealers penetrate the surface of the stone enough to anchor the material to the surface. They are generally longer lasting than topical sealers and often do not substantially alter the look of the
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The longevity and usefulness of stone can be extended by sealing its surface effectively, so as to exclude harmful liquids and gases. The ancient Romans often used olive oil to seal their stone. Such treatment provides some protection by excluding water and other weathering agents, but it stains the
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in capillary gaps can cause surface spalling. For example, various magnesium and calcium salts in sea water expand considerably on drying by taking on water of crystallization. However, even sodium chloride, which does not include water of crystallization, can exert considerable expansive forces as
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or modified silanes. These are a type of penetrating sealer, which penetrate deeply into the material, impregnating it with molecules which bond to the capillary pores and repels water and / or oils from within the material. Some modified silane sealers impregnate deeply enough to protect against
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draws in liquids over time, along with any dissolved salts and other solutes. Very porous stone, such as sandstone absorb liquids relatively quickly, while denser igneous stones such as granite are significantly less porous; they absorb smaller volumes, and more slowly, especially when absorbing
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is the formation of a gritty deposit, commonly white, on the surface. Efflorescence is usually the result of mineral solutions in the capillary channels being drawn to the surface. If the water evaporates, the minerals remain as the so-called efflorescence. It also can be the result of chemical
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Topical sealers are generally made from polyurethanes, acrylics, or natural wax. These sealers may be effective at stopping stains but, being exposed on the surface of the material, they tend to wear out relatively quickly, especially on high-traffic areas of flooring. This type of sealer will
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can be cut, cleft, or sculpted to shape as required, and the variety of natural stone types, textures, and colors provide an exceptionally versatile range of building materials. The porosity and makeup of most stone does, however, leave it prone to certain types of damage if unsealed.
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reaction; if badly prepared cement-based mortar is applied to maintain the stone in position, free calcium hydroxide may leach out. In the open air the lime reacts with carbon dioxide to form water-insoluble calcium carbonate that might take the form of powdery efflorescence or
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significantly change the look and slip resistance of the surface, especially when it is wet. These sealers are not breathable i.e. do not allow the escape of water vapour and other gases, and are not effective against salt attack, such as efflorescence and
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made from ingredients such as egg white, natural resins and silica, which were clear, could be applied wet and harden to form a protective skin. Most such measures did not last long, and some proved harmful in the long run.
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is the most common form of damage. It is the result of oils or other liquids penetrating deeply into the capillary channels and depositing material that is effectively impossible to remove without destroying the
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is the application of a surface treatment to products constructed of natural stone to retard staining and corrosion. All bulk natural stone is riddled with interconnected
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occurs when water or grout moves into the edges of the stone to create an unsightly darkening or "frame" affect. Such harm is usually irreversible.
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Modern stone sealers are divided into 3 broad types: topical sealers, penetrating sealers, and impregnating sealers.
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occurs when salts dissolved in water are carried into the stone. The two commonest effects are
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channels that permit penetration by liquids and gases. This is true for
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results when water freezes in the surface pores. The general term is
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Europeans experimented with the use of topical varnishes and
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293:. These porous channels act like a sponge, and
493:Marble Institute of America pp. 225 Glossary
61:Learn how and when to remove these messages
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216:Learn how and when to remove this message
158:Learn how and when to remove this message
314:Gargoyle in Bavaria damaged by acid rain
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192:Please help
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85:verification
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413:renaissance
411:During the
369:Acid Attack
333:Salt Attack
527:Categories
481:References
306:Motivation
287:travertine
148:March 2008
118:newspapers
47:improve it
361:dripstone
302:liquids.
291:sandstone
283:limestone
251:capillary
53:talk page
543:Coatings
469:See also
439:spalling
417:sealants
387:Spalling
341:spalling
324:Staining
281:such as
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462:silanes
300:viscous
259:granite
132:scholar
327:stone.
289:, and
277:, and
271:marble
263:basalt
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139:JSTOR
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